Liquefaction Technology Research Articles

Nucleation mechanism of methane heterogeneous condensation under different driving forces

Clarifying alkane gas condensation characteristics is crucial to designing and optimizing liquefaction heat exchangers, which imposes higher demands on the microscopic understanding of alkane heterogeneous condensation. Thus, in this study, the condensation process of methane nucleation under different driving forces is investigated by molecular dynamics (MD) simulations. The dynamics characteristics of nucleation in methane heterogeneous condensation are analyzed by varying initial gas-phase pressure, cold wall temperature, and ethane content. The results showed that increasing the initial gas-phase pressure enhances intermolecular interactions, which alter the cluster formation path and significantly increase the methane gas nucleation rate from 1.997 × 1033/(m3·s) to 1.068 × 1034/(m3·s). While lowering the cold wall temperature promotes condensation by weakening the thermal motion of the gas molecules. Once condensation nuclei form in the system, the lower temperature conditions from lowering the cold wall temperature result in a higher growth rate of the clusters. Additionally, the addition of easily condensable component ethane can improve the condensation nucleation characteristics of low-saturated methane gas, facilitating the liquefaction of methane. This study aims to provide a microscopic understanding of the advancement of gas liquefaction technology by investigating the heterogeneous nucleation of alkane under different conditions from a microscopic perspective.

Preparation and Characterization of Bio-Asphalt Based on Sludge-Derived Heavy Oil

To achieve the efficient resource utilization of municipal sludge and promote the sustainability of pavement materials, this study employed liquefaction technology to process municipal sludge. The resulting liquefied-sludge-derived heavy oil was blended with 50# asphalt to prepare a bio-asphalt that can replace petroleum asphalt. Firstly, orthogonal experiments were conducted to analyze the effects of the solid–liquid ratio (dried sludge:anhydrous ethanol), liquefaction temperature, and reaction time on the yield of the sludge-derived heavy oil. Then, the basic characteristics of the sludge-derived heavy oil were studied using an elemental analyzer, gel permeation chromatography, thermal analysis, gas chromatography–mass spectrometry, and Fourier transform infrared spectroscopy, and the differences between the sludge-derived heavy oil and petroleum asphalt were compared. Finally, to determine the appropriate content range of sludge-derived heavy oil in bio-asphalt, a comprehensive evaluation of the three major indicators, aging resistance, storage stability, low-temperature performance, and high-temperature performance was carried out for the prepared bio-asphalts. The results indicated that the optimal preparation process for liquefied sludge oil involves a liquefaction temperature of 275 °C, a solid–liquid ratio of 1:15, and a reaction time of 1 h, resulting in an oil production rate of 22.36%. The sludge-derived heavy oil demonstrated good thermal stability, with its primary components being aliphatic compounds (carboxylic acids, ketones, aldehydes, alcohols, alkanes, esters, etc.), with esters being the most abundant. Furthermore, the sludge-derived heavy oil was highly compatible with 50# asphalt, but no chemical reaction occurred between them. When the sludge-derived heavy oil content ranged from 5% to 20%, bio-asphalt showed favorable aging resistance and storage stability. As the content of the sludge-derived heavy oil increased, its low-temperature performance improved, but there was a slight decrease in high-temperature performance. Additionally, correlation analysis highlighted that the influence of sludge-derived heavy oil content on the high-temperature performance of bio-asphalt was notably greater than on other properties. Therefore, the recommended dosage of sludge-derived heavy oil should be between 5% and 10%.

Synthesis, structure, magnetic and magnetocaloric properties of hydrated terbium antimonate

In recent years, the idea of using magnetic cooling based on the magnetocaloric effect as an alternative to vapor–gas cooling in liquefaction technology has attracted increasing attention from researchers due to its energy efficiency. The aim of the present research was the synthesis of hydrated terbium antimonate promising for magnetic cooling technology by hydrolysis and mechanochemical activation, and complex analysis of the influence of modifying elements on the physicochemical, magnetic and magneticaloric properties and structure of polyantimonic acid. As a result of studies, the methodology for the synthesis of hydrated terbium antimonate has been developed and it has been demonstrated that the phase formation in the fully substituted compound of Tb0.67Sb2O6∙(3 + n)H2O composition occurs after grinding and calcination at 200 °C as a result of ion-exchange reaction. The Curie-Weiss temperature was determined to be θCW = − 5 K. The magnetic ordering temperature has been extrapolated from TP(H) data, as µ0H = 0, to be about 0.98 K, where TP is the minimum of temperature dependences dM/dT curve and varies as a linear function of TP = 2.93·H + 0.98. The values of ΔS and of RC are about 3.8 Jkg−1K−1, 6.2 Jkg−1K− 1 and 18 Jkg−1, 89 Jkg−1 for µ0H = 2 T and 7 T, respectively at T = 3 K.

Viability assessment of large-scale Claude cycle hydrogen liquefaction: A study on technical and economic perspective

The competitiveness of hydrogen as a sustainable energy carrier depends greatly on its transportation and storage costs. Liquefying hydrogen offers advantages such as enhanced purity, versatility, and higher density, yet current industrial liquefaction processes face efficiency and cost challenges. Although various large-scale and efficient liquefaction concepts exist in the literature, they often overlook the economic and technical viability of such plants. Here, we addresses this issue by establishing a framework for modeling a large-scale hydrogen liquefaction concept and conducting both technical and economic assessments, with a specific focus on 125 tonnes per day (TPD) high-pressure hydrogen Claude-cycle concept. The technical analysis involves preliminary designs of key process components, while the economic assessment utilizes Aspen Process Economic Analyzer. Our findings indicate that at an electricity price of €0.1/kWh, the Claude-cycle liquefier concept yields a specific liquefaction cost (SLC) of €1.55/kgLH2. A sensitivity analysis was performed, which shows that electricity price has a significant influence on the economics. Further investigation on the compressors design shows that incorporating high-speed centrifugal compressors could reduce the SLC by 5.42% and potentially more. Scaling up to 250 and 500 TPD reveals further cost improvements, while cost projections indicate substantial declines as the technology matures. Ultimately, this paper presents novel cost-scaling and experience curves of hydrogen liquefaction technology, demonstrating the compelling economic viability of integrating large-scale hydrogen liquefaction into sustainable energy infrastructure.

Recent Advances of Solvent Effects in Biomass Liquefaction Conversion

Liquefaction conversion technology has become one of the hottest biomass conversion methods due to its flexible material selection and extensive product applications. Exploring biomass liquefaction conversion focuses on catalysts, biomass/water ratio, and reaction temperature. However, it is found that solvents are crucial in the biomass liquefaction process and significantly impact the type of liquefied products and bio-oil yield. Given the current rapid development trend, timely sorting and summary of the solvent effect in the biomass liquefaction process can promote the subsequent development and industrialization of more efficient and cleaner biomass liquefaction technology. Therefore, this review first introduces the characteristics of water as the liquefaction solvent, then summarizes the effects of organic solvents on liquefaction, and finally elaborates on the synergistic effect of co-solvents, which provides a more systematic overview of solvent effects in the liquefaction process. Meanwhile, prospects are put forward for the future development of biomass liquefaction conversion.

Energy optimization of hydrogen liquefaction process via process knowledge combined with multivariate Coggin's algorithm

Sustainable and cost-effective transportation of hydrogen is one of the major challenges to futuristic hydrogen value chain. Hydrogen, in its produced form, exhibits low energy density and large volume, rendering it highly unsuitable for transportation, particularly over extended distances. Liquefaction is one of the promising approaches to improve hydrogen's energy density and to make it more compact. However, liquefaction is an energy intensive process, raising the cost of transportation. In this study, the specific energy consumption of the hydrogen liquefaction process is aimed to reduce through knowledge-based optimization followed by optimization using the multivariate Coggin's algorithm to improve energy and economic profiles of the process. Design variables, composite curve, exergy, and economic analyses are performed to evaluate and compare the thermodynamic, economic, and environmental feasibility of the optimized process. The results depict a significant reduction (14.3%) in specific energy consumption to 9.40 kW/kgLH2 without increasing process complexity. Further key improvements include a massive drop in refrigerant flowrates (9.2%), annualized cost (m$ 0.15), and annual CO2 emissions (1008.45 tCO2/annum). The largest exergy destruction is observed in CHX-201, reflecting further room for improvement. These results underscore the potential for optimizing hydrogen liquefaction processes to enhance energy efficiency, process economics and environmental impact, providing valuable insights for researchers and industry professionals seeking to advance hydrogen liquefaction technologies. However, challenges remain in the comprehensive evaluation of chemical exergy for ortho- and para-hydrogen and in conducting advanced exergy analyses to further optimize hydrogen liquefaction processes without adding complexity.

THE IMPORTANCE OF BIOETHANOL AS AN ENVIRONMENTALLY CLEAN FUEL

This article is a review based on literature sources. The production technology and areas of application of bioethanol, as well as ways to intensify the production of alcohol obtained from these natural sources, are analyzed. One such method is biomass liquefaction. Modern technologies for converting biomass into valuable biofuels were studied. Common biomass liquefaction technologies are indirect liquefaction and direct liquefaction. Direct biomass liquefaction involves converting biomass into bio-oil, and the main technologies are hydrolytic fermentation and thermodynamic liquefaction. Based on thermodynamic liquefaction, it can be divided into fast pyrolysis and hydrothermal liquefaction. In addition, this review provides an overview of the physicochemical properties of biodiesel and common methods for its processing. Keywords: bioethanol, yeast, natural food waste, purchasing biofuel.

Can process intensification of liquefaction technology for LNG and LH2 accelerate adoption for transportation use?

One of the reasons gaseous fuels, methane, and hydrogen, are renewable and sustainable replacements for traditional liquid hydrocarbon-based transportation fuels is their small carbon footprint. Global awareness of the immediate need to address impacts of emissions from transportation energy use has emphasized urgency of changes from business as usual. However, the transition from existing fuels to new fuels is complex because fuel usage is huge, and so many variables influence the rate of adoption. When one reads excellent energy outlooks of major energy companies, data driven reports of international and national energy agencies, along with thoughtful studies of the water, energy, food nexus, the systemic complexities are daunting. Marchetti’s insightful numerical modeling of the rate of transition among different energy sources over the past two centuries with credible validation from recorded usage data shows the time scale for appreciable changes among energy systems is several decades. A further important observation of Marchetti’s work is that transitions among energy sources were and are driven by substitution of superior technology rather than by depletion of prevalent sources. These observations incentivize developments of more efficient, less expensive, robust, scalable methods of production, liquefaction, storage, transport, delivery, and dispensing of hydrogen and natural gas to accelerate adoption by transportation customers. This paper presents a few examples of process intensification in advanced liquefiers for LNG and LH2 at the same location could reduce capital costs, energy costs, and footprints of different sized liquefiers. These combinations could help address gaps in existing technology for several essential needs such as liquefiers for heavy-duty vehicle refueling stations or marine vessel bunkering systems, or refrigerators for storage tank boil-off management systems. Modular, containerized liquefiers plants with several tonne/day capacity could be scaled by interconnecting multiple units to make small industrial plants that match localized fuel demands from distributed mobile users.

Конъюнктура мирового рынка СПГ в условиях санкционного давления

The article reveals aspects of the situation on the global LNG market in the context of sanctions pressure on Russian LNG enterprises, and suggests ways for Russian LNG enterprises to adapt to these conditions. The conditions of sanctions pressure on Russian LNG enterprises are described and the impact of sanctions on the LNG industry is revealed. The conducted research is based on statistical data from Russian and foreign sources. Aspects of the global LNG market environment include: an increase in the scale of LNG production in the world, the use of innovative gas liquefaction technologies, the development of a system for organizing and managing the transportation of liquefied gas, an increase in the number of states purchasing LNG for their needs, changes in the volume of LNG production and consumption in the world. The analysis presented in the article of the prospects and directions of development of this market in the future, as well as the main economic and technical factors influencing its functioning, and its conditions over the past five years have shown that this market is actively developing. The authors come to the conclusion: Russian LNG exporting enterprises have managed to adapt to the current competitive market conditions of global LNG trade, diversify their capacities and transport logistics, and have also significantly expanded the possibilities of transporting LNG along the Northern Sea Route.

Study on a novel hydrogen liquification process applying mixed-refrigerant for pre-cooling and cryogenics

Reducing the energy consumption of hydrogen liquefaction process is an urgent issue to improve the economy of liquid hydrogen transportation. A novel large-scale hydrogen liquefaction system, with a capacity of 100 TPD, is proposed in this paper. The pre-cooling system is composed of a mixed-refrigerant (MR) refrigeration cycle and a CO2–NH3 cascade refrigeration cycle. Due to the auxiliary pre-cooling effect of the CO2–NH3 cascade cycle, temperature of the pre-cooled hydrogen can be as low as −200.9 °C. A modified MR Joule Brayton cycle with an additional compressor is used as the cryogenic system to cool the hydrogen from −200.9 °C to −252.2 °C. Besides, a four-stage ortho-to-para conversion (OPC) process is utilized. Performance of the novel system is investigated and optimized using the Aspen HYSYS software. According to the results, the lowest specific energy consumption (SEC) of the proposed process is 6.15 kWh/kgLH2 and the exergy efficiency is as high as 67.4%. Based on the energy analysis, the best system coefficient of performance is 0.1751 with a 96.3% of p-H2 in the liquid hydrogen. In addition, compared to the initial conceptual system, the proposed system exhibits significant performance enhancements, a 20% reduction in SEC and a 27.9% increase in exergy efficiency. A sensitivity analysis is conducted to assess the impact of refrigerant composition and hydrogen pressure on the system, resulting in the determination of the optimal proportions of refrigerant components and the optimal inlet pressure. Results of the study can provide theoretical reference for the further development of large-scale hydrogen liquefaction technology.

Renewable green oil as a low-cost option for large-scale, long duration energy storage to produce on-demand electricity

<p class="MsoNormal" style="text-align: justify;"><span style="font-size: 14pt; font-family: 'times new roman', times, serif;">The rapid growth of renewable solar and wind energy necessitates extensive, long-term energy storage solutions to stabilize the electric grid and address the intermittent nature of these sources. In the absence of cost-effective long-duration, large-scale (LDLS) energy storage, there is a risk of increased disruptive blackouts and brownouts as intermittent energy sources approach 50% of electricity generation. Our analysis underscores volumetric energy density as a pivotal determinant in LDLS energy storage solutions, which is particularly crucial during periods of diminished renewable resource availability, such as the rainy season. Despite emphasis on conventional electric batteries and mechanical storage technologies such as compressed air and pumped hydro for LDLS, their costs pose a significant obstacle to widespread adoption, especially in emerging economies. In this study, we present a groundbreaking approach to LDLS: on-demand electricity generation from carbon-neutral renewable oil, known as "green oil," leveraging Reliance’s innovative catalytic hydrothermal liquefaction (R-CAT-HTL) technology. Our investigation evaluated two distinct sources of green oil production: organic waste streams (e.g., municipal solid waste, agricultural-waste, etc.) and on purpose production of algal biomass. We demonstrate that burning renewable green oil to produce electricity offers a cost-effective solution for large-scale (GWh) long-duration (many days) energy storage, ensuring the stability, reliability, and resiliency of the electric grid. We also demonstrate that minimum 14 days, ideally 30 days energy storage is needed for continuous uninterrupted service, especially critical for manufacturing facilities. Through a meticulous levelized cost of storage (LCOS) analysis comparing green oil with other LDLS technologies reported in literature, we demonstrate the cost effectiveness of green oil. In this model, green oil serves as stored energy, functions akin to a battery and is efficiently converted into electricity through conventional reciprocating engines or next-generation more efficient turbines. Our findings suggest that green oil derived from diverse organic sources is the most economically viable option for GWh-scale storage, particularly when storage requirements extend beyond a single day. This research thus presents a transformative cost-effective solution to the pressing challenge of LDLS energy storage, accelerating a sustainable and resilient energy future.</span></p>

Research Progress of Hydrogen Storage Materials

Hydrogen energy has become increasingly popular as a clean and renewable source of energy in recent years due to the high levels of carbon pollution worldwide. This essay examines the current research status on various hydrogen storage techniques and materials for hydrogen energy. There are currently three primary hydrogen storage methods: high-pressure gaseous hydrogen storage, low-temperature liquid hydrogen storage, and solid-state hydrogen storage. The most widely employed method in China is high-pressure gaseous hydrogen storage. It entails compressing hydrogen fuel into a container under high pressure. As a result, high-pressure gaseous hydrogen storage is commonly used for stationary hydrogen storage. Low temperature liquid hydrogen storage involves compressing the hydrogen at first and then cooling it down with liquefaction technology. However, due to the strict requirements for compression and container insulation, its actual performance is often limited. This paper focuses on the study of solid hydrogen storage materials. The physical adsorption materials that are successively introduced include carbon-based hydrogen storage materials, metal-organic frameworks (MOFs), and Covalent organic frameworks (COFs). In the current study, carbon-based hydrogen storage materials show better performance only in low-temperature and high-pressure environments, but MOFs and COFs have great prospects in hydrogen storage. The chemical absorption hydrogen storage materials introduced in this paper are metal alloy hydrogen storage and hydrogenation complexes hydrogen storage, mainly rare earth-based hydrogen storage materials and magnesium-based hydrogen storage materials. Among them, magnesium-based hydrogen storage materials have become one of the most promising hydrogen storage materials due to their low cost and good hydrogen storage performance.

Aqueous-phase product treatment and monetization options of wet waste hydrothermal liquefaction: Comprehensive techno-economic and life-cycle GHG emission assessment unveiling research opportunities

While wet waste hydrothermal liquefaction technology has a high biofuel yield, a significant amount of the carbon and nitrogen in the feedstock reports to the aqueous-phase product. Pretreatment of this stream before sending to a conventional wastewater plant is essential or at the very least, advisable. In this work, techno-economic and life-cycle assessments were conducted for the state-of-technology baseline and four aqueous-phase product treatment and monetization options based on experimental data. These options can cut minimum fuel selling prices by up to 13 % and life-cycle greenhouse gas emissions by up to 39 % compared to the baseline. These findings highlight the substantial influence of aqueous produce treatment strategies on the entire wet waste hydrothermal liquefaction process, demonstrating the potential for optimizing economic viability and environmental impact through further research and development of milder treatment methods and diversified by-product valorization pathways.

Improving hydrogen liquefaction efficiency based on the temperature-distributed refrigeration method in regenerative refrigerators

Liquid hydrogen has more advantages than gaseous hydrogen in terms of economy and convenience of storage and transportation owing to its higher energy density. Therefore, the hydrogen liquefaction technology is conducive to promotion and application for hydrogen energy in many sectors. The small-scale regenerative refrigerators usually use helium as the working fluid, which is of the high-low temperature cycle, and bring about a significant entropy generation during the cooling process. In this work, the study on the liquefaction rate and FOM (figure of merit) is implemented with a working fluid of hydrogen. It shows that the entropy generation much decreases when applying the distributed refrigeration method comparing to the high-low temperature cycle, and the COP (coefficient of performance) reaches 80 % when cooling the sensible heat load and conversion heat. The calculation results indicate that the liquefaction rate of the temperature-distributed cycle reaches 34.32 L/d at a refrigeration power of 15 W (a representative case). While the maximum of FOM is 0.483, which is improved by 21.7 % compared with the high-low temperature cycle.

Optimization of liquefaction process based on global meta-analysis and machine learning approach: Effect of process conditions and raw material selection on remaining ratio and bioavailability of heavy metals in biochar

<abstract> <p>Although liquefaction technology has been extensively applied, plenty of biomass remains tainted with heavy metals (HMs). A meta-analysis of literature published from 2010 to 2023 was conducted to investigate the effects of liquefaction conditions and biomass characteristics on the remaining ratio and chemical speciation of HMs in biochar, aiming to achieve harmless treatment of biomass contaminated with HMs. The results showed that a liquefaction time of 1–3 h led to the largest HMs remaining ratio in biochar, with the mean ranging from 84.09% to 92.76%, compared with liquefaction times of less than 1 h and more than 3 h. Organic and acidic solvents liquefied biochar exhibited the greatest and lowest HMs remaining ratio. The effect of liquefaction temperature on HMs remaining ratio was not significant. The C, H, O, volatile matter, and fixed carbon contents of biomass were negatively correlated with the HMs remaining ratio, and N, S, and ash were positively correlated. In addition, liquefaction significantly transformed the HMs in biochar from bioavailable fractions (F1 and F2) to stable fractions (F3) (<italic>P</italic> < 0.05) when the temperature was increased to 280–330 ℃, with a liquefaction time of 1–3 h, and organic solvent as the liquefaction solvent. N and ash in biomass were positively correlated with the residue state (F4) of HMs in biochar and negatively correlated with F1 or F2, while H, O, fixed carbon, and volatile matter were negatively correlated with F4 but positively correlated with F3. Machine learning results showed that the contribution of biomass characteristics to HMs remaining ratio was higher than that of liquefaction factor. The most prominent contribution to the chemical speciation changes of HMs was the characteristics of HMs themselves, followed by ash content in biomass, liquefaction time, and C content. The findings of this meta-analysis contribute to factor selection, modification, and application of liquefied biomass to reducing risks.</p> </abstract>

Review of Reliquefication Plant System for Liquified Natural and Petroleum Gas Carriers

Abstract: The effectiveness of the liquefaction process for natural and petroleum gas is crucial to the supply chains overall production capacity, energy use, economics, and safety. Many academics have developed several traditional methods and undertaken a lot of research on various LNG/LPG processes. The optimization and design of petroleum and natural gas liquefaction processes during the last few years are summarized and discussed in this study. Comparing and contrasting the benefits and drawbacks of various liquefaction methods. Furthermore, highlighted are the recent fast advancements in pressurized liquefaction technology and its anticipated applications.

Liquefied Natural Gas Value Chain: A Comprehensive Review and Analysis

AbstractOver the past few decades, the liquefied natural gas (LNG) business has experienced astounding expansion and gained global relevance. LNG has emerged as a key element in meeting the world's rising energy demand while working to cut carbon emissions, since it is a cleaner and more adaptable energy source. The entire process from natural gas extraction to consumption is covered in the presented analysis of the LNG value chain, starting out by looking at the discovery and production of natural gas reserves, highlighting important innovations and methods used during the extraction stage. The procedures used to treat and purify natural gas in order to meet the strict standards for liquefaction are detailed. Analysis of the liquefaction process reveals numerous liquefaction technologies, e.g. the well‐known conventional liquefaction and the cutting‐edge floating LNG and small‐scale LNG facilities. LNG storage and transportation, as critical components in the value chain, are examined in great detail. When the LNG reaches its destination, regasification plays a crucial role in repurposing it as a gas for distribution and consumption. Regasification technologies, such as conventional onshore terminals, floating storage and regasification units, and land‐based regasification facilities, are covered. Concerns regarding methane emissions and the carbon footprint, the potential for reducing greenhouse gas emissions through new technology, the environmental impact of LNG, and the economics of LNG are also considered across its value chain.

Detailed performance analysis of a novel small-scale biomethane liquefaction plant

In the current global energy scenario, an important role is played by the increasing production of biomethane, which is carbon-neutral when burned. In addition to production processes, it is paramount to increase the construction of liquefaction plants, in order to simplify the transportation and use of biomethane. However, biomethane liquefaction plants have limited diffusion because of the complexity of current biomethane liquefaction technologies, which have been adapted from natural gas liquefaction plants. Therefore, novel biomethane liquefaction plants are needed to assist the increasing demand of biomethane in the global market. In previous papers, an innovative biomethane liquefaction plant was proposed and studied; compared to current liquefaction technologies, the main advantage is given by the use of simplified heat exchangers. In this paper, the plant performance is explored in more detail by changing some operating parameters to study the efficiency of the whole process by means of a parametric analysis. The results confirm a high potential of the proposed plant, in terms of coefficient of performance and compactness of the heat exchangers.

An Innovative Approach for Natural Gas Liquefaction Using a Mixed-Multi-Component-Refrigerant

The natural gas liquefaction is the most expensive and energy-intensive phase in the natural gas-to-liquefied natural gas-to-natural gas chain. In addition, this region has the biggest development potential. As a result, numerous LNG production methods have been developed and are deployed at export facilities around the world. The goal of this study is to describe and assess an innovative approach for mixed-refrigerant (MR) LNG method. The authors have dubbed this technique the MR-X approach. The MR-X process was developed based on the globally proven liquefaction technology C3MR and its large-scale successor AP-X™ (which offers many benefits and flexibility), but with a novel precooling phase construct. In pre-cooling and liquefaction phases, the refrigerant is a combination of methane, nitrogen, propane, ethane, butane, and isobutane. The paper investigates the creation of the MR-X technology, as well as its modelling, energy, and exergy investigations.

Catalytic hydrothermal co-liquefaction of sewage sludge and agricultural biomass for promoting advanced biocrude production

Conventional hydrothermal liquefaction (HTL) technology is inhibited by the complicated feedstock properties, low biocrude yield, and poor biocrude quality. Herein, this work aimed to propose a novel catalytic hydrothermal co-liquefaction (catalytic co-HTL) route for enhancing high-quality biocrude production. Four representative biowastes were applied to determine the synergistic effects in co-HTL treatment. Binary sewage sludge (SS)/wheat straw (WS) presented the highest synergistic effect (14.05%) on biocrude production. Furthermore, homogenous and heterogeneous catalysts (i.e., Na2CO3, HY, SSB, CSB, and Ni@CSB) were comprehensively tested during catalytic co-HTL of binary SS/WS. Biocrude produced over Ni@CSB revealed the highest carbon content at 75.5% and HHV at 36.96 MJ/kg, due to the deoxygenation and desulfurization reactions enhanced by Ni@CSB. Thermalgravimetric behaviors and kinetic studies of biocrude degradation were further analyzed. Moreover, the byproducts (hydrochar and gaseous phase) were characterized. Overall, this study provides an effective and promising route to valorize biowastes into green high-quality biocrude.