Lithophile Elements Research Articles

LATE MESOZOIC RARE-METAL GRANITES, PEGMATITES, AND GREISENS OF MONGOLIA: AGE, MINERALOGY, GEOCHEMISTRY, ORE POTENTIAL, AND PETROGENESIS

Comparative analysis of the earlier obtained and new geological data, age, mineral, petrological, and geochemical compositions of plutons of calc-alkalic granitoids and rare-metal Li–F granites shows their evolution in a wide time interval during the formation of Mesozoic areas of granitoid magmatism. Mineralogical and geochemical analysis of the evolution of plutons of palingenetic calc-alkalic granitoids (Baga Hentiyn (MZ1) and Ikh Narotiin = Hiid (MZ2)) and intrusions of rare-metal Li–F granites of Central and Eastern Mongolia revealed their petrological and geochemical differences. The closure of the Mongol–Okhotsk Basin with the formation of large plutons of calc-alkaliс granitoids, obviously related to collisional processes, did not cause significant enrichment of the late granite phases with lithophile and ore elements. Within the peripheral zones of еру MZ1 and MZ2 magmatic areas, mineralization is often associated with Mongolian multiphase plutons and small intrusions of rare-metal Li–F granites. The rare-metal granites are characterized by a decrease in indicative K/Rb, Nb/Ta, and Zr/Hf values and a regular increase in F, Li, Rb, Cs, Sn, W, Be, Ta, and Nb contents during the evolution of Li–F magmas. Igneous and, particularly, metasomatic rocks in most intrusions of ore-bearing rare-metal Li–F granites are characterized by significant variations in Sn and W contents. At the magmatic stage, the pegmatoid varieties of amazonite–albite granites and pegmatites of the zonal Baga Gazriin (MZ1) and Barun Tsogto (MZ2) plutons are significantly enriched in both Sn and W. Maximum Sn and W enrichment has been established in greisenized granites and zoned greisen bodies (zwitters), which is due to the percolation of ore-bearing solutions into the upper horizons and the mineralization of ore elements in the late phases of intrusions and in metasomatites. The wide variations in the age (321–126 Ma) and trace element and isotope compositions of Mongolian rare-metal Li–F granites within various zones of large magmatic areas suggest the influence of mantle plume sources on the composition of rare-metal granitic magmas and on their ore potential in intermediate chambers in the continental crust.

Gold Mineralization at the Syenite-Hosted Anwangshan Gold Deposit, Western Qinling Orogen, Central China

The Anwangshan gold deposit is located in the northwestern part of the Fengtai Basin, Western Qinling Orogen (WQO). The gold ore is hosted within quartz syenite and its contact zone. The U–Pb weighted mean age of the quartz syenite is 231 ± 1.8 Ma. It is characterized by high potassium (K2O = 10.13%, K2O/Na2O > 1) and high magnesium (Mg# = 55.31 to 72.78) content, enriched in large ion lithophile elements (Th, U, and Ba) and light rare earth elements (LREE), with a typical “TNT” (Ti, Nb, and Ta) deficiency. The geochemical features and Hf isotope compositions (εHf(t) = −6.68 to +2.25) suggest that the quartz syenite would form from partial melting of an enriched lithospheric mantle under an extensional setting. Three generations of gold mineralization have been identified, including the quartz–sericite–pyrite (Py1) stage I, the quartz–pyrite (Py2)–polymetallic sulfide–early calcite stage II, and the epidote–late calcite stage III. In situ sulfur isotope analysis of pyrite shows that Py1 (δ34S = −1.1 to +3.8‰) possesses mantle sulfur characteristics. However, Py2 has totally different δ34S (+5.1 to +6.7‰), which lies between the typical orogenic gold deposits in the WQO (δ34S = +8 to +12‰) and mantle sulfur. This suggests a mixed source of metamorphosed sediments and magmatic sulfur during stage II gold mineralization. The fluid inclusions in auriferous quartz have three different types, including the liquid-rich phase type, pure (gas or liquid)-phase type, and daughter-minerals-bearing phase type. Multiple-stage fluid inclusions indicate that the ore fluids are medium-temperature (concentrated at 220 to 270 °C), medium-salinity (7.85 to 13.80% NaCleq) CO2–H2O–NaCl systems. The salinity is quite different from typical orogenic gold deposits in WQO and worldwide, and this is more likely to be a mixture of magmatic and metamorphic fluids as well. In summary, the quartz syenite should have not only a spatio-temporal but also a genetical relationship with the Anwangshan gold deposit. It could provide most of the gold and ore fluids at the first stage, with metamorphic fluids and/or gold joining in during the later stages.

Constraints of in-situ elemental compositions and U–Pb ages of cassiterite on the origin of the Cretaceous Gejiu and Dulong tin deposits, SW China: Implications for the linkage of tin belts in SE Asia

The western Yunnan tin belts in SW China and the southern Myanmar tin belt in SE Asia are traditionally thought to be part of the SE Asian tin metallogenic province. However, the tectonic setting of the Youjiang tin belt in SW China and its genetic relationship to the other tin belts are poorly documented. In this belt, the giant Gejiu and Dulong tin deposits are typical of skarn-type deposits and both contain contact and distal skarn orebodies. Tin ores of distal orebodies in these two deposits are composed of cassiterite, sulfide and calcite. In both deposits, most cassiterite grains from these ores are rich in Fe and W and depleted in Nb and Ta. They have 238U/206Pb ages between 81.4 and 84.1 Ma, similar to hosting granitic plutons. Two generations of cassiterite with distinctly different microtextures and trace elemental compositions can be recognized. The first generation (Cst-I) is compositionally and texturally homogeneous, but the second generation (Cst-II) displays distinctly oscillatory zoning. Cst-II contains Nb, W, and U lower, and Fe, Ta, Zr and chalcophile elements (Ga, Ge, In, and Sb) higher than Cst-I. These textural and compositional variations reflect the potential involvement of meteoric water in the magmatic-hydrothermal system. In this system, ore-forming fluids were evolved to more alkaline and oxidized to facilitate the precipitation of cassiterite. Our study indicates that these two deposits in the Youjiang tin belt have mineralization styles similar to those in the adjacent western Yunnan and southern Myanmar tin belts and all these tin belts belong to the SE Asian metallogenic provinces. A westward-younging trend of tin mineralization in these three belts can be explained by the rollback of the subducted Neo-Tethyan oceanic slab. This setting is different from the one related to the subduction of the Paleo-Pacific plate.

Geochemistry of Mafic Rocks From the Nagrota–Kathindi Section, Himachal Pradesh, Northwestern Himalaya: A Probable Example of Plume–Lithosphere Interaction

ABSTRACTThe Northwest Himalayan region has a record of several phases of mafic magmatic activity spanning from Precambrian to Cenozoic in a dynamic tectonic setting. Here, we studied detailed petrography and new whole‐rock geochemistry of mafic volcanic and dykes from the Nagrota–Kathindi Section (NKS), Himachal region of the NW Himalaya, to understand the petrogenesis and possible tectonic setting. Both rock types have comparable mineralogical compositions (clinopyroxene + plagioclase + actinolite‐tremolite + chlorite + iron oxides ± hornblende ± epidote ± quartz ± carbonates) overprinted by greenschist to lower amphibolite facies metamorphism. The mafic volcanic and dykes of NKS exhibit subalkaline basalts to basaltic andesites and a typical tholeiite compositional character. The chondrite‐normalized rare earth element pattern exhibits similar LREE‐enrichment and strong HREE‐fractionation, whereas primitive mantle‐normalized multi‐element patterns show pronounced LILE‐enrichment of Rb, Ba, Th, LREE, and HFSE depletion of Nb, K, P, and Ti. The Zr–Y–Nb–Th relationships indicate that both rock types were derived from the plume source, whereas low Nb/La (< 1), similar high large‐ion lithophile element concentrations, and pronounced negative Nb, Zr, P, and Ti anomalies suggest that components other than mantle plume must have been involved in the generation and evolution of both rock types, that is, most likely plume and subcontinental lithosphere mantle (SCLM) interaction. The genesis of parent magma for the NKS volcanic and dykes was derived by 4%–6% and 10%–20% partial melting from the spinel + garnet lherzolite stability field. The majority of the studied samples correspond to spinel + garnet peridotite melting on (Gd/Yb)N versus CaO/Al2O3 diagram, thereby corroborating residual garnet in the mantle restite. All the basalts and dykes from the NK section did erupt/intrude in an intracontinental rift setting based on geochemical discrimination. The key petro‐tectonic processes attributed to the formation of these rocks are as follows: (i) the melting of the ascending plume by adiabatic decompression; (ii) the partial melting of this plume–SCLM source in the melting regime, which produces basaltic magma with a tholeiitic composition; and (iii) the release of heat that provides the thermal condition for melting of SCLM and interaction between upwelling mantle plume and subduction metasomatized SCLM.

Petrogenesis and tectonic setting of granitic pegmatites in the Beishan orogenic Belt, Northwest China: Evidence from geology, geochronology and geochemistry

The Weiboshan (Li-, Cs- and Ta-enriched) LCT-type Nb–Ta deposit located in Ejin Banner, Inner Mongolia, represents a newly discovered pegmatite-type rare metal deposit of significant interest. In this paper, we describe the petrography and present new mineralogical and whole-rock geochemical data and zircon U–Pb ages of ore-related granitic pegmatites in this deposit. Pegmatite dikes can be divided into three distinct zones on the basis of their contents: the K-feldspar graphic granite pegmatite zone (Kf), microcline graphic granite pegmatite zone (Mic), and albite–muscovite granite pegmatite zone (Ab). The pegmatite dikes and associated mineralization formed during the Mesozoic. Granite pegmatites in various zones display distinctive geochemical features characterized by high silicon contents, substantial alkali enrichment, and relatively low iron, calcium, and magnesium levels. These pegmatites are classified as peraluminous or quasialuminous and exhibit low total rare earth element concentrations. Notably, these pegmatites are enriched in large ion lithophile elements (LILEs), such as Rb, K, and U, but depleted in high field strength elements (HFSEs), such as P and Ti. The progression from the Kf to Mic to Ab zones signifies the thorough evolution of the granitic magma, where the late-stage near-hydrothermal system assumed a crucial role in the mineralization of rare metals during magma differentiation. The Weiboshan pegmatites, which exhibit syncollisional attributes, are A-type granites formed through crustal partial melting induced by decompression. This process occurred against the background of postorogenic extension driven by asthenospheric mantle upwelling resulting from lithospheric delamination due to crustal collision and thickening.

Fluid inclusion and pyrite geochemistry of the Jiapigou gold deposit, North China Craton: Implication for origin of orogenic gold deposit?

The Jiapigou auriferous belt in Jilin province has been recognized as substantial gold-producers in the North China Craton (NCC). Gold mineralization in this district mainly occurs in mineralized quartz veins and alteration zones, characterized by silicification, pyritization, and argillitization. The quartz veins contain three generations of mineralized quartz, namely, qtz1 (probably oldest), qtz2 (slightly younger), and qtz3 (probably youngest) were identified using SEM-CL. The fluid inclusions in all three generations of quartz are broadly of three types, viz., bi-phase Ia (H2O-CO2), tri-phase Ib (H2O-CO2-NaCl ± CH4), and II (H2O-NaCl).The micro-thermometric analysis of the type Ia and Ib fluid inclusion in qtz1 & qtz2 have aqueous-carbonic composition and exhibit a similar salinity of 1.1 to 7.8 wt% NaCl equivalent, whereas the homogenization temperature (Th) range varies from ∼237 to ∼350 °C. These ore-related fluid inclusions are of low to moderate salinity, and show mixture of CO2 and CH4. On the other hand, Type II fluid inclusions are dominant in qtz3. They have salinity of 3.2 to 12.7 wt% NaCl equivalent and homogenization temperature varying between 180 °C and 210 °C. These data indicate that the ore-forming fluid evolved from a CO2–H2O–NaCl ± CH4 system during the mineralization period.The X-ray elemental maps of pyrite acquired using electron microprobe analysis (EPMA) show irregular zones of Co and Ni indicating two generations of pyrite. The early-stage pyrite which occupies core portion shows high Co and Ni, whereas the later-stage pyrite occupying rim has lower Co and Ni. The laser ablation-inductively coupled plasma-mass spectrometer (LA-ICPMS) analyses of pyrite has indicated that pyrite-1 is rich in Au + Ag + Se + Cu + Co + Ni, whereas, pyrite-2 has lower concentration of these elements. A positive correlation between Fe and other chalcophile elements reported here (i.e. Au + Ag + Se + Cu + Co + Ni), might be due to fluid-rock interaction resulting into a saturated fluid that subsequently precipitated along the microfractures within earlier-formed pyrite and quartz. The in-situ δ34S values in pyrite from Jiapigou deposits overlap in the range of +4.5 to +9.6 ‰, which is consistent with the ore-forming fluids of the crustal origin input during fluid-rock interaction. The systematic pyrite compositional observations and fluid inclusions study documented here to provide new insight into the process of ore formation for the Au enrichment in the Jiapigou deposit

Discovery of Late Cretaceous basalts in the Asuo area, Central Tibet: Implications for orogenic root removal beneath the Lhasa-Qiangtang orogenic belt

Post-collisional mafic rocks provide valuable insights into the mantle properties and evolution of orogenic belts. However, their origins remain unknown. In this study, comprehensive age, elemental, and zircon Lu–Hf isotopic data are presented for mafic dikes from the Asuo area of the Central Tibetan Plateau. The Asuo mafic dikes exhibit typical arc-related characteristics such as enrichment in large-ion lithophile elements and depletion in high-field-strength elements. This sodium-rich calc-alkaline mafic rocks has low K2O contents (0.98–1.26 wt%) and high Na2O/K2O ratios (2.55–2.97). The presence of xenolith zircons and varying zircon Hf isotopic composition [εHf(t): 1.33–8.32] indicate that the mafic magma assimilated juvenile crust. Zircon U-Pb dating results suggest that the Asuo mafic rocks were emplaced contemporaneously with the adakite-like rocks during ∼ 95–75 Ma. However, no genetic link between Asuo mafic rocks and the adakite-like rocks in the Lhasa–Qiangtang Orogenic belt was observed. The primary contribution of mantle-derived mafic magmas to the formation of coeval intermediate–felsic magmas is the provision of additional heat. The mass exchange between them may be limited. We suggest a geodynamic scenario in which the orogenic root may have been removed during the post-collisional period via repeated and localized lithospheric dripping. In this model, the formation of mafic and adakite-like intrusions occurred in two stages, that is, (1) partial melting of metasomatized lithospheric mantle generated mafic melts, and (2) underplating of these mafic melts beneath the thickened juvenile lower crust, which resulted in partial melting of the juvenile mafic lower crust and generation of adakite-like melts. Our results provide new insights into the magmatism in the terminal stage of an orogenic system.

The fate of ultramafic-rich mélanges in cold to hot subduction zones: Implications for diapirism (or not) and chemical geodynamics

Buoyant ultramafic-rich (serpentine- or chlorite-rich) mélange diapirs in sediment-starved subduction zones can transport slab material to arc sources. While the buoyancy of chlorite-rich mélanges was previously investigated, serpentine-rich mélanges were never explored. Thus, the overall contribution of ultramafic-rich mélanges to buoyancy, the conditions for diapir formation, and their fate in subduction zones are not well constrained. Here, we investigate the partial melting behavior and the associated density transformations of a serpentine-rich matrix (5–10 wt.% H2O) with minor sediments (9:1 ratio) at fore-arc (∼65 km) to sub-arc (∼95 km) depths (2–3 GPa and 800–1250 °C) and compare to that of chlorite-rich mélanges from the literature. Our results show that the solidus of serpentine-rich matrices is between 1050 and 1100 °C and requires either diapiric rise of the mélange into the hotter mantle wedge or interactions with a hotter asthenosphere through slab tears to partially melt and produce basaltic melts, whether in hot or cold slab channels. Chlorite-rich mélanges may account for the sources of some arc lavas, but partial melting of serpentine-rich mélanges produce melts depleted in CaO, TiO2, alkalis, and are highly enriched in MgO compared to basaltic arc lavas. Both serpentine-rich and chlorite-rich matrices dehydrate to form denser peridotite and lose buoyancy at ∼800 °C and ≥1000 °C, respectively. Even if diapirism initiates in such mélanges near the slab-mantle interface, they would likely lose buoyancy upon ascent into the hotter mantle wedge resulting in stalled or failed diapirs. Diapir growth (τa) is controlled by the interplay of density, thickness and viscosity of the mélange, as well as the timescale of slab subduction (τs) and thermal structure of the subduction zone. We observe that the onset of diapirs in cold subduction zones requires mélanges that may sometimes be thicker than that observed by field and geophysical studies, while hot subduction zones overall require thinner mélanges. Thus, ultramafic-rich mélange diapirs may occur but only under specific conditions and when the diapiric ascent timescale is faster than the thermal equilibration barrier of ∼800–1000 °C (especially at the core of the mélange). Dehydration or partial melting of ultramafic-rich mélanges can affect the large ion lithophile element (LILE), volatiles, and high-field strength element (HFSE) budgets in the mantle wedge. Partial melting (caused by a diapiric rise or slab tear) does not fractionate LILEs from HFSEs at T ≥ 1100 °C and if the mélange has a lower LILE/HFSE to begin with, that signature is transferred to arc sources. Dehydration releases aqueous fluids rich in fluid-mobile elements (LILE and volatiles) relative to HFSE. Thus, the characteristic high LILE/HFSE signature of aqueous fluids is transferred to arc magma sources. Given high LILE/HFSE ratio is a ubiquitous arc magma signature, but slab tears are not, and diapirism in ultramafic-rich mélanges is highly conditional, this study corroborates that aqueous fluids released from sediment-starved mélanges are the predominant mass transfer agents rather than diapirs.

Late Paleozoic–Early Mesozoic subduction history of Mudanjiang Ocean: New insights from greenschist in the Heilongjiang Complex, NE China

This paper presents zircon U-Pb ages, whole-rock major and trace element data, and Sr-Nd-Hf isotopic compositions for the greenschists from the Heilongjiang Complex in NE China. Based on the geochronological and geochemical characteristics, the greenschists from the Heilongjiang Complex can be categorized into three series: Early Permian tholeiitic series (275 ± 1 Ma and 273 ± 1 Ma), Middle Permian alkaline series (261 ± 1 Ma), and Early Jurassic alkaline series (179 ± 1 Ma). The Early Permian tholeiitic greenschist samples are characterized by remarkable negative Nb and Ta anomalies, and they exhibit relatively low whole-rock (87Sr/86Sr)i values (0.703896–0.704252), along with positive εNd(t) values (+7.66 to +8.65) and positive εHf(t) values (+0.92 to +11.51), implying that their protoliths originated from the partial melting of a depleted mantle wedge that has been metasomatized by subducted slab fluids. The Middle Permian alkaline greenschist samples have high Nb (17.3–19.0 ppm), TiO2 (1.40–1.64 wt%), and P2O5 (0.60–0.68 wt%) concentrations, and they are enriched in large ion lithophile elements and light rare earth elements, and depleted in high field strength elements and heavy rare earth elements, with high whole-rock (87Sr/86Sr)i values (0.709434–0.709949), negative εNd(t) values (−4.73 to −4.72) and varied εHf(t) values (−10.11 to +4.86), which compositionally align with those of Nb-enriched basalts. Based on the geochronological and geochemical characteristics, we propose that the protolith generation of Middle Permian alkaline greenschists was associated with the partial melting of a mantle wedge that had been metasomatized by subduction slab-derived melts. The Early Jurassic alkaline greenschist samples display OIB affinities, characterized by whole-rock (87Sr/86Sr)i values ranging from 0.705161 to 0.705926, εNd(t) values between +6.16 and +6.19, and εHf(t) values from +3.44 to +9.32, indicating the formation of the protolith for the Early Jurassic alkaline greenschist was related to the upwelling of the asthenosphere resulting from slab break-off. By integrating regional geological data, we can trace the subduction evolution of the Mudanjiang Ocean back to the Early Permian, and the slab break-off during the Early Jurassic likely corresponded to the early stage of the closure of the Mudanjiang Ocean.

Transcrustal magmatic systems in NE China: Insights from Early Cretaceous metaluminous–peraluminous–peralkaline rock associations in the southern Great Xing’an Range

The generation and evolution of crustal-scale magmatic systems are important in revealing the continental crust differentiation. In the Bayangeer-Aliwula area of Inner Mongolia, metaluminous–peraluminous–peralkaline rock assemblages provide a rare opportunity to evaluate Early Cretaceous magmatic systems. This study presents new geochemical data, including whole-rock and zircon geochemistry, zircon U–Pb dating, and Hf–O isotopic analysis of rocks formed between 132 and 121 Ma. The metaluminous rocks exhibit low SiO2 (55.35–65.65 wt%), low Rb/Sr (0.08–0.24) and (La/Yb)N (4.88–7.58) ratios, and positive εHf(t) values (+4.9 to +8.7). These features, along with enrichment in large-ion lithophile elements and depletion in Nb and Ta, suggest formation via partial melting of fluid-metasomatised lithospheric mantle. By contrast, peraluminous rocks have high SiO2 (69.37–80.58 wt%), a high differentiation index (DI = 88–95), and Fe-index (0.84–0.95), resembling highly fractionated I-type granites. They show high Rb/Sr (0.77–3.35) and (La/Yb)N (5.79–22.75) ratios, and positive εHf(t) values (+6.7 to +10.8), combined with the modelling results, indicating origin from partial melting of K-rich mafic lower crust followed by magma fractionation. Peralkaline rocks display typical ferroan A-type granite characteristics (Zr + Nb + Ce + Y = 906–4292 ppm; Fe-index = 0.96–0.99), with high SiO2 (74.02–77.50 wt%), high Rb/Sr (6.17–121.38), and (La/Yb)N ratios (2.19–17.72), and positive εHf(t) values (+3.1 to +9.6). Zircon geochemistry characteristics suggest that peralkaline and peraluminous felsic melts are different batches extracted from the same magma reservoir. Further analysis, including hyperbola diagrams and zircon oxygen isotope compositions, suggests peralkaline magma formation through the mixing of altered oceanic crust fluids and peraluminous melts after melt extraction. During Early Cretaceous, the transcrustal magmatic system provides a reasonable explanation for the petrogenesis of various contemporaneous rocks in the study area in southern Great Xing’an Range.

Lastarria volcano, a major emitter of boron and chalcophiles in northern Chile and the Central Volcanic Zone

This study examines the trace element chemistry of fumarolic deposits and fumarolic plumes at Lastarria volcano, located in northern Chile. Fumarolic deposits were manually collected, while fumarolic plumes were sampled using the filter pack technique; after sample preparation, both sample types were analyzed by ICP-MS. The research focuses on chalcophile elements (As, Cd, Sb, Te, Cu, Zn, Tl, Pb, and Bi) and B, with the findings revealing significant enrichment of As and Pb in fumarolic deposit samples, especially in medium- and high-temperature fumarolic vents, respectively. On the other hand, filter pack measurements in the fumarolic plume indicate a notable enrichment in Te, B, As, and Tl, with Sc-normalized enrichment factors within the range of 104–106. From these elements, B, Tl, and Te appear to be less scavenged at the vent, presenting more significant enrichments in fumarolic plumes than in fumarolic deposits. By comparing our results with subduction-related volcanoes such as Etna, Stromboli, Lascar, Masaya, or La Soufrière de Guadeloupe, Lastarria fumarolic plume can be regarded as the one with the highest concentrations of B and As ever recorded. Moreover, Lastarria has chalcophile enrichments comparable to those volcanoes with shallower magma chambers and high-temperature magmatic emissions such as Stromboli. The higher abundance of chalcophiles suggests a significant magmatic influence feeding Lastarria fumaroles and the presence of ligands, such as Cl, which can transport significant amounts of chalcophiles at shallower levels of the crust during late-stage magma crystallization. Large amounts of chalcophiles released by Lastarria and Lascar volcanoes could be responsible for the naturally elevated concentrations of these elements in the Altiplano-Puna area. Future studies should focus on the lifetime of chalcophiles in the Central Andean atmosphere, where these elements could reside for a longer time given the dominant hyperarid environment.

Ages, petrogenesis and metallogenesis implications of the Miocene adakite-like igneous rocks in the Beimulang porphyry Cu Deposit, southern Tibet

Understanding the petrogenesis of Miocene adakite-like igneous rocks is crucial for unraveling the formation processes of post-collision porphyry copper deposits within the Gangdese orogenic belt. This study focuses on the mineralogical, geochronological, and geochemical characteristics of the Beimulang Miocene adakite-like igneous rock series, with particular emphasis on two types of diorite porphyry (DP1 and DP2), to constrain their petrogenesis. Zircon U-Pb dating indicates that the monzogranite (MG), monzogranite porphyry (MGP), DP1, DP2 and granite porphyry (GP) were emplaced at 14.8 ± 0.1 Ma, 14.6 ± 0.1 Ma, 14.6 ± 0.1 Ma, 13.2 ± 0.1 Ma and 12.5 ± 0.1 Ma, respectively. The major element compositions of the Beimulang Miocene intrusions exhibit a differentiation trend. The Sr-Nd isotopic compositions of the MG, MGP, and DP1 align with the mixing line between the juvenile lower crust and the potassic lamprophyres. Conversely, the Sr-Nd isotopic compositions of DP2 and GP fall precisely on the Sr-Nd mixing line between DP1 and the ultrapotassic lamprophyres. Considering the reverse zoning of plagioclase in the DP1 and presence of high-Mg phlogopite in the DP2, we suggest that the Miocene magmatic series at Beimulang likely derived from the mixing of partial melts of Gangdese juvenile lower crust and mantle-derived potassic-ultrapotassic magmas. The increase in Th/Yb ratios from DP1, MG, MGP to DP2 and GP suggests that the mantle metasomatism material may have evolved from slab-derived fluids to melts derived from Indian crustal sediments. The magmatic water content and oxidation calculated from zircon trace elements, are nearly identical among the ore-causative MG and MGP, and the barren GP. However, the decrease in V/Sc ratios from the MG and MGP to GP indicates that magnetite-driven magma sulfide saturation leads to the depletion of chalcophile elements, significantly reducing the Cu mineralization potential of the GP. We suggest that the higher degree of magmatic evolution leads to the barren nature of Beimulang granite porphyry.

The genesis and mineralization potential of the Kunshan pluton in the Xuancheng district, Eastern China

The Xuancheng mineralization district (XMD) is an important part of the Middle-Lower Yangtze River Metallogenic Belt, and hosts a number of porphyry-skarn Cu poly-metal discoveries in recent years. The Kunshan pluton is located in the northeastern sector of the Xuancheng district, and is composed of fine-grained pyroxene diorite, coarse-grained pyroxene diorite and granodiorite. This study reports zircon LA-ICP-MS U-Pb chronology, whole-rock geochemistry and Sr-Nd isotope analysis of the Kunshan Complex pluton. The intrusions young from the fine-grained pyroxene diorite (137.2 ± 2.0 Ma), through the coarse-grained pyroxene diorite (136.1 ± 2.1 Ma) to the granodiorite (134.8 ± 2.2 Ma). All three stages of magmatic samples are high-potassium calc-alkaline to potassium dolerite series, they are enriched in light rare earth elements (LREE) and large ion lithophile elements such as Rb, Sr, and (Ba), but depleted in heavy rare earths elements (HREE), and high field strength elements such as Nb, Ta, Ti, and P. Their (87Sr/86Sr)i and (143Nd/144Nd)i values range from 0.706703 to 0.707618 and 0.512023 to 0.512064 respectively. The samples from the Kunshan complex pluton are consistently plotted the zone between the mantle evolution trending line and MLYB crust, which indicating the three-stage melt are derived from the crust-mantle mixed source, with closer to lithosphere mantle. All phases of the pluton were derived from the same magmatic source, likely the crust-mantle mixed zone between the lower Yangtze crust and enriched lithospheric mantle. The 3 stage melts formed Kunshan complex pluton gradually strengthen fractional crystallization (FC) during their emplacement process, while the late granodiorite melt with highest FC degree was the ore-forming intrusion, which is characterized with oxidized melt with low temperature, and high H2O content. After Compared with the mineralized granitoid intrusive rocks in the Middle-Lower Yangtze River Metallogenic Belt, it suggests that the late highly differentiated granitoids, like Kunshan granodiorite, are probably favorable metallogenic indications.

Geodynamic Evolution of the Proto-Tethys Ocean in the West Kunlun Orogenic Belt, northwest Tibetan Plateau: Implications from the Subarc Crust and Lithospheric Mantle Modification

Abstract Radiogenic isotopes serve as a crucial tool for investigating crustal evolution, playing a pivotal role in revealing magma sources and petrogenesis. However, they can be ineffective in distinguishing between distinct magmatic sources with similar radiogenic isotopic compositions, a common occurrence in nature. Here we addresse this challenge in the Ordovician igneous rocks from the West Kunlun orogenic belt (WKOB), aiming to distinguish between two potential magmatic sources (i.e. the Tarim Craton and the Tianshuihai terrane) with similar isotopic compositions using appropriate thermodynamic and geochemical modeling based on mineral and whole-rock geochemistry. Zircon U–Pb dating yields ages of 483 ± 3 Ma for the Pushou gabbros and 469 ± 2 Ma and 461 ± 2 Ma for the Datong monzogranites and syenites, respectively. The Pushou gabbros exhibit low SiO2 (47.4–49.1 wt %), high MgO (5.5–6.9 wt %), high large-ion lithophile elements (LILEs, e.g. Rb, Ba, Th, and K), and low high field-strength elements (HFSEs, e.g. Nb, Ta, Zr, Hf, P, and Ti), suggesting an origin in subduction-modified mantle. They display high whole-rock (87Sr/86Sr)i ratios (0.7156 to 0.7192), negative whole-rock εNd(t) values (−7.1 to −7.8), as well as high zircon δ18O values (7.6–7.9‰) and enriched zircon Hf isotopic compositions (εHf(t) = −5.3 to −7.7), which are consistent with 1–5% subducted sediments in an enriched mantle source. Trace element models further confirm that the gabbros are most likely derived from low-degree (~15%) partial melting of subduction-modified Tarim mantle in the spinel–garnet facies rather than from the Tianshuihai mantle. The Datong syenites belong to the shoshonitic series and are characterized by medium SiO2 (59.5–61.4 wt %), relatively low MgO (0.9–1.2 wt %) and Mg# (37–42), enrichment in LILEs and depletion in HFSEs. They have high whole-rock (87Sr/86Sr)i ratios (0.7103 to 0.7105) and negative whole-rock εNd(t) values (−3.8 to −4.3), along with negative to slightly positive zircon εHf(t) values (−3.8 to +2.6), similar to coeval mafic rocks. Thermodynamic and geochemical modeling suggest that the Datong shoshonitic rocks likely originated via crystal fractionation of shoshonitic basaltic magmas in the SW Tarim Craton. The Datong monzogranites have high SiO2 (69.7–72.6 wt %), low MgO (0.6–0.7 wt %), and a typical enrichment in alkalis, Zr, and Nb, with depletion in Sr, P, and Ti, consistent with A-type granites. They are characterized by high whole-rock (87Sr/86Sr)i ratios (0.7321 to 0.7323), negative whole-rock εNd(t) values (−11.3 to −11.8), negative zircon εHf(t) values (−11.0 to −16.5), and high zircon δ18O values (7.2–8.0‰), indicating derivation from the remelting of an ancient crustal source. Thermodynamic, major, and trace element modeling indicate that their parent magma may have been generated by water-deficient (~2 wt %) partial melting of ancient crustal material beneath the SW Tarim Craton rather than that of the Tianshuihai terrane, under high-temperature (T > ~950°C) and low-pressure (P = 5–8 kbar) conditions. Based on the tectonic framework of the WKOB, we propose that the original mantle and crust beneath the southern Kunlun terrane may have been modified or partially replaced by that beneath the SW Tarim Craton during the Ordovician. Therefore, this evidence for Tarim-derived magmatism, when combined with regional sedimentary and structural records, indicates that Ordovician magmatism in the southern Kunlun terrane is most consistent with episodic northward subduction of the Proto-Tethys Ocean, commencing at ~485 Ma. Middle Ordovician slab break-off can explain the formation of the A-type granites, but reinstated northward subduction is required for the generation of late Ordovician Datong syenites.

Formation of high-silica adakites and their relationship with slab break-off: Implications for generating fertile Cu-Au-Mo porphyry systems

In recent years, the characteristics and sources of fertile adakites has received considerable attention. As well, most recently the geodynamic environment of convergent margins subducting oceanic crust aiding arc formation, evolving to slab rollback, then slab break-off after collision (i.e. late- to post-collisional slab failure (arc-like magmatism) and transpression) has gained more recognition, although their relationship to each other has yet to be explored. The geochemical characteristics imply that adakites/adakite-like, in particular high-silica adakites (HSA), can form by partial melting of subducting hydrothermally altered oceanic crust in convergent plate boundary settings during the terminal stages of subduction, lithosphere thickening, and then failure (all late to post collisional), while the melting of the mantle wedge during subduction-related dehydration creates more typical calc-alkaline basalt-andesite-dacite-rhyolite series (ADR) to form intraoceanic island arc to intracontinental margin arc systems, before the collisional stage. HSAs are characterized by high-silica (SiO2 > 67 wt.%), Al2O3 > 15 wt.%, Sr > 300 ppm, Y<20 ppm, Yb < 1.8 ppm, and Nb ≤ 10 ppm, and MgO < 3 wt.%, with high Sr/Y (>50), and La/Yb (>10). Some specific geochemical features, such as high Mg# (ave 0.51), Ni (ave 924 ppm), and Cr (ave 36 ppm), in HSAs are typical, in contrast to calc-alkaline arcs, although both groups display similar but less pronounced negative anomalies of Nb, Ta, and Ti in primitive mantle-normalized trace element spider diagram profiles. These unique geochemical features are likely ascribed to the involvement of garnet, hornblende, and titanite either during partial melting of hydrous MORB-like oceanic crust with only minor assimilation and fractional crystallization (AFC) within the mantle and crustal during ascent in a transpressional collisional environment. Hypotheses for origin of HSA derivative from melting in convergent margins from young, hot oceanic plates subducting into the mantle is applicable to only some adakitic systems. The difference in geochemical characteristics of adakites compared to ADR, such as relative higher MgO, Cr, Cu, and Ni, are due to their slab source, as well as interaction of the slab-derived adakitic melts with overlying hot lithospheric mantle; altered oceanic slabs are also relatively rich in siderophile and other chalcophile elements, as well as sulfates and sulfides. HSA magmas related to slab failure have special geochemical properties, such as Sr/Y > 20, Nb/Y > 0.4, Ta/Yb > 0.3, La/Yb > 10, Gd/Yb > 2, and Sm/Yb > 2.5. Slightly higher Nb + Ta is due to high T melting of rutile. Varieties of Nb/Ta compared to silica are also significant in HSA as a result of slab failure (roll back to break-off). High T-P partial melting of the hydrothermally altered oceanic slab produces HSA with quite high activities of H2O, SO2, HCl, with chalcophile metals that remain incompatible at higher fO2 (low fH2); these situations happen in late- to post-collisional settings where the subducting oceanic crust experienced slab failure, resulting in advective heat addition to the system from upwelling asthenosphere. In such a slab failure setting, transpression and transtension play a significant role in the rapid emplacement of a high amount of fertile adakitic magmas through the subduction-modified lithosphere and crust into the upper crust. When oxidized slab melts interact with the subduction-modified lithospheric mantle, the resulting magmas stay oxidized, potentially contributing to the special conditions conducive to formation of porphyry Cu-Au mineralization.

Development of High-Silica Adakitic Intrusions in the Northern Appalachians of New Brunswick (Canada), and Their Correlation with Slab Break-Off: Insights into the Formation of Fertile Cu-Au-Mo Porphyry Systems

High-silica adakites exhibit specific compositions, as follows: SiO2 ≥ 56 wt.%, Al2O3 ≥ 15 wt.%, Y ≤ 18 ppm, Yb ≤ 1.9 ppm, K2O/Na2O ≥ 1, MgO &lt; 3 wt.%, high Sr/Y (≥10), and La/Yb (&gt;10). Devonian I-type adakitic granitoids in the northern Appalachians of New Brunswick (NB, Canada) share geochemical signatures of adakites elsewhere, i.e., SiO2 ≥ 66.46 wt.%, Al2O3 &gt; 15.47 wt.%, Y ≤ 22 ppm, Yb ≤ 2 ppm, K2O/Na2O &gt; 1, MgO &lt; 3 wt.%, Sr/Y ≥ 33 to 50, and La/Yb &gt; 10. Remarkably, adakitic intrusions in NB, including the Blue Mountain Granodiorite Suite, Nicholas Denys, Sugar Loaf, Squaw Cap, North Dungarvan River, Magaguadavic Granite, Hampstead Granite, Tower Hill, Watson Brook Granodiorite, Rivière-Verte Porphyry, Eagle Lake Granite, Evandale Granodiorite, North Pole Stream Suite, and the McKenzie Gulch porphyry dykes all have associated Cu mineralization, similar to the Middle Devonian Cu porphyry intrusions in Mines Gaspé, Québec. Trace element data support the connection between adakite formation and slab break-off, a mechanism influencing fertility and generation of porphyry Cu systems. These adakitic rocks in NB are oxidized, and are relatively enriched in large ion lithophile elements, like Cs, Rb, Ba, and Pb, and depleted in some high field strength elements, like Y, Nb, Ta, P, and Ti; they also have Sr/Y ≥ 33 to 50, Nb/Y &gt; 0.4, Ta/Yb &gt; 0.3, La/Yb &gt; 10, Ta/Yb &gt; 0.3, Sm/Yb &gt; 2.5, Gd/Yb &gt; 2.0, Nb + Y &lt; 60 ppm, and Ta + Yb &lt; 6 ppm. These geochemical indicators point to failure of a subducting oceanic slab (slab rollback to slab break-off) in the terminal stages of subduction, as the generator of post-collisional granitoid magmatism. The break-off and separation of a dense subducted oceanic plate segment leads to upwelling asthenosphere, heat advection, and selective partial melting of the descending oceanic slab (adakite) and (or) suprasubduction zone lithospheric mantle. The resulting silica-rich adakitic magmas ascend through thickened mantle lithosphere, with minimal affect from the asthenosphere. The critical roles of transpression and transtension are highlighted in facilitating the ascent and emplacement of these fertile adakitic magmas in postsubduction zone settings.

Recycling of terrigenous sediments recorded in late Permian-early Triassic Fe-rich intrusions from Yunkai Massif, South China

The origin of Fe-rich intrusion remains debatable regarding the respective role of magmatic evolution and Fe enrichment in the source. Here, we report detailed mineral and bulk-rock geochemistry of Permian-Triassic (251–250 Ma) mafic intrusions from the Tengxian area in Yunkai Massif, South China. These rocks consist of hornblende norites, show Fe-rich affinities with high FeO*(FeO* = FeOt / (FeOt + MgO) in weight ratio, >0.8, based on total iron oxide in the rock), and exhibit significant enrichment in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) but depletion in Sr and high field strength elements (HFSEs), resembling subduction-related magmas. In addition, they show remarkable features that include very high δ18O values in zircon (δ18O = 8.8–10.6 ‰) and apatite (δ18O = 8.7–10.8 ‰), and extremely enriched SrPb [e.g. 87Sr/86Sr(i) = 0.7181–0.7196, 207Pb/204Pb(i) = 15.77–15.78, 208Pb/204Pb(i) = 38.95–39.05] and nonradiogenic NdHf isotopic compositions [e.g. εNd(t) = −11.1 ~ − 10.1, εHf(t) = −8.8 ~ −7.3] in bulk rocks. These characteristics distinguish the Tengxian norites from modern arc basalts and subduction-related magmas in the Paleo-Pacific Tectonic Domain. Instead, they are isotopically similar to Cenozoic Tibetan and Mediterranean potassic to ultrapotassic rocks in the Tethys Tectonic Domain. Regardless of variable influence by orthopyroxene and plagioclase accumulation, the intrinsically low SiO2 and high FeOt and Fe/Mn ratios in these rocks were likely attributed to significant contribution of a Fe-rich mantle component such as Si-poor pyroxenite, which might have formed through crystal accumulation of mafic magmas at mantle conditions. The highly evolved Sr-Nd-Pb-Hf isotopic signatures and very high δ18O values in zircon and apatite required substantial (10–20 %) involvement of recycled crust in the mantle source. The combined mineral and bulk-rock geochemical data suggest that the parental magmas for the Tengxian norites originated from a metasomatized mantle wedge through addition of terrigenous sediment-derived melt following the subduction of Paleo-Tethys Ocean beneath the Yunkai Massif.

Miocene magmatism in Northern Tunisia and its geodynamic implications

The Nefza igneous rocks in Northern Tunisia belong to the Miocene magmatic belt extending from Northern Tunisia to Morocco and consist mainly of Serravallian–Tortonian granodiorite and rhyodacite (~ 14–8 Ma) and Messinian basalts (~ 8–6 Ma). Differences in geochemical composition between units have been interpreted to be the result of geodynamic processes in the upper mantle below the Western Mediterranean area, but their implications for Northern Tunisia are unclear due to limited data. In this contribution, we present an updated geodynamic model for Northern Tunisia based on new petrographic and whole-rock geochemical results from the Nefza magmatic suite from outcrop and OB45 drill core samples. Petrographic observations show that rhyodacites display a microlithic texture with quartz, plagioclase, K-feldspar, biotite, and glass, whilst granodiorite contains plagioclase, quartz and exhibits fine-grained texture with a 2–3 mm crystal size. The Nefza magmatic rocks are overprinted by multiple weathering and alteration processes with loss of ignition (LOI) ranging between 0.88 and more than 5 wt%. The linear relationships between mobile elements (Ca, Na, P, K, Mg, Si), large-ion lithophile elements (LILE), and LOI suggest element mobilisation during alteration. Major and trace element compositions show the Nefza magmatic rocks plot in the rhyolite, dacite, and trachydacite fields for felsic rocks and plot in the basalt and trachybasalt fields for mafic rocks. Granodiorite and rhyodacite rocks exhibit negative Eu anomalies and a LILE enrichment (Rb, Ba, Pb) relative to high-field-strength elements (HFSE: Nb, Ta, Hf, Zr, REE). Mafic rocks enriched in LILE show geochemical characteristics between calc-alkaline and alkaline trends. Comparison with nearby regions suggests that the generation of calc-alkaline magmas resulted from the partial melting of the lithospheric mantle due to slab break-off or tearing in Eastern Algeria. The upward flow of asthenospheric material through the widening tear in the sinking slab leads to partial melting of the mantle and shallowing of the lithosphere–asthenosphere boundary, ultimately leading to the formation of alkaline magma. The Nefza geochemical variations underscore Mediterranean upper mantle heterogeneity, offering crucial insights into Mediterranean geodynamics. More studies are needed to constrain mantle dynamics and the region’s complex geological history.

Geochemical features and radiological risk assessment of Wadi El-Regeita granites, South Central Sinai, Egypt

The exposed rocks in the Wadi El-Regeita area are quartz monzonite, granodiorite and monzogranite intruded by andesite and diorite dikes. The monzogranites studied show a marked enrichment in Rb, Ba and Sr (large ion lithophile elements, LILE) and Zr, Nb and Y (high field strength elements, HFSE), but depletion in P and Ti. The genetic characteristics of the granites revealed calc-alkaline affinity, metaluminous and/or peraluminous characteristics. The studied quartz monzonite, granodiorite, and diorite rocks represent I-type granites that were emplaced in a volcanic arc tectonic environment. The monzogranite falls into post-collisional A-type granite that was emplaced within a plate environment under extensional regime. The calculated isovalents LREE/HREE, La/Yb, La/Sm and Tb/Yb show a relative enrichment of the lighter ones in the monzogranite. The quantities of 238U, 232Th and 40K in diorite samples have been investigated by gamma-ray spectroscopy. The measured radioisotope activity concentrations in Wadi El-Regeita varied from 100 to 1604 Bq.kg−1, with a mean of 370 ± 341 Bq.kg−1 for 238U. For 232Th, the range was from 35 to 140 Bq.kg−1, with a mean of 68 ± 27 Bq.kg−1. Finally, for 40K, the range was 501–3067 Bq.kg−1, with a mean of 1355 ± 570 Bq.kg−1. The levels of 238U, 232Th, and 40K detected in the diorite samples examined were found to exceed the worldwide limits of 35, 45, and 412 Bq.kg−1, respectively. The primary radiological hazards associated with these diorite dikes were attributed to the gamma rays emitted by the radioactive elements. Estimates of the radiological hazards in the granites were made and statistical methods were used to demonstrate the relationships between radionuclides and radiological factors. The statistical evaluation confirmed that uranium and its associated minerals in the diorite dikes were the main factors contributing to the radiological risks. Consequently, the study concluded that the diorite dikes found in the study area were unsuitable for construction purposes due to their elevated levels of radioactivity.

The flotation of magmatic sulfides transfers Cu-Au from magmas to seafloor massive sulfide deposits

Copper and gold-rich seafloor massive sulfide deposits formed in intra-oceanic subduction settings are typically associated with hydrous and oxidized magmas, but processes leading to their formation remain controversial. Sulfide-bubble interaction has been suggested to play an important role in metal transfer from magmas to seawater-derived hydrothermal fluids. Here we use textural observations of magmatic sulfides, geochemical numerical models of chalcophile element concentrations, and numerical models of magmatic sulfide growth within a mafic to felsic submarine magmatic suite (Fatu Kapa, SW Pacific) associated with copper-gold-rich seafloor massive sulfide deposits. We demonstrate that concomitant sulfide and aqueous fluid formation at the andesitic stage results in floating sulfide-bubble compound drops in magmas, which play a crucial role in the transfer of copper and gold toward the surface. We emphasize that late sulfide saturation in copper-gold-rich intra-oceanic subduction-derived felsic magmas favors upward sulfide transfer via flotation.