Two-phase Liquid System Research Articles

Self-adaptive weighted physics-informed neural networks for inferring bubble motion in two-phase flow

Modeling complex fluid flow using machine learning is increasingly recognized as a valuable approach for revealing multiphase fluid phenomena. Bubble dynamics represent a classical two-phase flow problem that plays a crucial role in various engineering domains. In this paper, physics-informed neural networks (PINNs) are applied to facilitate incompressible two-phase bubble motion modeling by integrating governing equations and interface evolution equations. The loss function of PINNs consists of multiple loss terms, including initial and boundary conditions constraints, partial differential equations residuals, and volume fraction constraints. The performance of PINNs is influenced by the competing effects of these loss terms. Therefore, we introduce a heuristic adaptive weights approach to automatically adjust loss weights for each training point, avoiding manual tuning and improving the accuracy of PINNs. We investigate typical bubble motion cases, specifically focusing on bubble rising and breakup, to showcase the capabilities of the proposed method. We explore the impact of weights and present the results in comparison to the baselines. Through the bubble breakup case, we illustrate that our model shows superior performance even with more complex scenarios. Then we further discuss the generalization and robustness of our model, showing their indispensability over traditional solvers in gas–liquid two-phase systems. Specifically, we accelerate computation speed in transfer learning without the need to modify the original model. We also show that our method effectively solves ill-posed problems, such as those without initial data or with incomplete or noisy boundary conditions.

Phase behavior of aqueous two-phase systems formed with cholinium-based magnetic ionic liquids: Experimental insights and theoretical correlations

In this work, three cholinium-based MILs were synthesized, characterized and successfully applied to construct the magnetically responsive aqueous two-phase system (ATPs). This ATPs combined the advantages of ILs and magnetic responsiveness, and showed great potential in the field of extraction and separation. Phase behavior for the magnetic ionic liquid aqueous two-phase systems (MIL-ATPSs) containing [N 1 1n 2OH] [TEMPO-OSO3] + salts + water was investigated experimentally at different temperatures. Merchuk equation was adopted to fit the experimental binodal data with satisfactory correlation performances. The effects of the structure of MILs, temperature and types of salts on the phase behavior were evaluated. Investigation on the phase separation mechanism showed that the phase formation was affected by the structure and viscosity of MILs. The salting-out effect is recognized as the major force for phase separation, which is closely related to the Gibbs free energy of hydration (ΔhydG) and entropy of hydration (ΔhydS) of salts. In addition, a larger biphasic area was obtained by increasing the temperature, indicating the phase separation process was endothermic and entropically driven. The binodal curve at different temperature confirms that this MIL-ATPs has low critical solution temperature (LCST) phase transition behavior. All these experimentally measured data and the theoretical correlations can provide meaningful and valuable information that may promote further research and application.

Gas–Liquid Mixability Study in a Jet-Stirred Tank for Mineral Flotation

Micro- and nano-bubble jet stirring, as an emerging technology, shows great potential in complex mineral sorting. Flow field characteristics and structural parameters of the gas–liquid two-phase system can lead to uneven bubble distribution inside the reaction vessel. Gas–liquid mixing uniformity is crucial for evaluating stirring effects, as increasing the contact area enhances reaction efficiency. To improve flotation process efficiency and resource recovery, further investigation into flow field characteristics and structural optimization is necessary. The internal flow field of the jet-stirred tank was analyzed using computational fluid dynamics (CFDs) with the Eulerian multiphase flow model and the Renormalization Group (RNG) k − ε turbulence model. Various operating (feeding and aerating volumes) and structural parameters (nozzle direction, height, inner diameter, and radius ratio) were simulated. Dimensionless variance is a statistical metric used to assess gas–liquid mixing uniformity. The results indicated bubbles accumulated in the middle of the vessel, leading to uneven mixing. Lower velocities resulted in low gas volume fractions, while excessively high velocities increased differences between the center and near-wall regions. Optimal mixing uniformity was achieved with a circumferential nozzle direction, 80 mm height, 5.0 mm inner diameter, and 0.55 radius ratio.

Mechanism and rate of anomalous extraction of chloride salts from water to 1,2-dichloroethane

Open circuit potential (OCP) measurements, potentiostatic pulse (PP) amperometry and cyclic voltammetry (CV), were used to investigate and to sort by rate the anomalous extraction of the chloride salts RCl of the cations R+ = tetrabutylammonium (TBA+), tetrapentylammonium (TPeA+), tetrahexylammonium (THexA+), tetraheptylammonium (THepA+) and bis(triphenyl-phosphoranylidene)ammonium (BA+) from water to 1,2-dichloroethane (DCE). A tentative mechanism is proposed comprising (a) the diffusion-controlled transport of the ion-pairs (RCl)ip from the aqueous to the organic solvent phase providing a major contribution to the chloride extraction, (b) decomposition of the multiple ion-pairs or clusters (RCl)ipx, which are formed by agglomeration of the single ion-pairs (RCl)ip in the aqueous phase (w), and (c) the exponential decay of the ion-pairs (RCl)ip accumulated on the organic solvent side of the interface at the beginning of the OCP measurements. This model enables to simulate successfully the experimental time dependence of the chloride concentration. A conclusion is made that the effect of the composition of the organic solvent electrolyte RX, where X- = tetraphenylborate (TPB-) or tetrakis(pentafluorophenyl) borate (TB-), on the rate and extent of the anomalous accumulation of the chloride anion in the phase (o) of the two-phase liquid system LiCl(w)/RX(o) can be related to the hydrophobicity of the electrolytes RCl and RX. The latter property can be characterized by the standard Gibbs energy of transfer from the aqueous (w) to the organic solvent (o) phase. The accumulation of the chloride anion in the phase (o) appears to be promoted by the decreasing value of the transfer Gibbs energy of RCl in the sequence TBACl > TPeACl > THexACl > THepACl > BACl, while the decreasing value of the transfer Gibbs energy of RX in the sequence TBATPB > TPeATPB > THexATPB > THepATPB > BATPB > BATB starts to block the cycle combining the energetically unfavorable extraction of RX from the phase (o) to the phase (w) with the energetically favorable extraction of RCl in the opposite direction. IR spectroscopy provides evidence of the formation of the water clusters in the organic solvent phase equilibrated with the aqueous phase in the presence of the tetraalkylammonium cation in both phases, which are supposed to drive the anomalous accumulation of the chloride anion in the phase (o).

Simulating ion transfer across a liquid–liquid interface and electrocapillarity based on the electrochemical potential of all ions in the system

The liquid–liquid interface between two immiscible electrolyte solutions is an important subject in electrochemistry because ion-transfer reactions can be controlled externally. The electrochemical potentials of ions determine their behavior in a liquid–liquid two-phase system. The electrochemical potential is a continuous function of the system assuming a linear transition region at the interface. A simulation model that considers the electrochemical potential of all ions in the system was constructed for the liquid–liquid interface under electrochemical-measurement conditions. This model facilitates evaluating ion-transfer voltammograms affected by IR drops and separating charging currents from Faraday currents. Moreover, the model enables electrocapillary curves to be determined.

Effective separation of protein from Polygonatum cyrtonema crude polysaccharide utilizing ionic liquid tetrabutylammonium bromide.

Extraction of plant polysaccharides often results in a large amount of proteins, which is hard to eliminate from the crude extract, and conventional approaches for deproteinization are time-consuming and often involve hazardous organic solvents. In this study, ionic liquid tetrabutylammonium bromide (TBABr) was used to create an ionic liquid aqueous two-phase system (ILATPS) for the separation of the polysaccharide (PcP) and protein extracted from the rhizome of Polygonatum cyrtonema. Bovine serum albumin (BSA) was first applied to assess the feasibility of the ILATPS, and MgSO4 was determined to be the most suitable inorganic salt. By adopting the Taguchi experiment with an L9 (3^4) orthogonal array, it was found that the best condition for the efficient separation of crude PcP was at 25°C, with 1.5g of TBABr, 15mg of PcP, and 2.0g of MgSO4, with the extraction efficiency for the protein and polysaccharide as 98.6% and 93.5%, respectively. The purified PcP was homogeneous, and its weight average molecular weight (Mw) was 7,554Da. Monosaccharide composition analysis indicated the PcP comprised mannose, galactose, glucose, galacturonic acid, arabinose, and rhamnose at a molar ratio of 33:13:8:3.5:2:1. This approach offers a practical tactic to purify polysaccharides of plant origin.

ЕКІФАЗАЛЫ ЖҮЙЕЛЕРДЕГІ СҰЙЫҚ БӨЛШЕКТЕРІНІҢ ЕКІНШІ ТЕКТІ БҮРКІЛУІН МОДЕЛЬДЕУ БОЙЫНША ЕСЕПТЕУ ТӘЖІРИБЕЛЕРІ

Understanding the combustion of liquid fuels poses a complex challenge in thermal physics due to the interconnected nature of the various processes involved. It is becoming increasingly crucial to rely on computer-based experiments for understanding combustion and creating innovative burning-related devices. It may have increased importance in the role. In thermal physics, there is a growing trend toward utilizing computer-based techniques to study liquid fuels, offering the potential to enhance experiments through numerical simulations. This research involved conducting computerized experiments to understand the process of fuel combustion and the transformation into gas, focusing on the initial fragmentation and combustion stages. As a result of the computational experiments, the correlation between the temperature change of burning droplets, their size, and injection speed was investigated. Also, visual representations were created to demonstrate the dispersion of various fuel droplets in a combustion chamber. The obtained numerical calculations of the droplets' Sauter mean diameter distributions of 50 cm away from the nozzle of the injector were compared with experimental points, because of which the test demonstrated the accuracy of the numerical data for dodecane. The optimal combustion mode of octane and dodecane was established based on computer experiments to study the amount of fuel present and its temperature in a two-phase liquid system

VOF study of mesoscale bubble flow dynamics in the side-blown gas–liquid two-phase reactor

Understanding the flow and mixing characteristics of mesoscale bubbles within side-blown gas–liquid two-phase systems is paramount for the design and optimization of associated industrial processes. This study elucidates the gas–liquid side-blown two-phase reactor, employing the volume of fluid method coupled with the realizable k-ε turbulence model. Following the model validation through experimental measurements, the mesoscale bubble dynamics, flow characteristics, and multiscale coupling mechanisms inherent to side-blown gas–liquid reactor are explored. The key insights can be obtained: (1) the upward trajectory of bubbles originating from side-injection gas can be categorically divided into four phases with different bubble behaviors. (2) A reduction in the ratio of inertial forces to buoyancy forces during bubble ascent induces a decrease in the bubble shape factor. This transition manifests as a shift from vertical to flattened bubble shapes within the transition and plume regions. (3) Bubbles undergo transitions between states characterized by high buoyancy and low surface tension, accompanied by varying levels of viscous forces during their ascent. These dynamic states render bubbles susceptible to breakup. Under conditions of a constant nozzle diameter, the maximum bubble size within the reactor is inherently restricted. (4) Drawing upon the correlation between bubble Weber and Reynolds numbers, a predictive formula for determining the characteristic velocity of bubbles within side-blown reactors is proposed:uc=σ1-0.456(ρlLC)0.456512μl11.36Overall, this work offers meaningful insights into the fundamental mechanisms governing bubble cluster dynamics within side-blown gas–liquid reactors.

Ammonia Nitrogen Removal by Gas–Liquid Discharge Plasma: Investigating the Voltage Effect and Plasma Action Mechanisms

Atmospheric pressure gas–liquid discharge plasma has garnered considerable attention for its efficacy in wastewater contaminant removal. This study utilized atmospheric oxygen gas–liquid discharge plasma for the treatment of ammonia nitrogen wastewater. The effect of applied voltage on the treatment of ammonia nitrogen wastewater by gas–liquid discharge plasma was discussed, and the potential reaction mechanism was elucidated. As the applied voltage increased from 9 kV to 17 kV, the ammonia nitrogen removal efficiency rose from 49.45% to 99.04%, with an N2 selectivity of 87.72%. The mechanism of ammonia nitrogen degradation by gas–liquid discharge plasma under different applied voltages was deduced through electrical characteristic analysis, emission spectrum diagnosis, and further measurement of the concentration of active species in the gas–liquid two-phase system. The degradation of ammonia nitrogen by gas–liquid discharge plasma primarily relies on the generation of active species in the liquid phase after plasma–gas interactions, rather than direct plasma effects. Increasing the applied voltage leads to changes in discharge morphology, higher energy input, elevated electron excitation temperatures, enhanced collisions, a decrease in plasma electron density, and an increase in rotational temperatures. The change in the plasma state enhances the gas–liquid transfer process and increases the concentration of H2O2, O3, and, ⋅OH in the liquid phase. Ultimately, the efficient removal of ammonia nitrogen from wastewater is achieved.

Lubricity characteristics of edge and basal functionalized GO as PAO additives

It was studied that the dodecylamine was grafted to the edge (EGO) and basal (BGO) of graphene oxide by amidation and ring-opening reactions to study the effect of different reaction sites on the tribological properties of modified graphite oxide, respectively. The results showed that BGO and EGO were successfully synthesized by a controlled synthesis process. Dispersion experiments showed that GO was dispersed in water and BGO was dispersed in chloroform, while EGO formed a Pickering emulsion and showed amphiphilicity in the water/chloroform two-liquid phase system. Friction experiments showed that both additives improved the friction reduction of the base oil, while BGO showed a better one. The mechanism analysis showed that BGO and EGO participate in the tribochemical reaction, forming a dense carbon film and thus improving the tribological properties. It was also found that BGO and EGO participated in the cracking of base oil as tribocatalysts, which positively impacted the improvement of tribological properties.

An Investigation on the Removal of High Concentrations of PAHs Using Two-Liquid Phase System

Two-liquid phase systems consisting of two insoluble liquids can be effective in removing high concentrations of hydrocarbons from aqueous environments. In this study, the removal efficiencies of Naphthalene (Nap), Acenaphthene (Acn), Fluorene (Flu), Fluoranthene (Flr), Anthracene (Ant), and Pyrene (Pyr) at high concentrations in the two-liquid phase system were investigated. Two-liquid phase systems were constituted using Bis (2-Ethylhexyl) sebacate (BES) and aqueous fermentation media. Nutrient Broth (NB) and Bushnell Haas Yeast (BHY) medium were used as aqueous fermentation media. Acn, Flu, Flr, Ant, Pyr, and Nap were degraded at a rate of 93.1%, 80.8%, 57.6%, 68.5%, 63.8%, and 100%, respectively with BES/NB system. In the BES/BHY system, Acn, Flu, Flr, Ant, Pyr, and Nap, were degraded at a rate of 29.6%, 44.3%, 22.8%, 68.1%, and 19.7%, 45.4%, respectively. When both systems are compared, it has been shown that the BES/NB system can be effective under specified conditions.

Gold Clusters Immobilized by Post-Synthesis Methods on Thiol-Containing SBA-15 Mesoporous Materials for the Aerobic Oxidation of Cyclohexene: Influence of Light and Hydroperoxide

Gold nanospecies produced by a historically inspired two-liquid phase system were immobilized on plate-like mesoporous silica, SBA-15, functionalized with mercaptopropyl groups by a post-synthesis method, and the resulting materials were tested in the oxidation of cyclohexene with molecular oxygen at atmospheric pressure. The main purpose of this approach was to compare the physicochemical properties and catalytic performance of these materials with those of previously reported related materials functionalized by in situ methods during synthesis. In addition, catalytic tests under ambient lighting and darkness and also in the presence and absence of the initiator tert-butyl hydroperoxide (TBHP) were carried out. The samples were characterized by chemical analysis, N2 adsorption/desorption, TGA, SEM, HRTEM, UV-vis spectroscopy and XPS. Gold nanoclusters and isolated gold atoms but no AuNPs were found in the catalysts (0.31–2.69 wt.% of gold). The XPS shows that nearly 60% of the -SH groups (1.33 wt.% of S) were oxidized to sulphonic groups upon gold immobilization. The AuNCs and isolated gold atoms evolved in the the reaction medium to form AuNPs. The activity of the samples was lower than that of the catalysts supported on related S-bearing SBA-15 functionalized in situ, which was attributed to their different Au/S ratios, which in turn regulated the evolutionary process of the gold species during the reaction. The catalysts turned out to be inactive in darkness, which evidences that the cyclohexene oxidation carried out at ambient illumination is actually photocatalyzed by the AuNPs formed in situ during the reaction. The TBHP initiator is required to obtain the activity in order to counteract the inhibitors of cyclohexene auto-oxidation present in the commercial reagent. On the other hand, no major differences in the selectivity among the different catalysts and reactions were observed, with 2-cyclohexen-1-one and 2-cyclohexen-1-ol resulting from the allylic oxidation as main products (selectivity of (one + ol) ~80% at a conversion ≥ 35%; one/ol~2).

A decision approach on risk-control scheme recognition for karst excavation engineering

Risk events can be frequently encountered in karst geological environments during excavation construction; thus, a suitable risk-control scheme is essential to reduce the negative impact of accidents. A decision-making approach based on the fuzzy VIKOR method is proposed to identify the optimal risk-control scheme, where a triangular fuzzy set is adopted to express the experts’ judgements. A decision hierarchy is constructed based on four criteria and 12 sub-criteria, which are determined based on engineering experience and the construction environment. The developed approach was utilized to determine the optimal risk-control scheme to address risk events for excavation construction in karst regions. A countermeasure scheme, that is, pressure grouting with a two-phase liquid system, was implemented. The basic principles and steps of the implementation of the proposed scheme are presented. The applicability of the identified scheme was verified by the core recovery and modified number of blows using a standard penetration test. A flowchart of optimal scheme identification for geotechnical engineering practice is provided.

A novel method for determining the wax precipitation temperature in wax-based warm mix asphalt

ABSTRACT To accurately determine the wax precipitation temperature (WPT) of wax-based warm mix asphalt binder, a novel algorithm for WPT calculation was proposed, and the process of wax precipitation in asphalt, as well as the effects of aging, cooling rate, and shear rate on wax precipitation characteristics, were investigated through dynamic shear rheometer (DSR) tests and polarised light microscopy (PLM) experiments. The research findings reveal the following: The refined WPT algorithm exhibits heightened precision compared to the traditional viscosity method, showcasing superior reproducibility and mitigating human-induced errors. During the cooling process, wax molecules become oversaturated, leading to the precipitation of wax crystals and the transformation of asphalt into a solid–liquid two-phase system. The aging of asphalt causes changes in its composition, shifting the phase equilibrium towards favouring wax precipitation. The WPT of asphalt is also influenced by the cooling rate and shear rate, and a larger cooling rate and shear rate will reduce the WPT. Wax crystals are less numerous and more regular in shape at low cooling rates.

Symbolic transition network for characterizing the dynamics behaviors of gas–liquid​ two-phase flow patterns

Gas–liquid two-phase flows are widely encountered in many industrial applications, and the evolutionary dynamics of the flow patterns are fundamental knowledge for the establishment of the two-phase controlling system. In this work, we propose a symbolic complex network-based method for identifying the evolutionary dynamics of the gas–liquid​ two-phase flow system. First, we establish a series of symbolic networks with the derived gas–liquid two-phase flow symbolic series. Then we suggest a symbolic network index, which is the number of enumerated elementary cycles, to reveal the periodic oscillation properties of various gas–liquid flow patterns. In addition, we estimate the symbolic network average degree C and average shortest path length L to reveal the evolutionary dynamics of the flow patterns. The results suggest that our developed method is efficient for detecting the dynamics of the two-phase flow system, which can be further applied to other complex fluid systems.

Countercurrent Flow Limitation in a Pipeline with an Orifice

Countercurrent flow limitation (CCFL) refers to an important class of gravity-induced hydrodynamic processes that impose a serious restriction on the operation of gas–liquid two-phase systems. In a nuclear power plant, CCFL may occur in the liquid level measurement system where an orifice is applied in the pipeline, which may introduce error into the level measurement system. CCFL can occur in horizontal, vertical, inclined, and even much more complicated geometric patterns, and the hot-leg channel flow passage has been widely investigated; however, a pipeline with variable cross-sections, including an orifice, has not yet been investigated. An experimental investigation has been conducted in order to identify the phenomenon, pattern, and mechanism of CCFL onset in this type of geometry. Both visual and quantified experiments were carried out. A high-speed camera was applied to capture the flow pattern. Visual experiments were implemented at atmospheric pressure, while quantified pressurizer experiments were implemented at higher pressures. It was determined that if the condensate drainage is low and the liquid level is also low, with a stable stratified flow upstream of the orifice, there is no oscillation of the differential pressure. However, at higher condensate drainage levels, when the liquid level increases, a stratified wavy flow occurs. One of these waves can suddenly rise upstream of the orifice to choke it, which subsequently gives rise to differential pressure across the orifice, with periodic variation. This pattern alternately features stratified flow, stratified wavy flow, and slug flow, which indicates the occurrence of CCFL. The CCFL occurring under these experimental conditions can be expressed as a Wallis type correlation, where the coefficients m and C are 0.682 and 0.601, respectively.

Effect of liquid viscosity on the gas–liquid two phase countercurrent flow in the wellbore of bullheading killing

Studying the gas–liquid two-phase countercurrent flow under high liquid viscosities is key in designing the well-killing parameters of the bullheading method; however, currently, in-depth research on this issue is limited. Herein, using a self-designed vertical visualization wellbore gas–liquid two-phase flow experimental system with a tube diameter of 0.1 m and liquid viscosity in the range of 1–50 mPa s, a simulation experiment of bullheading killing was conducted. The effects of liquid viscosity on the bubble morphology, bubble migration, and gas–liquid countercurrent flow pattern were analyzed, and the mechanism of back pressing of gas during the well-killing process of the bullheading method in a large-scale tube was revealed. Moreover, the influencing factors and variation in the critical displacement of bullheading were analyzed. The results revealed that the stability of Taylor bubbles increased and the number of small bubbles decreased with the increase in liquid viscosity, resulting the gradual shrinkage or disappearance of the churn flow and bubbly flow, expansion of the region of slug flow, and downward movement of the transition boundary between bullet-cup flow and slug flow. On approaching the critical liquid displacement during the process of simulated bullheading, Taylor bubbles rapidly dissociated into small bubbles and turned around during the rising process, forming a gas–liquid downward flow, following which the gas was successfully pressed back. In addition, our analysis revealed that the press-back effect is not always positively correlated with the viscosity of the kill fluid. The critical displacement of the well-killing fluid first decreased and then increased with an increase in the liquid viscosity. Finally, based on the experimental results, an improved calculation method for the critical displacement of bullheading considering the influence of liquid viscosity was established, which could provide important theoretical guidance for the parameter design of bull heading.

Lattice Boltzmann Method simulation of wellbore gas–liquid​ phase transition

Whenever the drilling wellbore is at the state of gas–liquid two-phase flow, gas slips and migrates along the drilling fluid. Due to the decreased wellbore temperature and pressure during gas migration, gas volume will gradually increase. When the temperature and pressure reach the critical value of gas–liquid phase, phase change occurs. The volume of natural gas expands suddenly, and a large amount of gas is generated. It easily leads to a well blowout, which is a great challenge to well control. Therefore, analyzing the gas–liquid phase changes in drilling wellbore has important practical significance for realizing well control safety. In this paper, Lattice Boltzmann Method (LBM) is applied to simulate phase transition of wellbore gas–liquid​ two-phase system. Research results show that gas–liquid distribution after phase transition is closely related to the system original density. Compared to the critical density of gas–liquid phase change, when the system original density is lower, continuous gas forms in wellbore. While the system original density is higher, gas phase breaks out into small bubbles and migrates along the wellbore. Phase distribution directly determines gas–liquid two-phase flow pattern in wellbore, which is crucial to wellbore pressure accurate prediction. Some valuable attempts are conducted to investigate gas–liquid two-phase flow in wellbore by using LBM in this research.

A 3D measurement method of bubbles based on edge gradient segmentation of light field images

Based on the light field imaging technology, a three-dimensional(3D) measurement method of bubbles through the use of edge gradient segmentation (TMBEGS) is proposed in this paper. From the characteristic that the bubble edge image has great gray gradient, the coordinates of the bubble edge pixels are determined. The depths of the edge pixels are further derived by evaluating the sharpness of the edge pixels in the refocused light field images. On this basis, the depth coordinate of the bubble is calculated by averaging the depths of all edge pixels, and the 3D measurement of the bubble is then achieved by combining the centroid coordinate and equivalent diameter of the bubble. Finally, experiments are carried out to evaluate TMBEGS on a calibration setup and a bubbling bed experimental device. Results indicated that the relative errors of the bubble diameter and depth by TMBEGS are less than 1.18 % and 5.93 %, which are better than 2.99 % and 17.51 % by the existing method, respectively. On the bubbling bed experimental device, the equivalent diameter of bubbles is increased by 5.69 % compared with the existing method, and the standard deviation of the bubble depth is less than 1.78 mm, which is 21.3 % lower than the existing method. With the increase of the bubble equivalent diameter, the bubble surface deformation intensifies under the effects of the bubble surface tension, viscous force, and inertia force, which affects the imaging quality of the bubble, and reduces the measurement accuracy of the bubble edge and depth. These results illustrated that TMBEGS has high measurement accuracy of the bubbles and is capable of charactering the bubbles in the gas–liquid two-phase flow system.

Multifunctional CaF2: Yb3+, Ho3+, Gd3+ Nanocrystals: Insight into Crystal Growth and Properties of Upconversion Luminescence, Magnetic, and Temperature Sensing Properties.

The upconversion (UC) emission intensity of Ln3+-doped CaF2 nanomaterials is not ideal, which limits their application in some advanced scientific fields. Hence, it is extremely imperative to enhance the emission intensity of UC nanocrystals. In this work, an ionic-liquid-assisted hydrothermal method based on an ethylene glycol (EG) and ionic liquid (IL) two-phase system was used to synthesize CaF2 doped with Yb3+ and Ho3+. The influence of the amount of IL and the reaction time as well as the concentration of Gd3+ doping on morphology and size was studied in detail, and the growth mechanism was proposed. Green UC luminescence materials were obtained through co-doping Yb3+ and Ho3+ ions. Furthermore, the luminescence of UC was increased monotonically with the introduction of Gd3+ ions. The effect mechanism of Gd3+ doping on the UC luminescence was put forward, which might provide a new method for the promotion of UC luminescence. In addition, the temperature sensing of CaF2: Yb3+/Ho3+/Gd3+ was investigated, which demonstrated that the phosphor has a potential application prospect in thermal sensing. Meanwhile, CaF2: Yb3+/Ho3+/Gd3+ also exhibited a paramagnetic property at room temperature. Therefore, these multifunctional nanocrystals may have prospective applications in optical bioimaging, magnetic resonance imaging, and temperature sensing.