Liquid Crystal Alignment Properties Research Articles

Investigation of Polar Alignment Properties of Ferroelectric Nematic Liquid Crystals with Twist / Planar Alignment in Bulk

Investigation of Polar Alignment Properties of Ferroelectric Nematic Liquid Crystals with Twist / Planar Alignment in Bulk

Reformation of solution process NiO thin films with UV curable polymers for the self‐alignment of liquid crystals

AbstractLiquid crystal (LC) orientation films are one of the key technologies in display devices. Currently, the commonly used polyimide rubbing method exposes problems such as micro‐defects and static electricity. In this paper, a thin film was prepared from a mixture of UV‐curable polymer and NiO solution using the UV‐NIL method. At room temperature, all three temperatures showed good liquid crystal alignment properties. However, in terms of thermal stability, it was more thermally stable in the 1‐min sample. This means that the formation of patterns has a significant impact on orientation properties, and the change in van der Waals force due to chemical changes also affects the orientation properties to some extent. In addition, excellent electro‐optical properties were also confirmed.

Alignment properties of a ferroelectric nematic liquid crystal on the rubbed substrates.

The orientation characteristics of FNLC-919, a new material with a ferroelectric nematic phase at room temperature, were investigated. Its alignment characteristics varied greatly depending on the relative rubbing direction on both substrates of a liquid crystal cell. In a cell where the two substrates were rubbed in the same direction, they were arranged homogeneously along the rubbing direction without domains or defects in the ferroelectric nematic phase. In a cell where the two substrates were rubbed in the anti-parallel direction, the two domains were twisted in the opposite direction. We quantitatively obtained the twisted direction and angle by matching the experimental data and calculation results using Jones matrix calculations. From the electro-optical experiment, it was confirmed that the polarization direction was opposite to the rubbing direction. In addition, the wavelength and temperature dependence of birefringence was measured for FNLC-919. In a cell where the rubbing direction between two substrates was 90°, two domains of opposite directions were observed in the nematic phase. When it becomes a ferroelectric nematic phase on cooling, the twist is determined to be only in one direction. The twist direction and angle were quantitatively obtained in the nematic and ferroelectric nematic phases. It was twisted more in the ferroelectric nematic phase than in the nematic phase.

Nanostructured hafnium-doped strontium oxide film for homeotropic/homogeneous convertible liquid crystal alignment depending on the curing temperature

ABSTRACT A hafnium strontium oxide (HfSrO) liquid crystal (LC) alignment film was efficiently created through brush coating, and its ability to change the LC alignment direction was confirmed. A brush was applied to HfSrO sol coated on an indium-tin oxide substrate, after which the coating was solidified at various curing temperatures. It was confirmed that a directional micro/nanostructure was formed above 280°C due to the shear stresses caused by the movement of the brush hairs. Surface chemical changes were analyzed by using X-ray photoelectron spectroscopy and contact angle measurements. As the curing temperature increased, the prevalence of oxygen bonds increased and the contact angle decreased, thereby increasing the surface energy. The anisotropic boundary of the microgrooves and the van der Waals forces due to an increase in surface energy changed the alignment direction of LC molecules from vertical to horizontal, as verified through polarized optical microscopy and pretilt angle measurements. Thus, the efficiency of the brush-coating method, which dramatically simplifies the LC alignment film process, was confirmed. The homeotropic/homogeneous LC alignment property of the HfSrO film produced through brush coating depending on the curing temperature provides an innovative approach for LC alignment.

Surface reformed anisotropic polystyrene‐block‐poly(ethylene‐ran‐butylene)‐block‐polystyrene‐graft‐maleic anhydride layer via ion‐beam irradiation for liquid crystals

AbstractThe surface modifications and liquid crystal (LC) alignment properties of polystyrene‐block‐poly(ethylene‐ran‐butylene)‐block‐polystyrene‐graft‐maleic anhydride (SEBS‐g‐MA) films induced by ion‐beam (IB) irradiation are reported herein. Changes to the surfaces of the SEBS‐g‐MA films from IB irradiation at various incidence angles and changes in the LC orientations upon LC cell fabrication were analyzed. The physical surface modifications due to IB irradiation were observed via atomic force microscopy. Additionally, changes in the molecular composition of the surface were observed through X‐ray photoelectron spectroscopy analysis. Polarized optical microscopy analysis shows that excellent LC alignment properties could be obtained after IB irradiation at angles exceeding 45°. Further, the anisotropy caused by IB irradiation was more responsible for uniform LC alignment than the corrugated pattern.

Vertical Alignment of Liquid Crystals on Phenylphenoxymethyl-Substituted Polystyrene—PS Derivatives Structurally Similar to LC Molecules

A series of polystyrene derivatives containing precursors of liquid crystal (LC) molecules, phenylphenoxymethyl-substituted polystyrene (PPHE#; # = 5, 15, 25, 50, 75, and 100)—where # is the molar content of 4-phenylphenol using polymer modification reactions—were prepared in order to examine the effect of the polymer film, which possess similar LC molecular structure on the LC alignment properties. It was found that the Tg values of the PPHE# were higher than 100 °C due to their aromatic structure in the biphenyl-based PHE moiety. The LC cells fabricated with PPHE5 and PPHE15 films exhibited planar LC alignment. Conversely, LC molecules showed a vertical alignment in LC cells made using the polymer films with phenylphenoxymethyl side groups in the range of 25–100 mol %. The polar surface energies on the PPHE# films can be associated with the vertical LC alignment on the PPHE# films. For example, vertical LC alignment was exhibited when the polar surface energy of the polymer films was less than approximately 4.2 mJ/m2. Aligning stability was observed at 200 °C and UV irradiation of 20 J/cm2 for LC cells made using the PPHE100 film. Therefore, it was found that biphenyl, one of the LC precursors, modified polystyrene derivatives and can produce a next-generation vertical LC alignment system.

Influence of Periodic Non-Uniformities of Well-Structured Sapphire Surface by LIPSS on the Alignment of Nematic Liquid Crystal.

In this study, we report on the alignment properties of nematic liquid crystals on various transparent structured sapphire layers formed by laser-induced periodic surface structures (LIPSS). One-dimensional LIPSS (1D-LSFL) are generated by infrared femtosecond laser pulses along parallel lines covering an area of 5 × 5 mm2, with a line spacing that is varied between 7 and 17 µm. These periodic structures, employed as alignment layers, have a spatial periodicity of about 980 nm, a modulation depth of about 100 nm, and exhibit a high quality due to being characterized by a high degree of homogeneity and parallelism of the structured features. It is found that such alignment layers of the sapphire surface lead to a decreasing azimuthal anchoring energy, when the width of the unstructured gap is increased. Modifying the sapphire surface by an ITO-coating with further deposition of a polyimide film increases the azimuthal anchoring energy by a factor of about four up to Wφ ~ 4.25 × 10−6 J/m2, when the minimum width of the unstructured gap is 7 µm. Comprehensive measurements and comparisons of the azimuthal anchoring energy as well as the pretilt angle for the 1D-LSFL, unstructured gaps, and entire areas depending on the width of unstructured gaps are presented and discussed.

Vertical Alignment of Liquid Crystals on Comb-Like Renewable Chavicol-Modified Polystyrene.

This study demonstrates liquid crystal (LC) alignment behaviors on the surface of phytochemical-based and renewable chavicol-modified polystyrene (PCHA#, # = 20, 40, 60, 80, and 100, where # represent the molar content of chavicol moiety in the side group) via polymer modification reactions. Generally, a LC cell fabricated with a polymer film containing a high molar content of the chavicol side group exhibited a vertical LC alignment property. There is a correlation between the vertical alignment of LC molecules and the polar surface energy value of the polymer films. Therefore, vertical LC alignment was observed when the polar surface energy values of these polymer films were smaller than about 1.3 mJ/m2, induced by the nonpolar chavicol moiety having long and bulky carbon groups. Aligning stability under harsh conditions such as ultraviolet (UV) irradiation of about 5 J/cm2 was observed in the LC cells fabricated from PCHA100 film. Therefore, it was found that the plant-based chavicol-substituted polymer system can produce an eco-friendly and sustainable LC alignment layer for next-generation applications.

이온빔 조사된 인듐 아연 산화막 위 균일한 액정 배향 및 안정적 전기 광학 특성

이온빔 조사된 인듐 아연 산화막 위 균일한 액정 배향 및 안정적 전기 광학 특성

Vertical alignment of liquid crystals on plant-based vanillin derivative-substituted polystyrene films.

To investigate the alignment behavior of liquid crystal (LC) molecules, we synthesized a series of vanillin derivative-substituted polystyrene films (PVAN#, # = 20, 40, 60, 80, and 100), where # is the substitution ratio (%) of the vanillyl butyl ether (VAN) moiety as one of the bio-renewable vanillin derivatives. In general, a vertical LC alignment was observed in the LC cell fabricated using the polymer film having a higher molar content of VAN. Moreover, the surface energies of these polymer films were strongly related to the vertical LC alignment behavior. For example, a uniform vertical alignment was observed when the polar surface energy of the polymer was lower than approximately 2.05 mJ m−2, induced by the nonpolar and long carbon groups in the plant-based vanillin moiety. The LC cell fabricated using PVAN100 had good electrooptical characteristics such as voltage holding ratio and residual direct-current voltage and stable alignment under extreme external conditions.

Liquid crystal alignment properties on surface-reformed solution-derived lanthanum-doped zinc oxide films

ABSTRACTLiquid crystal (LC) alignment characteristics were investigated using a solution-derived lanthanum-doped zinc oxide (La:ZnO) film that was exposed to various intensities of ion-beam (IB) irradiation. At an IB intensity of 1700 eV, uniform and homogeneous LC alignment was achieved, as revealed by cross-polarized optical microscopy and pre-tilt angle measurement. Field-emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) were used to verify that the IB irradiation induced physical and chemical surface reformation of the La:ZnO film that relate to LC alignment. FE-SEM and AFM revealed that the IB irradiation reformed the existing surface structure into a new structure with an altered surface roughness. The XPS results showed that the van der Waals force with anchoring energy increased as the IB intensity increased, and this profoundly affected the state of LC alignment. The capacitance-voltage (C-V) hysteresis curve was measured as a function of IB intensity to characterize the accumulated charge as a residual DC. Nearly zero C-V hysteresis was achieved at an IB intensity of 1700 eV. Therefore, a solution-derived La:ZnO film with an IB intensity of 1700 eV has great potential for high-quality LC applications.

Improvement of liquid crystal alignment using photo-fragment reactions

ABSTRACTTwo photo-activators, AAP and CAP, were synthesized with cyclohexanone oxime with methyl and cronic anhydrides. They were used to improve the liquid crystal (LC) alignment properties by increasing the surface azimuthal anchoring energy, that has been an image-sticking problems. These photo-activators were respectively mixed with twisted nematic (TN) planar alignment agent (TN-PAA) or photo-polyamic acid (P-PAA), respectively. It is remarkable that a photo-activator using crotonic anhydride (CAP) what has allyl double bond showed very high anchoring energy, 6.92 × 10−5 J/m2, which is comparable or better than that obtained with rubbing, 1.65 × 10−5 J/m2. The anchoring and the alignment properties were observed with the P-PAA were the lower than the TN-PAA. The photochemical reactions and the surface properties of the photo-polyimide (P-PI) were more complex due to more than double photochemical reactions. The fourier transform infrared spectroscopy (FT-IR), contact angle, atomic force microscope (AFM) and differential thermal analysis and thermogravimetic analysis (DTA-TGA) measurements indicated that the surface of polyimide (PI) became more hydrophobic due to the photoreactions of alkyl radicals. These radicals were generated by the photo-irradiation and the reduction of hydrophilic functional groups. The high anchoring energy was assisted by the rough and robust surface induced by carbon dioxide generation. These properties contribute to prevent the image-sticking and shorten the irradiation time with energy.

Isomeric effects on liquid crystal alignment behaviors of polystyrene derivatives

ABSTRACTWe synthesized a series of 4-ethylphenoxymethyl (P4EP) and 3-ethylphenoxymethyl (P3EP) and 2-ethylphenoxymethyl-substituted polystyrenes (P2EP), using polymer analogous reactions, in order to study the isomeric effect of the ethylphenoxymethyl side groups on the liquid crystal (LC) alignment properties. The LC cells fabricated with the unrubbed P4EP, P3EP, and P2EP films exhibited uniform vertical, partial vertical, and random planar LC alignment. A high pretilt angle of about 90° was observed from the LC cell prepared from the rubbed film of P4EP at number of rubbing of 1. On the contrary, the LC cells prepared from the rubbed films of P3EP and P2EP showed pretilt angles of approximately 30° and 0° at number of rubbing of 1, respectively. Therefore, the position of ethyl group attached to phenyl group in the side chain was found to LC alignment behavior of the polystyrene derivatives. The LC alignment behavior was well correlated with the wettability of the polymer films. These polystyrene derivatives having good solubility in many organic solvents and their films having low process temperature can be candidates for LC alignment layer in the flexible display. This study contributes to the latest efforts to develop new alignment layers for pretilt angle control.

Vertical alignment of liquid crystal on tocopherol-substituted polystyrene films

ABSTRACTWe synthesised a series of vitamin-based and renewable tocopherol-substituted polystyrene (PTOC#, # = 20, 40, 60, 80 and 100), where # is the molar content of tocopherol moiety, using polymer analogous reactions to investigate their liquid crystal (LC) alignment properties. In general, the LC cell fabricated using the polymer film having a higher molar content of tocopherol side group showed vertical LC alignment behaviour. The vertical alignment (VA) behaviour was well correlated with the surface energy value of these polymer films. For example, VA was observed when the surface energy values of the polymer were smaller than about 35.22 mJ/m2 generated by the nonpolar tocopherol moiety having long and bulky carbon groups. Good electro-optical characteristics, such as voltage holding ratio and residual DC voltage, and aligning stabilities at 200°C and ultraviolet irradiation of 10 J/cm2 were observed for the LC cells fabricated using PTOC100 as a LC alignment layer. Therefore, it was first found that the renewable tocopherol-based materials can produce an eco-friendly vertical LC alignment system.

Free residual DC voltage for nematic liquid crystals on solution-derived lanthanum tin oxide film

ABSTRACTWe present the liquid crystal (LC) alignment properties of solution-derived lanthanum tin oxide (LaSnO) films cured at various temperatures and exposed to ion-beam (IB) irradiation. Using a solution process, LaSnO films were deposited on the indium-tin-oxide glass substrates and IB irradiation was used as an alignment method. Homogeneous and uniform LC alignment was achieved and observed by cross-polarised optical microscopy. Pre-tilt angle results with low standard deviation supported the notion of uniform LC alignment. The LaSnO film cured at 300°C showed nearly zero capacitance–voltage hysteresis. The change of the surface morphology of the LaSnO film due to IB irradiation was observed by atomic force microscopy. The effects of IB irradiation on the LC alignment layer were further demonstrated by X-ray photoelectron spectroscopy. The strong IB irradiation broke the metal–oxide bonds present, which in turn induced an increased number of oxygen vacancies on the whole surface. Uniform LC alignment was attributed to surface reformation and van der Waals forces.

Effects of morphology and concentration of CuS nanoparticles on alignment and electro-optic properties of nematic liquid crystal

Nanoparticles (NPs) with flower-like and frame morphologies were synthesized from CuS, a remarkable transition-metal sulfide. We introduced two kinds of CuS NPs into a nematic liquid crystal (LC) 4-cyano-4'-n-pentylbiphenyl (5CB) and investigated the morphology- and concentration-dependent alignment and electro-optic (E-O) effects of CuS NPs on 5CB. A trace amount of flower-like CuS NPs induced a uniform homeotropic orientation of LC molecules; this is attributable to the obtained desirable compact nanosheet structure. Moreover, both flower-like and frame CuS NPs induced a remarkable improvement in the E-O properties of 5CB, and the flower-like CuS/5CB system exhibited a better performance. The doped CuS NPs in the LC host suppressed the shielding effect and strengthened the electric field, resulting in outstanding E-O properties. At a doping concentration of 0.05 wt.%, CuS NPs were well-dispersed and achieved the optimum E-O performance. This study provides a novel method for inducing a uniform orientation and enhanced E-O properties of LC molecules by doping with extraordinary CuS NPs, leading to potential applications in establishing flexible LC displays.

Liquid Crystal Alignment Behaviors on Comb-Like Fluorinated Polystyrene Films

ABSTRACTWe synthesized a series of fluorinated polystyrene (PCMSF#, # = 50, 80, and 100), where # is the molar content of 1H,1H,2H,2H-perfluorodecanethiolate moiety, using polymer analogous reactions to investigate their liquid crystal (LC) alignment properties. In general, the LC cell fabricated using the polymer film having a higher molar content of fluorinated side group showed vertical LC alignment behavior with a pretilt angle of about 90°. The vertical alignment behavior was well correlated with the surface energy value and fluorine atomic percent of these polymer films. For example, vertical alignment was observed when the surface energy values of the polymer were smaller than about 8.77 mJ/m2 generated by the nonpolar and long fluorocarbon groups. Good electro-optical characteristics, such as voltage holding ratio (VHR) and residual DC voltage (R-DC), and aligning stabilities at 250°C were observed for the LC cells fabricated using PCMSF100 as a LC alignment layer.

Photoalignment Behavior on Polystyrene Films Containing Coumarin Moieties

We synthesized a series of polystyrene derivatives containing coumarin side groups, poly(6-(4-vinylbenzyloxy)coumarin)(P6COU#), where # is the molar content of 6-hydroxycoumarin using polymer modification reaction, in order to study the effect of the 6-hydroxycoumarin side groups on the liquid crystal (LC) alignment properties. The LC alignment behavior of these polymers was investigated using photoalignment method. The LC cells made from photoirradiated P6COU# films exhibited homogeneous planar LC alignment with a pretilt angle of approximately 0°. We found that LC aligning ability of the LC cells made from photoirradiated P6COU# films was affected by the molar content of 6-hydroxycoumarin side groups. For example, the azimuthal anchoring energy of a P6COU80 compared to P6COU25 is about 1 × 10−5 J/m2 and 5 × 10−7 J/m2, respectively. The electro-optical characteristics of the LC cells fabricated with P6COU80 films such as voltage holding ratio and residual DC voltage, threshold voltage, driving voltage, and response time were as good as those fabricated from rubbed polyimide films, the most commonly used LC alignment layers.

Homogeneous liquid crystal alignment on poly(vinylidene fluoride-trifluoroethylene) films subjected to ion-beam irradiation

We demonstrate homogeneous and uniform liquid crystal (LC) alignment on poly(vinylidene fluoride-trifluoroethylene) [PVDF-TrFE] films using ion-beam (IB) irradiation and a performance improvement of twisted nematic (TN) cells using IB-irradiated PVDF-TrFE films. Spontaneous ferroelectricity of the PVDF-TrFE films was modified by IB irradiation, which affected the LC alignment properties. The variation in the pre-tilt angles of the LC molecules on the IB-irradiated PVDF films is attributed to surface reformation, including defluorination and oxidation because the pre-tilt angles of LC molecules can be controlled by adjusting the fluorine content. The results of contact angle measurements supported this phenomenon. A 58% reduction in the switching voltage was observed for TN cells, indicating that the IB-irradiated PVDF-TrFE films are a promising candidate for use as an alignment layer.

Photoalignment behaviour on polystyrene films containing chalcone moieties

A series of polystyrene derivatives containing chalcone (one of the biological compounds) side groups, poly(4-(4-vinylbenzyloxy)chalcone) (PCHAL#), where # is the molar content of chalcone using polymer modification reactions, were prepared in order to study the effect of the chalcone side groups on the liquid crystal (LC) alignment properties. The LC alignment behaviour of the polymer was investigated using photoalignment method. The LC cells made from photoirradiated PCHAL# films exhibited homogeneous planar LC alignment with an extremely low pretilt angle of approximately 0°. We found that LC aligning ability of the LC cells made from photoirradiated PCHAL# films was affected by the molar content of chalcone side groups. For example, the azimuthal anchoring energy of a PCHAL100 (9 × 10−6 J/m2) was found to be much larger than that of PCHAL18 (5 × 10−7 J/m2). In addition the electro-optical characteristics of the LC cells fabricated with PCHAL100 films such as threshold voltage, driving voltage, and response time were as good as those fabricated from rubbed polyimide films, the most commonly used LC alignment layers.