Recognizing that wavelength modulation spectroscopy (WMS) is particularly important in the development of high-sensitivity gas sensing systems, this paper presents a detailed analysis of the R 1f /Δ I 1 WMS technique that has recently been successfully demonstrated for calibration-free measurements of the parameters that support detecting multiple gases under challenging conditions. In this approach, the magnitude of the 1f WMS signal (R 1f ) was normalized by using the laser's linear intensity modulation (Δ I 1) to obtain the quantity R 1f /Δ I 1 that is shown to be unaffected by large variations in R 1f itself due to the variations in the intensity of the received light. In this paper, different simulations have been used to explain the approach taken and the advantages that it shows. A 40mW, 1531.52nm near-infrared distributed feedback (DFB) semiconductor laser was used to extract the mole fraction of acetylene in a single-pass configuration. The work has shown a detection sensitivity of 0.32ppm for 28cm (0.089ppm-m) with an optimum integration time of 58s. The detection limit achieved has been shown to be better than the value of 1.53ppm (0.428ppm-m) for R 2f WMS by a factor of 4.7, which is a significant improvement.
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