Lithium Triborate Crystal Research Articles

Generation and Evaluation of an Efficient Femtosecond Green Laser.

We demonstrate femtosecond ultra-stable green laser generation by an ytterbium-doped polarization-maintaining fiber laser with a 2.4 mm long lithium triborate (LBO) crystal. We generated 5.6 W of femtosecond green light at 520 nm for a fundamental power of 12 W, which corresponds to a conversion efficiency of 46.7%. The fiber chirped-pulse amplifier, which has an environmentally immune front end, delivered 170 fs pulses at a 75 MHz repetition rate centered at 1040 nm. According to the dispersion of the optical material in a double-frequency setup, the introduced dispersion had a negligible effect for the green laser, and the pulse duration of the generated green laser was calculated to be 171 fs, resulting in an excellent power stability, with fluctuation as low as 0.16% of the generated green light. This system could be of great interest in ultrafast optical and photobiology research.

Continuous-Wave Self-Raman Vanadate Lasers Generating Versatile Visible Wavelengths

In this review, the developments of efficient high-power CW orange-lime-green lasers by using intracavity stimulated Raman Scattering (SRS) in Nd-doped vanadate lasers are systematically discussed. The overall properties of the spontaneous Raman spectra in Nd:YVO4 and Nd:GdVO4 crystals are overviewed. The critical phase matchings of using the lithium triborate (LBO) crystals for sum frequency generation (SFG) and second harmonic generation (SHG) are thoroughly reviewed. We make a detailed review for achieving the individual green-lime-orange emissions from the self-Raman Nd:YVO4 and Nd:GdVO4 lasers with LBO crystals. The following is to review the dual-wavelength operations of the lime-green and orange-green lasers. Finally, the procedure for generating the triple-wavelength operation of orange-lime-green simultaneous emissions is completely described. The present review is expected to be useful for developing compact, efficient, high-power CW visible lasers for applications including medical treatment, biology, spectroscopy, and remote sensing.

Spatial shaping of low- and high-order harmonics generated using vortex beams

We demonstrate the generation of the low- and high-order harmonic vortex beams from a single spiral phase plate illuminated by different laser wavelengths. The second harmonic (532 nm) originates from the application of the wavefront-structured 1064 nm femtosecond pulses with fractional orbital angular momentum (OAM) during propagation through a lithium triborate crystal, while the third harmonic (500 nm) originates from the application of the wavefront-structured near-IR (1500 nm) femtosecond pulses with integer OAM during propagation through a 150 μm thick fused silica plate. The topological charges (TCs) of the second and third harmonics are measured and compared. The increase in TC and the peculiarities in OAM variations during modification of the polarisation of the incident radiation are analysed and discussed. The two-colour-pump-driven second-harmonic vortex radiation interacted with an Ar gas jet to generate vortex harmonics up to the 14th order with double-lobe complex spatial profiles in the extreme ultraviolet region.

Compact efficient high-power continuous-wave Nd:YVO4/KGW/LBO Raman lasers for selectable wavelengths within 559-603 nm

Compact efficient high-power continuous-wave Nd:YVO4 Raman lasers for selectable wavelengths within 559-603 nm are achieved by using KGW crystal for intracavity stimulated Raman scattering (SRS) and lithium triborate (LBO) crystal for intracavity sum frequency generation (SFG) and second harmonic generation (SHG). The LBO crystal with the cut angle in the XY plane for the type-I phase matching is used to perform intracavity SHG or SFG. Experimental results reveal that the participated Stokes lines include the internal vibration mode at 901 cm-1, the external vibrational mode at 209 cm-1, and the combination mode of the 901 cm-1 and 209 cm-1 Raman shifts. By tuning LBO temperature for attaining the maximum output power, the output spectrum reveals the triple peaks of 588.7, 595.7, and 603.1 nm with the intensity ratio of 10:4:1. Under this circumstance, the output power can reach the highest value of 10.8 W at a pump power of 40 W. Furthermore, the output spectrum can be simply concentrated on the single peaks among 588.7 (orange), 565.7 (yellow), and 559.1 nm (lime) by tuning LBO temperature to fulfill the selection of the critical phase matching. The output powers at a pump power of 40 W can be up to 8.0, 6.1, and 9.8 W for the single-peak emission at 588.7, 565.7, and 559.1 nm, respectively. Finally, a dual-peak emission of 565.7 and 572.3 nm with total output power of 5.2 W can be generated by tuning LBO temperature to match the SFG for 572.3 nm.

A 172 mJ, high-energy picosecond 355 nm ultraviolet laser system at 100 Hz

Abstract A high-energy picosecond 355 nm ultraviolet (UV) laser operating at 100 Hz was demonstrated. A 352 mJ, 69 ps, 1064 nm laser at 100 Hz was realized firstly by cascaded regenerative, laser diode end-pumped single-pass and side-pumped main amplifiers. The stimulated Raman scattering-based beam shaping technique, thermally induced birefringence compensation and 4f spatial filter-image relaying systems were used to maintain a relatively homogeneous beam intensity distribution during the amplification process. By using lithium triborate crystals for second- and third-harmonic generation (THG), a 172 mJ, approximately 56 ps, 355 nm UV laser was achieved with a THG conversion efficiency of 49%. To the best of our knowledge, it is the highest pulse energy of a picosecond 355 nm UV laser so far. The beam quality factor ${M}^2$ and pulse energy stability were ${M}_x^2$ =3.92, ${M}_y^2$ =3.71 and root mean square of 1.48%@3 hours. This laser system could play significant roles in applications including photoconductive switch excitation, laser drilling and laser micro-fabrication.

Auto-pump-depleted stable single-longitudinal-mode 1.5 μm source with the assistance of SHG.

To realize a stable single-longitudinal-mode (SLM) 1550-nm light source for the generation of non-classical states, a ring auto-pump-depleted singly resonant optical parametric oscillator (SRO) with the assistance of second-harmonic-wave generation (SHG) is designed and built in this Letter. A magnesium oxide doped periodically polarized lithium niobate (MgO:PPLN) crystal and a lithium triborate (LBO) crystal are employed as the optical parametric downconversion (OPDC) and SHG crystals, respectively. Especially, the introduced SHG can firstly increase the loss difference between the lasing and non-lasing modes so that the dual-mode or multi-mode coupling in the achieved SRO can be effectively eliminated and the stable SLM operation is achieved. At the same time, the SHG will automatically adjust the output coupling efficiency of SRO, so as to achieve efficient conversion efficiency and auto-pump depletion of SRO. In addition, due to the SHG, it is easy to achieve the low-intensity noise multi-wavelength output for the stable SLM SRO. As a result, the output powers of the SLM 1550 nm and 775 nm are up to 4.05 W and 3.25 W, respectively, and the total optical conversion of the built SRO can achieve 45.58%. The presented method paves a way to develop a compact stable SLM multi-wavelength SRO, and the obtained SRO is further beneficial to develop compact continuous-variable non-classical light fields.

The femtosecond structure of extreme contrast, multi-terawatt second-harmonic laser pulses at 400 nm

Ultrahigh intensity contrast and short pulse laser–solid interactions offer an attractive platform for investigating high-energy-density matter, particularly in the context of structured and ultra-thin targets that form hot, dense plasma conditions. Harmonic generation can improve the contrast of laser pulses by several orders of magnitude. In this study, we present the characterization of extreme contrast, relativistic intensity second-harmonic pulses at 400 nm, using the self-diffraction frequency-resolved optical gating technique. The 400 nm pulses were generated at various input intensities using potassium dihydrogen phosphate and lithium triborate crystals. Our observations reveal the presence of spectral broadening, pulse compression, and complex structures at higher input intensities. We see that extreme contrast, few tens of femtosecond pulses can have multiple “prepulses” at the 100s femtosecond scale as large as ten percent of the peak value. These can preionize a solid significantly and may influence the interaction. Simulations based on nonlinear pulse propagation equations reinforce our findings.

Efficient Continuous-Wave Eye-Safe Nd:GdVO4/KGW Raman Laser and Sum Frequency Generation for Deep-Red Emission

A concise, efficient continuous-wave eye-safe Nd:GdVO4/KGW Raman laser at 1525 nm is here demonstrated. A Nd:GdVO4 crystal was used to produce the fundamental field at 1341 nm and a KGW crystal generated the intracavity Stokes field at 1525 nm via wavelength conversion of stimulated Raman scattering. The output power of the Stokes field at 1525 nm could achieve 2.1 W under the pump power of 30 W. Furthermore, two different lithium triborate (LBO) crystals with critical phase matching were exploited to obtain deep-red emission at 714 nm via the intracavity sum frequency generation of 1341 and 1525 nm waves. One cutting angle was in the XY plane and the other was in the XZ plane. The empirical thermo-optical coefficients for the LBO crystal were exploited to systematically analyze the critical phase matching conditions. Numerical results revealed that the type-I phase matching angle in the XY plane was near θ = 90° and ϕ = 3.3° at room temperature, whereas the type-I phase matching angle in the XZ plane was near θ = 86.3° and ϕ = 0° at a temperature around 47 °C. The numerical values for the optimal temperatures for the two different cutting angles were found to be in good agreement with experimental results. At the pump power of 30 W, the output power at 714 nm was approximately 2.9 W by using the LBO crystal with the cutting angle in the XY plane. On the other hand, the maximum output power at 714 nm could be up to 3.2 W under the pump power of 30 W by using the cutting angle in the XZ plane. Furthermore, the linewidth of the SFG emission was confirmed to be nearly the same for the two different cutting angles. The overall linewidth could be narrower than 0.2 nm. The developed laser at 714 nm can be useful in the exploration of ionic and atomic radium isotopes with laser spectroscopy.

RF oscillator circuit for absorption coefficient measurement of piezoelectric materials.

We have introduced an approach for low optical absorption coefficient measurement of piezoelectric materials based on the piezoelectric resonance laser calorimetry (PRLC) method. An RF oscillator circuit provides a convenient way to track the piezoelectric resonance frequency during laser irradiation. In this work, the optical absorption coefficient of lithium triborate crystal under high-power IR laser irradiation was measured using the oscillator circuit and the conventional PRLC technique.

Frequency-Doubled High-Power Optical Vortex Beam With Sub 500 fs Pulse Duration

We report on the generation of high-power ultrashort-pulsed optical vortex beams (VBs) with orbital angular momentum (OAM) of +1 in the infrared (IR) and +2 in the visible (VIS) spectral regions. The IR vortex beam was created from a Gaussian beam by employing a nanograting (S-waveplate) mode converter. With this approach we obtained an average power of up to 802 W at a wavelength of λ = 1030 nm in the IR-VB with a pulse energy of 802 µJ, a pulse duration of 460 fs, and a mode-conversion efficiency of 90.1%. By subsequent second harmonic generation, the IR-VB was frequency-doubled inside a lithium triborate (LiB <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> ) crystal. An average power of up to 320 W at λ = 515 nm was generated, with 320 µJ of pulse energy, 382 fs of pulse duration, and an IR-VB to SH-VB conversion efficiency of 39.9%. The generated IR and VIS VBs were characterized by a Mach-Zehnder type interferometric measurement, confirming the helical wavefronts at these high average powers. These results show that it is possible to efficiently generate high-quality VBs at multi hundreds of watts and confirm the OAM scaling law in harmonic generation processes.

Design of High Energy Single Longitudinal Mode 355 nm UV Laser

355 nm laser is a widely applied light source, of which the two features mostly used are the damaging effect and propagation characteristic in the atmosphere. Thus, higher laser energy has always been required to perform better damage and provide further propagation range. We demonstrate high energy single longitudinal ultraviolet (UV) laser using a nonlinear optical crystal of lithium triborate (LBO) cut at θ=90° and φ= 37° with sizes of 10 mm × 10 mm × 30 mm in type I phase-matching, the source light from a single longitudinal mode (SLG) inject master oscillator power amplifier (MOPA) operated at a repetition rate of 5 Hz with a pulse duration of 10 ns. The maximum output energy of 0.308 J of 355 nm UV laser was reached through a total pump energy of 1.82 J 1064 nm and 532 nm laser with an nonlinear conversion efficiency of 16.9%. The experimental results prove that the LBO crystal is a reliable candidate for high-energy UV laser generation. The output high energy 355 nm laser has great application potential in material processing, microchip manufacturing and remote sensing.

Kilowatt-class high-energy frequency conversion to 95 J at 10 Hz at 515 nm

Abstract We report on frequency doubling of high-energy, high repetition rate ns pulses from a cryogenically gas cooled multi-slab ytterbium-doped yttrium aluminum garnet laser system, Bivoj/DiPOLE, using a type-I phase matched lithium triborate crystal. We achieved conversion to 515 nm with energy of 95 J at repetition rate of 10 Hz and conversion efficiency of 79%. High conversion efficiency was achieved due to successful depolarization compensation of the fundamental input beam.

Features of noncollinear second harmonic generation by infrared laser pulses with opposite frequency chirps

The features of noncollinear second harmonic generation during the interaction of broadband laser pulses with opposite frequency chirps are considered. The impact of spectral phase mismatch of the interacting pulses on spectrum width and the efficiency of conversion to the noncollinear second harmonic is analyzed on an example of lithium triborate and beta-barium borate crystals.

Low-noise and high-power second harmonic generation of 532nm laser for trapping ultracold atoms.

Optical lattices for coherently manipulating ultracold atoms demand high-power, low-noise, narrow-line-width, and continuous-wave lasers. Here, we report the implementation of a 30W 532nm low-noise laser by second harmonic generation from a 1064nm fiber laser, which is capable to generate optical lattices for a quantum gas microscope of Rb87 atoms. The overall conversion efficiency is 59% at an input power of 51W with a lithium triborate crystal coupled to a ring cavity. The relative intensity noise of the output laser is suppressed to -120dBc/Hz in the range of 10Hz-100kHz with a high dynamic range of over 50dB, which is suitable for long-term trapping and coherent manipulation of the quantum gases.

Noncollinear frequency mixing and fourth-harmonic generation of oppositely chirped laser pulses

Highly efficient fourth-harmonic generation of 60 µJ, 25 ps chirped (compressible down to 340 fs FWHM) Yb:KGW laser pulses was demonstrated experimentally utilizing noncollinear opposite chirp frequency mixing in Type I beta-barium borate (BBO) and lithium triborate (LBO) crystals as second-harmonic generators followed by collinear frequency doubling in another BBO crystal as a fourth-harmonic generator. Second-harmonic spectral narrowing by a factor over 100 and output UV pulse energy of 10 µJ were achieved.

High power picosecond green and deep ultraviolet generations with an all-fiberized MOPA.

We demonstrate high power picosecond green and deep ultraviolet (DUV) lasers based on an all-fiberized master oscillator power amplifier (MOPA). The main power amplifier is fabricated with a highly Yb-doped large mode area (LMA) silicate glass fiber. It delivers 75.2-W laser output at 1029 nm with a pulse repetition rate of 10 MHz and a pulse duration of 70 ps. With a lithium triborate (LBO) crystal, a 43.0-W green output at 514.5 nm has been achieved with a pulse duration of 55 ps. With a caesium lithium borate (CLBO) crystal, a 14.5-W picosecond DUV output at 257 nm has been generated, which is the highest power for the all-fiber based DUV laser, to the best of our knowledge.

Power and energy scaling of an acousto-optically Q switched Raman deep-red laser.

An efficient high-power nanosecond pulsed deep-red laser at 745 nm is produced by intracavity frequency-doubling an acousto-optically Q switched Nd:YLF/KGW Raman laser using a lithium triborate (LBO) crystal. The critically phase-matched type-I LBO crystal with an optimized length of 25 mm is adopted to enable efficient second-harmonic generation and to suppress unwanted cascaded Stokes fields. Under a repetition rate of 4 kHz, the maximum average output power of 4.1 W is obtained with the launched pump power of 50 W, resulting in an overall optical power conversion efficiency of 8.2%. The average beam quality factor is determined to be M2 = 1.46. The pulse energy is scaled up to 3.3 mJ at the repetition rate of 1 kHz, corresponding to a pulse width of 4.2 ns and a peak power of up to 0.8 MW. Moreover, we theoretically investigate the dependence of the conversion efficiency on the walk-off angle as well as the fundamental and first-Stokes losses, which will guide further optimization of experimental devices.

Pulse temporal scaling of LIDT for anti-reflective coatings deposited on lithium triborate crystals.

Anti-reflective (AR) coatings minimize photon losses of optics when it comes to the transmission of light, thus, are broadly used for imaging and laser applications. However, the maximum output power in high-power lasers is limited by the so-called laser-induced damage threshold (LIDT) parameter of optical elements. Often AR coated nonlinear crystals are responsible for such limitations, however, LIDT data is rather scarce. Thus, only limited understanding about LIDT pulse temporal scaling laws for AR coatings exists, which also lacks the specificity about fatigue effect of distinct failure modes. To expand the present knowledge four identical lithium triborate (LBO) crystals were prepared. Each crystal had one side coated with the AR@1064+532 nm coating and the opposite side coated with the AR@355 nm coating. Multiple LIDT tests were then conducted following 1-on-1 and S-on-1 testing protocols at UV and IR wavelengths while varying laser pulse duration. Empirical scaling laws are then investigated for different failure modes and later interpreted using a numerical model.

Generation of 12 W 257 nm laser pulses by sum-frequency generation based on LBO crystals

We have generated high-power deep ultraviolet laser pulses from a Yb-doped rod-type fiber laser through sum-frequency generation (SFG) based on lithium triborate (LBO) crystals. The 1030 nm nanosecond laser pulses from the fiber laser are frequency-tripled to 343 nm pulses with two LBO crystals, and the residual 1030 nm fundamental laser pulses are mixed with the 343 nm pulses in an LBO crystal for the generation of 257 nm pulses. The maximum 257 nm radiation power is 12 W with a repetition rate of 500 kHz, and the conversion efficiency from 1030 nm to 257 nm is 12%. It is observed that the power of 257 nm radiation is limited by the temperature increase in the LBO crystal used for the SFG.

Nonlinear waveguides by femtosecond laser writing of lithium triborate crystals

Nonlinear optical waveguides play a crucial role in the wavelength/frequency conversion of light. Femtosecond laser direct writing is an efficient and flexible technique to produce waveguides in dielectrics. We report on the nonlinear waveguides in LiB3O5 crystals by femtosecond laser writing. The double-line and depressed-cladding structures inscribed by femtosecond laser pulses show excellent guiding properties at 405 nm or 810 nm for both TE and TM polarized light. The investigations of the confocal micro-Raman spectroscopy have indicated that lattice structures in waveguide cores remain almost unchanged compared with those of the bulk. Based on type-I phase matching condition, both second harmonic generation of 810 nm and spontaneous parametric down conversion of 405 nm have been obtained in the laser-written lithium triborate waveguides, suggesting potential applications in integrated nonlinear optics and quantum photonics.