Limited Regime Research Articles

Respective Roles of Electron-Phonon and Electron-Electron Interactions in the Transport and Quasiparticle Properties of SrVO_{3}.

The spectral and transport properties of strongly correlated metals, such as SrVO_{3} (SVO), are widely attributed to electron-electron (e-e) interactions, with lattice vibrations (phonons) playing a secondary role. Here, using first-principles electron-phonon (e-ph) and dynamical mean field theory calculations, we show that e-ph interactions play an essential role in SVO: they govern the electron scattering and resistivity in a wide temperature range down to 30K, and induce an experimentally observed kink in the spectral function. In contrast, the e-e interactions control quasiparticle renormalization and low temperature transport, and enhance the e-ph coupling. We clarify the origin of the near T^{2} temperature dependence of the resistivity by analyzing the e-e and e-ph limited transport regimes. Our work disentangles the electronic and lattice degrees of freedom in a prototypical correlated metal, revealing the dominant role of e-ph interactions in SVO.

Examining the Indonesian dual banking system: an exploration of market discipline indicators

PurposeThis research aims to investigate the disciplinary functions of depositors and subordinated debt holders within Indonesia's dual banking system, examining the impact of regulatory changes on market discipline.Design/methodology/approachThe study employs a comprehensive analysis of the dual banking system in Indonesia over 15 years. Utilizing a non-public dataset from the Financial Services Authority and the Indonesia Deposit Insurance Corporation, the study employs propensity score matching and difference-in-differences analysis.FindingsThe findings reveal distinct patterns in the exercise of market discipline by depositors over different regulatory regimes. During the blanket guarantee regime (2002–2005), depositors lacked the incentive to monitor banks but resumed their disciplinary role under the limited guarantee regime (2005–2017). Islamic banks faced simultaneous market and regulatory discipline, with market discipline prevailing.Originality/valueThis study contributes to the literature by providing novel insights into the interplay between regulatory changes, market discipline and depositor behavior within Indonesia's dual banking system. The utilization of a comprehensive non-public dataset from regulatory authorities adds to the originality of the research.

Capture zone scaling in 2D Ge island nucleation on Si(111)-(7 × 7) at elevated temperatures

Recently we have studied the concentration N2D of 2D Ge island nucleated on large-scale Si(111)-(7 × 7) terraces at 550 − 650 °C as function of the substrate temperature T and Ge deposition rate R [J. Cryst. Growth. 531 (2020) 125347], where we have shown that N2D(R) dependence is characterized by a power law with scaling exponent χ = 1 ± 0.1. However, in the frames of classical Venables rate-equation approach, the obtained range of χ values do not allow one to unambiguously determine the critical nucleus size i, since χ = 1 ± 0.1 can be attributed to both diffusion limited (DL) and attachment limited (AL) growth regimes. In order to determine an exact i size and growth kinetics, in this work, we have investigated the scaled capture-zone distribution (CZD) of nucleated 2D Ge islands on the same Ge/Si(111)-(7 × 7) samples and described it by the generalized Wigner distribution Pβ=aβAβexp-bβA2, where Pβ is the probability density of getting into some region of capture zone values, A is normalized Voronoi cell area for 2D island, β=iχ is scaling parameter directly related to the critical nucleus size i. It has been shown that the kinetics of 2D Ge island nucleation on the wide Si(111)-(7 × 7) terraces at elevated temperatures should procced under AL growth kinetics with i = 3–5 particles.

Limitation of property ownership in the conditions of the legal regime of martial law in Ukraine

The article is devoted to the disclosure of the issue of the limitation of property rights during the legal regime of martial law and measures that can be applied to property are analyzed. The author states that one of the unresolved legal problems of today is the problem of the possibility and proper implementation of the right to property ownership of measures and methods that can limit the rights of owners to property during martial law. The author, when analyzing the limitation of the constitutional right to own, use and dispose of one’s property, emphasized the uncertainty in the legislation of the mechanism of limitation and the lack of detail in which parts of the rights of owners may be limited. In the article, the author investigated such measures during the martial law regime as forced alienation of property and confiscation of property. Considering methods of forced alienation of property or seizure of property under martial law, the author found out that forced alienation of property should take place on the condition of prior full restitution of property or with subsequent full restitution of the value of the property. Considering the issue of confiscation of property, the author notes that confiscation of property, under the conditions of the legal regime of martial law, occurs without compensation for the value of the property. In the article, the author revealed the issue of receiving compensation for forcibly alienated property, which the author proposes to divide into two types: preliminary full compensation for the value of forcibly alienated property and subsequent full compensation for forcibly alienated property. During the research, the author considered the issue of making a decision on the introduction and implementation of measures of forced alienation of property or seizure of property and the implementation of such a decision. In the article, the author pays attention to the issue of the return of forcibly alienated property, which was preserved after the abolition of the legal regime of martial law, and the legal grounds and conditions for such return of property. According to the results of the research, the author claims that the realization of the right of ownership during the operation of the legal regime is of a limited nature, since there is a temporary limited regime during which the full realization of the right of ownership is not always possible.

Effect of deposition regime transition on the properties of Al:ZnO transparent conducting oxide layer by radio frequency magnetron sputtering system

High-quality zinc oxide thin films doped with aluminium adatoms have effectively been fabricated on pristine soda-lime silica glass substrates via radio frequency magnetron sputtering system. The deposition temperature was varied to explore the impact of deposition regime transition of as-deposited Al:ZnO thin films on their performance as transparent conducting oxide layers. In particular, the depositions were conducted at room temperature, 100 °C, 200 °C, and 300 °C, allowing for a comprehensive assessment of the resulting films. The Raman spectra depicted the modulation of Raman bands in correlation with the deposition regime transition, illustrating the impact of thermal induction on various properties of the as-deposited aluminium-doped zinc oxide thin films. Atomic force microscopy reveals the transformation from nearly spherical to elongated shape structure was obtained as the deposition process shifted from kinetic limited to thermodynamic limited regimes. The phase analysis and grazing incident of x-ray diffractometer disclose a single crystal orientation has been achieved at thermodynamic limited regime. However, two different crystal planes were predominant comparing between the surface and structural of as-deposited aluminium-doped zinc oxide thin films. It is also evident that a highly transparent with low lattice strain and better carrier concentrations of as-deposited aluminium-doped zinc oxide thin films were realized at thermodynamic limited regimes.

How molecular architecture defines quantum yields

Understanding the intricate relationship between molecular architecture and function underpins most challenges at the forefront of chemical innovation. Bond-forming reactions are particularly influenced by the topology of a chemical structure, both on small molecule scale and in larger macromolecular frameworks. Herein, we elucidate the impact that molecular architecture has on the photo-induced cyclisations of a series of monodisperse macromolecules with defined spacers between photodimerisable moieties, and examine the relationship between propensity for intramolecular cyclisation and intermolecular network formation. We demonstrate a goldilocks zone of maximum reactivity between the sterically hindered and entropically limited regimes with a quantum yield of intramolecular cyclisation that is nearly an order of magnitude higher than the lowest value. As a result of the molecular design of trifunctional macromolecules, their quantum yields can be deconvoluted into the formation of two different cyclic isomers, as rationalised with molecular dynamics simulations. Critically, we visualise our solution-based studies with light-based additive manufacturing. We formulate four photoresists for microprinting, revealing that the precise positioning of functional groups is critical for resist performance, with lower intramolecular quantum yields leading to higher-quality printing in most cases.

Transition from the regime of thermionic emission to the space-charge limited current regime under strong Shottky effects

Transition from the regime of thermionic emission to the space-charge limited current regime under strong Shottky effects

Modeling the Co-permeation of hydrogen isotopes through metals in all rate-limited regimes

Tritium safety plays a crucial role in D-T fusion engineering. During normal operations, tritium(T) is typically dissolved with protium(H) or deuterium(D) in structural materials. However, there are still controversial issues related to the synergistic isotopic effects when considering T permeation through metals with H/D. In this work, a numerical model is built to describe the co-permeation behavior of multi-component hydrogen isotopes through metals in all rate-limited regimes. This model involves isotope exchange reactions in the gas phase, molecular dissolution, and atomic recombination at the gas-solid interface, as well as the diffusion process in the bulk. By simulating the mixed hydrogen gas permeation through various metals, different results are observed. In surface limited regime, the effective permeation flux of D is slightly enhanced by the presence of H due to isotopic effect. In diffusion-limited regime, the recombination of heteronuclear hydrogen molecules (HD) will deviate the equilibrium concentration of D on the upstream side from Sievert's Law, thereafter suppressing the D permeation flux on the downstream side.

Efficient pyramid channel attention network for pathological myopia recognition with pretraining-and-finetuning

Pathological myopia (PM) is the leading ocular disease for impaired vision worldwide. Clinically, the characteristics of pathology distribution in PM are global-local on the fundus image, which plays a significant role in assisting clinicians in diagnosing PM. However, most existing deep neural networks focused on designing complex architectures but rarely explored the pathology distribution prior of PM. To tackle this issue, we propose an efficient pyramid channel attention (EPCA) module, which fully leverages the potential of the clinical pathology prior of PM with pyramid pooling and multi-scale context fusion. Then, we construct EPCA-Net for automatic PM recognition based on fundus images by stacking a sequence of EPCA modules. Moreover, motivated by the recent pretraining-and-finetuning paradigm, we attempt to adapt pre-trained natural image models for PM recognition by freezing them and treating the EPCA and other attention modules as adapters. In addition, we construct a PM recognition benchmark termed PM-fundus by collecting fundus images of PM from publicly available datasets. The comprehensive experiments demonstrate the superiority of EPCA-Net over state-of-the-art methods in the PM recognition task. For example, EPCA-Net achieves 97.56% accuracy and outperforms ViT by 2.85% accuracy on the PM-fundus dataset. The results also show that our method based on the pretraining-and-finetuning paradigm achieves competitive performance through comparisons to part of previous methods based on traditional fine-tuning paradigm with fewer tunable parameters, which has the potential to leverage more natural image foundation models to address the PM recognition task in limited medical data regime.

Capillarity in Interfacial Liquids and Marbles: Mechanisms, Properties, and Applications.

The mechanics of capillary force in biological systems have critical roles in the formation of the intra- and inter-cellular structures, which may mediate the organization, morphogenesis, and homeostasis of biomolecular condensates. Current techniques may not allow direct and precise measurements of the capillary forces at the intra- and inter-cellular scales. By preserving liquid droplets at the liquid-liquid interface, we have discovered and studied ideal models, i.e., interfacial liquids and marbles, for understanding general capillary mechanics that existed in liquid-in-liquid systems, e.g., biomolecular condensates. The unexpectedly long coalescence time of the interfacial liquids revealed that the Stokes equation does not hold as the radius of the liquid bridge approaches zero, evidencing the existence of a third inertially limited viscous regime. Moreover, liquid transport from a liquid droplet to a liquid reservoir can be prohibited by coating the droplet surface with hydrophobic or amphiphilic particles, forming interfacial liquid marbles. Unique characteristics, including high stability, transparency, gas permeability, and self-assembly, are observed for the interfacial liquid marbles. Phase transition and separation induced by the formation of nanostructured materials can be directly observed within the interfacial liquid marbles without the need for surfactants and agitation, making them useful tools to research the interfacial mechanics.

Temperature-dependent epitaxial evolution of carbon-free corundum α-Ga2O3 on sapphire

Unintentionally doped carbon impurities from organometallic precursors are primary sources of carrier compensation and mobility degradation in wide bandgap semiconductors, leading to lowered performance of power electronic devices. To address this challenge, carbon-free α-Ga2O3 single-crystalline thin films were heteroepitaxially grown on sapphire substrates by using gallium inorganic precursors through a mist chemical vapor deposition technique. Determined through a temperature dependence of growth rates, three distinct growth regimes are identified: the surface reaction limited regime below 480 °C, the mid-temperature mass-transport limited regime (480 °C–530 °C) and the high temperature limited regime related to desorption or phase transition. With an optimized around 530 °C, the densities of screw and edge dislocations are reduced to 7.17 × 106 and 7.60 × 109 cm−2, respectively. Notably, carbon incorporation was eliminated in the α-Ga2O3 grown by inorganic GaCl3, as evidenced by the absence of carbon-related vibrational bands in Raman scattering analysis, while crystalline quality was comparable to that grown with organometallic precursors. The high solubility of GaCl3 in water is expected to enable the rapid growth of high purity α-Ga2O3 with improved electronic transport performances.

Gravitational wave signals from early matter domination: interpolating between fast and slow transitions

An epoch of matter domination in the early universe can enhance the primordial stochastic gravitational wave signal, potentially making it detectable to upcoming gravitational wave experiments. However, the resulting gravitational wave signal is quite sensitive to the end of the early matter-dominated epoch. If matter domination ends gradually, a cancellation results in an extremely suppressed signal, while in the limit of an instantaneous transition, there is a resonant-like enhancement. The end of the matter dominated epoch cannot be instantaneous, however, and previous analyses have used a Gaussian smoothing technique to account for this, and consider only a limited regime around the fast transition limit. In this work, we present a study of the enhanced gravitational wave signal from early matter domination without making either approximation and show how the signal smoothly evolves from the strongly suppressed to strongly enhanced regimes.

A single-image GAN model using self-attention mechanism and DenseNets

Image generation from a single natural image using generative adversarial networks (GANs) has attracted extensive attention recently due to the GANs’ practical ability to produce photo-realistic images and their potential applications in computer vision. However, learning a powerful generative model that generates realistic, high-quality images from only a single natural image is still a challenging problem. Training GANs in limited data regimes often causes some issues, such as overfitting, memorization, training divergence, poor image quality, and a long training time. In this study, we investigated the state-of-the-art GAN models in computer vision tasks. We conducted several experiments to deeply understand the challenges of learning a powerful generative model. We introduced a novel unconditional GAN model that produces realistic, high-quality, diverse images based on a single training image. In our model, we employed a self-attention mechanism (SAM), a densely connected convolutional network (DenseNet) architecture, and a relativistic average least-squares GAN with gradient penalty (RaLSGAN-GP) for both the generator and discriminator networks to perform image generation tasks better. SAM controls the global contextual information level. It is complementary to convolutions for large feature maps and gives the generator and discriminator more capability to capture long-range dependencies in feature maps. It compensates for the long training time and low image quality issues. DenseNet connects each layer to every other layer in a feed-forward manner to ensure maximum information flow between layers in the network. It is highly parameter efficient and requires less computation to achieve high performance. It provides improved information and gradient flow throughout the network for easy training. It has a regularizing effect that reduces overfitting in image generation. RaLSGAN-GP further improves data generation quality and the stability of our model at no computational cost and provides much more stable training. Thanks to the appropriate combination of SAM, DenseNet, and RaLSGAN-GP, our model successfully generates realistic, high-quality, diverse images while maintaining the global context of the training image. We conducted experiments, user studies, and model evaluation methods to test our model’s performance and compared it with the previous well-known models on three datasets (Places, LSUN, ImageNet). We demonstrated our model’s capability in image synthesis and image manipulation tasks. In our experiments, we showed that our model utilized parameters more efficiently, prevented overfitting, better captured the internal patch statistics of images with complex structures and textures, achieved comparable performance in single image generation tasks, and had much better visual results than its competitive peers. User studies confirmed that the images generated by our model were commonly confused with the original images. Our model can provide a powerful tool for various image manipulation tasks as well as data augmentation in domains dealing with limited training data.

Mg-Composition Dependent Cycle Stability in Zn<sub>1-x</sub>Mg<sub>x</sub>O Li-ion Battery: Transition from Electronic Transport-Limited to Ionic Transport Limited Cycles

This study explores Mg-composition dependent cycle stability in a Zn<sub>1-x</sub>Mg<sub>x</sub>O Li-ion battery, where battery cycles transition from an electronic transport-limited to an ionic transport limited regime. We investigated the impact of Mg doping in Zn<sub>1-x</sub>Mg<sub>x</sub>O nanocrystals on Li-ion battery performance, focusing on Mg compositions between x=0.05 and x=0.15. Mg composition dependent structural and electrical properties were explored using field effect transistors (FETs) and various microscopic/spectroscopic methods. The electronic conductivity was found to be sensitive to changes in Mg composition. Consistently, the initial capacity decreased with an increase in Mg composition, aligning with the reduction in electronic conductivity due to Mg doping. However, with successive cycles, the capacity became independent of the electronic conductivity, an outcome attributed to the formation of a solid-electrolyte interphase (SEI) and the conversion reactions. Initially, Mg doping reduces electronic conductivity due to increased carrier trapping, leading to lower discharge capacity. However, as cycling progresses, the impact of Mg doping diminishes. The formation of the SEI layer becomes more influential, significantly affecting Li-ion transport. Over time, factors like SEI formation, conversion reaction dynamics, and structural changes within the electrode start to dominate the battery's capacity, rather than the initial electronic conductivity influenced by Mg doping. This understanding can guide the development of materials with lower resistance, facilitating faster charging and discharging rates. More importantly, this study indicates that the initial capacity is closely tied to the conductivity of the Zn<sub>1-x</sub>Mg<sub>x</sub>O material.

Vortex-induced rotation of a square cylinder under the influence of Reynolds number and density ratio

Numerical simulations are carried out on the vortex-induced rotations of a freely rotatable rigid square cylinder in a two-dimensional uniform cross-flow. A range of Reynolds numbers between 40 and 150 and density ratios between 0.1 and 10 are considered. Results show eight different characteristic regimes, expanding the classification of Ryu & Iaccarino (J. Fluid Mech., vol. 813, 2017, pp. 482–507). New regimes include the transition and wavy rotation regimes; in the ${\rm \pi}$ -limited oscillation regime we observe multipeak subregimes. Moment-generating mechanisms of these regimes and subregimes are further elucidated. A phenomenon related to the influence of density ratio is the tooth-like shape of the ${\rm \pi} /2$ -limit oscillation regime observed in the regime map, which is explained as a result of the imbalance relation between the main frequencies of rotation response and the vortex shedding frequency. In addition, existence of multiple regimes and multistable states are discussed, indicating multiple stable attractive structures in phase space.

Publisher's Note: “Investigation of phonon lifetimes and magnon–phonon coupling in YIG/GGG hybrid magnonic systems in the diffraction limited regime” [J. Appl. Phys. 135, 104401 (2024)

Publisher's Note: “Investigation of phonon lifetimes and magnon–phonon coupling in YIG/GGG hybrid magnonic systems in the diffraction limited regime” [J. Appl. Phys. 135, 104401 (2024)

The influence of the mass transport regime on laser chemical vapor deposited carbon fibers

Laser Chemical Vapor Deposition (LCVD) is a process through which fibers are additively deposited by the dissociation and deposition of a precursor gas into the solid phase under a translating laser focal point. In the hyperbaric pressure conditions, LCVD has two identified reaction regimes. The first being limited by surface reaction kinetics (SRK) and the second being limited by mass transport (MT). This article examines the effects of mass transport (MT) limitations on carbon fiber growth using either ethane (C2H6) or ethylene (C2H4). Both hydrocarbon precursors reveal a growth rate reduction when transitioning from SRK-to-MT to meet the no-slip condition in fluid dynamics. This transition correlates to a fiber microstructure change from a core shell morphology with a graphitic structure (SRK) to a nodular morphology with an amorphous structure (MT). The fiber fracture stress is generally found to be higher in the MT than SRK regime because of the reduction of easily cleaved graphitic planes in the MT fibers. Collectively, these results demonstrate the importance of the MT limited growth regime and how fiber characteristics can be manipulated when grown in this regime.

Faith-based organisations and disaster management in informal urban Accra

ABSTRACT Disaster risks in African cities are compounding due to the triple convergence of climate change impacts, unplanned urbanisation, and entrenched socio-spatial inequities. Disaster events are, therefore, common with disproportionate impacts on informal residents yet resting within reactive and extremely limited disaster management regime that leaves behind many voids in disaster risk reduction. Drawing on a qualitative approach and situated in a disaster-vulnerable community of Dome, Greater Accra, this paper unpacks the activities of Faith-based Organisations (FBOs) in filling the voids in disaster preparedness, response, and recovery. This research is timely because elevating and integrating FBOs activities in disaster management could concretise multi-actor frameworks for disaster risk reduction that are culturally sensitive, locally situated, and socially engaged. The paper documents that experimenting with formal-informal collaborations in community-based risk reduction and leveraging the practices and experiences of FBOs in disaster risk reduction holds the potential for building disaster prevention and resilient capacities in informal urban riskscapes. The study recommends that active collaboration between FBOs and government organisations can assist in bridging crisis management gaps and improving community disaster resilience.

An OpenFOAM multi-region solver for tritium transport modeling in fusion systems

The transport, permeation and retention of tritium inside nuclear fusion reactors is a topic of great interest due to the scarcity of the isotope, its ease of diffusion through materials and its radioactivity. An accurate balance of tritium is needed in all the fuel cycle, and each loss term needs to be evaluated in detail. In this context, reliable and flexible tools to evaluate tritium permeation and retention are a necessity for the development of fusion technologies. This work presents the OpenFOAM PermeAtion Solver for Tritium Analysis Foam (pastaFoam) solver and two custom boundary conditions, along with a series of verification and validation cases. The solver inherits all capabilities of the base solver, chtMultiRegionFoam, and is capable to simulate hydrogen transport in coupled fluid–solid systems in the presence of hydrogen traps, under diffusion limited regime or accounting for surface effects. All features are tested against analytical solutions and results are compared with other tritium transport codes. Agreement with experimental data is aligned with results of numerical benchmarks from literature.

Investigation of phonon lifetimes and magnon–phonon coupling in YIG/GGG hybrid magnonic systems in the diffraction limited regime

Quantum memories facilitate the storage and retrieval of quantum information for on-chip and long-distance quantum communications. Thus, they play a critical role in quantum information processing and have diverse applications ranging from aerospace to medical imaging fields. Bulk acoustic wave (BAW) phonons are attractive candidates for quantum memories because of their long lifetimes and high operating frequencies. In this study, we establish a modeling approach to design hybrid magnonic high-overtone bulk acoustic wave resonator (HBAR) structures for high-density, long-lasting quantum memories, and efficient quantum transduction devices. We illustrate the approach by investigating a hybrid magnonic system, consisting of a gadolinium iron garnet (GGG) thick film and a patterned yttrium iron garnet (YIG) thin film. The BAW phonons are excited in GGG thick film via coupling with magnons in the YIG thin film. We present theoretical and numerical analyses of the diffraction-limited BAW phonon lifetimes, modeshapes, and magnon–phonon coupling strengths in YIG/GGG planar and confocal HBAR (CHBAR) structures. We utilize Fourier beam propagation and Hankel transform eigenvalue problem methods and compare the two methods. We discuss strategies to improve the phonon lifetimes in the diffraction-limited regime, since increased lifetimes have direct implications on the storage times of quantum states for quantum memory applications. We find that ultra-high cooperativities and phonon lifetimes on the order of ∼105 and ∼10 milliseconds, respectively, could be achieved using a CHBAR structure with 10μm YIG lateral area. Additionally, high integration density of on-chip memory or transduction centers is naturally desired for high-density memory or transduction devices. The proposed CHBAR structure will offer more than 100-fold improvement of integration density relative to a recently demonstrated YIG/GGG device. Our results will have direct applicability for devices operating in the cryogenic or milliKelvin regimes. For example, our study will inform the design of HBAR devices that could couple with superconducting qubits for promising quantum information platforms.