Gravel Layer Research Articles

Performance of vertical flow wetland in the treatment of medium organic strength synthetic wastewater

Treatment wetlands have been used for decades to treat wastewaters with low organic strength, but little information is available on the treatment of wastewaters with high organic strength. The objective of this study was to evaluate the efficiency of a vertical flow wetland in the primary treatment of synthetic wastewater with medium organic strength (1976 mg COD/L). Alternatives in the reuse of the resulting treated wastewater were also considered. The wetland consisted of several layers of sand and gravel of different granulometry and was planted with the helophyte Eryngium horridum, a species rarely used in treatment wetlands. The wetland was fed with synthetic wastewater by a single feed pulse, with a hydraulic retention time of 24 h. The treatment removed 81% of TSS and 70% of COD. The concentrations of ammonium nitrogen and soluble reactive phosphorus increased due to partial mineralization of organic matter. Total phosphorus and total nitrogen removal were 28% and 5%, respectively. Wastewater suitability for reuse in irrigation increased after treatment. However, a later stage is recommended to further reduce COD and nutrient concentration and disinfect the water.

Large-Scale Triaxial Test on Mechanical Behavior of Coral Sand Gravel Layered Samples

Layered structures comprising coral sand and gravel have been observed in hydraulic filled foundations in the coral reefs in the South China Sea, leading to anisotropy in their physical and mechanical properties. However, the effect of a layered structure on the strength and deformation of the coral soil foundation remains unclear. In this study, a series of large-scale triaxial compression tests and step-loading tests were carried out on four types of samples, i.e., clean coral sand, clean coral gravel, sand-over-gravel layered sample, and gravel-over-sand layered sample, to investigate the impact of confining pressure and the layered structure on the strength and failure modes of these soils. The results indicate that the stress–strain relationships of all samples predominantly exhibit strain hardening under drained conditions. Under identical confining pressures, the peak strength of clean coral sand is the lowest, while that of coral gravel is the highest. The peak strengths of the two layered samples fall between these extremes, with the gravel-over-sand layered sample exhibiting higher strength. All four samples have similar peak friction angles, slightly exceeding 40°. The difference in peak strength among the four types of samples is attributed to the variations in cohesion, with the cohesion of clean coral gravel being up to four times that of clean sand, and the cohesion of layered samples falling between these two. Both clean sand and clean gravel samples exhibit a bulging phenomenon in the middle, while the layered samples primarily exhibit bulging near the coral gravel layer. In the step-loading tests, the bearing capacity of the layered samples falls between those of clean coral sand and coral gravel, with the gravel-over-sand layered samples demonstrating higher strength. Moreover, the p-s curve of the gravel-over-sand layered samples obtained from the large-scale triaxial apparatus under a confining pressure of 400 kPa resembles that from the plate load tests on the same samples.

Modeling the influences of rainfall conditions on nitrogen removal effects of a permeable pavement system

Permeable pavement systems are important facilities for alleviating runoff pollution. However, few studies have focused on outflow nitrogen processes under varying rainfall conditions. In this study, we proposed a permeable pavement system model that can simulate the nitrogen transformation processes. The model was verified with data on outflow rates and outflow nitrogen concentrations (ammonia nitrogen (NH4-N), nitrate nitrogen (NO3-N), and total nitrogen (TN)) processes for six consecutive rainfall events of a permeable pavement system in Shenzhen, China. Based on the validated model, scenarios were designed to simulate the influences of rainfall conditions on nitrogen removal effects at the single rainfall event and annual scale, respectively. The results indicate that: (i) the model can explicitly describe hydrological and nitrogen processes of the system, and the Nash Sutcliffe Efficiency and percent bias of outflow rates and outflow nitrogen concentrations range from 0.5 to 0.9 and from −22.4% to 24.9%, respectively; (ii) the sensitivity analysis reveals that the empirical coefficient (C) related to evaporation in the gravel layer is sensitive at the annual scale but not at rainfall events scale. Parameters related to mineralization and microbial assimilation (i.e., mineralization rate constant in the gravel layer (k3N,mine), microbial assimilation rate constant of NH4-N, NO3-N, and ON (k1N,bio, k2N,bio, k3N,bio)) are sensitive annually but not at rainfall events scale; (iii) in the single rainfall event simulations, nitrogen removal efficiencies decrease with increasing rainfall return periods but is not significantly affected by rainfall peak coefficients. Nitrogen removal efficiencies improve notably with antecedent dry period extension for single rainfall event with antecedent dry period less than 2 days. In addition, we found that the outflow process significantly affects the outflow nitrogen concentrations process. In annual-scale simulations, extending the antecedent dry period only significantly boosts runoff reduction efficiency and nitrogen removal efficiencies for rainfall events with less than 10 mm.

Performance of loach to reduce clogging matter in vertical-flow constructed wetlands: Hydraulic evaluation and metabolic processes

Extracellular polymeric substances (EPS) secreted by microorganisms cause constructed wetlands (CWs) clogging, which is a major challenge for the long-term stable operation of CWs. This study provided a comprehensive and in-depth study of the hydraulic evaluation and metabolic processes of loach (Misgurnus anguillicaudatus) in mitigating clogging. The results showed that the loach reduced the clogging content in the substrate layer and improved the hydraulic performance of the system. The loach system increased the initial porosity in the sand layer by 11.52 %, 25.11 %, and 28.15 %, and the initial porosity in the gravel layer by 15.49 %, 15.85 %, and 13.83 %, respectively. Loach also increased the actual and theoretical hydraulic retention time (HRT), improved the connectivity between different layers, and reduced the “dead zone” area of the system. The analysis of EPS components revealed that the daily EPS removal amount of each loach was 36.64 mg L-1, in which S-EPS, LB-EPS, and TB-EPS were 21.80, 8.02, and 6.82 mg L-1d-1, respectively. Direct feeding and the indirect coordination with microorganisms effectively reduced the contents of polysaccharides and proteins in EPS, and increased the proportion of humic acid and nucleic acid. The clogging characteristics analysis also confirmed that loach decreased tyrosine and tryptophan fluorophores groups and reduced the proportion of protein or peptide substances in the macromolecules in EPS. In addition, loach increased the activities of dehydrogenase, fluorescein diacetate, and the relative abundance of Chlorobiaceae in the sand layer, which was conducive to the hydrolysis of clogging matters with the metabolic activity of microorganisms. Loach increased the relative abundance of denitrifying microorganisms such as Aeromonadaceae, Rhodocyclaceae, and Hydrogenophilaceae in the gravel layer, which enhanced the denitrification process of the system and was conducive to pollutant transformation and clogging matter degradation. In conclusion, this study proposes a novel, eco-friendly strategy for preventing CW clogging in wetland animals.

Modeling the clogging process of leachate collection systems in municipal solid waste landfills: The role of temperature

The leachate collection system (LCS) is an important component of barrier systems in municipal solid waste (MSW) landfills. LCS Failure due to clogging could lead to leachate accumulation, potential soil and groundwater pollution and slope failure. LCS clogging is generally ascribed to particle deposition, biofilm growth, and calcium carbonate precipitation, while temperature strongly influences microbial activity and thus inevitably affects the clogging process of LCSs. However, the role of temperature in the process of clogging and leachate accumulation in LCSs remains unclear. The main objective of this study was to bridge this research gap by developing reasonable mathematical models and comprehensively analyzing this issue. The mathematical model involved leachate flow, solute migration, physical–chemical-biological clogging, and heat transfer processes. By conducting a series of numerical simulations, the temperature variation, clogging development, and corresponding leachate accumulation inside the system during long-term operation in both the geotextile and gravel layers were numerically analyzed and predicted. The results demonstrated that, in the gravel layer, due to the higher temperature, more thorough microbial substrate consumption led to higher production of carbonate ions and hence faster and more notable calcium carbonate precipitation. Overall, the bioactivity changes due to high temperatures could considerably accelerate the failure of LCS.

Experimental evaluation on in-soil water migration reducing performance of restraining moisture geotextile (RMG)

Engineering materials such as geosynthetics clay liners (GCL) and gravel layers are effective to cut off the in-soil water migration and have been widely employed to stabilize the moisture content of subgrades. However, the moisture stabilizing performance of GCL or gravel layer is usually compromised due to the complexity of service condition. This paper introduces an engineering material named restraining moisture geotextiles (RMG), which is expected to show low permeability as GCL. With characterization of basic properties of RMG, moisture migration column test of silty soil and test cases with employments of RMG, GCL, and gravel layer are performed, respectively. The temperature and moisture fields of soil columns subjected to a freezing-thawing process are measured, and the capillarity and in-soil water migrating behavior are analyzed. Carbon footprints of GCL and RMG are compared and discussed. Test results show that RMG, GCL and gravel layer are effective to cut off the capillarity, but the gravel layer can result in higher moisture content in silty soil due to the vapor migration and capillary isolation. In conclusion, RMG can be an alternative method with low permeability on reducing the in-soil water migration, and is much lighter and more engery-efficient than GCL.

Construction Technology and Service Performance of Waterproof Curtain for Foundation Pit in Large-Particle Pebble Gravel Layer of Yangtze River Floodplain

A foundation pit is constructed in the floodplain of Yangtze River, and a deep and thick layer of large-particle pebble gravel exists below the base slab, thus forming a connected supply channel with the adjacent Yangtze River. The large water volume, high water pressure, and strong permeability of this layer bring great risks to the foundation pit construction. In view of the fact that conventional waterproof curtain construction technologies such as the deep mixing column and high-pressure jet grouting column cannot meet the engineering requirements under these kinds of geological and environmental conditions, a new waterproof curtain construction technology that combines the trenching technology of the diaphragm wall with the TRD (Trench cutting Remixing Deep wall) technology is proposed, i.e., the trenching-and-replacing-style TRD technology, as well as the construction process of this technology, is presented. After the waterproof curtain is built using the proposed technology, the strength, integrity, uniformity, and service performance of the waterproof curtain wall are tested and evaluated by the comprehensive methods of coring, borehole television imaging, resistivity CT, and a group well pumping test. The results show that the proposed technology overcomes the adverse effects of underlying large-particle pebble gravel layer, and the waterproof curtain built by it effectively cuts off the hydraulic connection inside and outside the pit. The technical proposal can provide useful references for similar projects.

Sedimentary characteristics and model of Cambrian storm in Xuzhou area

The storm deposition types within the Dabeiwang area of Xuzhou City, Jiangsu Province, China, showcase a wide range of diversity and distinctly apparent characteristics. Based on measured sections and thin-section observations, we have studied the typical characteristics of storm deposition in this area, divided the sedimentary sequence, and summarized a comprehensive model of storm deposition. Various rock types such as thick-bedded dolomitic limestone, oolitic limestone, and calcirudite are developed in the study area. The calcirudite exhibits bamboo leaf-like morphology and various distribution forms. Typical storm sedimentary structures such as scour surfaces and mound cross-bedding were identified in the study area. Based on the distance of the gravel layer from the storm center and the depositional environment, the storm sedimentary sequence in the study area can be divided into allopatric-proximal-lagoon facies storm deposit, allopatric-distal-oolitic shoal facies storm deposit, autochthonous-supratidal facies storm deposit, allopatric-distal-interbeach marine storm deposit, sub-allopatric-tide zone facies storm deposit, and autochthonous-tide zone facies storm deposit. We summarize the comprehensive model of Cambrian storm deposition in the Dabeiwang area of Xuzhou, which has enriched the research results of Cambrian storm deposition in Xuzhou and provides support for the construction of a lithofacies paleogeographic pattern.

2D model of groundwater flow and total dissolved HCH transport through the Gállego alluvial aquifer downstream the Sardas landfill (Huesca, Spain)

The organic pollutants disposed at the Sardas landfill in Sabiñánigo (Huesca, northeastern Spain) by the INQUINOSA lindane factory have reached the Gállego alluvial aquifer and could affect the Sabiñánigo reservoir. The daily oscillations of the reservoir water level produce a tidal effect on the piezometric heads of the aquifer. These oscillations are transmitted in a damped way with a time lag, thus attesting that the silting sediments of the reservoir and the natural silts of the Gállego alluvial are interposed between the reservoir water and the layer of sands and gravels. A 2D finite element groundwater flow and total dissolved hexachlorocyclohexane (HCH) transport model through the Gállego alluvial aquifer is presented here. The flow model was constructed to: (1) Quantify the tidal effect, produced by the daily fluctuations of the reservoir water level on the aquifer; (2) Estimate the hydrodynamic parameters of the layer of sands and gravels; and 3) Estimate the vertical hydraulic conductivity of the silting sediments and silts; and (4) Quantify aquifer/reservoir interactions. The flow model reproduces the dynamics of the tidal effect and attests that groundwater velocity and flow direction changes daily in response to the oscillations of the reservoir level. Model results reproduce the measured well hydrographs and the Darcy velocity derived from tracer tests and confirm the validity of the conceptual model. The transport model of total dissolved HCH simulates the time evolution of the contaminant plume. The computed concentrations of total dissolved HCH and the contaminant mass outflux are very sensitive to changes in the source terms and the distribution coefficient, Kd of HCH. The best fit to the measured HCH plumes in September 2010 and December 2020 is obtained with a Kd ranging from 1 to 3 L/kg. The computed flux of dissolved HCH leaving the Sardas site in 2020 towards the Sabiñánigo reservoir ranges from 0.6 kg/year for Kd = 3 L/kg to 3.1 kg/year for Kd = 1 L/kg. The findings of this study will be most useful for planning and designing remedial and containment actions at the Sardas site and other similar lindane-affected sites.

Orbital global change drove fluvial aggradation and incision in Tibetan upper Mekong river: Chronological perspectives

The Tibetan Plateau (TP), often known as the “Asia Water Tower”, is the source region of several continental-scale rivers. However, due to the extremely difficult access and harsh living conditions in the interior plateau, fluvial processes in the headwaters of these large rivers and their connections to global climate changes remain unknown. In this study, the luminescence (using both quartz and K-feldspar) and AMS 14C dating techniques were employed to date the four terraces of the Zado Basin in order to elucidate the aggradation and incision history of the initial intermontane basin in the headwater of the Mekong River. One sample from the upper part of T4 terrace (which features a 12 m thick gravel layer, the base of which is unexposed) provides a K-feldspar pIR50IR225 age of 125 ± 10 ka, indicating that the initial deposition of this terrace could predate marine isotope stage (MIS) 5. Considering the margin of error, this age also suggests that the onset of incision on T4 terrace during the climate transition from MIS 6 (glacial) to early MIS 5 (interglacial). This incision likely occurred due to increased meltwater and precipitation, causing the Mekong carving into the bedrock for more than 50 m. Eight luminescence samples are collected from T3 terrace (26.5 m in thickness) with ages ranging from 83 ± 7.6 ka to 22.3 ± 1 0.2 ka, indicating T3 formation/aggradation from late MIS 5 to the Last Glacial Maximum (LGM), possibly owing to reduced precipitation and enhanced sediment supply from intensive glacial activities. At around 22 ka, the Mekong once again shifted towards incision, crafting the T3 terrace, situated roughly 28 m above the current floodplain. This incision event was recorded by two luminescence samples from a sandy lens located at the top of gravel layer of T3, with OSL ages of about 22 ka. Floodplain samples from T2 and T1, dated at 16 ka and 2.8 ka respectively, demonstrate that from the last deglaciation to the Holocene, the Mekong continued its downward incision. This erosion developed two cut and fill terraces at elevations of 22 m and 11 m above the present floodplain, likely due to increased precipitation and enhanced vegetation at that time. Overall, the glacial–interglacial climate changes were the most likely driving force behind fluvial processes in the upper Mekong basin since the Late Pleistocene, with aggradation occurring during the glacial period while incision in deglacial and interglacial periods, suggesting a close link between the fluvial geomorphic evolution and orbital-scale climate changes.

Turbulent flow characteristics over rough permeable and impermeable gravel-bed stream- an experimental study

Abstract The study aims to presents flow heterogeneity over rough permeable and impermeable gravel-bed stream. The rough permeable stream is prepared by laying multiple layers of gravel, whereas its impermeable counterpart is presented by a resin-casted gravel-bed. In general, a common approach can be found in literature to mimic an impermeable bed by laying single layer of gravels, therefore some results are compared with single layer gravel-bed stream keeping the hydraulic conditions same. An acoustic Doppler velocimeter was used for flow measurements whereas; double averaging (DA) methodology was adopted for data analysis. The larger flow penetration depth and intense flow mixing in permeable gravel-bed infer sufficient impetus for organized flow turbulence and damping of DA Reynolds shear stresses whereas; the wall-blocking in resin-casted gravel-bed prevents fluid infiltration which leads to follow the linear stress profile away from the crest level. The damping of DA Reynolds shear stress (RSS) is compensated by enhanced DA form-induced shear stress (FISS). The results are further analysed under the light of the energy budget to characterize the mass-momentum exchange as it penetrates the subsurface layers. The energy budget indicates negative pressure energy diffusion rates corroborating gain in turbulence production in the permeable gravel-bed stream.

Appraisal of lacustrine aquifer’s groundwater potentiality and its hydrogeological modelling in southeastern Peshawar, Pakistan: implications for environmental geology, and geotechnical engineering

The Peshawar Basin is a part of the lower Himalayas that contains an enormous amount of groundwater storage. The evaluation of groundwater potential in the southern Peshawar district was done using well logging, lithostratigraphic properties, and combined hydrogeological and geophysical techniques. A total of 13 Vertical Electrical Sounding (VES) profiles were utilised to assess potential groundwater zones for surface resistivity studies. The aquifer system was delineated by comparing the data from five boreholes with the VES findings. An exploration of super-saturated groundwater potential was conducted, utilising parameters such as transmissivity (T), hydraulic conductivity (K), storativity, and the Dar Zarrouk analysis. The Dar Zarrouk analysis yielded average values of transverse resistance (TR), longitudinal conductance (S), and anisotropy (λ), which were determined to be 8069.12, 0.51, and 0.561, respectively. Similarly, average values of transmissivity (T), hydraulic conductivity (K), and storativity were obtained, resulting in 28.67, 0.24, and 0.000177, respectively. The saturated confined layer, characterized by highly saturated zones, was identified to begin at a depth of approximately 119 m and extend down to the lower boundary of the aquifer. The examined aquifer is composed of clay, sand, gravel, boulders, and loose layers of lacustrine mud that are interlayered to form an unconsolidated groundwater aquifer system. The aquifers in the region are highly developed and consisted of unconfined, semi-confined, and confined aquifer systems. As a result, it is possible to use the aquifer for groundwater development in the study area because of its low -to-medium discharge.

Prediction of ground surface settlements by analytical and finite element methods

The soil surrounding the excavation of shallow tunnels may experience destructive deformation near the tunnels. Particularly in densely populated areas where land resources are scarce, ground subsidence caused by tunnel excavation, which in turn affects surrounding structures, deserves more attention. Over the past few decades, various research methods for predicting the maximum vertical ground surface settlement have been proposed. In this study, an empirical estimation method, an analytical technique for evaluating ground movements, and a numerical simulation method using Plaxis 2D, a finite element model software, were selected as prediction approaches for ground surface settlements. Subsidence measurements were obtained from a metro tunnel excavated using an earth pressure balance shield tunnel boring machine and constructed in a dense sandy gravel layer. Comparison of the monitored deformations with the estimation results calculated by different prediction approaches showed that the maximum vertical settlement of the ground surface evaluated by the analytical technique and finite element model agreed well with the actual measured values. This suggests that these two prediction methods have the potential for conserving nearby structures during the construction of underground infrastructures.

Unveiling Subsurface Characteristics of Cliff Land in Sibang, Bali Through Geoelectric Investigation

The unique geological formations and environmental dynamics of cliffs underscore the significance of comprehending soil composition and structural integrity for diverse applications, such as infrastructure development and environmental conservation. Geoelectrical needs to be done because the underground geological conditions of the cliff must be researched and assessed first before construction is carried out so that construction failure does not occur. This research aims to reveal the subsurface characteristics of cliff soil in Sibang, Bali through geoelectrical investigation. This research was conducted by evaluating the soil condition in the field using the geoelectric resistivity method to the ability of a material to inhibit the flow of electric current and geological regional theories. At points BL-01 and BL-04, there is a significant potential risk of landslides due to the thick layer of breccia, especially during high rainfall or additional loads in the area. Point BL-02 also has a potential risk of landslides due to the thick layer of basalt and wet sand. Meanwhile, points BL-03 and BL-05 are more ideal locations for construction because they consist of relatively stable hard rock. Point BL-06 outside the development zone has layers of gravel, weathered tuffa and andesite which could be considered for future development. Thus, a deep understanding of the geological characteristics of each point is important to manage risks and ensure the safety and sustainability of construction projects in that area.

Porewater microbiomes in buried wetland soils: Synergic effects of water chemistry and redox gradients associated with hydrological processes

Abstract Interstitial water or pore water occupies the space between soil particles and provides “hotspots” and “fluvial networks” for microbial activities in floodplain soil. However, to date, we know very little about the microorganisms living in pore water and how they respond to environmental changes. This study aimed to understand microbial distribution and assemblage in riparian pore waters, and how they respond to water chemistry and redox gradients associated with hydrological processes. We analysed the annual changes of porewater microbial communities from the east and west banks of the White Clay Creek, a site at the Christina River Basin – Critical Zone Observatory, Pennsylvania, USA. Microbial abundances were quantified by epifluorescence microscopy and detailed community structures were characterised by high‐throughput sequencing. Water chemistry and redox gradients were also monitored and recorded, and their interactions with porewater microbiomes were analysed using correlations and multivariate analyses. Abundance of microbial cells increased during summer and late autumn. Wetland porewater microbiomes mainly contained Acidobacteria, Bacteroidetes, Nitrospirae and Proteobacteria, and microbiome structures were easily distinguishable from those in the underlying hyporheic gravel layer. Seasonal dynamics of bacterial community structure in the east and west wetlands were distinct, responding to floodplain topography and associated hydrological/geochemical processes. Iron (Fe)‐cycling bacteria (mainly Gallionellaceae and Rhodoferax spp.) dominated the porewater microbiome, and their relative abundance was significantly higher in the east than the west wetland. Furthermore, Fe‐oxidising bacteria (Gallionellaceae) were negatively correlated with Fe‐reducing bacteria (Rhodoferax spp.) at the east wetland. Microbial abundances (cell density) in pore waters showed similar seasonal patterns across stream banks, but microbial community structure did not. Microbiome assembly in pore water is correlated with water chemistry and redox gradients primarily associated with local hydrological processes. As a consequence of their significance for carbon (C) mineralisation and Fe reduction at terrestrial–aquatic interfaces, microbiomes in riparian pore waters and associated microbial activity play an essential role in C and mineral dynamics. These findings will inform future studies of the response of freshwater ecosystems to hydrological dynamics influenced by global climate change.

Post-glacial small delta process uncovered by luminescence and radiocarbon chronology of core sediments from coastal South China Sea

Reliable chronology is crucial for reconstructing delta processes. The past decades witnessed a boost of dating works on the most economically influential large deltas (i.e., subaerial area >1000 km2), but chronology remains lacking on many small deltas (i.e., subaerial area <1000 km2) that are also densely populated and economically active. Luohe River Delta (LRD) in the coastal South China Sea is such a small delta, whose evolution concerns hundreds of thousands of people, and literally no reliable dating results have been reported to support research of its processes. Herein, dating work combining radiocarbon (14C) on mollusk shells and quartz Optically Stimulated Luminescence (OSL) methods were performed on core LFZK06 from LRD, to test applicability of both methods by age comparison and to establish a chronological framework, using Bayesian age-depth models, of LRD for the first time. 14C ages are systematically c. 0.5–1 ka younger than OSL ages from the same depths. Such young bias of 14C ages in LRD contrasts with previously observed overestimated 14C results in the nearby Pearl River Delta (PRD), likely due to the distinction in bedrock types between Luohe River (granites and sandstones only) and Pearl River (limestone prevalence causing hardwater effect) drainages. Ages of core LFZK06 span from 57 ± 7 ka to 3.42 ± 0.05 cal ka BP and contain a hiatus between 57±7–11.9 ± 1.7 ka. Holocene deltaic sequence of the core shows three-stage sedimentary processes: (1) rapid deposition of prodelta/delta front sediments at 10.2‐0.4+0.5 ka–7.7‐0.3+0.4 ka related to rapid sea level rise, (2) hiatus during 7.7‐0.3+0.4 ka–5.7‐0.8+0.5 ka likely due to reduced sediments input or river channel migration, (3) rapid accumulation of delta plain sediments during 5.7‐0.8+0.5 ka–3.42‐0.85+0.42 ka reflecting depocenter shift toward core location. Moreover, changes of quartz OSL sensitivity were detected, indicative of sediment provenance transition. A change in sediment source from nearby granite weathering towards fluvial long-transported materials occurred at a depth of 24.7 m, with low quartz OSL sensitivity in the gravelly layer below (11.9 ± 1.7 ka) and one magnitude higher quartz OSL sensitivity in prodelta deposits above (10.2‐0.4+0.5 ka).

The Removal of As(III) Using a Natural Laterite Fixed-Bed Column Intercalated with Activated Carbon: Solving the Clogging Problem to Achieve Better Performance

Natural laterite fixed-bed columns intercalated with two types of layers (inert materials, such as fine sand and gravel, and adsorbent materials, such as activated carbon prepared from Balanites aegyptiaca (BA-AC)) were used for As(III) removal from an aqueous solution. Investigations were carried out to solve the problem of column clogging, which appears during the percolation of water through a natural laterite fixed-bed column. Experimental tests were conducted to evaluate the hydraulic conductivities of several fixed-bed column configurations and the effects of various parameters, such as the grain size, bed height, and initial As(III) concentration. The permeability data show that, among the different types of fixed-bed columns investigated, the one filled with repeating layers of laterite and activated carbon is more suitable for As(III) adsorption, in terms of performance and cost, than the others (i.e., non-intercalated laterite; non-intercalated activated carbon, repeating layers of laterite and fine sand; and repeating layers of laterite and gravel). A study was carried out to determine the most efficient column using breakthrough curves. The breakthrough increased from 15 to 85 h with an increase in the bed height from 20 to 40 cm and decreased from 247 to 32 h with an increase in the initial As(III) concentration from 0.5 to 2 mg/L. The Bohart–Adams model results show that increasing the bed height induced a decrease in the kAB and N0 values. The critical bed depths determined using the bed depth service time (BDST) model for As(III) removal were 15.23 and 7.98 cm for 1 and 20% breakthroughs, respectively. The results show that the new low-cost adsorptive porous system based on laterite layers with alternating BA-AC layers can be used for the treatment of arsenic-contaminated water.

Enhancing pollutant removal efficiency in urban domestic wastewater treatment through the hybrid multi-soil-layering (MSL) system: A case study in Morocco.

This paper evaluates the performance and potential of a full-scale hybrid multi-soil-layering (MSL) system for the treatment of domestic wastewater for landscape irrigation reuse. The system integrates a solar septic tank and sequential vertical flow MSL and horizontal flow MSL components with alternating layers of gravel and soil-based material. It operates at a hydraulic loading rate of 250 L/m2/day. Results show significant removal of pollutants and pathogens, including total suspended solids (TSS) (97%), chemical oxygen demand (COD) (88.57%), total phosphorus (TP) (79.93%), and total nitrogen (TN) (88.49%), along with significant reductions in fecal bacteria indicators (4.21 log for fecal coliforms and 3.90 log for fecal streptococci) and the pathogen Staphylococcus sp. (2.43 log). The principal component analysis confirms the effectiveness of the system in reducing the concentrations of NH4, COD, TP, PO4, fecal coliforms, fecal streptococci, and fecal staphylococci, thus supporting the reliability of the study. This work highlights the promising potential of the hybrid MSL technology for the treatment of domestic wastewater, especially in arid regions such as North Africa and the Middle East, to support efforts to protect the environment and facilitate the reuse of wastewater for landscape irrigation and agriculture.

Sedimentary Characteristics, Ages, and Environmental Significance of Gravel Deposits and Loess in Shandong, Eastern China: Regional Response to Global Change Since the Last Glacial Period

AbstractInvestigation of rarely studied gravel layers found in the loess in Shandong Province, eastern China, reveals the fabric characteristics of two gravel layers (G1, G2) and the sedimentary characteristics of loess at the typical and well‐preserved Heiyu section (HY), where, to determine the paleoclimatic changes during Marine Isotope Stage 3a. Optically stimulated luminescence dates of the HY formation range from 0.26 ± 0.02 ka to 39.00 ± 2.00 ka. In addition, the ages of G1 and G2 were estimated using the Bayesian model to be 39.60–40.50 and 29.00–29.50 ka. G1 and G2 are mainly composed of fine and medium gravel, both of which were subangular to subrounded limestone, with gravel directions to NE and E. The average flow velocity, average depth, and flood peak flow of G1 are 1.10 m/s, 0.49 m, and 37.04 m3/s, respectively, calculated using the flow energy method, whereas those of G2 are 0.98 m/s, 0.38 m, and 18.38 m3/s, respectively. Analysis of climate proxy indices show that the sedimentary environment of the gravel and loess in HY might be a regional response to global change.

Improving household water treatment: using zeolite to remove lead, fluoride and arsenic following optimized turbidity reduction in slow sand filtration

Despite the United Nations 2030 agenda, large number of both urban and rural dwellers in low-income countries continue to lack access to improved water. Thus, increased effort is required towards enhancing low-cost drinking water treatment technologies especially for developing countries. Slow sand filter (SSF) is one of the most commonly used low-cost and efficient technologies for treating household drinking water. However, effectiveness of SSF is substantially affected by very high turbidity and relatively large amounts of dissolved heavy metals. To enhance removal of both turbidity and heavy metals, this study optimized sand bed depth (SBD) of SSF and investigated the potential of natural zeolite from Uganda for removal of lead, arsenite (As(III)) and fluoride ions from water. To remove lead ions, the zeolite was used in its natural form. However, to remove As(III) and fluoride, the natural zeolite was modified using hexadecyltrimethylammonium bromide solution. Removal of high turbidity was found to require a large optimal SBD. Furthermore, efficiency of treating synthetic turbid water increased with increasing initial turbidity. Variation of final turbidity with SBD was found to be best described by an exponential function. Optimal SBDs on top of an underdrain gravel layer of 0.2 m were 453, 522, 561, and 580 mm for turbidity of 60, 80, 100, and 120 NTU, respectively. Optimized SBD used achieve at least 95% efficiency in removing suspended particles from water with turbidity 120 NTU was found to save up to 35% of the total cost for acquiring sand volume required by a conventional SSF. For a particular zeolite mass, removal efficiencies of lead, As(III) and fluoride generally increased with increasing contact time. Removal efficiencies of lead, As(III), and fluorides were also shown to increase with increasing zeolite mass. Lead removal efficiencies using natural zeolite were 75 and 98% under 20 and 40 min, respectively. Removal of As(III) using modified zeolite mass was 91% within contact time of 10 min. Adsorption of fluoride on modified zeolite was 80% within 5 min. Adsorption of lead, As(III), and fluorides indicated promising potential of natural zeolites from Uganda for treating polluted water.