The application of conventional fly ash and zeolite powder in the field of concrete durability is limited. In this study, durability tests coupling dry-wet cycling and sulfate erosion were conducted on concrete with varying dosages of modified fly ash (MFA) and modified zeolite powder (MZP). The compressive strength, failure mode, water absorption rate, and ion concentration changes were systematically investigated. The reaction products and structure were analyzed through SEM, EDS, and XRD tests, correlating with macroscopic parameters. An effective transport model for sulfate ions in concrete was established, considering the material influence coefficient km and the effective diffusion coefficient De. The results indicate that a higher content of Ca phases in MFA leads to a reduction in concrete early strength, while later stages exhibit rapid strength growth due to pozzolanic reactions. MZP contains a significant amount of Al and Si phases, which promote both early and later-stage concrete strength. MFA and MZP enhance the resistance of concrete to sulfate erosion, with MZP exhibiting a significantly superior improvement effect compared to MFA. This is attributed to the following factors: on the one hand, the addition of MFA and MZP reduces the porosity and improves the pore structure of concrete, thus delaying the diffusion of sulfate ions into the concrete; on the other hand, the pozzolanic reactions of MFA and MZP consume available calcium hydroxide, leading to the formation of C–S–H and C-A-S-H gels, which densify the microstructure and reduce the probability of leaching erosion of hydration products, thereby limiting the formation of ettringite. The applicability and reliability of the sulfate-ion effective transport model were verified based on experimental data. The model can be employed to predict the distribution of sulfate ions in different types of concrete under various erosion durations, reducing workload and providing a theoretical basis for the durability design and service life prediction of concrete structures in sulfate environments.
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