Light Rare Earth Element Patterns Research Articles

Petrogenesis of the Girnar Complex in the Deccan Traps Province, India

AbstractThe c. 66 Ma Girnar Complex of the Deccan Traps consists of various mafic to silicic rocks and provides a unique setting for understanding the dynamics of magma chamber processes. The intrusive alkaline rocks in Girnar are diorites/monzodiorites and contain syenite/nepheline syenite veins. Several (alkaline) mafic dykes cut the alkaline rocks. These rocks are surrounded by intrusive tholeiitic gabbro and extrusive basaltic flows and a silicic (SiO2 > 65 wt%) ring dyke at the outer margin of the complex. The tholeiitic gabbro and basaltic lavas have relatively flat light rare earth element (REE) patterns (La/SmN ~ 0.8 to 1.8) with positive Eu anomalies of 1.1–1.3. The tholeiitic basalts formed by 3–5% partial melting of an incompatible element depleted mid-ocean ridge basalts (MORB)-like source. Accumulating c. 20–30% of (olivine, orthopyroxene, clinopyroxene, and plagioclase) crystals from the tholeiitic melt generated the tholeiitic gabbro. The alkaline rocks display enriched light REE patterns (La/SmN ~ 5.0 to 7.8) consistent with (~9%) partial melting of a spinel lherzolite source, different from the MORB-like source for tholeiitic rocks. The subsequent 58–72% fractional crystallization of olivine, clinopyroxene, plagioclase, orthoclase, spinel, and apatite mineral assemblage formed the alkaline rocks. Reverse and oscillatory zoning in plagioclase (An30 to An50) phenocrysts of the silicic rocks suggest that convective movement of crystals in a magma chamber led to initial crystallization of high-An plagioclase in the hotter zone of the magma chamber, followed by addition of low-An plagioclase in cooler regions of the magma chamber. Pressure estimates from shattered (xenocryst or antecryst) clinopyroxene crystals in silicic rocks give a minimum value of 450 MPa. Ti-in-quartz geothermometry gives a crystallization temperature between 690°C and 1080°C. The distinct isotopic composition of the silicic rocks (87Sr/86Sri = 0.7204–0.7275, εNd(i) = −6.8 to −7.3, 206Pb/204Pbi = 18.74–19.02, 207Pb/204Pbi = 15.76–15.79, 208Pb/204Pbi = 39.63–40.03, εHf(i) = −6.0 to −7.3) further indicates that the silicic rocks assimilated 7 to 9% granitic basement rocks. Overall, therefore, the Girnar Complex started to form with the emplacement of mafic rocks (both alkaline and tholeiitic) in the central part along a reactivated fault lineament and silicic rocks along the concentric marginal fault. Petrography, mineral chemistry, and whole-rock geochemical and Sr-Nd-Pb-Hf isotope ratios of the Girnar Complex rocks indicate that despite the close spatial association of tholeiitic gabbro and basalt, alkaline rocks, and silicic rocks, these rocks originated from multiple sources and evolved in a complex magma drainage and storage network in a continental setting of the Deccan Large Igneous Province (LIP).

Tectonic evolution of circum-Rodinia subduction: Evidence from Neoproterozoic A-type granitic magmatism in the Central Tianshan Block, northwest China

Neoproterozoic igneous rocks associated with the assembly and configuration of the Rodinia supercontinent are widely distributed in the Central Tianshan Block, southwestern Central Asian Orogenic Belt (CAOB), northwest China. The Central Tianshan Block is an important geological unit in tectonic reconstructions of the CAOB and Rodinia. However, the early Neoproterozoic tectonic framework and evolution of the Central Tianshan Block are poorly understood. Here we present a geochronological, mineral and whole-rock geochemical, and Nd–Hf isotopic study of early Neoproterozoic augen granites from the Bingdaban area. In situ zircon U–Pb dating shows that the augen granites have crystallization ages of 1002–992 Ma. The augen granites have high SiO2 (70.46–76.24 wt%) and K2O (3.36–4.96 wt%) contents, and FeOT/(FeOT + MgO) ratios (0.76–0.84), low Mg# values (29–39), slightly enriched light rare earth element patterns, enriched large-ion lithophile elements, depleted high-field-strength elements (e.g., Nb, Ta, and Ti), and high 10,000 × Ga/Al ratios (2.3–8.3) and Zr + Nb + Ce + Y contents (256–408 ppm). The augen granites have geochemical features typical of A2-type granites, variable εNd(t) values of –1.64 to +6.87 and Nd model ages of 1.78–1.08 Ga, and zircon εHf(t) values of −1.96 to +6.42 with Hf model ages of 1.98–1.48 Ga. These data indicate the granites had a juvenile crustal-dominated source, with subordinate input of ancient crustal components, and formed in a subduction-related extensional setting. The extension might have been related to slab break-off beneath Rodinia. The early Neoproterozoic igneous rocks in the Central Tianshan and adjacent microcontinental blocks in the southwestern CAOB formed at or near an active continental margin, possibly part of the circum-Rodinian subduction zone during or after the assembly of Rodinia. Similar Neoproterozoic magmatism in the Central Tianshan and Yili blocks suggests that they had a comparable crustal evolution and a close tectonic and paleogeographic relationship during the Neoproterozoic. However, significant age and isotopic differences characterize the Central Tianshan–Yili blocks and Tarim Craton, suggesting that the Central Tianshan–Yili blocks were not separated from the Tarim Craton during the early Neoproterozoic.

Intra-oceanic subduction in the southeastern Paleo-Asian ocean: Evidence from early Permian gabbro of the Diyanmiao ophiolite in central Inner Mongolia, North China

Investigation of intra-oceanic subduction can improve our understanding of plate tectonic processes and the history of continental growth. Evidence for intra-oceanic subduction in the Paleo-Asian Ocean has recently become an important focus of research, including the Diyanmiao ophiolite in central Inner Mongolia, North China. Here, we report a newly discovered occurrence of early Permian gabbro in the Diyanmiao ophiolite zone. The gabbro yields a weighted mean zircon U–Pb age of 294.4 ± 2.2 Ma. The gabbro samples are characterized by moderate SiO2 (47.32–50.51 wt%), low TiO2 (0.26–0.54 wt%) and K2O (0.04–0.75 wt%), and high Na2O (1.84–4.52 wt%) contents, high Na2O/K2O ratios (2.92–58.29), and depleted chondrite-normalized light rare Earth element patterns that are similar to N-MORB. The gabbros show slightly lower contents of high-field-strength elements (e.g., Nb, Ta, and Ti) and slightly higher contents of large-ion lithophile elements (e.g., K, Rb, Ba, and U) relative to N-MORB. In addition, the gabbros show high εNd (t) values (8.0–9.8) that are similar to those of forearc basalt in the Diyanmiao ophiolite and N-MORB. Integrating these new data with available results for ophiolite and arc-magmatic rocks of central Inner Mongolia, we propose that the studied gabbro was formed during the initial stage of intra-oceanic subduction and that the Paleo-Asian Ocean was still in a subduction setting during the early Permian.

Ultra-depleted melt product preserved in the Ladong ophiolitic peridotites of the North Qilian Orogenic Belt, Northern Tibet

In Earths upper mantle, the compositions of both migrating magmas and solid residues are basically controlled by source materials and melting behavior which are related to tectonic dynamics. Thus, infrequent geochemical signatures recorded by ophiolitic lithologies may reflect a unique source or specific melting history. Here, we report whole-rock and mineral compositions of the harzburgite, wehrlite, and olivine websterite in the Ladong ophiolite complex of the North Qilian Orogen Belt (northern Tibet). The dominant spinel harzburgite has high spinel Cr# values of 65–70 and light rare earth element (LREE) depleted patterns (LaN/YbN = 0.04–0.12), resembling the residua after 20% or more of melt extraction. Wehrlite lenses within the harzburgite display extremely depleted LREE patterns (whole-rock LaN/YbN = 0.04–0.05) and low Na and Ti contents in clinopyroxene. They are interpreted as products of reaction between the host harzburgite and an ultra-depleted melt produced by asthenospheric decompression melting. Outcrops of olivine websterite have well-equilibrated triple junction textures between pyroxene grains and high-Mg olivine (Fo = 85–86; bulk rock Mg# = 93), consistent with a cumulate origin. In the olivine websterite, the depleted LREE concentrations (LaN/YbN = 0.05–0.18) in clinopyroxene suggest a less depleted nature than the wehrlite-forming melt. Thus, the Ladong ophiolite records two episodes of melt activity that produced depleted to ultra-depleted magmas, which may have been generated during subduction initiation in eastern Proto-Tethyan belt.

Late Carboniferous bimodal volcanic rocks of the West Junggar Terrane, NW China: Implications for the postcollisional tectonic setting of the southwestern CAOB

ABSTRACT The West Junggar terrain (WJT), as a crucial part of the Central Asian Orogenic Belt (CAOB), is distributed with numerous igneous rocks, which provide critical information for crustal growth. However, the closure of the Junggar Ocean (JO) and the beginning of the postcollisional tectonic stage of the WJT have been controversial. This study delimited the regional lithologic units based on remote sensing geological mapping and recognized a series of bimodal volcanic rocks (BVR) in Hala’alate Mountain of the WJT. LA-ICP‒MS zircon U‒Pb geochronology and geochemistry were used to discuss the petrogenesis of the BVR and determine the stage of regional tectonic evolution. Geochronological results yield crystallization ages of 302 ± 4 Ma, 298 ± 2 Ma, 304 ± 1 Ma, and 303 Ma± 2 Ma for the basaltic andesite, basalt, and two rhyolitic samples, respectively. Basalts and basaltic andesites are calc-alkaline, and display enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) and depletion in high field strength elements (HFSEs). Notably, basaltic andesites in this area were once misjudged as sanukitoids owing to their low contents of Mg#, Ni, Cr, and other characteristics that are inconsistent with the typical definition of sanukitoids. The rhyolites are A2-type granitoids with high SiO2 contents and are depleted in Nb, Ta, P, Ti, and Sr, showing enriched LREE patterns with negative Eu anomalies. These features indicate that the magma of the mafic end-member of the BVR is derived from the partial melting of the depleted lithospheric mantle, whereas the felsic end-member magma can be associated with the remelting of the lower crust due to the upwelling and underplating of mafic magma. In combination with previous studies of simultaneous basic dikes and felsic rocks, a postcollisional tectonic stage was proposed for the WTJ during the late Carboniferous, suggesting that the JO was closed.

Formation of the Nephrite Deposit With Five Mineral Assemblage Zones in the Central Western Kunlun Mountains, China

Abstract The Saidikulam nephrite deposit, which is famous for its high-quality white nephrite no matter in history and nowadays, is located in the eastern part of the Western Kunlun Orogen, in the northwestern margin of the Tibetan Plateau, Yutian County, Xinjiang, China. Field investigations and petrographic observations revealed the presence of five mineral assemblage zones from granodiorite to dolomitic marble in the Saidikulam nephrite deposit: slightly epidote-altered granodiorite → epidote-altered diopsidite → nephrite → calcite tremolitite → calcite-bearing dolomitic marble. However, little is known about the relationships among these five zones or the formation age of the deposit. The slightly epidote-altered granodiorite consists of plagioclase, orthoclase, quartz, biotite, and epidote, with accessory apatite, zircon, and allanite. They exhibit slightly negative Eu anomalies (0.69–0.72), with declined light rare earth element (LREE) and flat heavy rare earth element (HREE) patterns. They are also strongly enriched in Rb, Zr, U, and Sm and depleted in Hf, Ti, P, and Nb. The epidote-altered diopsidite close to the granodiorite intrusions is a relatively high-temperature metasomatic rock composed of Fe-rich diopside and actinolite, while the calcite tremolitite adjacent to the dolomitic marble is a relatively low-temperature rock composed of prismatic tremolite and calcite. The main mineral component of the nephrite is tremolite, with minor epidote, chlorite, apatite, calcite, graphite, and allanite. The nephrites have low ∑REE contents (4.38–18.53 ppm), with declined LREE and flat HREE patterns. All of the analyzed nephrite exhibits pronounced negative Eu anomalies (δEu = 0.20–0.82), and they are strongly enriched in Rb, U, and Ti and relatively depleted in Ba and HFSEs. SHRIMP U–Pb dating of zircons from the granodiorite yielded a Concordia age of 453.8 ± 3.7 Ma, which is interpreted as the upper limit of the Saidikulam nephrite formation age. The zircons in the epidotized syenite in the deposit yielded a SHRIMP Concordia U–Pb age of 489.2 ± 4.2 Ma. These two ages indicate that the dolomitic marble experienced at least two thermal events. The approximate ages of the nephrite deposits along the giant Kunlun-Altyn Tagh belt indicate that the closure of the Proto-Tethys may have been the predominant driving force for the formation of the whole nephrite deposits. The multistage metasomatism and the Fe absorption of epidote-altered diopsidite had a positive impact on the formation of high-quality nephrite.

Magma evolution of the South China Sea basin from continental-margin rifting to oceanic crustal spreading: Constraints from In-situ trace elements and Sr isotope of minerals

The South China Sea (SCS) has undergone a complete Wilson cycle. We studied the volcanic rocks from IODP Sites U1502, U1500, U1431, U1433, and U1434 that record the exact mantle dynamics of the SCS basin from continental rifting to oceanic crustal spreading. We present in-situ major and trace element data for minerals (olivine, clinopyroxene, and plagioclase) and melt inclusions; and in-situ Sr isotopic ratios for plagioclases from the volcanic samples. All SCS volcanic rocks belong to the tholeiite series. Most Site U1431 basalts are slightly depleted in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) and similar to that of normal mid-oceanic ridge basalts (N-MORB). All clinopyroxenes and olivines, and the calculated equilibrium melts of clinopyroxene cores display depletion of LREEs and enrichment of heavy rare earth elements (HREEs) similar to N-MORB-type primary magma. Thus, these volcanic rocks are likely formed by the extension decompression partial melting of shallow depleted magma. The Sites U1502, U1500, U1433, and U1434 bulk-rocks and melt inclusions show flat LREE and HREE patterns similar to that of enriched MORB (E-MORB), likely attributed to the partial melting of a depleted mantle source with different degrees of lower continental crustal contamination. The increase in 87Sr/86Sr ratios from core to rim in Site U1500 plagioclases further prove the crustal contamination during magmatism. Site U1431 clinopyroxene and Site U1500 plagioclase show normal zoning textures and slight enrichment of incompatible elements in their rims but depletion in their cores, likely indicating significant crystallization of late-stage differentiated melts. Although some clinopyroxene and plagioclase were likely crystallized in a relatively closed environment, the existence of melt inclusions and the large Sr isotopic variations between the plagioclase rim and groundmass suggest a dynamic and open magmatic system that likely experienced melt–rock interactions and magma mixing processes. Melt supply rate changes from low to high during the SCS evolution process from initial rifting (Site U1500) to later spreading (Sites U1431 and U1433) indicating that: (1) the number of high-An plagioclase-hosted melt inclusions has gradually decreased; and (2) the zoning textures of clinopyroxene and plagioclase have gradually changed from simple to complex. The influence of mantle plumes and the upwelling of fertile subduction-related asthenospheric magma were negligible during the continental-margin breakup and initial SCS spreading, but played an important role during the late SCS spreading period, as revealed by the variation in Sr isotopic compositions of high-An plagioclase cores, the different mantle potential temperatures and source lithologies.

From subduction initiation to hot subduction: Life of a Neoarchean subduction zone from the Dengfeng Greenstone Belt, North China Craton

Abstract We report a spatially and temporally linked arc magmatic association of 2.55–2.50 Ga mid-ocean ridge basalt (MORB)-affinity gabbros, arc-affinity basalts, high-Mg basalts/basaltic andesites (HMBA), Nb-enriched basalts (NEB), and a tonalite-trondhjemite-granodiorite (TTG)-like granodiorite from the Dengfeng greenstone belt (DFGB), North China Craton. These are identical to arc magmatic rock suites from hot subduction in the present plate mosaic, and resemble suites formed during subduction initiation. Laser ablation–inductively coupled plasma–mass spectrometry zircon U-Pb dating indicates that gabbros and granodiorites intruded at ca. 2.55 Ga and the HMBAs formed at ca. 2.50 Ga, indicating a long duration of subduction zone magmatic activity of at least 50 m.y. in the DFGB. The gabbros are characterized by flat light-rare earth element (LREE) patterns without negative Nb and Zr anomalies, showing a MORB-like geochemical affinity. Combined with previously reported normal-MORB-type basalts, we suggest that they may represent magmatic products during intraoceanic subduction initiation where their mantle source was slightly metasomatized by subduction-derived fluids during the initiation stage. The arc-affinity basalts are characterized by slightly enriched LREE patterns with negative Nb and Zr anomalies. The HMBAs have higher contents of MgO, Ni, and Cr and display more fractionated rare earth element (REE) patterns and large negative Nb and Zr anomalies than the arc-affinity basalts. The NEBs are characterized by high absolute contents of Nb (9.9–14 ppm) and high ratios of Nb/Laprimitive mantle (pm) (0.40–0.46) and Nb/Thpm (0.44–0.54), and moderately fractionated REE and minor negative Nb anomalies with no Zr anomalies. One granodiorite sample is characterized by a highly fractionated REE pattern and negative Nb and Zr anomalies. Geochemical modeling suggests that the association of the normal arc-affinity basalt (NAB)-HMBA-NEB can be interpreted to be generated by hybridization of mantle wedge peridotites by slab-derived TTG-like melts. Positive values of whole-rock εNd (t) and zircon εHf (t) of the 2.55–2.50 Ga magmatic associations are consistent with a long-term depleted mantle source for the mafic assemblage. The 2.55–2.50 Ga magmatic association from MORB-affinity gabbros and basalts to arc-affinity NAB-HMBA-NEB may record a continuous Neoarchean geodynamic process from intraoceanic subduction initiation to mature arc magmatism. The NAB-HMBA-NEB association with regional sanukitoids and high-Al TTGs indicates that hot subduction may have played an important role in the production of arc-related magmatism during the Archean.

Geochemistry and geochronology of intermediate volcanic rocks from the Compostela area, Nayarit, Mexico: Implications for petrogenesis and tectonic setting

The Compostela area is located in the western Trans‐Mexican Volcanic Belt, which consists of volcanic rocks that produced during the Pliocene to Recent volcanism. In this paper, we present petrography, whole‐rock major‐ and trace‐element concentrations, Ar–Ar ages, and Sr–Nd isotopic data of volcanic rocks from the Compostela area in the south of the city of Tepic, Nayarit, Mexico. These volcanic rocks are of intermediate composition and belong to the transitional series: basaltic trachyandesites [52.72–53.94 wt% SiO2; 0.69–2.53 wt% MgO] and subalkaline series: low‐Si [55.11–60.94 wt% SiO2; 0.79–2.74 wt% MgO] and high‐Si [61.60–62.71 wt% SiO2; 0.36–0.80 wt% MgO] andesites. The 40Ar/39Ar dating of two basaltic trachyandesites yields plateau ages of 1.05 ± 0.15 Ma and 1.07 ± 0.17 Ma and the andesites yielded a plateau age of 2.42 ± 0.36 Ma. These results indicate that the studied rocks were formed during the Pleistocene in two discrete episodes. The basaltic trachyandesites show enriched light rare earth elements patterns relative to high rare earth elements [(La/Yb)N = 5.81–8.07] with negligible Eu anomalies. The andesites display enriched large‐ion lithophile elements (Ba, K) with anomalies of Nb (Th/Ce) and Ti in the three groups identified in the subalkaline series. The basaltic trachyandesites appear in a tight cluster of initial 87Sr/86Sr ratios (0.703519–0.703882) as compared to the basaltic andesite 87Sr/86Sr (0.704073) and positive ɛNd(t) values of +5.6 to +3.4, respectively, indicating that the basaltic trachyandesites were derived from intermediate magmas from a shallow mantle source. Geochemical modelling reveals that both basaltic trachyandesite and andesite rocks were derived by a process of crystal fractionation accompanied by assimilation of crustal rocks at the lower or middle level. Geochemical ratios and multidimensional discrimination diagrams, combined with the cross‐section of the subduction zone indicates that basaltic trachyandesites were generated from a rift and/or Ocean Island Basalt‐type source, whereas andesites were generated from a slab‐derived source in a subduction environment.

Partial melting and subduction-related metasomatism recorded by geochemical and isotope (He-Ne-Ar-Sr-Nd) compositions of spinel lherzolite xenoliths from Coyhaique, Chilean Patagonia

Spinel lherzolite xenoliths from Coyhaique, Chilean Patagonia, are located ~320 km from the Chile Trench and, therefore, their geochemical and isotopic compositions may record slab-derived metasomatism from current and/or earlier subduction zones. We present new mineral and whole-rock major and trace elements that are discussed together with noble gas data (He, Ne, Ar) and Sr-Nd isotopic ratios. Partial melting is recorded by negative correlations between basaltic elements vs. MgO in whole-rock and minerals. In general, silicate minerals show depleted light-rare earth element (LREE) over heavy-REE (HREE) patterns. Whole-rock compositions and clinopyroxene record variable degrees of partial melting (1–15%), which is corroborated by the Sr-Nd depleted character of the lherzolites. Cryptic metasomatism is evidenced by: 1) enriched LREE patterns in whole-rock and type-2 clinopyroxenes; 2) negative anomalies of Nb-Ta-Ti in whole-rock samples coupled with enrichment of large ion lithophile elements and chalcophile elements over high field strength elements and HREE; 3) positive correlations of Pb and U vs. La and negative correlations of Nb/Nb* and Ti/Ti* vs. La in clinopyroxene, and 4) positive anomalies of Li in all silicate minerals. Geochemical differences between whole-rocks and their mineral constituents indicate selective enrichment of the whole-rock samples due to grain-boundary components. 3He/4He ratios reported here are the first strongly radiogenic values found in the Patagonian subcontinental lithospheric mantle (SCLM; 0.20–2.52 RA). Most Ne isotopic ratios are indistinguishable from air composition with few samples showing a nucleogenic component, whereas Ar isotopic ratios are extensively affected by an atmospheric component. The correlation between 3He/4He and 4He/40Ar* corroborates the metasomatism recorded by lithophile and chalcophile elements. Therefore, we identify a heterogeneous SCLM affected by low but variable degrees of partial melting and subsequent enrichment by melts or fluids from recycled subduction-related materials in the spinel stability field (1.06–1.90 GPa and 886–1150 °C).

Evolution of Syenite Magmas: Insights from the Geology, Geochemistry and O-Nd Isotopic Characteristics of the Ordovician Saibar Intrusion, Altai-Sayan Area, Russia

In this paper, we provide insight into the evolution of syenite magmas based on geological data and petrographic, geochemical, and O-Nd isotope parameters of rocks of the Saibar intrusion located within the Minusinsk Trough, Altay-Sayan area. The intrusive suite includes predominant syenites, few bodies of melanocratic and leucocratic nepheline syenites (foyaites), and granites. In addition, dykes of granites and mafic rocks are present. The U-Pb zircon age from the melanocratic foyaites was determined to be 457 ± 10 Ma? Examined rocks show fractionated light rare earth element patterns, normalized to chondrite, with (La/Sm)n varying from 4 to 9, and a weakly fractionated distribution of medium and heavy rare elements, with (Dy/Yb)n from 0.35 to 1.23 and (Sm/Yb)n from 0.63 to 2.62. The spidergram normalized to the primitive mantle shows negative Ba, Sr, Nb, Ta, Ti, and Eu anomalies (Eu* = 0.48–0.60) and positive Rb, Th, and U anomalies. The δ18O values vary within 6.3 to 10.2‰, and εNd(t) from +4.1 to +5.0. We observe gradual transitions from syenites to foyaites. Assimilation by syenite magma of the host carbonate rocks was followed to transition from silica-saturated to silica-undersaturated conditions and removal of anorthite from the melt, which then led to nepheline. Granites of the main phase show depleted lithophile incompatible elements in comparison with syenites and foyaites. They originate via interaction of magmas at the marginal part (endocontact zone) of the intrusion, corresponding to north contact of the granites with the host felsic rocks. In comparison, the rock composition of granite dykes is enriched in lithophile incompatible elements, except for Zr, Hf, and Ti. These rocks are formed due to the differentiation of syenite magma without a significant effect of host rock assimilation. Mantle magmas must be used as parent magmas for syenites based on analysis of the formation model of other alkaline intrusions, which are similar in age to the Saibar intrusion. In the line of syenite intrusions of the Altai-Sayan province, the Saibar intrusion is no exception, and its origin is related to the evolution of mafic magmas that arose during the melting of the mantle under the influence of a mantle plume.

Possible imprints of late Paleoproterozoic orogeny in the Dunhuang terrane, NW China: Constraints from igneous and metapelitic rocks

The Dunhuang terrane is a NEE trending tectonic belt confined by the Tarim Craton, Beishan Orogen, Alxa Block and Altyn Tagh Fault. To constrain the late Paleoproterozoic geotectonic background of this terrane, a synthetic research on petrology, geochemistry, zircon and monazite geochronology, and zircon Lu-Hf and whole-rock Nd isotopes of late Paleoproterozoic (ca. 1.9–1.8 Ga) igneous rocks and metapelites was conducted. The Sanweishan-Dongshuigou Na-rich rhyolite and granite formed at ca. 1.84–1.82 Ga exhibit enriched light rare earth elements (LREEs), depleted heavy rare earth elements (HREEs) and insignificant Eu anomalies, with low Y (3.44–6.39 ppm) and Yb (0.29–0.53 ppm) but relatively high Mg# (54.5–58.5) and Sr (368–643 ppm), and variable Cr (5.58–29.7 ppm) and Ni (2.82–15.6 ppm) contents, as well as negative to positive εHf(t) (−6.1 to +6.4) values, indicating subduction-related arc magmatism accompanied by crustal-mantle interaction. The Shuwozi granitic gneiss crystallized at ca. 1.81 Ga displays S-type granite affinity (A/CNK > 1.1) and has low Sr/Y (1.0–1.3) and (Gd/Yb)N (1.50–1.98) ratios, and negative εHf(t) (−20.3 to −5.1) and εNd(t) (−4.3) values, suggesting partial melting of crustal rocks at shallow crustal depth. The Hanxia amphibolite with protolith age of ca. 1.86–1.84 Ga is featured by depleted LREE and flat HREE patterns, insignificant Eu anomalies, low Nb/Ta (11.0–12.0), Ta/Yb (0.02–0.04), Th/Yb (0.01–0.04) and Th/Ta (0.7–1.3) but high Ti/V (22.9–26.7) ratios, and positive εNd(t) (2.7–4.0) values, resembling depleted mantle-derived N-MORB- or BABB (back-arc-basin basalt) geochemical affinities. The metapelite, characterized by mineral assemblage of garnet, biotite, sillimanite, plagioclase, K-feldspar, quartz and rutile, documented ca. 1.81 Ga upper amphibolite-facies metamorphism with peak metamorphic P-T conditions being restricted to 690–810 °C and 5.3–6.4 kbar based on conventional geothermobarometry. These magmatic and metamorphic rocks were variously altered and deformed during Paleozoic (ca. 430–360 Ma) tectonothermal event. Integrated with published data, it can be inferred that the Dunhuang terrane underwent ca. 1.89–1.81 Ga subduction-collisional orogeny related to late Paleoproterozoic (ca. 2.0–1.8 Ga) global assembly of the Columbia supercontinent, similar as those recorded in the northern Tarim Craton, Alxa Block and Quanji massif, and then overprinted Paleozoic (ca. 440–360 Ma) orogenic process, corresponding to the previously proposed composite orogeny in the Dunhuang terrane.

The petrology, geochronology and tectono-magmatic setting of igneous rocks in the Suckling-Dayman metamorphic core complex, Papua New Guinea

Southeastern Papua New Guinea has hosted magmatism throughout the Cenozoic, with the latest phase being concurrent with active extension in the Woodlark Rift. There, the Suckling-Dayman metamorphic core complex (SDMCC) has exhumed middle-crustal rocks in the past few million years along a still-active low-angle normal fault, the Mai'iu Fault. Uplift of the SDMCC has exposed metasedimentary and metaigneous rocks of Late Cretaceous-Pleistocene age that record an evolution from oceanic spreading to subduction, to collision, and finally to subduction-inversion and extensional exhumation. We present new petrographic, whole-rock geochemical and geochronologic (zircon U–Pb LA-ICP-MS) data from the SDMCC to reconstruct its long-term evolution. The dominant footwall-lithology of the SDMCC, the Goropu Metabasalt, has a MORB composition. Detrital zircons from metasedimentary beds intercalated with these basalts yield U–Pb-based maximum estimates for deposition of ~103 and ~72 Ma, suggesting a Late Cretaceous spreading age of the oceanic protolith. Bulk compositions of low-grade tholeiitic meta-gabbroic and -tonalitic rocks (Yau Igneous Complex) that intrude the Goropu Metabasalt reveal both enriched and depleted light rare earth element patterns. Zircon U–Pb ages from the Yau Igneous Complex range between ~60 and ~57 Ma, providing a minimum age for the formation of the Goropu Metabasalt. Much younger syn-extensional granitoids in the mafic footwall of the SDMCC have calc-alkaline to high-K compositions and U–Pb ages on zircon between ~3.7 and ~2.0 Ma. Our data indicate that the Mai'iu Fault had re-activated a Paleogene thrust as an extensional detachment fault by 3.7 ± 0.2 Ma. U–Pb ages of detrital zircons in modern streams draining the footwall of the SDMCC essentially reflect the ages revealed by the Paleocene and Plio-Pleistocene intrusions. Xenocrystic zircons in the Plio-Pleistocene granitoids imply that the crust underlying the metabasaltic carapace of the SDMCC consists chiefly of Australian-continent derived sedimentary rocks.

Petrogenesis of low-Ti and high-Ti basalt, adakite and rhyolite association in the Peddavuru greenstone belt, eastern Dharwar craton, India: A Neoarchean analogue of Phanerozoic-type back-arc magmatism

The petrogenetic record, available in the literature, illustrating Neoarchean arc magmatic processes in a back-arc setting is rare. In this contribution, we present a comprehensive account of field, petrography and geochemistry of the Neoarchean bimodal mafic – felsic metavolcanic rock association in the Peddavuru greenstone belt, eastern Dharwar craton, India.Basalt is the predominant rock type. Felsic volcanic rocks are interleaved with the basalts, in the central part. The basalts are fine grained, aphyric and essentially composed of amphibole and plagioclase with rutile, magnetite and ilmenite as accessory Fe-Ti oxide phases. The felsic volcanic rocks exhibit porphyritic texture. Based on the composition of the phenocryst type i.e. feldspar or quartz, two variants have been recognized. Biotite is present in subordinate amounts while, apatite and magnetite are the accessory phases.Basalts are tholeiitic in composition, whereas the felsic volcanic rocks are calc-alkaline in nature. On the basis of TiO2 contents, the basalts can be classified into low-Ti (< 1 wt. % TiO2) and high-Ti (> 1 wt. % TiO2) geochemical subgroups. The two subgroups, however, are consanguineous in nature. They display slightly depleted (La/Sm ∼ 0.89) and mildly enriched (La/Sm ∼ 1.44) chondrite normalized light rare earth element patterns (REE), and slightly depleted heavy REE (Gd/Yb ∼ 1.2). On a primitive mantle normalized trace element variation diagram, irrespective of low- or high-Ti, the basalts display negative Nb and Ti anomalies, and zero to negative Zr-Hf anomalies relative to the neighbouring REE.The felsic volcanic rocks are characterized by contrasting geochemical compositions. On the basis of high field strength element systematics, they are classified as dacites and rhyolites. Compared to the rhyolites, the dacites are characterized by high Mg# (39 ± 9 vs. 24 ± 5), low Nb (≤ 5 ppm vs. 14 ppm), Y (5.9 ± 1.8 ppm vs. 19 ppm) and Yb (0.47 ± 0.17 ppm vs. 1.72 ppm) contents. Further, the dacites exhibit comparatively steep chondrite normalized REE patterns (LaN/YbN ∼ 30 vs. 10) with negligible to slightly positive Eu anomaly (Eu/Eu* = 0.9–1.2 vs. 0.6). On a primitive mantle normalized trace element variation diagram they exhibit negative Nb and Ti anomalies, similar to the rhyolites, but contrasting positive Zr-Hf peaks and high Zr/Sm ratio (73 ± 18 vs. 24). The trace and rare earth element attributes of these dacites are identical to the adakitic rocks that have been recognized from the Phanerozoic intraoceanic arcs. On the contrary, rhyolites are the partial melt products involving minor plagioclase fractionation that are generated beneath the arc crust under extension.Overall, the chemical compositions of the mafic and felsic volcanic rocks in the Peddavuru belt indicate that interaction with the Archean upper continental crust, magma mixing and/or assimilation and fractional crystallization processes cannot be the cause of these geochemical patterns. The attributes instead reflect primary mantle source characteristics. MORB-like trace element signatures in combination with arc-like geochemical affinity in the Peddavuru basalts, provides compelling evidence of their origin in an intraoceanic back-arc setting. Accordingly, the Peddavuru greenstone belt presents a Neoarchean analogue of Phanerozoic-type back-arc magmatism.

Petrology and Geochemistry of Mafic Intrusive Rocks from the Sapi-Shergol Ophiolitic Mélange, Indus Suture Zone, Western Ladakh: Constraints on Petrogenesis and Tectonic Setting

This article reports the existence of subduction-related tholeiitic, normal mid-ocean ridge basalt (N-MORB)-type mafic intrusives emplaced within the Sapi-Shergol ophiolitic mélange of the Indus Suture Zone, western Ladakh. The Shergol mafic intrusives show Fe enrichment with basalt to basaltic-andesite composition. Based on their mineralogy and textures, these mafic rocks can be identified as fine- to medium-grained gabbros that have undergone greenschist-grade metamorphism. These rocks have N-MORB-type geochemical characteristics, exhibiting nearly flat to depleted light rare earth element patterns ((La/Sm)N=0.66–1.05). Petrogenetic modeling suggests <20% partial melting of a depleted MORB-type mantle source, within the spinel peridotite stability. The presence of slightly negative anomalies of high field strength elements like Nb, Zr, and Ti in multielement patterns reflect the influence of subduction zone magmatism. The presence of low-Ti clinopyroxene (En38–50Fe11–25Wo31–43; enstatite-ferrosilite-wollastonite), Ca-rich plagioclase (An2–36; andesine), and pargasitic amphibole also reflects their subduction-related depleted-mantle origin. The MORB–island arc tholeiite signature displayed by the Shergol gabbros intrusive in Shergol peridotites reflect their generation in a mantle wedge associated with the Early Cretaceous intraoceanic subduction within the Neo-Tethys Ocean. They are similar to Spongtang ophiolite gabbros intrusive in the Spongtang ophiolite mantle peridotites from south Ladakh, ophiolitic mélange gabbros from southern Tibet, and Muslim Bagh ophiolite gabbros from Pakistan. Based on this study, we offer a geodynamic model suggesting that the Sapi-Shergol ophiolitic slice was intruded by mafic intrusive rocks that represent the relict of the intraoceanic substratum of the Cretaceous Dras arc complex.

Widespread Os-isotopically ultradepleted mantle domains in the Paleo-Asian oceanic upper mantle: evidence from the Paleozoic Tianshan ophiolites (NW China)

The scale and extent of isotopic heterogeneities in the Paleo-Asian oceanic mantle remain poorly constrained. Here, we report Os isotopic data for mantle peridotites from the Paleozoic Gangou and Kumishi ophiolites, which are preserved in the western Chinese Tianshan sutures (Xinjiang, China) and considered to sample the Paleo-Asian oceanic upper mantle. These heavily serpentinized peridotites display positive correlations between Al2O3, Ti, and Yb contents, indicating variable degrees of melt extraction from fertile mantle sources. However, enriched light rare-earth element patterns in the peridotites are inconsistent with simple residues of partial melting, thus reflecting the effect of post-melting melt percolation. Peridotites from both ophiolites show wide variation of Os isotopic compositions, several of which are characterized by highly unradiogenic 187Os/188Os values (0.117–0.118), reflecting Proterozoic melt depletion. Such feature is common in modern oceanic peridotites and most Phanerozoic ophiolites, meaning that Os-isotopically ultradepleted domains should be widespread in the Paleo-Asian oceanic mantle. The overall similarity of Os-isotope distribution between the Paleozoic Tianshan ophiolites and modern oceanic peridotites suggests that they derive from the same heterogeneous upper mantle reservoir. This might support the hypothesis that isotopically ultradepleted domains are inherent components of the convecting upper mantle and have not been sufficiently homogenized by convection. Alternatively, Re-depletion ages (TRD) for these ancient domains are broadly coincident with the major peaks in crustal zircon ages that are thought to reflect episodes of continental crust growth in the adjacent Yili–Central Tianshan microcontinents. This suggests that the ultradepleted mantle domains in some of the Tianshan ophiolites may derive from ancient subcontinental lithospheric mantle, which detached and were exhumed to form the substrate of ocean basins.

Age and composition of dykes emplaced before and during the opening of the Tasman Sea—source implications

Dykes are common in the wave-cut platforms along the coast from Newcastle to Sydney. According to some authors, they may be related to the opening of the Tasman Sea that commenced ca 84 Ma ago. However, there are few detailed radiogenic dating and geochemical studies to evaluate this. We attempt to resolve this by K–Ar dating of plagioclase in and geochemical studies of, basaltic dykes intruding Permo-Triassic sequences on the wave-cut platforms and Carboniferous and Permo-Triassic sequences inland. The plagioclase separated from the dykes give K–Ar ages ranging from 266 to 53 Ma with the majority older than 84 Ma indicating that most dykes were emplaced before the Tasman Seafloor formation. The dykes are generally mildly alkaline, high-Ti basalts; fewer are tholeiitic and calc-alkaline, low-Ti basalts. Strongly light rare earth element (LREE)-enriched patterns typify the former and flat, LREE-depleted or slightly to moderately enriched LREE patterns, the latter. High-Ti basalts have ocean-island-basalt-like and low-Ti basalts, calc-alkaline or mid-ocean ridge basalt (MORB)-like patterns. Most high-Ti and some low-Ti basalts show plume-like characteristics, others N-type MORB and arc-like characteristics. Dykes intruding the Carboniferous sequences show a distinct contamination signature that could be crustal or due to subduction-related metasomatism of the subcontinental lithospheric mantle. The sources of the basaltic magmas vary substantially and in places changes with time. All alkali basalts are derived from enriched asthenospheric sources at varying depths (90–147 km) and most tholeiitic, low-Ti basalts have been extracted from asthenospheric and depleted asthenospheric–lithospheric sources indicating substantial compositional heterogeneity of the mantle. Further, Nd model ages varying from Neoproterozoic (940–580 Ma) to Paleozoic (460–370 Ma) suggest variation in the age of mantle sources for the basalts.

Modern carbonate ooids preserve ambient aqueous REE signatures

Skeletal and non-skeletal components of marine sedimentary rocks have been analyzed for the purpose of reconstructing the rare earth element (REE) and yttrium (Y) compositions of paleo-seawater, but skeletal carbonates frequently have proven to be unreliable recorders of seawater chemistry. Here, we present a systematic multi-technique assessment of rare earth and other trace elements in ooid sands from the modern Great Bahama Bank (GBB–marine) and Great Salt Lake (GSL–continental) based on strong-acid (hydrofluoric and nitric) and weak-acid (acetic) digestions, as well as laser ablation (LA) of ooid cortices and nuclei. The results show that Bahamian ooid cortices possess shale-normalized REE + Y features nearly identical to those of shallow seawater, including limited contamination from siliciclastic REEs. An admixture of even 0.2% of detritally sourced material can modify the primary marine REE + Y patterns by, for example, increasing the light REE (LREE) content. Mean values of LA data for Bahamian ooid cortices exhibit similar REE + Y signatures to those produced by acetic acid digestion, but LA data are generally noisier, primarily as a result of low REE concentrations and the small volume of carbonate ablated in analysis. Screening out samples with ΣREE <0.9 ppm reveals more uniform, seawater-like REE + Y patterns in individual ooid cortices as well as high, uniform REE distribution coefficients (116 ± 21, from La to Lu) with respect to ambient seawater. Ooid laminae show no distinct alternation between oxic and anoxic pore fluid characteristics, suggesting that growing ooids primarily formed under oxic conditions in carbonate shoal settings, even when buried during their resting phase. Unlike Bahamian ooids, shale-normalized REE + Y patterns of GSL ooids digested in weak acid show slightly depleted LREE compositions that may deviate from ambient fluids owing to release of REEs from an included clay fraction based on comparison between digestion and LA methods. Multiple ablation spots within the same cortex allowed direct comparison of more and less contaminated portions of a single ooid. Nearly uniform positive Ce anomalies may be related to strongly alkaline water conditions. Individual ablation spots that are partially overprinted by siliciclastic-derived REEs contain variable Zr contents (from 0.096 to ~4 ppm) and flattened shale-normalized LREE patterns. The least-contaminated GSL ooid cortex yields an LREE-depleted REE + Y distribution. Normalization of the REE + Y distributions of least-contaminated GSL ooids using reliable GBB ooid distributions (i.e., with ΣREE > 0.9 ppm) returns a flat pattern, suggesting similar degrees of LREE depletion controlled by carbonate complexation under similar aqueous alkalinity conditions in Great Salt Lake and Bahamian waters. In summary, ooids can be a reliable proxy for REE + Y characteristics of ambient surficial waters when adopting suitable analytical methods, including laser ablation, that allow the identification and isolation of a contamination signal from siliciclastic detritus.

A middle Permian ophiolite fragment in Late Triassic greenschist- to blueschist-facies rocks in NW Turkey: An earlier pulse of suprasubduction-zone ophiolite formation in the Tethyan belt

The Eastern Mediterranean region within the Tethyan belt is characterised by two main pulses of suprasubduction-zone ophiolite formation during the Early–Middle Jurassic and Late Cretaceous. Despite vast exposures of the Permo-Triassic accretionary complexes, related suprasubduction-zone ophiolites and the timing of subduction initiation leading to the formation of Permo-Triassic accretionary complexes are unknown so far. Here we report on a ~40km long and 0.3 to 1.8km wide metaophiolite fragment within transitional greenschist- to blueschist-facies oceanic rocks from NW Turkey. The metaophiolite fragment is made up mainly of serpentinite and minor dykes or stocks of strongly sheared metagabbro with mineral assemblages involving actinolite/winchite, chlorite, epidote, albite, titanite and phengite. The metagabbro displays (i) variable CaO and MgO contents, (ii) anomalously high Mg# (=100∗molar MgO/(MgO+FeOtot)) of 75–88, and (iii) positive Eu anomalies, together with low contents of incompatible elements such as Ti, P and Zr, suggesting derivation from former plagioclase cumulates. The serpentinites comprise serpentine, ±chlorite, ±talc, ±calcite and relict Cr-Al spinel surrounded by ferrichromite to magnetite. Relict Cr-Al spinels are characterised by (i) Cr/(Cr+Al) ratios of 0.45–0.56 and Mg/(Mg+Fe2+) ratio of 0.76–0.22, (ii) variable contents of ZnO and MnO, and (iii) extremely low TiO2 contents. Zn and Mn contents are probably introduced into Cr-Al spinels during greenschist- to blueschist metamorphism. Compositional features of the serpentinite such as (i) Ca- and Al-depleted bulk compositions, (ii) concave U-shaped, chondrite-normalised rare earth element patterns (REE) with enrichment of light and heavy REEs, imply that serpentinites were probably derived from depleted peridotites which were refertilised by light rare earth element enriched melts in a suprasubduction-zone mantle wedge. U-Pb dating on igneous zircons from three metagabbro samples indicates igneous crystallisation at 262Ma (middle Permian). Timing of the metamorphism is constrained by incremental 40Ar/39Ar dating on phengitic white mica at 201Ma (latest Triassic). We conclude that the metaophiolite represents a fragment of middle Permian suprasubduction-zone oceanic lithosphere, involved in a latest Triassic subduction zone. These data, together with several reports in literature, indicate that the middle Permian was a time of suprasubduction-zone ophiolite formation in the Tethyan belt.

Rare earth element partitioning and subsolidus exchange behaviour in olivine

The systematics of the rare earth element (REE) abundances in olivine are poorly understood and this undermines their usefulness in deciphering petrogenetic processes. Here we report a novel REE dataset for olivine spanning a wide range in Mg number (Mg# 1–59) from the Skaergaard Layered Intrusion.Olivine La and Lu concentrations vary from 0.68 to 56ppb and 66 to 571ppb, respectively. Apparent olivine/melt partition coefficients for the heavy to middle REE define near-symmetrical parabolas, consistent with lattice strain theory, indicating that these elements are structurally bound within the olivine lattice. The parabolas define peaks with variable optimal radii (ro). This suggests that the Fe-content of olivine exerts a strong influence on REE partitioning, as fayalitic olivines display more open parabolas (higher apparent Young's modulus, E) than forsteritic olivines. The greater site elasticity is manifest as higher REE concentrations in the fayalitic samples. The observation that E and ro are not constant accross a range of Mg# has implications for predictive models for olivine REE.The CI chondrite-normalised olivine REE patterns show smooth trends from the heavy to the middle REE, with greater variation amongst the light REE (LREE). Variation and enrichment of the LREE are ubiquitous within published data for natural olivine, yet are not predicted by experimental results. This study also presents two-dimensional REE maps illustrating the behaviour of the REE in olivine in unprecedented detail. Mapping of magnesian olivine shows core to rim increase in Al, LREE, and Eu and the development of a positive Eu anomaly in olivine, resulting from solid-state, likely diffusive re-equilibration with adjacent plagioclase. We propose that secondary redistribution is the principal cause of elevated LREE patterns in natural olivine.The results from the present investigation show that from a petrological point of view, MREE to HREE systematics of olivine hold promise for study of olivine petrogenesis and that the LREE in olivine may be further developed to understand diffusion time scales and cooling rates in magmatic systems.