Latent Heat Loss Research Articles

James Hutton and the measurement of atmospheric moisture

Measuring the amount of water in the air has been one of the most challenging of routine tasks in meteorology. From the 1650s onwards the methods involved either the uptake of moisture by organic materials such as human hair and whalebone (hygrometry) or the measurement of cooling due to loss of latent heat during evaporation (psychrometry). In 1792 James Hutton reported that a thermometer previously moistened by water records a lower temperature when exposed to cooling in the wind. This led to the development of the first condensation hygrometer by John Leslie in 1801 based on wet- and dry-bulb thermometers, whose design was refined and improved throughout the nineteenth century. Determining relative and absolute humidity values from a hygrometer required the use of a psychrometric equation, first developed by James Ivory in 1822 and later refined by Ernst Ferdinand August, James Apjohn and many others. Modern-day determinations of humidity often involve an aspirated psychrometer located in a Stevenson screen, whose origin can be traced directly back to Hutton’s observation of cooling due to evaporation. An extensive review of the literature on psychrometry records only cursory and ill informed acknowledgement of Hutton’s contribution. This article reasserts Hutton’s seminal role in the history of psychrometry.

Low cloud-SST variability over the summertime subtropical Northeast Pacific: Role of extratropical atmospheric modes

Abstract Over the subtropical Northeast Pacific (NEP), highly reflective low clouds interact with underlying sea-surface temperature (SST) to constitute a local positive feedback. Recent modeling studies showed that, together with wind-evaporation-SST (WES) feedback, the summertime low cloud-SST feedback promotes nonlocal trade wind variations, modulating subsequent evolution of El Niño-Southern Oscillation (ENSO). This study aims to identify drivers of summertime low-cloud variations, using satellite observations and global atmosphere model simulations forced with observed SST. A trans-basin teleconnection is identified, where the North Tropical Atlantic (NTA) warming induced by the North Atlantic Oscillation (NAO) increases precipitation, exciting warm Rossby waves that extend into the NEP. The resultant enhancement of static stability promotes summertime low cloud-SST variability. By regressing out the effects of the preceding ENSO and NTA SST, atmospheric internal variability over the extratropical North Pacific, including the North Pacific Oscillation (NPO), is found to drive the NEP cooling by latent heat loss and subsequent summer low cloud-SST variability. With the help of the background trade winds and WES feedback, the SST anomalies extend southwestward from the low-cloud region, accompanied by ENSO in the following winter. This suggests the nonlocal effects of low clouds identified by recent studies. Analysis of a 500-year climate model simulation corroborates the NTA and NPO forcing of NEP low cloud-SST variability and subsequent ENSO.

Thermal performance of a novel composite phase change material for solar-assisted air source heat pump packed bed thermal energy storage application

The thermal properties of the heat storage medium in the solar-assisted air source heat pump (SAASHP) systems must be aligned with the system’s heat generation temperature while satisfying the heat demand. In this study, a novel composite phase change material (CPCM) for efficient heat storage in SAASHP systems was developed. Our investigation revealed that the incorporation of 8 wt% KNO3, 1.5 wt% thickener, and 1.0 wt% Al2O3 nanoparticles into sodium acetate trihydrate resulted in the manifestation of desirable properties suitable for SAASHP systems. The compound exhibited a suitable melting point of 48.66 °C, high latent heat of 235.97 kJ/kg, low supercooling degree of 2.25 °C, and good thermal conductivity of 0.905 W/(m·K). Furthermore, the novel CPCM demonstrated exceptional thermal stability, with only an 8.64 % loss of latent heat after undergoing 200 cycles, while maintaining a supercooling degree within a range of 6 °C for each cycle. Moreover, molecular dynamics simulation results further indicated that the presence of KNO3 weakened the interaction between CH3COONa molecules and water molecules, leading to a reduction of the melting point. Additionally, numerical analysis revealed that the total heat storage capacity and exergy storage capacity of the packed bed thermal energy storage (PBTES) system filled with the novel CPCM are 358.8 MJ and 25.1 MJ, respectively. With an increase in the heating power of the SAASHP system from 10 kW to 30 kW, the cycle heat storage time of the PBTES system can decrease by 38.8 %, while an increase in the flow rate from 2 m3/h to 6 m3/h can reduce the time by 26.3 %. These findings have significant implications for the selection and composition design of thermal storage materials in SAASHP systems.

Controllable heat release of supercooled Erythritol-based phase change materials for long-term thermal energy storage

Transeasonal heat storage in organic phase change materials (PCMs) present a promising solution to the intermittent nature of renewable energy. However, PCMs are prone to spontaneous crystallization during storage, leading to the loss of stored latent heat in low-temperature environments. In this study, we incorporated tetrasodium ethylenediaminetetraacetic acid (EDTA-4Na) and superabsorbent polymer (SAP) to erythritol (ERY), referred to as EES-PCMs, to overcome these challenges and achieve more controllable and stable thermal energy storage. The incorporation of EDTA-4Na and SAP into ERY significantly improves the supercooling stability and phase change enthalpy. The optimal ratio (EES-PCMs-2) of phase change enthalpy reaches an impressive 286.62 J/g, with stable performance maintained for 120 days at room temperature. The EES-PCMs-2 exhibits exceptional thermal cycling stability, retaining its properties even after 100 cycles. A novel air-triggered crystallization method is demonstrated, enabling a temperature increase from room temperature to 48.21 °C in 320 s after being exposed to air for long-term storage. This innovative approach effectively overcomes the limitations of traditional triggering mechanisms, providing a straightforward and efficient method for thermal management. The high thermal storage capacity, stability, and controlled exothermic properties of EES-PCMs position them as promising candidates for applications in seasonal solar thermal energy storage.

Chlorophyll Production in the Amundsen Sea Boosts Heat Flux to Atmosphere and Weakens Heat Flux to Ice Shelves

AbstractThe Amundsen Sea in West Antarctica features rapidly thinning ice shelves, large polynyas, and sizable spring phytoplankton blooms. Although considerable effort has gone into characterizing heat fluxes between the Amundsen Sea, its associated ice shelves, and the overlying atmosphere, the effect of the phytoplankton blooms on the distribution of heat remains poorly understood. In this modeling study, we implement a feedback from biogeochemistry onto physics into MITgcm‐BLING and use it to show that high levels of chlorophyll—concentrated in the Amundsen Sea Polynya and the Pine Island Polynya—have the potential to increase springtime surface warming in polynyas by steepening the attenuation profile of solar radiation with depth. The chlorophyll‐associated warm anomaly (on average between +0.2C and +0.3C) at the surface is quickly dissipated to the atmosphere, by increases in longwave, latent and sensible heat loss from open water areas. Outside of the coastal polynyas, the summertime warm anomaly leads to an average sea ice thinning of 1.7 cm across the region, and stimulates up to 20% additional seasonal melting near the fronts of ice shelves. The accompanying cold anomaly, caused by shading of deeper waters, persists year‐round and affects a decrease in the volume of Circumpolar Deep Water on the continental shelf. This cooling ultimately leads to an average sea ice thickening of 3.5 cm and, together with associated changes to circulation, reduces basal melting of Amundsen Sea ice shelves by approximately 7% relative to the model scenario with no phytoplankton bloom.

Interaction Between Typhoon, Marine Heatwaves, and Internal Tides: Observational Insights From Ieodo Ocean Research Station in the Northern East China Sea

AbstractTyphoons, fueled by warm sea surface waters, heighten concern as they increasingly interact with frequent Marine Heatwaves (MHWs) in a changing climate. Typhoon Hinnamnor (2022) weakened and re‐intensified as it approached the Korean Strait, interacting with an underlying MHW in the northern East China Sea (nECS). In‐situ observations and reanalysis products revealed a significant increase in latent heat loss from the nECS during the MHW period, contributing to the typhoon re‐intensification. Strong sea surface wind forcing with the typhoon enhanced vertical mixing and upwelling, resulting in a pronounced (0.90°C) sea surface cooling after the typhoon passage, facilitating MHW disappearance with reduced thermal stratification. During MHWs, increased background stratification increases temperature oscillations associated with semidiurnal internal tides. Furthermore, post‐typhoon changes in stratification weakened semidiurnal internal tides due to unfavorable conditions for generation from a nearby source. These findings highlight the importance of continuous time‐series observations to monitor interactions among climatic extremes.

Near-surface ocean temperature and air-sea heat flux observed by a buoy array during summer to autumn in year 2014 in the northern South China Sea

The observational data of the air-sea interface and upper ocean elements from a buoy array deployed in the northern South China Sea from June to November 2014 is analyzed. The COARE 3.0 algorithm was adopted to examine the variability of air-sea heat fluxes and their contributions to near-surface ocean temperature changes. During the observation period, air-sea heat exchange in the northern South China Sea is primarily determined by solar shortwave radiation and latent heat flux, with net heat flux mostly negative, indicating that the ocean predominantly loses heat. In autumn, net heat flux loss significantly increased by an average of 34.4 W/m2, primarily due to enhanced latent heat loss driven by stronger winter monsoon. During typhoon period, net air-sea heat flux was significantly suppressed, mainly due to reduced solar shortwave radiation, with minimal contribution from sensible heat flux. Near-surface ocean temperature exhibited a seasonal cooling trend, averaging 29.7°C in summer and 28.4°C in autumn. The maximum cooling during typhoon reached 3.1°C, with minimal contribution from air-sea heat flux. During the monsoon transition period, weaker winds led to a slight increase in near-surface ocean temperature, with air-sea heat flux contributing 70.2% and 56.3% to this process. During winter monsoon, more uniform water column mixing resulted in a gradual decrease in near-surface ocean temperature, with air-sea heat flux contributing over 60% to this process.

Mesoscale Ocean–Atmosphere Coupling Effects on the North Pacific Subtropical Mode Water

Abstract Subtropical mode water (STMW) is a thick layer of water mass characterized by homogeneous properties within the main pycnocline, important for oceanic oxygen utilization, carbon sequestration, and climate regulation. North Pacific STMW is formed in the Kuroshio Extension region, where vigorous mesoscale eddies strongly interact with the atmosphere. However, it remains unknown how such mesoscale ocean–atmosphere (MOA) coupling affects the STMW formation. By conducting twin simulations with an eddy-resolving global climate model, we find that approximately 25% more STMW is formed with the MOA coupling than without it. This is attributable to a significant increase in ocean latent heat release primarily driven by higher wind speed over the STMW formation region, which is associated with the southward deflection of storm tracks in response to oceanic mesoscale imprints. Such enhanced surface latent heat loss overwhelms the stronger upper-ocean restratification induced by vertical eddy and turbulent heat transport, leading to the formation of colder and denser STMW in the presence of MOA coupling. Further investigation of a multimodel and multiresolution ensemble of global coupled models reveals that the agreement between the STMW simulation in eddy-present/rich coupled models and observations is superior to that of eddy-free ones, likely due to more realistic representation of MOA coupling. However, the ocean-alone model simulations show significant limitations in improving STMW production, even with refined model resolution. This indicates the importance of incorporating the MOA coupling into Earth system models to alleviate biases in STMW and associated climatic and biogeochemical impacts. Significance Statement North Pacific subtropical mode water (STMW) is a distinct pycnostad within the main thermocline located south of the Kuroshio Extension. As short-term heat and carbon silos, STMW is traditionally thought to be driven by the basin-scale atmospheric forcing. The role of air–sea interactions at mesoscales residing in the Kuroshio Extension region has been overlooked. Here, we demonstrate that the strong thermal feedback of mesoscale sea surface temperature anomalies is not negligible for the STMW formation. This is achieved by accelerating wind and consequently promoting ocean latent heat release. Our results pinpoint the significance of accounting for the role of oceanic mesoscale feedback in improving the simulation of STMW as well as its climatic and biogeochemical impacts in Earth system models.

Assessing the impact of evapotranspiration from green roofs on reducing surface temperatures

Evapotranspiration is an important process in green roofs to reduce surface temperature; however, it is still not well understood. This study aims to assess the influence of irrigation and vegetation parameters in the evapotranspiration of green roofs and surface temperature. Green roofs with almost no vegetation, short Sedum and tall Sedum with 0, 3 and 6 mm irrigation were considered in Lisbon (Portugal) and Florianópolis (Brazil) climates. The outside roof surface temperature was experimentally assessed in an extensive green roof prototype and used to validate the computer simulation. The results showed that although irrigation can enhance evapotranspiration, mainly in drier regions, denser vegetation has a higher impact on this process. The annual latent heat losses of the tall Sedum green roof overcome those of roofs with almost no vegetation by 695.9 kWh/m2 in Lisbon and by 471.8 kWh/m2 in Florianópolis. Green roofs with tall Sedum also resulted in lower substrate temperatures, even without irrigation. The hourly substrate temperature of green roofs with tall Sedum can be lower than the outside surface temperature of traditional roofs by up to 33.4 °C in Lisbon and up to 24.0 °C in Florianópolis. In these roofs, the latent heat fluxes correspond to 40 % and 48 % of the total losses in Lisbon and Florianópolis, respectively. It was concluded that latent heat losses accounted for a higher percentage of the energy balance of the green roofs whose reductions in surface temperature were more significant. This research provides valuable insights regarding the relationship between evapotranspiration and surface temperature and the role of evapotranspiration on the energy balance of green roofs with crassulacean acid metabolism (CAM) plants.

Aerobic composting characteristics of corn straw and pig manure under dynamic aeration

ABSTRACT The conventional aeration method is compulsorily continuous ventilation or aeration at equal intervals, and a uniform aeration rate does not vary during composting. A dynamic on-demand aeration approach based on the diverse oxygen consumption of microorganisms at different composting stages could solve the problems of insufficient oxygen supply or excessive aeration. This study aims to design an aerobic composting system with dynamic aeration, investigate the effects of dynamic aeration on the temperature rise and physicochemical characteristics during the aerobic composting of corn straw and pig manure, and optimise the control parameters of oxygen concentration. Higher temperatures and longer high-temperature durations were achieved under dynamic aeration, thereby accelerating the decomposition of organic compounds. Dynamic aeration effectively reduced the aeration frequency, the convective latent heat and moisture losses, and the power consumption in the middle and later stages of composting. The dynamic aeration regulated according to the oxygen concentration of 14%–17% in the exhaust was optimum. Under the optimal conditions, the period above 50 ℃ lasted 8.5 days, and the highest temperature, organic matter removal, and seed germination index reached 65.82 ℃, 37.59%, and 74.59%, respectively. The power consumption was decreased by 33.58% compared to the traditional intermittent aeration. Dynamic aeration would be a competitive approach for improving aerobic composting characteristics and reducing the power consumption and the hot exhaust gas emissions, especially in the cooling maturation stage, which was of great significance for realising the low-cost production of composting at scale and promoting the blossom of the organic fertiliser industry.

Latent Heat Loss Through Fabrics During an Alternate Simulated Work–Rest Sequence

Humans produce different rates of sweating depending on the intensity level of a given activity. The clothing worn during the activity has a significant effect on the latent heat loss that can occur before, during, and after the activity. The water adsorption and spreading properties of a material yield differences in the amount of heat exchange that can occur between the person and the environment. Current test methods evaluate this using a value known as evaporative resistance, which is used to determine the heat exchange potential of a material. However, this value is only taken once the material has reached “steady state” and does not consider the sweating period before steady state is reached, or the drying period after steady state is reached. Therefore, an area under the curve (AUC) value was derived during these periods to compare the heat exchange properties of different materials. A sweating guarded hot plate was used to simulate different sweat rates, and therefore activity levels, to compare materials constructed of cotton, viscose, polyester, and wool. The overall latent heat loss of the hydrophobic wool was much less compared to the other samples with a gentler slope and lower AUC values than the other samples. It was found that the segment of time analyzed has a significant impact on the conclusion drawn about the latent heat loss of a material, p < 0.0001. Sweat rate also has a significant impact on the heat loss value, p < 0.0001, but is perhaps less useful when comparing samples to each other. It was found that comparing the different periods of the test could yield different conclusions when comparing materials for latent heat loss. Several current test methods do not consider phases outside of the steady state period and therefore miss valuable information pertinent to user comfort during these phases, especially in the post-exercise phase.

An experimental approach to heat loss measurement of horizontal two-phase flow boiling in low-pressure low-flow (LPLF) conditions

A crucial parameter remarkably influencing the reliability and accuracy of vapor quality measurements in flow boiling experiments is the measurement of heat loss. The latent heat loss estimation in two-phase flow boiling sounds more demanding than that of sensible heat loss in single-phase flow experiments. To accurately investigate the impact of vapor quality on the heat transfer coefficient of flow boiling, accurate estimates of heat loss and subsequent calibration of heat supplies are of a great significance. It is widely common that the single-phase flow tests are performed to estimate a fixed heat loss percentage and calibrate heat supplies for further measurements of vapor quality and heat transfer coefficient of flow boiling experiments. In the present work, an empirical methodology is first proposed to measure heat losses and calibrate latent heat supplies directly from flow boiling process. The proposed methodology is then compared and verified with the commonly applied methodology which uses single-phase flow experiments. The proposed methodology exhibited higher accuracy than the single-phase-based methodology to estimate heat losses and measure vapor quality within two-phase flow boiling under low-pressure low-flow (LPLF) operating conditions.

The Respective Roles of Ocean Heat Transport and Surface Heat Fluxes in Driving Arctic Ocean Warming and Sea Ice Decline

Abstract Arctic Ocean warming and sea ice loss are closely linked to increased ocean heat transport (OHT) into the Arctic and changes in surface heat fluxes. To quantitatively assess their respective roles, we use the 100-member Community Earth System Model, version 2 (CESM2), Large Ensemble over the 1920–2100 period. We first examine the Arctic Ocean warming in a heat budget framework by calculating the contributions from heat exchanges with atmosphere and sea ice and OHT across the Arctic Ocean gateways. Then we quantify how much anomalous heat from the ocean directly translates to sea ice loss and how much is lost to the atmosphere. We find that Arctic Ocean warming is driven primarily by increased OHT through the Barents Sea Opening, with additional contributions from the Fram Strait and Bering Strait OHTs. These OHT changes are driven mainly by warmer inflowing water rather than changes in volume transports across the gateways. The Arctic Ocean warming driven by OHT is partially damped by increased heat loss through the sea surface. Although absorbed shortwave radiation increases due to reduced surface albedo, this increase is compensated by increasing upwelling longwave radiation and latent heat loss. We also explicitly calculate the contributions of ocean–ice and atmosphere–ice heat fluxes to sea ice heat budget changes. Throughout the entire twentieth century as well as the early twenty-first century, the atmosphere is the main contributor to ice heat gain in summer, though the ocean’s role is not negligible. Over time, the ocean progressively becomes the main heat source for the ice as the ocean warms. Significance Statement Arctic Ocean warming and sea ice loss are closely linked to increased ocean heat transport (OHT) into the Arctic and changes in surface heat fluxes. Here we use 100 simulations from the same climate model to analyze future warming and sea ice loss. We find that Arctic Ocean warming is primarily driven by increased OHT through the Barents Sea Opening, though the Fram and Bering Straits are also important. This increased OHT is primarily due to warmer inflowing water rather than changing ocean currents. This ocean heat gain is partially compensated by heat loss through the sea surface. During the twentieth century and early twenty-first century, sea ice loss is mainly linked to heat transferred from the atmosphere; however, over time, the ocean progressively becomes the most important contributor.

Understanding Biases in Indian Ocean Seasonal SST in CMIP6 Models

AbstractThe latest generation of climate models continue to exhibit biases in their representation of climatological sea surface temperature (SST), affecting their ability to simulate climate variability including the Indian Ocean Dipole which is typically too strong. Here, we analyze the surface layer heat budget of the Indian Ocean to diagnose the processes leading to biases in climatological SST biases in 20 Coupled Model Intercomparison Project Phase 6 (CMIP6) models, in comparison to a suite of observational and reanalysis products. In the western tropical Indian Ocean, we find that weaker than observed winds reduce the strength of surface currents leading to warm SST bias. In the south‐eastern tropical Indian Ocean, overly strong southeasterly winds are associated with overestimated coastal upwelling that increases cooling across CMIP6 models. In the Arabian Sea, overly strong surface winds increase latent heat loss and leads to cool SST biases. We also analyze other regions like the Bay of Bengal, where a persistent cool bias cannot be explained by seasonal heat budgets, and southern Indian Ocean, where overly strong surface winds are responsible for cool SST biases. These biases in surface processes are supported by intermodel relationships between relevant variables, thus explaining differences in simulating the climatological SSTs across the model ensemble. Our analysis suggests that biases in atmospheric processes in particular surface winds are a primary cause of biases in Indian Ocean SST. Reducing these biases would improve the simulation of climate variability in the Indian Ocean toward more reliable climate projections and predictions.

Drivers of marine heatwaves in a stratified marginal sea

Marine heatwaves (MHWs) can cause devastating impacts in coastal marine ecosystems, particularly in shallow marginal seas, thereby making the understanding of the drivers of these events of paramount importance. Here, drivers for summer and winter MHWs are explored for the period 1980–2016 in the Baltic Sea, a mid-latitude marginal sea with a permanent haline water-column stratification located on the northwestern European shelf. It was found that summer MHWs are mainly forced by local meteorological conditions over the open water. They are caused by a dominant blocking over Scandinavia promoting anomalous strong shortwave downflux, calm winds, and low vertical mixing with colder sub-thermocline waters. Wintertime MHWs are linked to the advection of warm and moist air originating from the North Atlantic. These air masses lower the oceanic net heat loss at the sea surface primarily in the form of reduced latent and sensible heat losses. Vertical ocean dynamics are also affected during winter MHWs. This study finds a strengthened coastal up- and downwelling due to anomalous strong westerly winds during the time before MHWs culminate in their maximal surface extension.

Photo-cured phase change energy storage material with photo-thermal conversion, self-cleaning and electromagnetic shielding performances via the lamellar structure strengthened by segment rearrangement of dynamic disulfide bond

At present, phase change materials (PCMs) with single function hardly meet the needs of advanced intelligent materials in practical applications, and the multifunction integration is the current trend. However, photo-cured multifunctional PCMs are hampered by insufficient transparency due to adding functional fillers, such as carbon and metal materials. The novel strategy is necessary to overcome this limitation. Here, a photo-cured multifunctional PCM is prepared by using the design of a lamellar structure composing the photo-cured phase change polymer layer and the functional fillers layer. The curing of the phase change polymer is realized by the photo-induced "thiol-ene" click reaction, and reversible dynamic disulfide bonds are introduced into the PCM, which not only gives the phase change crosslinked network reprocessability, but also strengthens the interface layer by the chain rearrangement to form a stable composite structure. The carboxylated multiwalled carbon nanotubes (CCNTs) and silver nanowires (AgNWs), as functional fillers, give the PCM photo-thermal conversion, self-cleaning and electromagnetic shielding (EMI SE) performances. Its phase change latent heat and photo-thermal conversion can reach 105.2 J/g and 78.5%, and the water contact angle is 142° with self-cleaning performance. In addition, due to the dense and well-developed conductive path formed by AgNWs layer on the PCM surface, the EMI SE effect can reach 39 dB with only 6.3% (in mass) filler content and 7.2% phase change latent heat loss. As far as we know, this is the first report about photo-cured PCMs with self-cleaning, photo-thermal conversion and EMI SE performances.

Preparation and properties of shape-stable phase change material with enhanced thermal conductivity based on SiC porous ceramic carrier made of iron tailings

SiC porous ceramic carriers with adjustable porosity of 79.9%–90.7% were prepared by foam gel-casting forming and carbothermal reduction reaction sintering, using industrial waste fine-grained iron tailings and graphite powder as raw materials. Then paraffin/SiC shape-stable phase change materials were prepared by spontaneous infiltration employing paraffin as phase change material. Thermal conductivity of the SiC carriers (0.17–0.31 W/m·K) is 2.7–3.7 times higher than that of iron tailings porous ceramics with the same porosity. A thermal conductivity model of the SiC carrier is established and verified by experimental data. Phase composition, microstructure, molecular structure, mechanical properties and thermal properties of the shape-stable phase change materials were characterized by XRD, SEM, FT-IR, WDW, Hot Disk and DSC, respectively. There is only a physical combination between paraffin and SiC carriers. The compressive strength of the shape-stable phase change materials (2.0–2.3 MPa), weight loss and latent heat loss are less than 5% and 4.7% after 100 thermal cycles, respectively, which can meet the application requirements as a functional material. Thermal conductivity of the shape-stable phase change materials (0.7–0.73 W/m·K) is significantly improved, a latent heat of 138.5 J/g, and the efficiency of energy storage and release is 2.3–3.3 times as good as than that of paraffin, suggesting that this material is capable of recycling and reusing waste heat as a highly efficient thermal energy storage system.

Light-driven phase change microcapsules modified by TiN/CNTs nanocomposites for enhancement of solar energy storage and solar photocatalytic efficiency

The development of microencapsulated phase change materials (PCMs) integrating solar photothermal conversion and storage holds significant for solar energy utilization. Herein, this study developed an efficient light-driven phase change microcapsule system by encapsulating paraffin within a brookite TiO2 shell through sol-gel interfacial polymerization, followed by wrapping titanium nitride (TiN)/carbon nanotubes (CNTs) nanocomposites on the shell surface. The microcapsule system exhibited a regular spherical core-shell structural morphology. The encapsulation of TiO2 and the introduction of the highly thermal conductivity enhancement phase increased the thermal conductivity of the microcapsule system by approximately 151.5 % compared to pure paraffin while maintaining latent heat of over 135 J·g−1. Furthermore, TiN/CNTs were combined with the microcapsule shell through hydrogen bonds and shared electron pairs, constructing localized surface plasmon resonance (LSPR)-enhanced heterojunction. The microcapsule system demonstrated excellent broad-spectrum light absorption capacity, resulting in a remarkable 112.01 % enhancement in the optimum photothermal conversion efficiency. Concurrently, the degradation rate of MB was increased by 59.52 % due to the synergistic catalytic action of photothermal, semiconductor, and LSPR effects. The microcapsule system also exhibited excellent thermal and cycling stability, with only 1.6 % latent heat loss after 500 thermal cycles. This study provides a promising strategy for developing energy storage microcapsule composite PCMs for the efficient collection and utilization of solar energy.

Characterisation of erythritol as a potential phase change material

ABSTRACT Erythritol ((2 R,3S)-Butane-1,2,3,4-tetrol) is being considered as a phase change material (PCM) of interest owing to its potential applicability for solar thermal applications. But however, lack of inclusive material characterisation outcomes drives the need to bridge this research gap. In this study, erythritol was subjected to both chemical and thermal characterisation investigations. X-ray diffractometry (XRD) investigation estimated the degree of crystallinity to be 73.48% and the crystallite size to be 38.79 nm. The fourier transform infrared spectroscopy (FT-IR) investigation has identified -OH, -C-H and -CH2 to be the major functional groups. The scanning electron microscopy (SEM) investigation visualised the crystalline architecture of the PCM. The energy dispersive x-ray spectroscopy (EDAX) investigation quantified the composition of C and O in the eclectic constituency. The UV-visible spectrophotometry investigations confirmed that erythritol could be utilised for direct solar thermal applications. The thermal characterisation investigations rendered the latent heat of the PCM to be 333.48 kJ kg −1 and its peak melting temperature to be 118.18°C. The thermal stability investigations estimated the latent heat loss per cycle to be 1.1451 kJ kg −1.

Thermal-Conductivity-Enhancing Copper-Plated Expanded Graphite/Paraffin Composite for Highly Stable Phase-Change Materials.

Paraffin (PA)/expanded graphite (EG) is an important composite phase change material with low cost, high heat storage, good thermal conductivity and cycling stability. Its thermal conductivity needs to be further improved for application in the thermal management system of power lithium-ion batteries. In this paper, copper plated expanded graphite (CPEG) with 3D porous structure was prepared by electroless copper plating method, which was used as thermal conductivity enhancing material to replace part of EG in PA/EG composite materials. For the optimized phase change material composed of 80%PA-14%EG-6%CPEG, the copper content is very low (0.768 wt%), but its thermal conductivity can be significantly improved without loss of latent heat and thermal cycling stability. Its thermal conductivity is increased from 11 times to 16.5 times that of paraffin while compared with the copper-free composite material (80%PA-20%EG). The PA/EG/CPEG composite material exhibits good temperature control effect on power lithium-ion batteries.