Light Neutron-capture Elements Research Articles

The R-Process Alliance: Analysis of limited-r stars

In recent years, the $R$-Process Alliance (RPA) has conducted a successful search for stars that are enhanced in elements produced by the rapid neutron-capture ($r$-)process. In particular, the RPA has uncovered a number of stars that are strongly enriched in light $r$-process elements, such as Sr, Y, and Zr. These so-called limited-$r$ stars were investigated to explore the astrophysical production site(s) of these elements. We investigate the possible formation sites for light neutron-capture elements by deriving detailed abundances for neutron-capture elements from high-resolution spectra with a high signal-to-noise ratio of three limited-$r$ stars. We conducted a kinematic analysis and a 1D local thermodynamic equilibrium spectroscopic abundance analysis of three stars. Furthermore, we calculated the lanthanide mass fraction ($ X_ La $) of our stars and of limited-$r$ stars from the literature. We found that the abundance pattern of neutron-capture elements of limited-$r$ stars behaves differently depending on their $ Ba/Eu $ ratios, and we suggest that this should be taken into account in future investigations of their abundances. Furthermore, we found that the $ X_ La $ of limited-$r$ stars is lower than that of the kilonova AT2017gfo. The latter seems to be in the transition zone between limited-$r$ $ X_ La $ and that of $r$-I and $r$-II stars. Finally, we found that unlike $r$-I and $r$-II stars, the current sample of limited-$r$ stars is largely born in the Galaxy and is not accreted.

Four-hundred Very Metal-poor Stars Studied with LAMOST and Subaru. III. Dynamically Tagged Groups and Chemodynamical Properties

Very metal-poor (VMP) stars record the signatures of early accreted galaxies, making them essential tools for unraveling the early stages of Galaxy formation. Understanding the origin of VMP stars requires comprehensive studies of their chemical compositions and kinematics, which are currently lacking. Hence, we conduct a chemodynamical analysis of 352 VMP stars selected from one of the largest uniform high-resolution VMP star samples, jointly obtained from LAMOST and Subaru. We apply a friends-of-friends clustering algorithm to the master catalog of this high-resolution sample, which consists of 5778 VMP stars. It results in 131 dynamically tagged groups with 89 associated with known substructures in the Milky Way, including Gaia-Sausage-Enceladus (GSE), Thamnos, Helmi streams, Sequoia, Wukong, Pontus, and the very metal-poor disk (VMPD). Our findings are: (i) the VMPD shows lower Zn abundances than the rest, which indicates that it could be a relic of small stellar systems; (ii) Sequoia shows moderately high r-process abundances; (iii) Helmi streams show deficiencies in carbon and light neutron-capture elements; (iv) the fraction of carbon-enhanced metal-poor stars with no enhancement in heavy elements (CEMP-no stars) seems low in the VMPD and the Helmi streams; and (v) a subgroup in GSE exhibits a very high fraction of r-process enhanced stars, with four out of five showing [Eu/Fe]> +1.0. The abundance patterns of other elements in VMP substructures largely match the whole VMP sample. We also study large-scale correlations between abundance ratios and kinematics without classifying stars into substructures, but it does not yield significant correlations once the overall chemical evolution is considered for most elements.

High-precision chemical abundances of Galactic building blocks

Context. The Helmi streams are a kinematic substructure whose progenitor is likely a dwarf galaxy. Although 20 years have passed since their discovery, it is still unclear whether their members are chemically distinguishable from other halo stars in the Milky Way. Aims. We aim to precisely characterize the chemical properties of the Helmi streams. Methods. We analyzed high-resolution, high signal-to-noise ratio spectra for 11 Helmi stream stars through a line-by-line abundance analysis. We compared the derived abundances to homogenized literature abundances of the other halo stars, including those belonging to other kinematic substructures, such as Gaia-Enceladus and Sequoia. Results. Compared to typical halo stars, the Helmi stream members clearly show low values of [X/Fe] in elements produced by massive stars, such as Na and α-elements. This tendency is seen down to metallicities of at least [Fe/H] ∼ − 2.2, suggesting type Ia supernovae already started to contribute to the chemical evolution at this metallicity. We find that the [α/Fe] ratio does not evolve significantly with metallicity, making the Helmi stream stars less distinguishable from Gaia-Enceladus stars at [Fe/H] ≳ − 1.5. The almost constant but low value of [α/Fe] might be indicative of quiescent star formation with low efficiency at the beginning and bursty star formation at later times. We also find extremely low values of [Y/Fe] at low metallicity, providing further support for the claim that light neutron-capture elements are deficient in Helmi streams. While Zn is deficient at low metallicity, it shows a large spread at high metallicity. The origin of the extremely low Y abundances and Zn variations remains unclear. Conclusions. The Helmi stream stars are distinguishable from the majority of the halo stars if homogeneously derived abundances are compared.

A high-precision abundance analysis of the nuclear benchmark star HD 20

Metal-poor stars with detailed information available about their chemical inventory pose powerful empirical benchmarks for nuclear astrophysics. Here we present our spectroscopic chemical abundance investigation of the metal-poor ([Fe/H] = −1.60 ± 0.03 dex), r-process-enriched ([Eu/Fe] = 0.73 ± 0.10 dex) halo star HD 20, using novel and archival high-resolution data at outstanding signal-to-noise ratios (up to ∼1000 Å−1). By combining one of the first asteroseismic gravity measurements in the metal-poor regime from a TESS light curve with the spectroscopic analysis of iron lines under non-local thermodynamic equilibrium conditions, we derived a set of highly accurate and precise stellar parameters. These allowed us to delineate a reliable chemical pattern that is comprised of solid detections of 48 elements, including 28 neutron-capture elements. Hence, we establish HD 20 among the few benchmark stars that have nearly complete patterns and low systematic dependencies on the stellar parameters. Our light-element (Z ≤ 30) abundances are representative of other, similarly metal-poor stars in the Galactic halo that exhibit contributions from core-collapse supernovae of type II. In the realm of the neutron-capture elements, our comparison to the scaled solar r-pattern shows that the lighter neutron-capture elements (Z ≲ 60) are poorly matched. In particular, we find imprints of the weak r-process acting at low metallicities. Nonetheless, by comparing our detailed abundances to the observed metal-poor star BD +17 3248, we find a persistent residual pattern involving mainly the elements Sr, Y, Zr, Ba, and La. These are indicative of enrichment contributions from the s-process and we show that mixing with material from predicted yields of massive, rotating AGB stars at low metallicity improves the fit considerably. Based on a solar ratio of heavy- to light-s elements – which is at odds with model predictions for the i-process – and a missing clear residual pattern with respect to other stars with claimed contributions from this process, we refute (strong) contributions from such astrophysical sites providing intermediate neutron densities. Finally, nuclear cosmochronology is used to tie our detection of the radioactive element Th to an age estimate for HD 20 of 11.0 ± 3.8 Gyr.

The vertical Na–O relation in the bulge globular cluster NGC 6553

ABSTRACT In this article, we present a detailed chemical analysis of seven red giant members of NGC 6553 using high-resolution spectroscopy from VLT FLAMES. We obtained the stellar parameters (Teff, Log(g), vt, [Fe/H]) of these stars from the spectra, and we measured the chemical abundance for 20 elements, including light elements, iron-peak elements, α-elements, and neutron-capture elements. The metallicities in our sample stars are consistent with a homogeneous distribution. We found a mean of [Fe/H] = −0.14 ± 0.07 dex, in agreement with other studies. Using the α-elements Mg, Si, Ca, and Ti, we obtain the mean of [α/Fe] = 0.11 ± 0.05. We found a vertical relation between Na and O, characterized by a significant spread in Na and an almost non-existent spread in O. In fact, Na and Al are the only two light elements with a large intrinsic spread, which demonstrates the presence of multiple populations (MPs). An intrinsic spread in Mg is not detected in this study. The α, iron-peak, and neutron-capture elements show good agreement with the trend of the bulge field stars, indicating similar origin and evolution, in concordance with our previous studies for two other bulge globular clusters (NGC 6440 and NGC 6528).

Tracing the Origin of Moving Groups. II. Chemical Abundance of Six Stars in the Halo Stream LAMOST-N1

Abstract We present the chemical abundances of six stars in the halo stream Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST)-N1, a new kinematically selected substructure from LAMOST data, from high-resolution spectra obtained with the Subaru/High Dispersion Spectrograph. Atmospheric parameters were determined by an iterative procedure based on spectroscopic analysis. Abundances of 11 elements, including α elements (Mg, Ca, Ti), odd-Z light elements (Na), iron-peak elements (Sc, Cr, Mn, Fe, Ni), and neutron-capture elements (Y, Ba), are measured by local thermodynamic equilibrium analysis procedures. [Fe/H] of the six stars ranges from −1.5 to −0.66. The abundance patterns of α elements show a similar trend to those of low-α stars in Nissen et al. and over 0.1 dex lower than those of Galactic field stars. The Sc, Cr, Mn, and Ni abundances of these six stars exhibit a positive trend with increasing iron abundance, with varying gradients. In addition, abundance distribution between [Na/Fe] and [Ni/Fe] and between that of [Ba/Y] and [Fe/H] of these six stars is different from both Galactic stars and the known dwarf galaxies. Our results suggest that LAMOST-N1 might be a relic of a system with slower chemical evolutions than the Milky Way.

Stochastic Chemical Evolution of Galactic Subhalos and the Origin of r-process Elements

Abstract Mergers of compact binaries (of a neutron star and another neutron star or a black hole, NSMs) are suggested to be the promising astrophysical site of the r-process. While the average coalescence timescale of NSMs appears to be , most of previous chemical evolution models indicate that the observed early appearance and large dispersion of in Galactic halo stars at favors shorter coalescence times of 1–10 Myr. We argue that this is not the case for the models assuming the formation of the Galactic halo from clustering of subhalos with different star formation histories as suggested by Ishimaru et al. We present a stochastic chemical evolution model of the subhalos, in which the site of the r-process is assumed to be mainly NSMs with a coalescence timescale of . In view of the scarcity of NSMs, their occurrence in each subhalo is computed with a Monte Carlo method. Our results show that the less massive subhalos evolve at lower metallicities and generate highly r-process-enhanced stars. An assembly of these subhalos leaves behind the large star-to-star scatters of in the Galactic halo as observed. However, the observed scatters of [Sr/Ba] at low metallicities indicate the presence of an additional site that partially contributes to the enrichment of light neutron-capture elements such as Sr. The high enhancements of at low metallicities found in our low-mass subhalo models also qualitatively reproduce the abundance signatures of the stars in the recently discovered ultra-faint dwarf galaxy Reticulum II. Therefore, our results suggest NSMs as the dominant sources of r-process elements in the Galactic halo.

The R-Process Alliance: Discovery of the First Metal-poor Star with a Combined r- and s-process Element Signature*

Abstract We present a high-resolution (R ∼ 35,000), high signal-to-noise ratio (S/N > 200) Magellan/MIKE spectrum of the star RAVE J094921.8−161722, a bright (V = 11.3) metal-poor red giant star with [Fe/H] = −2.2, identified as a carbon-enhanced metal-poor (CEMP) star from the RAVE survey. We report its detailed chemical abundance signature of light fusion elements and heavy neutron-capture elements. We find J0949−1617 to be a CEMP star with s-process enhancement that must have formed from gas enriched by a prior r-process event. Light neutron-capture elements follow a low-metallicity s-process pattern, while the heavier neutron-capture elements above Eu follow an r-process pattern. The Pb abundance is high, in line with an s-process origin. Thorium is also detected, as expected from an r-process origin, as Th is not produced in the s-process. We employ nucleosynthesis model predictions that take an initial r-process enhancement into account, and then determine the mass transfer of carbon and s-process material from a putative more massive companion onto the observed star. The resulting abundances agree well with the observed pattern. We conclude that J0949−1617 is the first bonafide CEMP-r + s star identified. This class of objects has previously been suggested to explain stars with neutron-capture element patterns that originate from neither the r- nor the s-process alone. We speculate that J0949−1617 formed in an environment similar to those of ultra-faint dwarf galaxies like Tucana III and Reticulum II, which were enriched in r-process elements by one or multiple neutron star mergers at the earliest times.

Abundance patterns of the light neutron-capture elements in very and extremely metal-poor stars

Aims. The abundance patterns of the neutron-capture elements in metal-poor stars provide a unique record of the nucleosynthesis products of the earlier massive primitive objects. Methods. We measured new abundances of so-called light neutron-capture of first peak elements using local thermodynamic equilibrium (LTE) 1D analysis; this analysis resulted in a sample of 11 very metal-poor stars, from [Fe/H] = –2.5 to [Fe/H] = –3.4, and one carbon-rich star, CS 22949-037 with [Fe/H] = –4.0. The abundances were compared to those observed in two classical metal-poor stars: the typical r-rich star CS 31082-001 ([Eu/Fe] > +1.0) and the r-poor star HD 122563 ([Eu/Fe] < 0.0), which are known to present a strong enrichment of the first peak neutron-capture elements relative to the second peak. Results. Within the first peak, the abundances are well correlated in analogy to the well-known correlation inside the abundances of the second-peak elements. In contrast, there is no correlation between any first peak element with any second peak element. We show that the scatter of the ratio of the first peak abundance over second peak abundance increases when the mean abundance of the second peak elements decreases from r-rich to r-poor stars. We found two new r-poor stars that are very similar to HD 122563. A third r-poor star, CS 22897-008, is even more extreme; this star shows the most extreme example of first peak elements enrichment to date. On the contrary, another r-poor star (BD–18 5550) has a pattern of first peak elements that is similar to the typical r-rich stars CS 31082-001, however this star has some Mo enrichment. Conclusions. The distribution of the neutron-capture elements in our very metal-poor stars can be understood as the combination of at least two mechanisms: one that enriches the forming stars cloud homogeneously through the main r-process and leads to an element pattern similar to the r-rich stars, such as CS 31082-001; and another that forms mainly lighter, first peak elements.

Diversity of Abundance Patterns of Light Neutron-capture Elements in Very-metal-poor Stars∗

Abstract We determine the abundances of neutron-capture elements from Sr to Eu for five very-metal-poor stars ( ) in the Milky Way halo to reveal the origin of light neutron-capture elements. Previous spectroscopic studies have shown evidence of at least two components in the r-process; one referred to as the “main r-process” and the other as the “weak r-process,” which is mainly responsible for producing heavy and light neutron-capture elements, respectively. Observational studies of metal-poor stars suggest that there is a universal pattern in the main r-process, similar to the abundance pattern of the r-process component of solar-system material. Still, it is uncertain whether the abundance pattern of the weak r-process shows universality or diversity, due to the sparseness of measured light neutron-capture elements. We have detected the key elements, Mo, Ru, and Pd, in five target stars to give an answer to this question. The abundance patterns of light neutron-capture elements from Sr to Pd suggest a diversity in the weak r-process. In particular, scatter in the abundance ratio between Ru and Pd is significant when the abundance patterns are normalized at Zr. Our results are compared with the elemental abundances predicted by nucleosynthesis models of supernovae with parameters such as electron fraction or proto-neutron-star mass, to investigate sources of such diversity in the abundance patterns of light neutron-capture elements. This paper presents that the variation in the abundances of observed stars can be explained with a small range of parameters, which can serve as constraints on future modeling of supernova models.

Explaining the Ba, Y, Sr, and Eu abundance scatter in metal-poor halo stars: constraints to the r-process

Context. Thanks to the heroic observational campaigns carried out in recent years we now have large samples of metal-poor stars for which measurements of detailed abundances exist. [...] These data hold important clues on the nature of the contribution of the first stellar generations to the enrichment of our Galaxy. Aims. We aim to explain the scatter in Sr, Ba, Y, and Eu abundance ratio diagrams unveiled by the metal-poor halo stars. Methods. We computed inhomogeneous chemical evolution models for the Galactic halo assuming different scenarios for the r-process site: the electron-capture supernovae (EC) and the magnetorotationally driven (MRD) supernovae scenario. We also considered models with and without the contribution of fast-rotating massive stars (spinstars) to an early enrichment by the s-process. A detailed comparison with the now large sample of stars with measured abundances of Sr, Ba, Y, Eu, and Fe is provided (both in terms of scatter plots and number distributions for several abundance ratios). Results. The scatter observed in these abundance ratios of the very metal-poor stars (with [Fe/H] < -2.5) can be explained by combining the s-process production in spinstars, and the r-process contribution coming from massive stars. For the r-process we have developed models for both the EC and the MRD scenario that match the observations. Conclusions. With the present observational and theoretical constraints we cannot distinguish between the EC and the MRD scenario in the Galactic halo. Independently of the r-process scenarios adopted, the production of elements by an s-process in spinstars is needed to reproduce the spread in abundances of the light neutron capture elements (Sr and Y) over heavy neutron capture elements (Ba and Eu). We provide a way to test our suggestions by means of the distribution of the Ba isotopic ratios in a [Ba/Fe] or [Sr/Ba] vs. [Fe/H] diagram.

THE ABUNDANCES OF NEUTRON-CAPTURE SPECIES IN THE VERY METAL-POOR GLOBULAR CLUSTER M15: A UNIFORM ANALYSIS OF RED GIANT BRANCH AND RED HORIZONTAL BRANCH STARS

The globular cluster M15 is unique in its display of star-to-star variations in the neutron-capture elements. Comprehensive abundance surveys have been previously conducted for handfuls of M15 red giant branch (RGB) and red horizontal branch (RHB) stars. No attempt has been made to perform a single, self-consistent analysis of these stars, which exhibit a wide range in atmospheric parameters. In the current effort, a new comparative abundance derivation is presented for three RGB and six RHB members of the cluster. The analysis employs an updated version of the line transfer code MOOG, which now appropriately treats coherent, isotropic scattering. The apparent discrepancy in the previously reported values for the metallicity of M15 RGB and RHB stars is addressed and a resolute disparity of $\Delta(RHB-RGB) \approx 0.1$ dex in the iron abundance was found. The anti-correlative behavior of the light neutron capture elements (Sr, Y, Zr) is clearly demonstrated with both Ba and Eu, standard markers of the {\it s}- and {\it r}-process, respectively. No conclusive detection of Pb was made in the RGB targets. Consequently for the M15 cluster, this suggests that the main component of the {\it s}-process has made a negligible contribution to those elements normally dominated by this process in solar system material. Additionally for the M15 sample, a large Eu abundance spread is confirmed, which is comparable to that of the halo field at the same metallicity. These abundance results are considered in the discussion of the chemical inhomogeneity and nucleosynthetic history of M15.

Error Analysis of Light n-Capture Element Abundances in the Metal-Poor Halo Star HD74462

ABSTRACTThe origin of light neutron-capture elements in the early Galaxy is an unsolved problem of nuclear astrophysics. Previous studies have not been able to provide a satisfactory mechanism for the production of elements such as zirconium (Zr), yttrium (Y), and strontium (Sr) in the early Galaxy. In a previous article, these elements were studied using high-resolution spectra to reduce uncertainty. Determining the abundances of elements in distant stars requires the use of computer models of the stellar atmosphere. We now analyze the impacts of possible errors in those computational models on the calculated elemental abundance in the star. By adjusting model parameters for the prototypical metal-poor halo star HD074462—specifically: effective temperature, microturbulent velocity, surface gravity, and metallicity—we can judge the relative sensitivity of our calculations to errors in these values. Four lines of Zr, as well as five lines of Y, were observed in this article. Our findings show that the calculated elemental abundance is most sensitive to errors in the effective temperature of the star, while microturbulent velocity had little-to-no effect. Errors in surface gravity and metallicity of ± 0.5 dex caused a wider variety of errors in the abundance value, with none greater than 0.25 dex.

NEW ABUNDANCE DETERMINATIONS OF CADMIUM, LUTETIUM, AND OSMIUM IN THE r -PROCESS ENRICHED STAR BD +17 3248 ,

We report the detection of Cd I (Z = 48), Lu II (Z = 71), and Os II (Z = 76) in the metal-poor star BD+173248. These abundances are derived from an ultraviolet spectrum obtained with the Space Telescope Imaging Spectrograph on the Hubble Space Telescope. This is the first detection of these neutron-capture species in a metal-poor star enriched by the r-process. We supplement these measurements with new abundances of Mo I, Ru I, and Rh I derived from an optical spectrum obtained with the High Resolution Echelle Spectrograph on Keck. Combined with previous abundance derivations, 32 neutron-capture elements have been detected in BD+173248, the most complete neutron-capture abundance pattern in any metal-poor star to date. The light neutron-capture elements (38 <= Z <= 48) show a more pronounced even-odd effect than expected from current Solar system r-process abundance predictions. The age for BD+173248 derived from the Th II/Os II chronometer is in better agreement with the age derived from other chronometers than the age derived from Th II/Os I. New Hf II abundance derivations from transitions in the ultraviolet are lower than those derived from transitions in the optical, and the lower Hf abundance is in better agreement with the scaled Solar system r-process distribution.

CHEMICAL COMPOSITIONS OF KINEMATICALLY SELECTED OUTER HALO STARS

Chemical abundances of 26 metal-poor dwarfs and giants are determined from high-resolution and high signal-to-noise ratio spectra obtained with the Subaru/High Dispersion Spectrograph. The sample is selected so that most of the objects have outer-halo kinematics. Self-consistent atmospheric parameters were determined by an iterative procedure based on spectroscopic analysis. Abundances of 13 elements, including alpha-elements (Mg, Si, Ca, Ti), odd-Z light elements (Na, Sc), iron-peak elements (Cr, Mn, Fe, Ni, Zn), and neutron-capture elements (Y, Ba), are determined by two independent data reduction and local thermodynamic equillibrium analysis procedures, confirming the consistency of the stellar parameters and abundances results. We find a decreasing trend of [alpha/Fe] with increasing [Fe/H] for the range of -3.5< [Fe/H] <-1, as found by Stephens and Boesgaard. [Zn/Fe] values of most objects in our sample are slightly lower than the bulk of halo stars previously studied. These results are discussed as possible chemical properties of the outer halo in the Galaxy.

THE CHEMICAL COMPOSITION OF RED GIANT STARS IN FOUR INTERMEDIATE-AGE CLUSTERS OF THE LARGE MAGELLANIC CLOUD

This paper presents the chemical abundance analysis of a sample of 27 red giant stars located in 4 popolous intermediate-age globular clusters in the Large Magellanic Cloud, namely NGC 1651, 1783, 1978 and 2173. This analysis is based on high-resolution (R ~ 47000) spectra obtained with the UVES@VLT spectrograph. For each cluster we derived up to 20 abundance ratios sampling the main chemical elemental groups, namely light odd-Z, alpha, iron-peak and neutron-capture elements. All the analysed abundance patterns behave similarly in the 4 clusters and also show negligible star-to-star scatter within each cluster. We find [Fe/H]=-0.30+-0.03, -0.35+-0.02, -0.38+-0.02 and -0.51+-0.03 dex for NGC 1651, 1783, 1978 and 2173, respectively. The measurement of light odd-Z nuclei gives slightly subsolar [Na/Fe] and a more significant [Al/Fe] depletion (~ -0.50 dex). The [alpha / Fe] abundance ratios are nearly solar, while the iron-peak elements well trace that one of the iron. s-process elements behave in a peculiar way: light s-elements give subsolar [Y/Fe] and [Zr/Fe] abundance ratios, while heavy s-elements give enhanced [Ba/Fe], [La/Fe] and [Nd/Fe] with respect to the solar values. Also, the [Eu/Fe] abundance ratio turns out to be enhanced (~ 0.4 dex).

Neutron‐Capture Elements in the Very Metal‐poor Star HD 88609: Another Star with Excesses of Light Neutron‐Capture Elements

We obtained a high-resolution, high-signal-to-noise UV-blue spectrum of the extremely metal-poor red giant HD 88609 to determine the abundances of heavy elements. Nineteen neutron-capture elements are detected in the spectrum. Our analysis revealed that this object has large excesses of light neutron-capture elements, while heavy neutron-capture elements are deficient. The abundance pattern shows a continuously decreasing trend as a function of atomic number, from Sr to Yb, which is quite different from those in stars with excesses of r-process elements. Such an abundance pattern is very similar to that of HD 122563, which was studied in our previous work. The results indicate that the abundance pattern found in the two stars could represent the pattern produced by the nucleosynthesis process that provided light neutron-capture elements in the very early Galaxy.

Neutron‐Capture Elements in the Very Metal Poor Star HD 122563

We obtained high-resolution, high signal-to-noise ratio (S/N) spectroscopy for the very metal poor star HD 122563 with the Subaru Telescope High Dispersion Spectrograph. Previous studies have shown that this object has excesses of light neutron-capture elements, while its abundances of heavy ones are very low. In our spectrum, which covers 3070-4780 A of this object, 19 neutron-capture elements have been detected, including seven for the first time in this star (Nb, Mo, Ru, Pd, Ag, Pr, and Sm). Upper limits are given for five other elements including Th. The abundance pattern shows a gradually decreasing trend, as a function of atomic number, from Sr to Yb, which is quite different from those in stars with excesses of r-process elements. This abundance pattern of neutron-capture elements provides new strong constraints on the models of nucleosynthesis responsible for the very metal poor stars with excesses of light neutron-capture elements but without enhancement of heavy ones.

The Abundances of Light Neutron-Capture Elements in Planetary Nebulae

We present preliminary results from a large-scale survey of the neutron( n )-capture elements Se and Kr in Galactic planetary nebulae (PNe). These elements may be produced in PN progenitors by s -process nucleosynthesis, and brought to the stellar envelope by third dredge-up (TDU). We have searched for [Kr iii] 2.199 and [Se iv] 2.287 $\mu$ m in 120 PNe, and detected one or both lines in 79 objects, for a detection rate of 66%. In order to determine abundances of Se and Kr, we have added these elements to the atomic database of the photoionization code CLOUDY, and constructed a large grid of models to derive corrections for unobserved ionization stages. Se and Kr are enriched in $\sim$ 73% of the PNe in which they have been detected, and exhibit a wide range of abundances, from roughly solar to enriched by a factor of 10 or more. These enrichments are interpreted as evidence for the operation of the s -process and TDU in the progenitor stars. In line with theoretical expectations, Kr is more strongly enhanced than Se, and the abundances of both elements are correlated with the carbon abundance. Kr and Se are strongly enhanced in Type I PNe, which may be evidence for the operation of the $^{22}$ Ne neutron source in intermediate-mass AGB stars. These results constitute the first broad characterization of s -process enrichments in PNe as a population, and reveal the impact of low- and intermediate-mass stars on the chemical evolution of trans-iron elements in the Galaxy.

Neutron-Capture Elements in the Metal-poor Globular Cluster M15

We report on observations of six giants in the globular cluster M15 (NGC 7078) using the Subaru Telescope to measure neutron-capture elemental abundances. Our abundance analyses, based on high-quality blue spectra, confirm the star-to-star scatter in the abundances of heavy neutron-capture elements (e.g., Eu), and we found no significant s-process contribution to them, as was found in previous studies. We have found that, for the first time, there are anticorrelations between the abundance ratios of light to heavy neutron-capture elements ([Y/Eu] and [Zr/Eu]) and the heavy neutron-capture elements (e.g., Eu). This indicates that the light neutron-capture elements in these stars cannot be explained by only a single r-process. Another process that contributed significantly to the light neutron-capture elements is required in M15. Our results suggest a complicated enrichment history for M15 and its progenitor.