Free-Space Optical communication (FSO) offers unregulated bandwidth of up to 200 THz, security, higher speed, unlimited data rate and shortest installation time. However, weather attenuation, especially scintillation, has a massive impact on the performance of the FSO transmission channel. This paper evaluates link availability and effect of scintillation on FSO performance in terms of eye diagrams, Bit Error Rate (BER), Q-factor, and signal-to noise ratio. Our work used data collected from January 2018 to December 2021 by Tanzania Meteorological Authority (TMA) in Mwanza and Arusha regions for link availability and performance analysis. Simulation was performed to determine the FSO link availability, and we analyzed the scintillation effect on FSO performance using Submarine Laser Communication II and Hufnagel Valley (HV) day prediction models. It is observed that the HV day model performs better in predicting scintillation intensity compared to the former. In both regions, for the same transmission power of 20 dBm, the signal quality is better for a distance of 6 km where the BER value is found to be 10-8. These results suggest that, to achieve high-speed data transmissions, the maximum separating distance between FSO transceivers should not exceed 6 km.