Nitrate Levels In Groundwater Research Articles

Groundwater nitrate contamination in China: Spatial distribution, temporal trend, and driver analysis

China's groundwater is facing a significant threat from nitrate pollution. Here we analyzed 2348 regional surveys of groundwater nitrate levels in China from 1990 to 2020, examining distribution, trends, and drivers. This study uncovers a concerning rise in nitrate pollution, with estimated median nitrate levels climbing from 3.84 mg/L in 1990 to 6.94 mg/L in 2020. A stark contrast is observed between regions: the northern areas have a median nitrate concentration of 8.54 mg/L, significantly higher than the southern regions, where the median is just 7.15 mg/L. From 1990 to 2020, agricultural activity consistently emerges as the dominant driver of changes in groundwater nitrate concentrations, while groundwater exploitation, domestic pollution, and industrial production also contribute to varying degrees. This analysis highlights the urgency for region-specific policies and interventions to address the escalating nitrate pollution in China's groundwater.

Human health risk and water quality assessment due to fluoride and nitrate around Cauvery River basin, southern India.

Good quality water for human consumption, irrigation, and industrial use is very important. Today, around the world, water is contaminated by natural processes and human activities. This study aimed to evaluate the suitability of groundwater for drinking and irrigation, identifythe source of fluoride and nitrate contamination, and assess thehuman health risks around the Cauvery River basin in southern India. A total of 30 groundwater samples were collected and analyzed for hydrochemical parameters, including EC, TDS, pH, Ca, Mg, Na, K, HCO3, Cl, SO4, NO3, and F-. The majority of groundwater samples in the study area are used for drinking and irrigation. The pH of groundwater in the study area was observed to be dominantly alkaline. The levels of TDS, Ca, Na, K, F, and TH exceeded the permissible limits recommended by BIS and WHO. Fluoride and nitrate levels in groundwater exceeded the permissible limits for drinking purposes in 43% and 50% of the samples, respectively. The excessive concentration of fluoride and nitrate in groundwater could pose serious human health problems. Fluoride and nitrate concentrations in groundwater vary between 0.1 and 2mg/l and 12 and 95mg/l, respectively. Based on the computation of the drinking water quality index, about 73% of groundwater samples were classified asexcellent to good. Health risk was assessed for infants, children, and adults using non-carcinogenic risk indices such as hazard quotients (HQ), hazard indexes (HI), total hazard indices (THI), and carcinogenic risk indices (CR). Infants, children, and adults have different total hazards indexes ranging from 1.508 to 5.733, 1.579 to 6.003, and 0.011 to 0.046, respectively. Health risk assessment results indicatedthat the hazard index and hazard quotient were above the recommended limit of > 1 in most of the samples for infants and children. Non-carcinogenic risk and carcinogenic risks were more likely to affect infants and children rather than adults through ingestion of contaminated water.

A pragmatic approach of hydrochemical and irrigation indices of groundwater quality of district Ballia, U.P. India

ABSTRACT In the groundwater aquifer media, enormous amounts of ions can be found naturally in rocks from the Pleistocene and Holocene ages. There are several reports of metals and ionic contamination in the different blocks of the Ballia district. This article focuses on a thorough investigation of the hydrogeochemical properties and the cause of ionic contamination in the Ballia district's groundwater system. This article discusses the interactions between the numerous cations and anions that are hydro-geologically present as well as several physico-chemical factors. The relationship analysis was conducted utilizing irrigation indices and a Stufzand classification, which was further supported by a Durov and Stiff plot. The Durov plot shows the mineralization of the aquifer by sand and evaporates of geological formation. The Gibbs plot shows that the rock–water interaction, weathering of silicates, evaporates dissolution, carbonate dissolution, and anthropogenic activities. The Stiff plot shows the highest concentration of Mg-rich minerals and Cl due to the weathering of calcite, amphiboles, and anthropogenic activities also proven by the Irrigation indices and Stufzand classification. The high water quality index (WQI) value was discovered to be mostly due to greater EC, total dissolved solids, hardness, nitrate, sulfate, chloride, and magnesium levels in groundwater.

Enhancing Groundwater Quality Evaluation Using Associative Rule Mining Technique with Random Forest Split Gini Indexing Algorithm for Nitrate Concentration Analysis

Human actions and changing weather patterns are contributing to the growing demand for groundwater resources. Nevertheless, evaluating the quality of groundwater is crucial. Nitrate is a significant water contaminant that can lead to blue-baby syndrome or methemoglobinemia. Therefore, it is necessary to assess the level of nitrate in groundwater. Current methods involve evaluating the quality of groundwater and integrating it into the models. The inappropriate datasets, lack of performance, and other constraints are limitations of current methods. Ground water dataset is used and pre-processed the data’s. Selected data’s are feature extracted and associated with the rule ranking. In the suggested model, the use of associative rule mining technique has been implemented to address these challenges and assess nitrate levels in groundwater. The method of rule ranking is carried out using association rule mining technique to divide the datasets. The split gini indexing algorithm is introduced in the proposed model for data classification. The Split Gini Indexing algorithm is a decision tree induction algorithm that is used to build decision trees for classification tasks. It is based on the Gini impurity measure, which measures the heterogeneity of a dataset. The quality of groundwater has been classified using Naïve Bayes, SVM, and KNN algorithms. The proposed approach's efficiency is evaluated by calculating performance metrics such as precision, accuracy, F1-score, and recall values. The suggested method in the current research attains an improved accuracy of 0.99, demonstrating enhanced performance.

Tracing Mine Water Flows in a Dolomite Quarry, South Africa, Using Hydrochemistry and Stable Isotopes

South Africa has a growing population, a relatively dry climate, and abundant mining activity, all of which increase the importance of water management. The Mooiplaas Dolomite Quarry, south east of Pretoria, has been mining metallurgical grade dolomite since 1969, within the productive karst aquifers of the Malmani Subgroup, Transvaal Supergroup. This study was conducted to elucidate the flow of water around the site, including the mine water and groundwater. The site was investigated by sampling precipitation, surface water, groundwater, and mine water for hydrochemical and stable isotope analysis from 2011 to 2017, totalling over 400 samples. Levels of nitrate in groundwater and mine water were marginally above drinking water limits, from explosives residues, and ammonia in the nearby Hennops River was unacceptably high due to municipal sewage outfalls, but otherwise, water quality was very good. Alkalinity from rock weathering, aided by crushing of dolomite, was the main control on water chemistry. Combined analysis of dissolved matter (TDS, nitrate, Mg, etc.) suggested that the dewatering of the mine and resultant recharge from the slimes dams caused an aerated zone of groundwater, which mixed with regional groundwater flowing beneath the site. Stable isotopes, with an evaporated signature from the mine open water bodies, also showed how mine operations cause recharge to groundwater and subsequent seepage back into the pit lakes. The mine appears not to contaminate the regional groundwater; however, mine designs should avoid situations where process water flows via groundwater back into pits, causing excessive dewatering costs.

Spatial distribution, sources, and human health risk assessment of elevated nitrate levels in groundwater of an agriculture-dominant coastal area in Hainan Island, China

In order to comprehend the groundwater nitrate contamination in Hainan Island, which is recognized as China's sole “tropical agricultural production base,” the distribution characteristics of nitrate in different aquifers and land-use types were elucidated through hydrochemical and geostatistical analysis methods. Principal component analysis (PCA), hierarchical cluster analysis (HCA), and absolute principal component score-multiple linear regression (APCS-MLR) were employed for qualitative and quantitative analysis of the nitrate source. The results showed that NO3−-high (>88.57 mg/L) groundwater accounted for about 10 % of the total distribution area of the western coastal area in Hainan Island. Moreover, the proportions of NO3−-high groundwater in pore water and fissure water were 10 % and 7 %, respectively. The order of groundwater nitrate concentration in different land-use types was as follows: bare land, cultivated land, construction land, grassland, and woodland. The main sources of elevated nitrate concentrations in pore water were animal feces and nitrogen/potassium fertilizers, accounting for 45.4 % of the overall contribution. These substances infiltrated through the vadose zone, leaching out and mobilizing selenium within this zone, ultimately leading to the characteristic enrichment patterns observed in pore water, including nitrate, arsenic, potassium, and selenium. Furthermore, the occurrence of high nitrate in fissure water was mainly attributed to the leaching of cultured manure, septic tank leakage, and infiltration of domestic sewage, accounting for a contribution rate of 32.9 %. Simultaneously, under oxidizing conditions, selenium became activated and entered groundwater through water flow, thereby exhibiting common enrichment characteristics with nitrate and potassium in fissure water. In addition, the assessment of human health risks revealed that 16 % and 40 % of groundwater samples posed unacceptable non-carcinogenic risks to adults and children respectively, with a higher risk for local children. The study recommends the reasonable application of chemical fertilizers, as well as the strengthening of sewage treatment capacity and standardized disposal of manure and feces, to reduce nitrate contamination of groundwater at source and ensure the safety of drinking water.

Bimetallic Pd‐Sn Catalytic Electrodes from Deep Eutectic Solvents for Selective Nitrate Reduction Toward Nitrogen

AbstractNitrate is one of the most widespread water contaminants globally. Nitrate levels in groundwater and surface water can rise to unhealthy levels as a result of nitrogen fertilizer runoff from lawns and farms. This research aims to selectively convert nitrate to gaseous nitrogen using Palladium‐Tin (Pd‐Sn) bimetallic electrodes electrodeposited on stainless‐steel (SS). Inductively coupled plasma optical emission spectrometry, scanning electron microscope, and X‐ray diffraction are used to analyze the composition, surface morphology, and crystal structure of the electrodes. The XRD analysis reveals that the Pd‐Sn/SS electrode has a crystalline nature when a Pd molar ratio >0.5 while an amorphous phase is detected over a Pd molar ratio (≤0.5). The electrochemical nitrate reduction is carried out in a 0.1 M HClO4 / 8 mM NaNO3 solution for 5 h using electrodes prepared in deep eutectic solvent (DES) system. The Pd0.93Sn0.07/SS electrode shows the best catalytic performance in terms of high nitrate conversion of 97%, N2 selectivity of 88%, and N2 yield of 86% compared to counter electrodes. These findings demonstrate a considerable impact of the electrode preparation process on nitrogen conversion, selectivity, and yield.

Risk assessment for the distribution and levels of fluoride and nitrate in groundwater in a semi-arid area of northern Mexico

This study assessed groundwater quality and associated risks in a semi-arid region located in a city in the Northern zone of Mexico. To conduct this study, we collected 92 groundwater samples and analyzed 14 physicochemical parameters across 18 sectors. Only fluoride (F−) and nitrate (NO3–N) exceeded Mexican regulations and WHO guidelines for drinking water. Approximately 65 % of samples surpassed the 1.5 mg/L permissible limit for F−, with the highest recorded concentration reaching 3.60 mg/L in two sectors among the 18 studied, 34 % of samples exhibited NO3−-N concentrations in the 10.64–17.27 mg/L range across three sectors, surpassing permissible levels. Pearson Correlation Analysis revealed strong positive correlations with HCO3−, EC, Mg2+, Ca2+, NO3−, Cl−, SO42−, and Na+. Moderate correlations existed for the total hardness, alkalinity, Cl−, NO3−, SO42−, Na+, Mg2+, and EC. K+ showed weak correlations. PIG values indicated significant pollution of F− in all of 18 sectors (PIG <1). HQ for F− exceeded tolerable levels in 14 adult and 16 child sectors, posing an intolerable risk. Nitrate's HQ was below <1 for all age groups, suggesting non-carcinogenic effects. THI indicated high F− and NO3−-N exposure risks for children in the study area. It is recommended to implement effective water treatment technologies, such as reverse osmosis or adsorptive materials, in those sectors reported as a potential risk to human health to ensure access to safe drinking water.

Using selectivity to evaluate aqueous- and resin-phase denitrification during biological ion exchange.

An increased fertilizer application for agricultural purposes has resulted in increased nitrate (NO3-) levels in surface water and groundwater around the globe, highlighting demand for a low-maintenance NO3- treatment technology that can be applied to nonpoint sources. Ion exchange (IEX) is an effective NO3- treatment technology and research has shown that bioregeneration of NO3- laden resins has the potential to minimize operational requirements and brine waste production that often prevents IEX application for decentralized treatment. In this work, batch denitrification experiments were conducted using solutions with low IEX selectivity capable of supporting the growth of denitrifying bacteria, while minimizing NO3- desorption from resins, encouraging resin-phase denitrification. Although only 15% of NO3- was desorbed by the low selectivity solution, this initial desorption started a cycle in which desorbed NO3- was biologically transformed to NO2-, which further desorbed NO3- that could be biotransformed. Denitrification experiments resulted in a 43% conversion rate of initially adsorbed NO3-, but biotransformations stopped at NO2- due to pH limitations. The balance between adsorption equilibria and biotransformation observed in this work was used to propose a continuous-flow reactor configuration where gradual NO3- desorption might allow for complete denitrification in the short retention times used for IEX systems.

A Review on In-Situ Denitrification Technology for Consideration in Jaffna Peninsula Aquifer Remediation

A Review on In-Situ Denitrification Technology for Consideration in Jaffna Peninsula Aquifer Remediation

Groundwater contamination apportionment in Beida-Bordj rural territory, northeast Algeria, using the nitrate pollution index (NPI) and groundwater pollution index (GPI)

Most of the time, too much use of artificial fertilizers in rural areas, especially nitrogen fertilizers used to make crops grow faster, causes nitrate levels in groundwater to rise. In the Beida-Bordj area in northeast Algeria, groundwater is the main source of water for agriculture and drinking. Because of this, the quality of groundwater is very important. Therefore, nitrogen pollution in groundwater, which is one of the most important environmental problems, needs to be looked into. Therefore, evaluating groundwater contamination to protect human health was the primary focus of this investigation. As a result, 111 samples were taken in May 2022 from wells in different parts of the study area for physical and chemical research. Therefore, the nitrogen pollution index (NPI) and the groundwater pollution index (GPI) have been used to measure how clean groundwater is. The results show that the groundwater in the area that was tested is alkaline. Based on their average values, the abundance of cations and anions is as follows: Ca2+ > Na+ > Mg2+ > K+; and SO42− > Cl− > HCO3− > NO3−, in that order. The estimated NPIs ranged from – 1 to 4.5, with 0.92 being the average. Overall, the NPI data showed that only 25% of groundwater samples were clean, and the other 75% were dirty. The GPI readings ranged from 6.3 to 0.4, with an average of 1.2. This means that only 54% of the samples of groundwater from the study area were safe to drink. According to analyses of water quality parameters like SAR, SSP, RSC, PI, MH, and KR, the majority of groundwater samples from the research region are suitable for irrigation, because they fall into the "good" or "suitable" quality classes. This study's findings offer some intriguing suggestions for lowering pollution levels and bolstering groundwater management strategies for the future.

Identifying nitrate sources and transformations in an agricultural watershed in Northeast China: Insights from multiple isotopes

Accurate identification of riverine nitrate sources is required for preventing and controlling nitrogen contamination in agricultural watersheds. The water chemistry and multiple stable isotopes (δ15N–NO3, δ18O–NO3, δ2H–H2O, and δ18O–H2O) of the river water and groundwater in an agricultural watershed in China's northeast black soil region were analyzed to better understand the sources and transformations of riverine nitrogen. Results showed that nitrate is an important pollutant that affects water quality in this watershed. Affected by factors such as seasonal rainfall changes and spatial differences in land use, the nitrate concentrations in the river water showed obvious temporal and spatial variations. The riverine nitrate concentration was higher in the wet season than in the dry season, and higher downstream than upstream. The water chemistry and dual nitrate isotopes revealed that riverine nitrate came primarily from manure and sewage (M&S). Results from the SIAR model showed that it accounted for more than 40% of riverine nitrate in the dry season. The proportional contribution of M&S decreased during the wet season due to the increased contribution of chemical fertilizers and soil nitrogen induced by large amounts of rainfall. The δ2H–H2O and δ18O–H2O signatures implied that interactions occurred between the river water and groundwater. Considering the large accumulation of nitrates in the groundwater, restoring groundwater nitrate levels is essential for controlling riverine nitrate pollution. As a systematic study on the sources, migration, and transformations of nitrate/nitrogen in agricultural watersheds in black soil regions, this research can provide a scientific support for nitrate pollution management in the Xinlicheng Reservoir watershed and provide a reference for other watersheds in black soil regions in the world with similar conditions.

TENEURS EN NITRATES DANS LES AQUIFERES DISCONTINUS DU SOCLE DU DAMAGARAM MOUNIO (EST DU NIGER)

The basement of Damagaram Mounio, study area, outcrops in the eastern part of the Zinder region. It is a very populated area and where the problem of water resources is acute. In addition to the low availability of this water resource, its quality remains questionable in several areas. Thus, the contents of certain chemical parameters, including nitrates in particular, greatly exceed the drinking water standards for human consumption, hence the present study, which has as its main objective, the determination of the percentages of boreholes whose the waters have nitrate levels above the WHOstandard. The methodological approach based on the sampling of hydraulic structures capturing the aquifers of the basement, the analysis of the physicochemical and isotopic parameters of the waters of several boreholes, the determination of the characteristics of the nitrates, made it possible to lead to several interesting results.Thus, the nitrate contents of the waters of the Damagaram Mounio basement aquifers vary from 0.22 to 313.3 mg/L, with an average of 72.23 mg/L, and a standard deviation of 62.23. This study made it possible to show that 32% of the modern structures sampled have nitrate levels above the admissible limit value for drinking water, set at 50 mg/L, according to the standards of the World Health Organization (WHO) these waters are unfit for human consumption. The spatial distribution of nitrate levels in groundwater in the area showed that these are more accentuated between the towns of Damagaram Takaya and Birni Kazoe, which are characterized by values ​​above 100 mg/l. The relation between nitrate contents and water electrical conductivity values ​​showed that the mineralization of groundwater in the area is controlled by nitrate ions. Furthermore, the isotopic levels of Nitrogen 15 (15N), obtained in the waters of the area, vary from 0 to 7.2, thus showing that these nitrates could come from the nature of the soil (quagmire around water points) and chemical fertilizers (ureas and fertilizers used in the study area).

A revised hydrogeological conceptual model of the Fell Sandstone aquifer, Northumberland and its impact on the interpretation of long-term nitrate trends

Northumbrian Water abstract groundwater from the Fell Sandstone Formation (part of the Carboniferous Border Group) in north Northumberland, which is a groundwater-only water resource zone providing drinking water to Berwick-upon-Tweed and the surrounding area. Groundwater in observation and abstraction boreholes shows significant rising nitrate levels derived from agricultural land use, and are predicted to have an impact on groundwater quality by 2030. Northumbrian Water policy is to use catchment management techniques to mitigate rising nitrate levels through influencing land-use practices and reducing nitrate concentration in groundwater recharge. This paper demonstrates how a detailed geological and hydrogeological understanding of the area has been used to identify specific areas where appropriate catchment management techniques may be most effectively applied. Northumbrian Water and the Environment Agency jointly funded the British Geological Survey to develop a numerical groundwater model of the Fell Sandstone aquifer and to undertake a review of the geology of the Fell Sandstone Formation as part of a Water Industry National Environment Programme (WINEP). Combining the results of these two studies, supported by spatial and temporal field measurements of groundwater nitrate levels, an improved understanding of the potential fate and transport of nitrate in the Fell Sandstone aquifer has emerged. This allows a better prediction of the spatial and temporal impacts of nitrate losses from the soil zone to the aquifer in support of a catchment management approach to mitigating rising nitrate levels. Thematic collection: This article is part of the Hydrogeology of Sandstone collection available at: https://www.lyellcollection.org/cc/hydrogeology-of-sandstone

Hydroxyl-radical based advanced oxidation processes can increase perfluoroalkyl substances beyond drinking water standards: Results from a pilot study

Advanced oxidation processes (AOPs) are popular technologies employed across the U.S. for wastewater reclamation and drinking water treatment of recalcitrant chemicals. Although there is consensus about the ineffectiveness of AOPs to treat perfluoroalkyl substances (PFASs; not polyfluoro compounds by definition here), there is a lack of field data demonstrating their impact on the transformation of unknown PFAS precursors during groundwater treatment. In this study, the fate of PFASs in seven pilot-scale AOPs, including four different technologies (UV/H2O2, UV/Cl2, UV/TiO2, and O3/H2O2), was assessed at four drinking water systems across New York State (NYS), USA. Seven of 18 PFASs were detected in the influent at concentrations ranging from below method detection to 64 ng/L. Across all systems, all detected PFASs showed an increase in concentration after treatment presumably due to unknown precursor transformation with specific increases for perfluorobutane sulfonate (PFBS), perfluorohexanoic acid (PFHxA), perfluoroheptanoic acid (PFHpA), perfluorohexane sulfonate (PFHxS), perfluorooctanoic acid (PFOA), perfluorooctane sulfonate (PFOS), and perfluorononanoic acid (PFNA) averaging 405 (range: 0 – 1220) %, 1.0 (-7 – 9) %, 3.8 (0 – 9.5) %, 3.3 (-11 – 13) %, 14 (0 – 48) %, 13 (3 – 25) %, and 2 (0 – 5.2) %, respectively. The increase in PFAS concentration was dependent on UV and oxidant dose, further confirming that transformation reactions were occurring due to AOPs similar to a total oxidizable precursor assay. At one of the sites, PFOA levels exceeded the current NYS drinking water standard of 10 ng/L after, but not before treatment, highlighting the importance of considering the potential impact of AOP on treated water quality when designing treatment systems for regulatory compliance. The increase in PFAS concentration in the AOP systems positively correlated (r = 0.91) with nitrate levels in groundwater, suggesting that onsite septic discharges may be an important source of PFAS contamination in these unsewered study areas. Results from this pilot-scale demonstration reveal that hydroxyl radical-based AOPs, although ineffective in treating PFASs, can help to reveal the true extent of PFAS contamination in source waters.

Nitrate in groundwater and agricultural products: intake and risk assessment in northeastern Iran

The suitability of groundwater and agricultural products for human consumption requires determining levels and assessing the health risks associated with potential pollutants. Here, particularly pollution with nitrate still remains a challenge, especially for those urban areas suffering from insufficient sewage collection systems, resulting in contaminating soil, endangering food safety, and deteriorating drinking water quality. In the present study, nitrate concentrations in the commonly consumed fruit and vegetable species were determined, and the results, together with the groundwater nitrate levels, were used to assess the associated health risks for Mashhad city residents. For this assessment, 261 water samples and 16 produce types were used to compute the daily intake of nitrate. Nitrate in groundwater was analyzed using a spectrophotometer, and produce species were examined using High-Performance Liquid Chromatography. Ward’s hierarchical cluster analysis was applied for categorizing produce samples with regard to their nitrate content. Additionally, to account for the sanitation hazards associated with groundwater quality for drinking purposes, total coliform and turbidity were also assessed using the membrane filter (MF) technique and a nephelometer, respectively. Nitrate concentrations exceeded the prescribed permissible limits in 42% of the groundwater wells. The outcomes also exhibit significantly higher nitrate accumulation levels in root-tuber vegetables and leafy vegetables compared to fruit vegetables and fruits. Using cluster analysis, the accumulation of nitrate in vegetables and fruits was categorized into four clusters, specifying that radish contributes to 65.8% of the total content of nitrate in all samples. The Estimated Daily Intake (EDI) of nitrate and Health Risk Index (HRI) associated with consumption of groundwater exceeded the prescribed limit for the children’s target group in Mashhad’s south and central parts. Likewise, EDI and HRI values for produce consumption, in most samples, were found to be in the tolerable range, except for radish, lettuce, and cabbage, potentially posing risks for both children and adult consumers. The total coliforms in groundwater were found to violate the prescribed limit at 78.93% of the sampling locations and were generally much higher over the city’s central and southern areas. A relatively strong correlation (R2 = 0.6307) between total coliform and nitrate concentrations suggests the release of anthropogenic pollution (i.e., sewage and manure) in the central and southern Mashhad.

Patterns and Drivers of Groundwater and Stream Nitrate Concentrations in Intensively Managed Agricultural Catchments

The environmental loss of nitrogen in agricultural landscapes has pervasive consequences, including human health implications, eutrophication, loss of habitat biodiversity and greenhouse gas emissions. The efficacy of mitigation strategies designed to control or prevent nitrate contamination of waterbodies requires an understanding of catchment scale pressures and processes. Groundwater and stream nitrate concentrations fluctuate over temporal scales ranging from the daily to the decadal. Identifying spatiotemporal trends and dominant drivers of nitrate in water is challenging as the drivers are intertwined. The effects of agronomic, meteorological and hydrogeological drivers on groundwater and stream nitrate were investigated over seven years in two well-drained agricultural catchments, dominated by tillage and grassland farming, respectively. A significant positive temporal trend in nitrate concentration was observed in the tillage catchment, whereas no long-term trend was observed in the grassland catchment. Agronomic, meteorological and hydrogeological factors were significantly related to temporal nitrate changes across both catchments. Clearly identifying the drivers influencing temporal changes in nitrate concentrations is critical to improving water quality. The study highlighted that to reduce groundwater nitrate levels in areas of high risk (thin soils, low clay content and shallow groundwater), nitrogen applications need to be reduced and/or tailored, particularly at times of restricted crop growth.

Nitrogen rate, irrigation and rainfall impacts on groundwater nitrate levels in sandy coastal golf courses

AbstractThere have been concerns over fertilizer nitrogen (N) applied to turfgrass areas affecting groundwater quality in sandy coastal areas since the 1970s . Extensive amount of small‐scale research studies has determined the major factors that contribute to excessive nitrate‐N leaching from turfgrass ecosystems. There are limited data on large‐scale groundwater monitoring of turfgrass sites, such as golf courses, which are related to management inputs. There are land‐use regulations limiting the amount of fertilized turfgrass in coastal area in the United States which assume a linear relationship between the amounts of N applied and leached. The purpose of this study is to evaluate the long‐term impact of yearly variations in N application rate, irrigation amounts, and seasonal precipitation on groundwater quality on golf courses in critical groundwater recharge areas. Two golf courses, The Bridge and Sebonack Golf Club, in this study are in eastern Long Island, NY with systematic groundwater monitoring for NO3–N. Each golf course follows best management practices (BMP) including limitations on amount, rate, source and timing of N applications as well as controlled irrigation based on on‐site evapotranspiration measurements. The results of this study clearly show that on golf courses in sandy critical groundwater recharge areas that follow BMP, the amount of N applied is not related to NO3–N levels in groundwater. Rainfall amounts more closely followed NO3–N levels in groundwater, thus abnormally high rainfall can result in higher NO3–N levels. Implementing fertilizer BMP can be very effective in protecting groundwater quality.

Deep soil nitrogen storage slows nitrate leaching through the vadose zone

Nitrogen (N) fertilizer applications are important for agricultural yield, yet not all the applied N is taken up by crops, leading to surplus N storage in soil or leaching to groundwater and surface water. Leaching loss of fertilizer N represents a cost for farmers and has consequences for human health and the environment, especially in the southern Willamette Valley, Oregon, USA, where groundwater nitrate contamination is prevalent. While improved nutrient management and conservation practices have been implemented to minimize leaching, nitrate levels in groundwater continue to increase in many long-term monitoring wells. To elucidate controls on leaching rates and N dynamics in agricultural soils across soil depths, and in response to seasonal and annual variation in management (e.g., fertilizer input amount and summer irrigation), we intensively monitored the transport of water and nitrate every two weeks for four years through the vadose zone at three depths (0.8, 1.5, and 3.0 m) in a sweet corn (maize) field. Though nitrate leaching was highly variable among lysimeters at the same depth and across years, a strong pattern emerged: annual nitrate leaching significantly decreased with depth across the study, averaging ~104 kg N ha-1 yr-1 near the surface (0.8 m) versus ~56 kg N ha-1 yr-1 in the deep soil (3.0 m), a 54% reduction in leaching between the soil layers. Even though crops were irrigated in summer, most leaching (~72% below 3.0 m) occurred during the wet fall and winter. Based on steady state assumptions, a net equivalent of ~29% of surface N inputs leached below 3.0 m into the deeper soil and groundwater, while ~44% was removed in crop harvest, indicating considerable N retention in the soil (~27% of inputs or approximately 58 kg N ha-1 yr-1). The accumulation and long-term dynamics of deep soil N is a legacy of agricultural management that should be further studied to better manage and reduce nitrate loss to groundwater.

Geochemical factors controlling natural background levels of phosphate in various groundwater units in a large-scale urbanized area

Assessing natural background levels (NBLs) of groundwater chemical components is useful to the identification of geochemical factors controlling the origin of high levels of chemical components in groundwater. This study assessed the NBLs of phosphate in various groundwater units in the Pearl River Delta (PRD) where urbanization is a large-scale by the combination of a modified pre-selection method and Grubbs’ test, and discussed main geochemical processes controlling the origin of high levels of phosphate in groundwater. Here, the PRD is divided into four groundwater units according to its hydrogeological conditions. The modified pre-selection method consists of detected organic contaminants, the oxidation capacity, as well as the high levels of ammonium and nitrate in groundwater. Results showed that the NBL of phosphate in the coastal-alluvial aquifer was abnormal high (1.8 mg/L), and was >4 times that in other groundwater units. This is mainly attributed to the co-release of phosphate, bicarbonate, and Fe(II) accompanied with the elevated pH and decreased Eh, which resulted from the mineralization of organic matter accompanied with the reductive dissolution of Fe(III)-(hydr)oxides as well as the desorption of other secondary minerals such as aluminum oxyhydroxides in the overlaid marine stratum. Besides, unlike other groundwater units, the property of discharge area of the coastal-alluvial aquifer with more reducing environment also contributes the higher NBL of phosphate in the coastal-alluvial aquifer than in other groundwater units.