Visible light communication (VLC) has been viewed as one promising candidate to mitigate the challenging spectrum crisis and radio frequency interference in future 6G mobile communications and networking. Due to the relatively limited baseband modulation bandwidth of VLC light sources—typically, light-emitting diodes—non-orthogonal multiple access (NOMA) techniques have been proposed and explored to enhance the spectral efficiency (SE) of VLC systems. However, almost all reported NOMA VLC schemes focus on well-discussed applications employing a Lambertian light beam configuration and ignore the potential applications with distinct non-Lambertian optical beam configurations. To address this issue, in this work, the performance of non-Lambertian optical beam configuration-based NOMA VLC is comparatively investigated for future 6G mobile networks. The numerical results demonstrate that, for a fundamental two-user application scenario with the far user located at the corner position, a maximum sum rate gain of about 15.6 Mbps could be provided by the investigated distinct non-Lambertian beam-based NOMA VLC, compared with the maximum sum rate of about 93.3 Mbps for the conventional Lambertian configuration with the same power splitting factor.