Lithification Process Research Articles

Stone Babies: A Pictorial Essay With Insights From 25 Museal Lithopaedions.

Lithopaedion, or "stone baby," represents an exceptionally rare clinical phenomenon with fewer than 350 documented cases existing in the medical literature. This condition arises when an advanced extrauterine pregnancy ceases its developmental trajectory and undergoes a lithification process, potentially resulting in a calcified mass with fetal-like morphology. Typically, lithopaedions remain asymptomatic for decades, but may occasionally elicit acute symptoms necessitating medical intervention. However, predominantly, these entities are incidental findings discovered during radiological examinations or autopsies. In this article, we present a comprehensive overview of 25 lithopaedion cases, including unreported cases from several European medical museums. When feasible, additional radiological imaging was conducted to enhance diagnostic clarity. Furthermore, this article situates lithopaedions within a broader historical perspective and a detailed etiopathogenetic framework, elucidating the physiological and pathological mechanisms contributing to their formation. The phenomenon of lithopaedion is a testimony to the complex and often enigmatic nature of the human body. By compiling and scrutinizing a substantial number of cases, this review offers valuable insights into the clinical implications of lithopaedions. Furthermore, it highlights the necessity for ongoing research and meticulous documentation of rare medical conditions like this, in order to contribute to a deeper understanding of extraordinary phenomena.

Insight into the 2021 Semeru volcano eruption from rapid monitoring of its pyroclastic deposits using Google Earth Engine and multi-sensor data

The objective of this study is to map the pyroclastic deposits resulting from the Semeru eruption in 2021 and to analyse the process of pyroclastic deposit formation, including the tephra and lithification phases, using multi-sensor data. The distribution of pyroclastic deposits was mapped using machine learning algorithms, Sentinel 2 and Sentinel 1 imagery on Google Earth Engine. Data acquisition in the Semeru volcano area was conducted both prior to and following the 2021 eruption. Additionally, field investigations were conducted to analyse the distribution of pyroclastic deposits, including the characteristics of individual layers, the lithification process of pyroclastic layers, and their relationship with the characteristics of the eruption. The results demonstrate that pyroclastic deposits in the proximal facies are composed of lithic, lapilli tuff, lava and tuff. The mapping results also indicate the presence of volcanic ash deposits in the central facies or summit area of Semeru, exhibiting distinctive characteristics associated with volcanic ash. The 2021 eruption has also resulted in rapid changes to river morphometry, as evidenced by notable shifts in a significant decrease in pixel values for NDVI (−0.0781-0.0625), a significant increase in pixel frequency of EVI (1800–6000), and MNDWI (1700–3000), respectively. The change of pyroclastic fall into consolidated tephra occurred from December 2021 to May 2023, where in May 2023 volcanic ash had changed into tuff and lapilli had changed into lapilli tuff. Furthermore, data from Sentinel-1 indicated that pyroclastic flows could be identified using both vertical and horizontal polarization. It can therefore be concluded that the 2021 eruption of Semeru exhibited distinctive characteristics of pyroclastic deposits, where some of the characteristics of the pyroclastic distribution can be monitored rapidly with Google Earth Engine. Therefore, the use of Google Earth Engine with integration of radar and optical data can be recommended to mapping pyroclastic deposits rapidly.

The lithologic diversity of the Moon recorded in lunar meteorites Northwest Africa 7611 and 10480

AbstractNorthwest Africa (NWA) 7611/10480 are lunar regolith breccia meteorites, composed of mineral fragments and various clasts including mare basalts, volcanic glasses, gabbroic lithologies, and a diverse variety of highland materials (ferroan anorthosite, Mg‐suite, magnesian anorthosite, and alkali suite rocks) as well as different subvarieties of impact melt breccia. The Apollo two‐component mixing model calculation reveals that the NWA 7611 source region contains 58 wt% mare materials and 42 wt% highland components, but the estimated mare components in NWA 10480 have a higher abundance (66 wt%). The predominantly very low‐Ti (VLT) composition in both fine‐grained basaltic and coarse‐grained gabbroic lithologies indicates a provenance associated with a thick lava flow or a single magmatic system. The co‐occurrence of zoning patterns and fine‐scale exsolution lamellae in pyroxene debris supports a cryptomare deposit as the best candidate source. Phosphate Pb–Pb ages in matrix fragments, impact melt breccia, and basaltic clast indicate that the breccia NWA 7611 records geological events spanning approximately 4305–3769 Ma, which is consistent with the ages of ancient lunar VLT volcanism and the products of basin‐forming impacts on the lunar nearside. The youngest reset age at ~3.2 Ga is potentially related to the strong shock lithification process of breccia NWA 7611. Moreover, the similar petrology, texture, geochemistry, cosmic‐ray exposure data, and crystallization ages support that basaltic component in Yamato (Y)‐793274, and Queen Alexandra Range (QUE) 94281, NWA 4884, and NWA 7611 clan came from the same basalt flow.

Electro-cementation of calcareous sand using colloidal silica (CS) nanoparticles and alumina powder

The research investigates the effectiveness of a ground improvement technique that involves the electro-cementation of an onshore calcareous sand containing 95.3% calcium carbonate through a series of laboratory experiments. Colloidal silica (CS) nanoparticles and alumina powder were introduced as pozzolanic materials in the sand, and a direct current (DC) was passed through the sand-silica-alumina mix inside an electrokinetic (EK) cell. The method resulted in the electro-cementation of the calcareous sand through the formation of calcium silicate hydrates (C–S–Hs) and calcium aluminate hydrates (C–A–Hs) as products of the pozzolanic reactions between Ca(OH)2, SiO2 and Al2O3 after electrolysis occurred. Iron-rich cements were also formed by the degradation of anodes. These newly formed compounds changed the nature of the treated soil from a granular material into a rock. Results show that the compressive strength of the resulting rock formation is significantly improved. The treatment can be considered as an artificial lithification process through which the nature of the treated soil was changed from a granular material into a rock formation. The electro-cementation achieved by the treatment was further assessed by spectroscopic analyses including FE-SEM, EDX and XRD, which confirmed the formation of cementing agents within the structure of the treated sand. Potential applications of the technique include caissons, highway construction projects, dune fixation and erosion control, in addition to liquefaction mitigation due to electrolysis of pore water and plugging the pores with cementitious materials.

Lava – substrate interaction: Constraints on flow emplacement and basal sintering, Lebuj rhyolitic flow, Tokaj Mountains, Carpathian-Pannonian region

The surface extrusion of rhyolite lava is linked with a complex edifice morphology and texturally diverse internal structure. The rarely exposed basal flow/dome zones provide a textural record of the mechanical and thermal stress between the overlying lava and existing topography. The Lebuj flow (Tokaj Mountains, Hungary) developed in a Miocene caldera setting, where the erosion exposed its basal zone, including various textures due to the lava substrate interaction. The flow margin is contacted with underlying volcaniclastics along a steeply inclined (50–75°) plane. The lithology describes a complex ductile-brittle transition in the flow and lithification process in the substrate. The relict obsidian grains (marekanite, 0.1% H2O) in the perlite (2–3% H2O) are proof of an incomplete hydration process below the glass transition temperature. The dynamic loading of the lava caused irregular fragmentation developing a brittle basal shear zone with lens-like glass deformation. The substrate has suffered syn-emplacement lithification and the primary glass structure is completely re-crystallized. FTIR and Raman measurements identified low-temperature phyllosilicate minerals and SiO2 polymorphs, which caused additional porosity loss and densification. Using cooling time-temperature-porosity information given by this reconstruction, we suggest parallel-acting processes at elevated (groundmass crystallization-devitrification) and lower temperature (hydration-secondary mineralization) range. These define a relative timescale for the textural development in the lithologically heterogeneous contact zone.

Controls on the Stratiform Copper Mineralization in the Western Syncline, Upper Peninsula, Michigan

The Western Syncline hosts reduced-facies, or Kupferschiefer-type, sedimentary rock-hosted stratiform Cu deposits (SSC) in the lowermost meters of the Nonesuch Formation, which is part of a thick section of clastic sedimentary rocks that comprise the upper fill of the Mesoproterozoic Midcontinent Rift of North America. Located in the Porcupine Mountains Cu district in Upper Peninsula, Michigan, these blind deposits were discovered in 1956, but are not yet developed, although recent renewed interest may result in near-term production. The deposits are distinguished by their relatively undeformed nature and lack of superposed hydrothermal events. Prior to lithification, chalcocite mineralization replaced diagenetic pyrite within two discrete tabular, albeit discontinuous, potential orebodies referred to as the lower Cu-bearing sequence (LCBS) and the upper Cu-bearing sequence (UCBS). The Top Cu Zone transgresses lithologic boundaries, suggesting that a limited volume of Cu-bearing fluids moved vertically upwards through the unlithified stratigraphy, since reductant pyritic rocks above this zone are essentially barren of Cu. The total Cu inventory that has a reasonable expectation of economic extraction is 3678 M lbs. of Cu with 15.3 M oz. of byproduct Ag. When a cutoff grade of 0.9% Cu over a minimum thickness of 2 m is applied to justify an underground room-and-pillar mine, the LCBS and UCBS are not continuous over the Western Syncline. Sedimentology is the first-order control of potential ore and its continuity; dark-gray shales and siltstones deposited under low-energy, anoxic conditions are preferred host rocks, whose thickness must be >2 m to be potential ore since host-rock thickness determines economic viability of extraction. Furthermore, stratigraphy influences the time constraints on mineralization as the lithification process impedes vertical permeability and thus the flow of Cu-bearing fluids upward through the unlithified section. Syn-sedimentary tectonic movements, likely along pre-existing buried faults, are a third-order control as the thickness of host rocks is enhanced under such conditions. Therefore, an understanding of the depositional and tectonic history throughout the Western Syncline is fundamental to understanding the limits of possible economic exploitation and to optimizing ore extraction.

The role of methane seepage in the formation of the Northern Adriatic Sea geosites

The northern Adriatic Sea hosts patches of rock formations that have given rise to large biodiversity not otherwise found on the predominantly sandy and flat seabed. Various hypotheses have been invoked concerning the origin of these features, which are widespread in the northern Adriatic Sea and have been intensively studied since the eighteenth century. Here, we provide a significant advancement of knowledge in the lithification process associated with these peculiar rock formations. This study is based on geological, geophysical and mineralogical analyses performed on 45 rock outcrops identified in the study area. A key result of our analysis is the reconciliation of the different models related to the genesis of the northern Adriatic Sea outcrops, i.e., Holocene beach rocks that typically formed in the intertidal zone; cementation of paleo-channel systems, implying a groundwater influence; and methane-derived carbonates. Regardless of the depositional environment, we highlight the relationship between sediments and the processes that led to their evolution into the sandstone formation. We suggest that a common cementation process occurred in the various sedimentary deposits that are representative of different environments of the northern Adriatic Sea and was related to the post depositional precipitation of methane-derived carbonates. Our findings highlight the potential key role of widespread methane seepage from very shallow marine environments into the water column and then, eventually, into the atmosphere as a potential source of an increasing greenhouse gas.

Multiple Types of Porosity – P‐Wave Velocity Relationships for the Nankai Trough

The empirical relationship between the porosity and P-wave velocity is a useful tool for probing large-scale underground physical properties and stress states based on P-wave velocity structures acquired by seismic surveys. In this study, the porosity-velocity curves were examined using local core sample and logging datasets acquired along the Kumano transect in the Nankai Trough, Southwest Japan. We tested Hashimoto et al.’s (2010) hypothesis that slope apron and accreted sediments have different relationships. Our advantage is using a large amount of logging and core data obtained at multiple sites in the Nankai Trough under various geological conditions, from the incoming oceanic plate to the inner wedge. We identified multiple types of porosity – P-wave velocity relationships: 1) The first type agrees with the low-velocity model in the global empirical relation of Erickson and Jarrard 1998), which is observed at lithostatic stress state condition (incoming upper Shikoku basin and slope sediments), 2) The second type consistent with high-velocity models of the global empirical relation observed at compressive stress state condition (accreted sediments), which have a higher velocity and larger dependence on the porosity than the first type with the same porosity, and 3) The third type for incoming sediments with high smectite content has lower velocity than the first type. Based on our results, the transition between the first and second porosity – velocity relationships occurs in the prism toe, implying that compressive stress due to subduction controls acoustic properties and the lithification process of these sediments.

Timescales of speleogenesis in an evolving syngenetic karst: The Tamala Limestone,Western Australia

The Tamala Limestone, a vast Quaternary carbonate sequence exposed on the coast of Western Australia, forms one of the most geographically-extensive deposits of carbonate aeolianite in the world. It is also considered an excellent example of so-called ‘syngenetic karstification’, where the processes of lithification and karst development occur in close temporal association. Speleothems, hosted in caves throughout the region, provide an opportunity to explore the timescales of speleogenesis in such a young karst environment. A compilation of existing limestone ages suggests that the unit has been forming since at least 800 ka, mediated by glacial-interglacial cyclicity and with older units identified in the extreme south. We present 225 new U-Th and U-Pb age determinations on speleothem ‘rubble’ — providing minimum ages for cave formation — which reveal that speleogenesis has also occurred throughout the region for at least the last 200 kyr. Speleothems from Jewel Cave, the oldest yet documented from the region, extend far beyond the range of the U-Th chronometer, with U-Pb dating revealing a distinct early phase of cave formation extending from around 2 Ma. These data confirm previous suggestions that extensive karstification can occur rapidly, within a few tens to hundreds of thousands of years after limestone formation, but also reveal that initial deposition of the Tamala Limestone units began much earlier than previously suspected.

Chemostratigraphic and Textural Indicators of Nucleation and Growth of Polymetallic Nodules from the Clarion-Clipperton Fracture Zone (IOM Claim Area)

The detailed mineralogical and microgeochemical characteristics of polymetallic nodules collected from the Interoceanmetal Joint Organization (IOM, Szczecin, Poland) claim area, Eastern Clarion-Clipperton Fracture Zone (CCFZ, Eastern Pacific) were described in this study. The obtained data were applied for the delimitation of nodule growth generations and estimation of the growth ratios (back-stripping using the Co-chronometer method). The applied methods included bulk X-ray powder diffraction (XRD) and electron probe microanalysis (EPMA), providing information about Mn-Fe minerals and clays composing nodules, as well as the geochemical zonation of the growth generations. The analyzed nodules were mostly diagenetic (Mn/Fe > 5), with less influence on the hydrogenous processes, dominated by the presence of 10-Å phyllomanganates represented by todorokite/buserite, additionally mixed with birnessite and vernadite. The specific lithotype (intranodulith), being an integral part of polymetallic nodules, developed as a result of the secondary diagenetic processes of lithification and the cementation of Fe-rich clays (potentially nontronite and Fe-rich smectite), barite, zeolites (Na-phillipsite), bioapatite, biogenic remnants, and detrital material, occurs in holes, microcaverns, and open fractures in between ore colloforms. The contents of ∑(Ni, Cu, and Co) varied from 1.54 to 3.06 wt %. Several remnants of siliceous microorganisms (radiolarians and diatoms) were found to form pseudomorphs. The applied Co-chronometer method indicated that the nodules’ age is mainly Middle Pliocene to Middle Pleistocene, and the growth rates are typical of diagenetic and mixed hydrogenetic–diagenetic (HD) processes. Additionally, few nodules showed suboxic conditions of nucleation. Growth processes in the eastern part of the CCFZ deposit might have been induced with the Plio-Pleistocene changes in the paleooceanographic conditions related to the deglaciation of the Northern Hemisphere.

The Effects of 180 years of Aging on the Physical and Seismic Properties of Partially Saturated Sands

AbstractConstraining how the physical properties and seismic responses of recently deposited sands change with time is important for understanding earthquake site response, subsurface fluid flow, and early stages of lithification. Currently, however, there is no detailed (cm‐scale) assessment of how sand's physical properties and associated seismic velocities evolve over the first two centuries after deposition. Here, we integrate sedimentation rates with seismic velocity and sediment physical properties data to assess how the vadose zone sands at Port Royal Beach, Jamaica, change within 180 years after deposition. We show that compressional and shear wave velocities increase with sediment age, whereas porosity, grain size, sorting, mineralogy, and cementation fraction remain relatively unchanged during the same period. Rock physics models (constrained by the measured physical properties) predict constant seismic velocities at all sites regardless of sediment age, though misfits between modeled and observed velocities increase with sediment age. We explain these misfits by proposing that shallow sands undergo microstructural grain reorganization that leads to a more uniform distribution of grain contact forces with time. Our results imply that beach sands undergo a previously undocumented lithification process that occurs before compaction.

Diagenesis and genesis of clay minerals in the Triassic sandstones of the Panchet and Parsora formations, Damodar–Son Basin, India

The Triassic sandstones of the Panchet and Parsora formations are deposited in the Damodar and Son basins of the Peninsular India. Though both the formations have similarity in depositional and lithification processes, their diagenetic history and authigenic clay minerals formation have little differences. To improve understanding of diagenesis and associated clay minerals, the present study examined in Triassic sandstones. The Lower Triassic Panchet sandstones are poorly sorted arkose and originate from nearby granitoid terrain. The early diagenetic assemblages of the sandstones are kaolinite–iron oxide, montmorillonite, quartz and cement in the sandstones formed in oxy-acidic environment under shallow burial condition. Authigenic chlorite and recrystallised interstitial components such as orthomatrix are the main late diagenetic products formed, respectively, at oxy-acidic and reducing alkaline conditions where carbonate and allogenic iron cements were emplaced as the latest events. The Panchet and the Parsora formations are the riverine Triassic deposits and have almost identical early diagenetic assemblages. The kaolinisation in sandstone is loss of feldspar and is more pronounced in the Parsora Formation. The late diagenetic products in both the formations essentially similar and differ only in their relative chlorite content, which was formed under elevated temperature as an effect of tectonic activity. Allogenic iron and carbonate cements are post-tectonic.

Velocity-weakening friction induced by laboratory-controlled lithification

Regarding the occurrence of seismicity on major plate-boundary fault zones, one leading hypothesis is that the processes of lithification is responsible transforming loose, unconsolidated sediment that does not host earthquake nucleation into the frictionally unstable rocks that inhabit the seismogenic zone. Previous laboratory studies comparing the frictional properties of intact rocks and powdered versions of the same rocks generally support this hypothesis. However, systematically quantifying frictional behavior as a function of lithification remains a challenge. Here, we simulate the lithification process in the laboratory by consolidating mixtures of halite and shale powders with halite-saturated brine, which we then desiccate. The desiccation allows precipitation of halite as cement, creating synthetic rocks. We quantify lithification by: (1) direct measurement of cohesion, and (2) measuring the porosity reduction of lithified samples compared to powders. We observe that powdered samples of each halite-shale proportion exhibit predominantly velocity-strengthening friction, whereas lithified samples exhibit a combination of velocity strengthening and significant velocity weakening when halite constitutes at least 30 wt% of the sample. Analysis of the individual rate-dependent friction parameters shows that the occurrence of velocity weakening is due to relatively low values of a for lithified samples. Larger velocity weakening is associated with cohesion of >∼1 MPa, and porosity reduction of >∼50 vol%. Microstructural images reveal that the shear surfaces for powders tend to exhibit small cracks not seen on the lithified sample shear surfaces. Our results suggest that lithification via cementation and porosity loss can facilitate slip instability, supporting the lithification hypothesis for seismogenic slip.

Lack of synsedimentary chemical alteration in polar carbonates (Ross Sea, Antarctica): Resolution of a conundrum

ABSTRACTAlthough rare in space and time, skeletal carbonates deposited on polar shelves hold great potential for improving understanding of the oceanography of the high latitudes. Low temperatures, low carbonate saturation states, and strong seasonality govern not only the nature of carbonate communities, but also how their deposits translate into the rock record. To understand the effects of early seafloor processes on preservation, we investigated late Quaternary carbonates recovered in piston cores from the Ross Sea, Antarctica. Sediments are unconsolidated skeletal gravels and sands that mantle areas of the outer shelf swept by strong bottom currents. Deposits are dominated locally by either stylasterine hydrocorals, barnacles, or bryozoans, which comprise assemblages with strong similarities to modern benthic communities. Radiocarbon ages indicate that carbonate factories were most prolific during the lead-up to the Last Glacial Maximum (Tartanian), when sediment input was minimized, and have been mostly dormant since. Results show that synsedimentary alteration is not substantially different in the temperate and polar realms with the significant exception of chemical diagenesis. As is common in temperate deposits, skeletal grains undergo disarticulation, fracturing, abrasion, and intense bioerosion. By contrast, cementation is absent and rare aragonite grains are preserved, indicating that taphonomic loss is not as prevalent as in temperate deposits. Primary skeletal microstructures and stable-isotope compositions are preserved, indicating that chemical alteration of grains is negligible. The preservation of aragonite in polar settings is herein attributed to low rates of organic-matter burial and very low temperatures, which strongly limit microbial activity. These factors allow interstitial waters to remain weakly supersaturated with respect to aragonite. Comparison with Permian analogs indicates that lithification is delayed until deposits reach burial depths at which chemical compaction proceeds. The ultimate end product is limestone with prominent compaction features and a tightly packed fabric. Calcitic skeletal material can retain primary geochemical compositions through the lithification process, although growth of burial cement in intraparticle porosity complicates selective sampling of unaltered material. In providing a cold-water end member for the spectrum of synsedimentary diagenetic processes, results highlight specific differences that should be accounted for when interpreting the deposits of polar, cold-water carbonate systems.

Evidences of seismic events during the sedimentation of Sete Lagoas Formation (Bambuí Group – Ediacaran, Brazil)

The Sete Lagoas Formation (Ediacaran), located in the central part of the São Francisco Craton (Brazil), consists of limestones and dolostones deposited in very shallow waters in the inner part of the carbonate platform. Four breccia types occur throughout the stratigraphic succession: evaporitic breccia with tepees, flat-pebble breccia, hydrothermal breccia and brecciated stromatolites. Here we combine a detailed sedimentological and stratigraphic analyses of the flat-pebble breccia in order to determine its origin and the processes and environmental conditions that originated these brecciated facies. The studied interval consists of a 20 m thick succession of tabular beds composed of flat-pebble breccia interbedded with laminated microbialites. In these breccia beds, the clasts are usually platy or oblate with angular edges and are mainly disposed horizontally within the sedimentary bed, suggesting that they were not transported or reworked. The presence of microbialite clasts with sharp edges and vertices in the Sete Lagoas flat-pebble breccia suggests that the lithification process started very early in diagenesis and, even the sediments exposed at the bottom were, at least, partially lithified. Some breccia levels show bidirectional imbrication and clast size analyses reveal a NE-SW long-axis clast orientation whereas square clasts tend to fill the space among oriented clasts. Breccia clasts are vertically oriented and show deformation features increasing upwards, typically of deforming beds formed by ascendant expulsion of liquefied sediment. Disrupted layers or presenting folds and synsedimentary faults commonly occur confined between undeformed beds. Other evidences of liquefaction and soft-sediment deformation are the injection structures, as flame and load cast-like features, in the base of the brecciated beds. These structures commonly penetrate the upper bed and disrupt the sedimentary layer immediately above promoting local brecciation. These features are found both in modern and ancient deposits of seismic influence, which suggests a similar origin for the Sete Lagoas flat-pebble breccia. Thus, the processes that led to the formation of the studied flat-pebble breccia are interpreted as seismically triggered, since: a) the breccia beds are laterally continuous and extend for several kilometers; b) the breccia beds are restricted to a 20 m thick stratigraphic interval; c) the clasts of the breccia are the same lithology of non-deformed beds below and above the interval of breccia; d) the interbedding of breccia beds and laminated microbialite beds is recurrent; e) the breccia beds are subhorizontal and present irregular upper and lower contacts; f) the presence of liquefaction structures and dyke injection. Thus, this seismic-triggered breccia deposits represent the product of the synsedimentary tectonism occurred within the São Francisco Craton during the terminal Ediacaran and correspond to a very well-defined local stratigraphic marker in the Bambuí Basin. The seismic activities could be related to the NW regional faults in the regional Paleoproterozoic basement of the study area, which were reactivated during the deposition of the Sete Lagoas Formation in the Ediacaran Period.

Sulfate-Reducing Bacteria That Produce Exopolymers Thrive in the Calcifying Zone of a Hypersaline Cyanobacterial Mat.

Calcifying microbial mats in hypersaline environments are important model systems for the study of the earliest ecosystems on Earth that started to appear more than three billion years ago and have been preserved in the fossil record as laminated lithified structures known as stromatolites. It is believed that sulfate-reducing bacteria play a pivotal role in the lithification process by increasing the saturation index of calcium minerals within the mat. Strain L21-Syr-ABT was isolated from anoxic samples of a several centimeters-thick microbialite-forming cyanobacterial mat of a hypersaline lake on the Kiritimati Atoll (Kiribati, Central Pacific). The novel isolate was assigned to the family Desulfovibrionaceae within the Deltaproteobacteria. Available 16S rRNA-based population surveys obtained from discrete layers of the mat indicate that the occurrence of a species-level clade represented by strain L21-Syr-ABT is restricted to a specific layer of the suboxic zone, which is characterized by the presence of aragonitic spherulites. To elucidate a possible function of this sulfate-reducing bacterium in the mineral formation within the mat a comprehensive phenotypic characterization was combined with the results of a comparative genome analysis. Among the determined traits of strain L21-Syr-ABT, several features were identified that could play a role in the precipitation of calcium carbonate: (i) the potential deacetylation of polysaccharides and consumption of substrates such as lactate and sulfate could mobilize free calcium; (ii) under conditions that favor the utilization of formate and hydrogen, the alkalinity engine within the mat is stimulated, thereby increasing the availability of carbonate; (iii) the production of extracellular polysaccharides could provide nucleation sites for calcium mineralization. In addition, our data suggest the proposal of the novel species and genus Desulfohalovibrio reitneri represented by the type strain L21-Syr-ABT (=DSM 26903T = JCM 18662T).

From supratidal to subtidal, an integrated characterisation of Carbla Beach shallow microbial mats (Hamelin Pool, Shark Bay, WA): Lipid biomarkers, stable carbon isotopes and microfabrics

Modern microbial mats from Shark Bay are commonly regarded as robust analogues for Precambrian stromatolites. These microbial mats are complex ecosystems that exhibit intense biogeochemical recycling. In this study, a multi-proxy approach (including lipids, compound-specific carbon isotope analysis and petrography) is used to characterise microbial communities in three different types of mats (tufted, pustular and smooth) along the shallowest section of a tidal flat gradient. Cyanobacterial lipids were present in all three mats. Petrographical (optical and scanning electron microscopy) investigations also revealed that ooids in the tufted mat were larger and more common compared to the pustular and smooth mats. Biomarkers specific to sulfate reducing bacteria were detected in all mats. The diatom-specific C25:1 highly branched isoprenoid (HBI) alkene was most abundant in the smooth mat. However, imaging revealed that the smooth mat only contained rare diatoms of small size (~10 μm), whereas the pustular mat contained a variety of larger diatoms (~50 μm). The C25:1 HBI alkene marker is only produced by four diatom genera, which were most likely more represented in the smooth mat. Additionally, the smooth mat contained a greater contribution from aquatic macrophytes (Paq = 0.38) compared to the shallower mats, which is corroborated by the presence of 13C-enriched seagrass lipids (i.e. C29 steradiene). In all the mats, a major eukaryotic contribution was revealed via imaging techniques and supported by a high sterol content. This eukaryotic component (e.g. benthic foraminifera, diatoms) can impact the cohesive structure of the mats, the lithification processes and the lipid distribution, potentially complicating comparisons with Precambrian microbialites that were not affected by eukaryotic activity. This study reemphasizes the complexity of microbial ecosystems, and therefore highlights the benefit of multi-proxy approaches to characterise these biological systems.

GEOMETRI PERLAPISAN BATUPASIR KONGLOMERATAN SEBAGAI SISIPAN PADA FORMASI NANGGULAN DI KALI WATUPURU DAN KALI SONGGO, PEGUNUNGAN KULON PROGO, YOGYAKARTA

Nanggulan Conglomeratic Sandstone is one of important part of Nanggulan Formation which is deposited during Middle Eocene to early Late Eocene (Saputra & Akmaluddin, 2015) or Late Oligocene (Rahardjo, 1995). The grain composition of Nanggulan conglomeratic sandstone is characterized by various rock fragments (metamorphic, igneous, sedimentary rocks) which mixture up to fine to coarse sand-sized matrix. Other materials present within the Nanggulan conglomerathic sandstone are shell fragments, coal remains, siderithic concretions which is deposited within high energy condition. Geometry of conglomeratic sandstone stratification is still being a question among the researchers due to discontinuous sand body character. To study external form of sandstone body needs to combine with internal characters such are grain texture, grain or fragment composition, sedimentary structures to predict a depositional facies. This research is dedicated to study the character of the Nanggulan conglomeratic sand body. Field geological observation was conduct to two rivers i.e Kali Watupuru and Kali Songgo where transecting the Nanggulan beds. The grain or fragments concentration of Nanggulan conglomeratic sandstone displays in various condition for example lying above an erosional surface to the bottom position, or concentrate to the upper layer. It also appears to be engaged in coarser size matrix, or displays a dense grain composition to elsewhere. Geometry of the Nanggulan conglomeratic sandstone represents a lens geometry which pinching-out to the edge of body. However, to the top of lens geometry were found steep joints cross cutting the sand layers. Initial geometry of Nanggulan conglomeratic sandstone indicates a channel fill shape due to filling sediments into the erosional feature of underlying beds. When lithification and compaction process occurred along the burial and uplifting tectonic phase, a channel fill geometry becomes lens geometry. Bulging to the centre part and thinning to the edge of sandstone body, is caused by differential compaction process. Lens geometry is believed as one example of structural trap model for sandstone reservoir. The occurrences of vertical joints to the Nanggulan conglomeratic sandstone need to be considered as seal potential within clossure trap or even more causing hydrocarbon leakings. If development of vertical joint occurs along migration process, it may be potentially leak. However, if joints already sealed parts of hydrocarbon pool may create a compartmentalization reservoir body. By doing this investigation could predict an advance reservoir modelling study using outcropp analogues. Keyword: Nanggulan conglomeratic sandstone, lens geometry, sandstone body.

Petrographic and geochemical characterization of the early formative stages of Northern Adriatic shelf rocky buildups

A peculiar type of marine rocky outcrops is generated under temperate conditions through the cementation of carbonate and siliciclastic sediments on the northwestern Adriatic shelf. The lithification process results into the genesis of punctiform outcrops (tegnùe) that serve as substrate to substantial coralligenous epibenthic growth. These buildups have been often described as beachrock. More recently, an alternative genetic mechanism, implying precipitation of carbonate cements in the marine phreatic zone, has been hypothesized for the rocky outcrops off the coast of Chioggia (south of Venice). These rocky outcrops are settled along the levee of meandering channels inherited from Pleistocene fluvial systems.Petrographic analyses of the Chioggia rocky outcrops allowed distinguishing three (3) main lithofacies: 1) biofouled sandstone blocks; 2) cross-stratified slabs and 3) bioclastic carbonates. These lithofacies have a common substrate mainly made by allochemic sandstone and sandy allochem limestone consisting in rounded grains of limestones and dolostones. The host sediments are cemented by a thin micrite coating followed by isopachous rims of scalenohedral and bladed calcite. Geochemical analyses revealed a sensible decrease in Mg contents between the early and late generations of isopachous cements. Vadose cements are missing suggesting that the precipitation of calcite cements occurred in marine phreatic zone without supra-tidal exposure. The lack of aragonite cements suggests that seawater was mixing with meteoric groundwater. The mixing of groundwater induced a partial dissolution of high-Mg calcite and precipitation of a later stage low-Mg calcite.The lithification of the morphologies inherited from Pleistocene fluvial systems provided the nucleus for the development of the coralligenous buildups observed in the North Adriatic Sea shelf. It is possible that diagenetic processes, other than those normally responsible for the formation of beachrocks worldwide, have been active in the northern Adriatic Sea starting from the post-Last Glacial Maximum transgression. It is therefore likely that these processes are more relevant for the coralligenous epibenthic growth in temperate siliciclastic shelves than previously thought.

Relationships among physical properties as indicators of high temperature deformation or post-shock thermal annealing in ordinary chondrites

Collisions and attendant shock compaction must have been important for the accretion and lithification of planetesimals, including the parent bodies of chondrites, but the conditions under which these occurred are not well constrained. A simple model for the compaction of chondrites predicts that shock intensity as recorded by shock stage should be related to porosity and grain fabric. To test this model, we studied sixteen ordinary chondrites of different groups (H, L, LL) using X-ray computed microtomography (μCT) to measure porosity and metal fabric, ideal gas pycnometry and 3D laser scanning to determine porosity, and optical microscopy (OM) to determine shock stage. These included a subsample of six chondrites previously studied using transmission electron microscopy (TEM) to characterize microstructures in olivine. Combining with previous data, results support the simple model in general, but not for chondrites with low shock-porosity-foliation (low-SPF chondrites). These include Kernouvé (H6), Portales Valley (H6/7), Butsura (H6), Park (L6), GRO 85209 (L6), Estacado (H6), MIL 99301 (LL6), Spade (H6), and Queen’s Mercy (H6), among others. The data for these meteorites are best explained by high ambient heat during or after shock. Low-SPF chondrites tend to have older 40Ar/39Ar ages (∼4435–4526Ma) than other, non-low-SPF type 6 chondrites in this study. We conclude that the H, L, and LL asteroids all were shock-compacted at an early stage while warm, with collisions occurring during metamorphic heating of the parent bodies. Results ultimately bear on whether chondrite parent bodies have internal structures more akin to a metamorphosed onion shell or metamorphosed rubble pile, and on the nature of accretion and lithification processes for planetesimals.