Layered Structure Research Articles

A novel layered structure of the heterometallic oxalate compound [NH2(CH3)2]2[NaFe(C2O4)3]·0.33NH(CH3)2·0.33H2O: synthesis, crystal structure and thermal decomposition.

The synthesis, single-crystal X-ray structure determination and thermal analysis are reported for a novel heteronuclear oxalate compound synthesized from a mixture of Fe and Na salts, oxalic acid and N,N-dimethylformamide (DMF) in aqueous solution. The new metallooxalate compound was obtained and identified as a dimethylammonium tris(oxalato)ferrate(III), namely, poly[[bis(dimethylammonium) [tri-μ-oxalato-sodium(I)iron(III)]]-dimethylamine-water (3/1/1)], [NH2(CH3)2]2[NaFe(C2O4)3]·0.33NH(CH3)2·0.33H2O, which crystallizes in the orthorhombic noncentrosymmetric space group C2221. In this novel structure, each Fe atom is hexacoordinated by three non-equivalent bidentate oxalate ligands, while the four Na atoms adopt different coordination numbers, i.e. 6, 7 and 8. The structure consists of bimetallic anionic A layers, {[NaFe(C2O4)3]2-}n, displaying a layered structure with infinitely linked Fe2Na2 tetramers on the ab plane. Two kinds of bimetallic parallel layers (A1 and A2) are present alternately and are found to be staggered, while only the A2 layer is crossed by a twofold axis parallel to the a axis through two Na atoms. The [NH2(CH3)2]+ (HDMA) cations occupy the voids between the anionic layers, while the free molecules, i.e. NH(CH3)2 (DMA) and H2O, are located between two different anionic layers. In addition to ionic bonds, the stability of the structure is ensured by hydrogen-bond interactions involving the oxalate ligands and the nitrogenous and water molecules. The layered structure appears to be different in the family of oxalate-bridged NaI-FeIII compounds. It is in agreement with the predicted 2D or layered structure of bimetallic complexes containing anionic tris(oxalato)metallate(III) with the [XR4]+ counter-ion template (X= N, P or S, and R= alkyl group or H). The thermal decomposition of the compound shows the final residual product to be NaFeO2.

Flexible and free-standing MXene decorated biomass-derived carbon cloth membrane anodes for superior lithium-ion capacitors

Two-dimensional transition metal materials, MXenes, have attracted tremendous attention in energy storage applications due to their layered structure, good electrical conductivity, and abundant functional groups. In this work, Ti3C2Tx MXene nanosheets and carbon nanotubes (CNTs) were uniformly sprayed and successfully loaded on the cotton nonwoven fabric-derived carbon cloth (CC) substrate by electrostatic self-assembly. The as-prepared flexible MXene-CNTs-CC membrane electrodes with enlarged interlayer spacing and high conductivity fabric support exhibited excellent electrochemical performance. In terms of lithium-ion batteries, the optimized MXene-CNTs-CC anode delivered an ultrahigh initial discharge capacity of 2277.5 mAh g−1 at 0.1 A g−1 along with notable cyclability (1149.8 mAh g−1 after 100 cycles) and rate capability (544.1 mAh g−1 after 200 cycles at 2 A g−1) in half cells. The full cells assembled with LiCoO2 cathode also displayed good cycling stability with a high reversible discharge capacity of 833.5 mAh g−1 after 100 cycles at 0.1 A g−1. Remarkably, the further constructed lithium-ion capacitors with the designed porous carbon nanofiber cathode could maintain energy densities of 121.5 to 20.8 Wh kg−1 with the corresponding power densities of 125 to 12,500 W kg−1, and achieved capacitance retention of 76.3 % after 10,000 cycles at 1 A g−1, demonstrating excellent long-term cycle durability.

Relationship between soil structure and hydrological properties of the active layer in the permafrost region of the Qinghai–Tibet Plateau based on fractal theory

Soil structure and hydrological properties influence ecosystem stability and hydrological cycles. Fractal theory has been widely used in the quantitative analysis of soil particle-size distribution (PSD), aggregate and pore distribution, and evaluation of soil degradation, desertification, and wind erosion. However, the complex relationships between soil physiochemical properties and soil hydrological processes based on fractal theory have not been thoroughly investigated. This study focused on the correlation among soil structure, physicochemical properties, and hydrological properties in the active layers of various soil types and vegetation coverages in the permafrost region of the Qinghai–Tibet Plateau (QTP) using the principles of fractal theory. The results showed that the fractal dimension of soil PSD (DPSD) in the active layer of the QTP was predominantly within the range of 2.13–2.70, which is notably smaller than the fractal dimension of the soil water retention curve (DWRC: 2.72–2.93). With decreased vegetation coverage, the alpine soil particles exhibit gradual fineness, increasing the DPSD. Soil physicochemical properties were affected by the interactions among internal factors and the external environment, such as geographical locations, slope orientations, vegetation coverages, and soil freeze–thaw cycles. The results of correlation analysis indicated that the fractal dimension of PSD and the soil water retention curve (WRC) were significantly correlated with soil textural, physicochemical, and hydraulic properties, particularly in clay, silt, and very fine sand content. Finally, a fractal model of WRC in the permafrost region was established based on DPSD and WRC parameters of the Gardner and van Genuchten models. The study provides an improved perspective for revealing the transport process and influencing mechanism of soil water and salt in the active layer of the QTP and a more accurate prediction of soil physiochemical and hydrological properties for climate warming and wetting.

The role and mechanism of vascular wall cell ion channels in vascular fibrosis remodeling.

Fibrosis is usually the final pathological state of many chronic inflammatory diseases and may lead to organ malfunction. Excessive deposition of extracellular matrix (ECM) molecules is a characteristic of most fibrotic tissues. The blood vessel wall contains three layers of membrane structure, including the intima, which is composed of endothelial cells; the media, which is composed of smooth muscle cells; and the adventitia, which is formed by the interaction of connective tissue and fibroblasts. The occurrence and progression of vascular remodeling are closely associated with cardiovascular diseases, and vascular remodeling can alter the original structure and function of the blood vessel. Dysregulation of the composition of the extracellular matrix in blood vessels leads to the continuous advancement of vascular stiffening and fibrosis. Vascular fibrosis reaction leads to excessive deposition of the extracellular matrix in the vascular adventitia, reduces vessel compliance, and ultimately alters key aspects of vascular biomechanics. The pathogenesis of fibrosis in the vasculature and strategies for its reversal have become interesting and important challenges. Ion channels are widely expressed in the cardiovascular system; they regulate blood pressure, maintain cardiovascular function homeostasis, and play important roles in ion transport, cell differentiation, proliferation. In blood vessels, different types of ion channels in fibroblasts, smooth muscle cells and endothelial cells may be relevant mediators of the development of fibrosis in organs or tissues. This review discusses the known roles of ion channels in vascular fibrosis remodeling and discusses potential therapeutic targets for regulating remodeling and repair after vascular injury.

Theoretical precipitation modeling and multidimensional characterization of sulfide inclusions in tellurium-containing steels

This study investigates the precipitation characteristics of sulfide inclusions during the solidification of alloy steels under the combined influence of sulfur (S), manganese (Mn), and tellurium (Te). A multidimensional characterization and comparison of sulfide inclusions in Te-containing steels with varying sulfur content and cooling conditions were performed using X-ray Micro-CT, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM). Both 2D and 3D analyses confirmed that increasing the S content in Te-containing steels leads to a higher overall number of sulfide inclusions. In particular, the rise in the proportion of small-sized inclusions was analyzed from the perspectives of interfacial dynamics and equilibrium thermodynamics. Regarding inclusion morphology, 2D characterization exhibited significant inaccuracies in assessing large inclusions in high-S, Te-containing steels, while X-ray Micro-CT proved advantageous for evaluating both the spatial distribution and morphology of inclusions. In addition, X-ray Micro-CT was used for the first time in this study to perform a non-destructive analysis of the layered MnS-MnTe structure, expanding the method's application in the metallurgical field. A predictive model based on inter-element activity interaction coefficients was employed to determine the first-order activity interaction coefficient of Te for Mn. Furthermore, a thermodynamic model for sulfide precipitation in Te-containing steels was developed. This study lays a theoretical foundation for better control of sulfide inclusions in future Te-containing specialty steels.

Regulating the space charge at interface by negative polar biomolecule enabling ultrastable Zn anode chemistry

The irreversibility of Zn metal anode arising from uncontrollable dendrite growth and hydrogen evolution reaction, especially at high current densities, has challenged the commercialization application of aqueous Zn-ion batteries. Here we report biomolecule additive, named xanthan gum, to solve these issues through making use of dissociated electronegative groups to reduce space charge near the anode-electrolyte interface, tuning solvation structure and form H2O-poor electrical double layer to regulate the Zn deposition behaviors. Meanwhile, the dissolved xanthan gum with multiple polar groups can break the association between H2O and Zn2+ to reconstruct solvated structures of Zn ions to suppress hydrogen evolution reaction (HER). Therefore, the Zn//Zn symmetric cells in ZnSO4 electrolyte with xanthan gum deliver an ultra-long cycle life (>4700 h), and also present excellent cycling performances in other electrolytes (Zn(OAc)2 and Zn(OTf)2). More importantly, a high coulombic efficiency of 99.7 % is achieved using Zn//Cu half cells tested and excellent cycling life for KVO//Zn full cells. This work provides a guidance to design the electrolyte additive for highly reversible Zn metal batteries.

Numerical study on dynamic response characteristics of proton exchange membrane water electrolyzer under transient loading

Under dynamic operating conditions, the proton exchange membrane water electrolyzers are prone to voltage overshoot, resulting in fluctuations under transient operation. In this paper, a three-dimensional, two-phase, non-isothermal model is developed to investigate the role of various factors on the dynamic response characteristics of electrolyzers. The results demonstrate that the overshoot phenomenon can be significantly mitigated by using a linear loading strategy and a multi-step loading strategy compared to a step loading strategy. Meanwhile, the effect of the flow field structure was examined, revealing that single-serpentine flow field exhibited excellent dynamic response performance. Additionally, calculated through multiple evaluation methods, it was found that the effect of loading magnitude was significantly greater than that of the other factors, including temperature, flow field structure and anode porous transport layer porosity. Finally, under combined variable load conditions, research revealed that whereas single-serpentine flow field shown benefits regarding dynamic response and energy dissipation.

Opposite synaptic plasticity in oxidation-layer-controlled 2D materials-based memristors for mimicking heterosynaptic plasticity

Memristors with nonstoichiometric tungsten oxide (WOx) as an active layer, derived from the oxidation of atomically thin two-dimensional tungsten diselenide (WSe2), enable the creation of the monolithic layered structure of WOx/WSe2. These devices are promising candidates for emulating various biological synaptic functions in the human brain. In this study, we fabricate monolithic few-layer WOx/WSe2 memristors with precisely controlled WOx thickness by UV-ozone treatment from 1 L to 9 L, depending on chuck temperature. The postsynaptic responses of the topmost single-layer (1 L) oxidized WSe2 and fully (9 L) oxidized WSe2 memristors exhibit sharply contrasting behaviors, which can be applied to mimic the heterosynaptic plasticity in the CA1 region of the hippocampus. Beyond the significance of emulating the biological synaptic characteristics, we explore the feasibility of using each oxidation-layer-controlled memristor as a hardware accelerator. Their performances are assessed through application in a CIFAR-10 pattern recognition task using a convolutional neural network. Pattern recognition rates of 84 % and 71 % are obtained for the 1 L and 9 L WOx-based devices, respectively. We also examine the applicability of a synaptic cell composed of devices with oppositely switched characteristics. Consequently, the synaptic weight—defined as the difference in conductance between two synaptic devices—can be either increased (potentiated) or decreased (depressed) by simultaneously updating both devices with the same voltage signal. This weight update concept achieves a moderate recognition rate of 85.94 % when using an MNIST pattern-based recognition task, simplifying the complex weight-adjustment process.

Two novel 3D polyoxometalate-based metal–organic frameworks for structure-directed selective adsorption and photodegradation of organic dyes

Degradation of organic dyes from industrial wastewater is crucial for human health and ecological balance. Synergy adsorption and photodegradation is one of the effective methods to degrade organic dyes at present. The former is usually limited by the challenge of its the recovery and the poor adsorption capacity of the adsorbent, whereas the latter frequently suffers from sluggish reaction kinetics. Herein, the introduction of the unique electron-rich Keggin polyoxometalates (CuW12 and SiW12) into electron-deficient metal photosensitive viologen framework to construct two polyoxometalate(POM)-based metal organic frameworks (POMOFs) of 3D porous layered structures, namely [Cu2(ipbp)2(H2O)2][CuW12O40]·3H2O (1) and [Co2(H2ipbp)3(H2O)2(CoO6)2][SiW12O40]·H2O (2); (H2ipbp·Cl = 1-(3,5-dicarboxyphenyl)-4,4′-bipyridinium), which enable selective adsorption of methylene blue (MB) and effectively photocatalytic degradation cationic dyes. In addition, POMs and metal-organic frameworks act in synergy to result in much improved adsorption of certain cationic dyes as well as enhanced photocatalytic activity that allow the catalyst to show better excellent reusability and stability. The adsorption degradation rate of MB and rhodamine B (RhB) of 2 is faster than that of 1 because of the lower Zeta potential of 2 suggesting that there are electrostatic interactions in the adsorption process. This work adopted a novel view to comprehening the technology.

Preparation and Characterization of Waste Cotton Fabric Reinforced Polylactic Acid Green Composites with Multifunctional Properties in a Low-Carbon Process

The development and design of eco-friendly materials prove crucial for promoting the recycling of waste cotton textiles and reducing environmental pollution. In this study, waste cotton fabric (WCF) and polylactic acid (PLA) serve to produce cotton fabric-reinforced PLA composite material (CF/P). The CF/P is then integrated with traditional porous sound-absorbing materials to create a novel composite plate. This research highlights the potential of WCF reinforced plates for sound absorption and thermal insulation applications in the construction field of construction and reports the effects of variables such as hot pressing temperature, WCF mass fraction, and WCF layer alignment angle on the material properties. The optimum tensile strength, water absorption, and thermal conductivity of the prepared CF/P are 64.2 ± 1.8MPa, 1.98% ± 0.04%, and 0.03W/(m·K), respectively. By combining with porous sound-absorbing materials and modifying the layering structure of composite plates, its acoustic performance can be adjusted. The highest Sound Absorption Average (SAA) of plates with a multilayer composite structure is 0.67. Direct shaping through hot pressing diminishes the use of adhesives, thereby reducing costs and health hazards. This approach offers a practical and efficient solution for the recycling and repurposing of natural fibers.

Juncus effuses biochar-assisted preparation of oxygen vacancies-rich BiOCl for photocatalytic degradation of pollutants and CO2 reduction

BiOCl has attracted widespread attention due to its unique layered structure and excellent photocatalytic performance. However, the intense application of BiOCl is limited by its wide bandgap and high recombination of e-/h+ pairs. In this paper, juncus effuses biochar/BiOCl (BC/BiOCl) photocatalysts with tunable oxygen vacancies (OVs) were successfully constructed by adjusting the ratio of biochar (BC) to BiOCl using juncus effuses biochar as a carbon source. Addition of BC affects the crystal growth of BiOCl, constructing of OVs. The synergistic effect of BC and OVs improves the photogenerated charge pairs separation efficiency of the photocatalyst and promotes the production of reactive oxygen species (·OH, ·O2-). Under a 300W xenon lamp irradiation, the degradation rate constant of rhodamine B (RhB) and tetracycline hydrochloride (HCl-TC) on the 0.5% sample (mass ratio of BC/BiOCl is 0.5%) is 3.53 times and 3.20 times of that on the reference BiOCl, respectively. In addition, photocatalytic materials prepared also show excellent versatility. After a 300W xenon lamp irradiation for 4h, the average conversion of CO2 on the 0.5% sample is 2.47 times of that on the reference BiOCl. This work provides a feasible strategy for rationally regulating the level of OVs.

Study on mechanical properties of large deformation segmental cement-based honeycomb structure

Honeycomb structures provide a new means of controlling and supporting the tunnel envelope. However, traditional honeycomb structures have low strength and poor stability, and are prone to stress concentration and instability, further limiting their application in deep tunnel support projects. In this paper, a new type of segmental cementitious honeycomb structure is investigated, its performance under different loading rates is tested, and its application in deep large deformation tunnel support is discussed. Firstly, the honeycomb model was drawn and the honeycomb skeleton was prepared. Then, the cement suspension technique was optimised. Secondly, the effects of different loading rates on the performance of segmented cement-bonded honeycomb structures were investigated by laboratory experiments. The results show that when the loading rate is 3 mm/min, the structure has the maximum load capacity and the best energy absorption performance. It is worth noting that too fast or too slow loading rate will affect the performance of the structure. Finally, the damage mechanism of the segmented honeycomb structure was further investigated by using an acoustic emission system, and the acoustic emission characteristics showed that the segmented cementitious honeycomb structure firstly went through a relatively stable stage of microcrack development under the action of the loads in all bands, and then a large area of damage was observed in the top layer of the honeycomb skeleton when the peak load was reached, resulting in the collapse of the whole layer of the honeycomb structure, which led to the collapse of the whole layer of the honeycomb skeleton. This led to the collapse of the whole layer of the honeycomb structure and a significant decrease in the bearing capacity, which confirmed the layer-by-layer damage characteristics of segmental cementitious honeycomb structures. In addition, the RA-AF values show that the loading rate has little effect on the crack type, which is almost unchanged with the increase of loading rate. These studies verify the feasibility of using honeycomb structure to support roadway with fast deformation speed and large deformation. It is of great significance to guide the application of honeycomb structure in deep roadway support engineering.

Enhancing DF-GAN for Text-to-Image Synthesis: Improved Text-Encoding and Network Structure

Enhancing DF-GAN for Text-to-Image Synthesis: Improved Text-Encoding and Network Structure

Synergistic Effect Enables Aqueous Zinc‐Ion Batteries to Operate at High Temperatures

AbstractThe performance of aqueous zinc‐ion batteries (AZIBs) at high temperatures (HT) is severely compromised by active water corrosion, parasitic reactions, and dendrite growth. Herein, zinc trifluoroacetate is introduced at a low concentration (0.2 m), dissolved in triethyl phosphate (TEP)and H2O. The active water is suppressed due to the reconstructed original hydrogen bond network, which helps inhibit parasitic reactions and severe corrosion. Meanwhile, a solid electrolyte interphase (SEI) formed on the zinc anode due to the decomposition of the introduced zinc salt. The high‐tolerance SEI physically separates the electrolyte and anode, reducing the corrosion caused by active water. Moreover, TEP, as a prevalent fire‐retardant cosolvent, can preferentially anchor on the zinc sheet, serving as a shielding buffer layer. TEP is not only reconstructing the structure of the electric double layer (EDL), decreasing the content of active water, but also accelerating the prompt formation of SEI further. As proof of this synergistic effect, the assembled symmetric Zn.

Construction of Lamellar CoFe-LDHs@MoS2 to Promote Permonosulfate Properties Leading to Effective Photocatalytic Degradation of Norfloxacin

The utilization of the photo catalytic activation of permonosulfate (PMS) for the combined breakdown of pollutants has become a focal point in research. Layered double hydroxides (LDHs) have a unique layered structure which is conducive to the adsorption and diffusion of reactants, and can provide more active sites for photocatalytic reactions. The anions between the layers can be exchanged with a variety of substances so that specific catalytically active species can be introduced as needed. LDHs themselves have certain catalytic activity, which can produce synergistic catalysis between LDHs and the supported photocatalytic active substances, and further improve the degradation effect of antibiotics. In actual wastewater treatment, LDHs as a catalyst carrier have a good application prospect. However, the poor activation effect is attributed to the low separation efficiency of catalyst carriers and insufficient active sites. In this study, a dual active site system consisting of Co and Fe, known as CoFe-LDHs@MoS2, was developed as a catalyst to facilitate the synergistic degradation of norfloxacin (NOF) by PMS under visible light. The findings demonstrate that the material possesses an effective capacity for the synergistic degradation of NOF. A comprehensive investigation was conducted to assess the impact of different catalysts, PMS dosage, degradation systems (Vis, PMS, or Vis PMS), catalyst dosage, NOF concentration, pH, and cycle times on the degradation performance. The active free radicals, degradation pathways, and intermediate toxicity were elucidated through capture experiments, Electron Paramagnetic Resonance Spectrometer (ESR) analysis, a liquid mass spectrometry (LC-MS) toxicity assessment, and theoretical calculations. This research offers a novel approach for designing catalysts with exposed high activity sites for the effective removal of NOF from environmental water.

Advances in constructing Carbon Fiber‐MXene multilevel structures to reinforce interfacial properties of carbon fiber reinforced polymer composites

AbstractCarbon fiber reinforced polymers (CFRPs) have received widespread attention due to their excellent mechanical properties. However, the poor interfacial properties between CF and resin matrix urgently need feasible and efficient surface modification strategies of CF to regulate the interface. Due to its unique layered structure and abundant surface groups, MXene has been increasingly used in the field of CFRP interfacial modification in recent years. It possesses the advantages of good stability, large specific surface area, abundant adsorption sites and rich functional groups, which could effectively improve surface polarity, roughness and wettability of carbon fibers, thus enhancing effective interfacial bonding and enabling hierarchical regulation of interface in CFRPs. This paper reviews feasible strategies for constructing CF‐MXene multilevel structures, including electrophoretic deposition, chemical grafting, electrostatic self‐assembly, and sizing coating. Then, the strengthening mechanism involving surface morphology, mechanical properties, and interfacial strength of CFRPs are systematically evaluated centered on interfacial activity, interfacial adhesion, surface roughness and surface energy. Meanwhile, the problems in introducing MXene to CF surfaces and future research directions are systematically prospected. This paper could provide valuable guidance to construct CF‐MXene multilevel structures to reinforce interfacial properties of CFRPs composites, thus realizing hierarchical modulation of CFRPs interfaces.Highlights A feasible strategy for constructing CF‐MXene multilevel structures is built. The main methods for constructing CF‐MXene multilevel structures are provided. Treatment processes and reinforcing mechanisms of CFRPs are evaluated.

Ultracompact Electrical Double Layers at TiO2(110) Electrified Interfaces.

Metal-oxide aqueous interfaces are important in areas as varied as photocatalysis and mineral reforming. Crucial to the chemistry at these interfaces is the structure of the electrical double layer formed when anions or cations compensate for the charge arising from adsorbed H+ or OH-. This has proven extremely challenging to determine at the atomic level. In this work, we use a surface science approach, involving atomic level characterization, to determine the structure of pH-dependent model electrified interfaces of TiO2(110) with HCl and NaOH using surface X-ray diffraction (SXRD). A comparison with ab initio molecular dynamics calculations reveals the formation of surprisingly compact double layers. These involve inner-sphere bound Cl and Na ions, with respectively H+ and O-/OH- in the contact layer. Their exceptionally high electric fields will play a key role in determining the chemical reactivity.

Friction drag model for axial turbulent flow along the surface of a circular cylinder based on the universal characteristics of wall turbulence

The friction drag of the axial flow along the outer surface of a cylinder varies with the cylinder radius and flow conditions. This study included direct numerical simulations of the axial turbulent flow along a circular cylinder under different conditions for obtaining the turbulence statistics and wall friction coefficient. Then the characteristics of velocity streaks were observed from a geometrical perspective of turbulence structures around the circular cylinder, and compared with the characteristics of the turbulence structures in a boundary layer on a flat plate. The results showed that the velocity streak spacing and the distance between the velocity streak and the cylinder surface in the viscous length scale do not vary substantively with the radius of the cylinder, and are the same as those of the turbulent flow along a flat plate. Therefore, they can be considered geometrical characteristics of the turbulence structure independent of the cylinder radius. Moreover, the friction coefficient per pair of high- and low-speed velocity streaks is the same as that of flat-plate turbulent flow, independent of the cylinder radius, and can be regarded as a dynamical characteristic for a pair of velocity streaks. Two equations were derived based on the characteristics of wall turbulence. The characteristics of the turbulence predicted by the two formulae were consistent with the simulation results. Consequently, we showed that the wall friction coefficient and number of the velocity streak pairs, which are statistical and structural characteristics of wall turbulence, can be predicted appropriately by specifying the radius Reynolds number.

Large deformation induced deflection analysis of debonded layer structure under hygro-thermo-mechanical loading: a micromechanical FE approach

Large deformation induced deflection analysis of debonded layer structure under hygro-thermo-mechanical loading: a micromechanical FE approach

High-Performance Flexible and Symmetric Supercapacitors Based on Micro-Flower-Like MnSe@Ti3C2Tx Heterostructure.

Flexible supercapacitors, renowned for their exceptional power density and cycling stability, are a focus in the field of energy storage. Ti3C2Tx MXene is a promising electrode material for supercapacitors owing to its excellent metallic conductivity. However, its stacking layered structure limits device performance on specific capacitance, operating voltage, and energy density. Herein, a MnSe@Ti3C2Tx heterostructure is developed to enhance the electrochemical performance of Ti3C2Tx-based electrode materials. With the solvothermal synthesis method, MnSe nanosheets are in situ grown on Ti3C2Tx surface to form micro-flower-like MnSe@Ti3C2Tx heterostructures by adjusting the ratio of ethanolamine solvent and the amount of Ti3C2Tx. The specific capacitance of the optimized heterostructure (E3/MnSe@Ti3C2Tx-45) is as high as 721.4Fg-1 at 1Ag-1, approximately ten times higher than that of pure Ti3C2Tx. The MnSe@Ti3C2Tx flexible symmetric supercapacitor (MT-FSC) based on E3/MnSe@Ti3C2Tx-45 exhibits a wide working voltage window of 1.2V and a large energy density of 28.68Whkg-1 at 308.23Wkg-1. The capacitance retention rate keeps 90.77% after 4000 charge-discharge cycles. Furthermore, MT-FSC can power LEDs even under large-angle (90°) bending. This heterostructure electrode material not only improves the electrochemical performance of Ti3C2Tx-based flexible supercapacitors but also offers a robust energy supply for flexible wearable electronic devices.