The subject of our research was to assess the suitability of maize grown in lead-contaminated soil for energy purposes. Lead is toxic to the natural environment. Therefore, the recultivation of soil polluted with this element is very important in stabilizing the natural environment. In the present research, maize was used as a remediating plant, and its effects were enhanced by soil fertilization with biocompost and biochar. The aim of the research was to determine the influence of Pb2+ on maize biomass, its combustion heat and heating value, and the biochemical and physicochemical properties of the soil. It was accomplished in a pot experiment by testing the effects of 800 mg Pb2+ kg−1 d.m. soil and biocompost and biochar applied of 20 g kg−1 d.m. soil. Lead was found to drastically deteriorate soil quality, which reduced the biomass of maize. Lead negatively affected the activity of the soil enzymes tested and modified the physicochemical properties of the soil. Fertilization with biocompost and biochar mitigated lead-induced interference with soil enzymatic activity. The applied biocomponents also had positive effects on the chemical and physicochemical properties of the soil. Maize cultivated on lead-polluted soil did not lose its energetic properties. The heating value of maize was stable, which shows its potential in the recultivation of lead-contaminated soils.