Maximum In Late Spring Research Articles

The Seasonal Cycle of Significant Wave Height in the Ocean: Local Versus Remote Forcing

AbstractSignificant wave height (SWH) stems from a combination of locally generated “wind‐sea” and remotely generated “swell” waves. In the Northern and Southern Hemispheres, wave heights typically undergo a sinusoidal annual cycle, with larger SWH in winter in response to seasonal changes in high‐latitude storm patterns that generate equatorward propagating swell. However, some locations deviate from this hemispheric‐scale seasonal pattern in SWH. For example, in the California coastal region, local wind events occur in boreal spring and summer, leading to a wind speed (WSP) annual cycle with a distinct maximum in boreal spring and a corresponding local response in SWH. Here ocean regions with a WSP annual cycle reaching a maximum in late spring, summer, or early fall are designated as seasonal wind anomaly regions (SWARs). Intra‐annual variability of surface gravity waves is analyzed globally using two decades of satellite‐derived SWH and WSP data. The phasing of the WSP annual cycle is used as a metric to identify SWARs. Global maps of probability of swell based on wave age confirm that during the spring and summer months, locally forced waves are statistically more likely in SWARs than in surrounding regions. The magnitude of the deviation in the SWH annual cycle is determined by the exposure to swell and characteristics of the wave field within the region. Local winds have a more identifiable impact on Northern Hemisphere SWARs than on Southern Hemisphere SWARs due to the larger seasonality of Northern Hemisphere winds.

Contribution of meteor flux in the occurrence of sporadic-E (Es) layers over the Arabian Peninsula

Abstract. A sporadic-E (Es) layer is generally associated with a thin-layered structure present in the lower ionosphere, mostly consisting of metallic ions. This metallic ion layer is formed when meteors burn in the upper atmosphere, resulting in the deposition of free metal atoms and ions. Many studies have attributed the presence of the Es layer to the metallic ion layer, specifically when the layer is observed during the nighttime. Using data from a network of meteor monitoring towers and a collocated digital ionosonde radar near the Arabian Peninsula, in this paper, we report our observations of Es layer occurrences together with the meteor count. The trend of monthly averages of Es layer intensity shows a maximum in late spring and early summer months and a minimum in winter months, whereas the meteor counts were highest in winter months and lowest in spring and early summer months. This shows that the presence of the Es layer and the meteor counts have no correlation in time, both diurnally and seasonally. This leads us to conclude that the presence of meteors is not the main cause of the presence of the Es layer over the Arabian Peninsula.

The representation of ionospheric potential in the global chemistry-climate model SOCOL

In this paper, we present the first results of the ionospheric potential (IP) calculations with the chemistry-climate model (CCM) SOCOL (Solar Climate Ozone Links). For the study, we exploit a parameterization of the difference in electric potential between Earth's surface and lower boundary of the ionosphere as a function of thunderstorm and electrified cloud properties. The model shows a good enough agreement with the IP obtained by balloon soundings. The simulated UT variation of IP exhibits a maximum at 20 Universal time (UT) and minimum at about 2 UT which agree with the UT cycle of the lightning activity. The obtained results allow understanding of IP variability pattern at diurnal, seasonal and annual timescales. We also compare our results with the IP simulated with the climate model INMCM4 using similar IP parameterization. The comparison shows a good agreement of UT cycles especially before 12 UT. Simulated IP annual cycle reaches its maximum in late spring in both models. However, the comparison also reveals some differences in amplitudes of IP variability on different time scales. The large deviations occur after 12 UT for all seasons except summer where the maximum of both results happens before 12 UT. The UT cycle of IP simulated with CCM SOCOL is in a better agreement with observations after 12 UT in terms of phase with similar timing of maximum values. The calculation of IP using climate models can help to fill up the gaps when the observed IP is not available. The interactive calculation of IP is also a step forward in coupling atmospheric and ionospheric processes.

Ground-truthing the planktic foraminifer-bound nitrogen isotope paleo-proxy in the Sargasso Sea

We report the nitrogen (N) isotope ratios (δ15N) of planktic foraminifera collected from upper-ocean net tows (surface to 200 m), moored sediment traps, and core-top sediments at the Bermuda Time-series Site in the northern Sargasso Sea between 2009 and 2013. Consistent with previous measurements from low-latitude core-top sediments, the annually-averaged δ15N of organic matter bound within the shells of euphotic zone-dwelling, dinoflagellate symbiont-bearing foraminifera collected in net tows (2.3‰ on average) approximates that of shallow thermocline (∼200 m) nitrate (2.6‰), the dominant source of new N to Sargasso Sea surface waters. Deeper-dwelling foraminifer species without dinoflagellate symbionts tend to have a higher δ15N (3.6‰ on average). We observe no systematic difference between the bulk tissue and shell-bound δ15N in net tow-collected foraminifera. A decline in shell N content is observed from net tows (6.8 nmol/mg) to sediment traps (5.4 nmol/mg) and surface sediment (3.0 nmol/mg). On average, shell-bound δ15N rises from net tows (3.1‰) to sediment traps (3.7‰) but does not change further upon incorporation into the sediments (3.7‰). Together, these observations are consistent with preferential loss of shells or shell portions with lower δ15N and higher N content during sinking through the upper 500 m, followed by a non-isotope fractionating decrease in N content between sinking and burial. Time-series data from sediment traps (and to a lesser extent, surface net tows) exhibit seasonal δ15N variations, with a minimum in early spring, a maximum in late spring and a decline from summer to fall. These variations appear to arise from seasonal changes in the δ15N of total upper-ocean biomass, which are, in turn, driven by early springtime nitrate supply, subsequent nitrate drawdown, and an increase in the relative importance of ammonium recycling into the late summer and early fall. The δ15N connection between total upper ocean biomass and foraminifera indicates that foraminifer-bound δ15N records the δ15N of the annual nitrate supply in oligotrophic (e.g., subtropical) environments but will also be sensitive to the degree of nitrate consumption in high-nutrient regions and possibly to changes in upper-ocean ammonium recycling under some conditions.

Annual variations in hepatic antioxidant defenses and lipid peroxidation in a temperate fish, common bream Abramis brama (L.)

Alternation of physiological states during the annual cycle (pre-spawning mobilization, spawning energy loss, post-spawning accumulation of energy reserve, declined metabolic activity during the wintering) occurring in the wide temperature range requires high plasticity of fish defense systems. The article presents a 2-year study of hepatic antioxidant defenses and lipid peroxidation in the temperate cyprinid fish, common bream Abramis brama (L.), in relation to basic annual rhythms, such as photoperiodic and temperature cycling, reproduction and feeding activity. The objective of the study was to evaluate the plasticity of antioxidant defenses in bream under normal conditions throughout the annual cycle, by measuring hepatic antioxidants (superoxide dismutase, catalase, glutathione-S-transferase activities and reduced glutathione concentrations) and products of lipid peroxidation (thiobarbituric acid reactive substances concentrations). The results suggested that hepatic levels of antioxidants in bream varied dramatically during the annual cycle allowing bream to develop necessary adaptation and implement reproduction program. The lowest values of all studied antioxidants were witnessed in the middle of winter. In early spring, antioxidant enzyme activities increased rapidly reaching their maxima in late spring and summer. Toward the end of autumn, enzyme activities were declining toward the levels observed before the ice breakup. Spring–summer up-regulation of antioxidant defenses along with increased lipid peroxidation indicated bream to be experiencing mild oxidative stress.

Seasonal variation of the O3–CO correlation derived from remote sensing measurements over western Japan

We used a lower tropospheric ozone column (LTOC) and column-averaged dry-air mole fraction of carbon monoxide (XCO) data observed in the area around Saga, which is located in western Japan and is close to the Asian continent, with an aim to investigate whether these data can characterize the seasonal variation of the photochemical ozone (O3) formation in the northeast Asian Pacific rim region. The LTOC data after April 2009 were retrieved from thermal infrared spectra measured by the Thermal and Near Infrared Sensor for Carbon Observation-Fourier Transform Spectrometer (TANSO-FTS) onboard the Greenhouse Gases Observing Satellite (GOSAT). The XCO data after July 2011 were obtained from ground-based high-resolution FTS measurements at Saga. The retrieved LTOCs were validated with those derived from a differential absorption lidar for O3 at Saga. The LTOCs showed a distinct seasonal variation that reached a maximum in late spring (May or June) and a local minimum in winter. In addition to the general seasonal pattern, we observed pronounced minimums in July or August. The XCO concentrations showed a maximum in spring and a minimum in summer. These seasonal patterns are consistent with those observed from mountainous sites in Japan. The origins of the air masses reaching Saga were characterized for each season according to backward trajectories, and the factors causing the temporal variations of the LTOCs and the XCO were identified based on the transport paths of the air masses. The enhancement of the LTOC relative to the XCO (ΔO3/ΔCO ratio) reveals significant positive correlations in the spring and summer seasons with slopes of 0.21 and 0.45 ppb/ppb, respectively. The effects of stratospheric air intrusion on the observed ΔO3/ΔCO ratio in spring were investigated using meteorological data (backward trajectory and potential vorticity) and column-averaged hydrogen fluoride data derived from the ground-based FTS measurements. It was found that there was little contribution of the stratospheric intrusion. This suggests that the positive correlations of the ΔO3/ΔCO ratio are likely to be a result of photochemical O3 production in the troposphere.

Quantifying isentropic stratosphere‐troposphere exchange of ozone

AbstractThere is increased evidence that stratosphere‐troposphere exchange (STE) of ozone has a significant impact on tropospheric chemistry and radiation. Traditional diagnostics of STE consider the ozone budget in the lowermost stratosphere (LMS) as a whole. However, this can only render the hemispherically integrated ozone flux and therefore does not distinguish the exchange of ozone into low latitudes from that into high latitudes. The exchange of ozone at different latitudes may have different tropospheric impacts. This present study extends the traditional approach from the entire LMS to individual isentropic layers in the LMS and therefore gives the meridional distribution of STE by the latitudes where each isentropic surface intersects the tropopause. The specified dynamics version of the Whole Atmosphere Community Climate Model is used to estimate the STE ozone flux on each isentropic surface. It is found that net troposphere‐to‐stratosphere ozone transport occurs in low latitudes along the 350–380 K isentropic surfaces and that net stratosphere‐to‐troposphere ozone transport takes place in the extratropics along the 280–350 K isentropes. Particularly, the seasonal cycle of extratropical STE ozone flux in the Northern Hemisphere displays a maximum in late spring and early summer, following the seasonal migration of the upper tropospheric jet and associated isentropic mixing. Furthermore, differential diabatic heating and isentropic mixing tend to induce STE ozone fluxes in opposite directions, but the net effect results in a spatiotemporal pattern similar to the STE ozone flux associated with isentropic mixing.

Seasonal variation of phytoplankton nutrient limitation in Lake Taihu, China: A monthly study from Year 2011 to 2012

Lake Taihu is the third largest freshwater lake in China with severe eutrophication issues. However, it remains ambiguous how its phytoplankton growth is limited by various nutrients in different seasons. A series of bottle-enrichment assays in Meiliang Bay was thus performed once a month from July, 2011 to June, 2012 in the present study. The initial chlorophyll a concentration and phytoplankton cell density ranged from 4.70 to 34.6μg/l and from 1.25×106 to 6.72×108cells/l with three peaks in July, November, and March. Although Cyanophyta was dominant (30.9–99.2 percent) in most cases, other phyla like Chlorophyta, Bacillariophyta, and Cryptophyta could account for as much as 69.1 percent of total phytoplankton in cold seasons. The microcystin-LR content in the particulate phase followed a similar seasonal pattern as Cyanophyta. It further went up exponentially with the proportion of cyanobacteria in phytoplankton suggesting more toxigenic species and (or) upregulated microcystin synthesis when the contribution of Cyanophyta was enhanced. On the other hand, the dissolved concentrations of various nitrogen and phosphorus species reached their maxima in late spring and autumn, respectively. According to its growth response to nutrient addition, phytoplankton in Meiliang Bay was restricted by nitrogen in August, October, and November. No nutrient limitation occurred in July, September, and April, whereas phosphorus deficiency prevailed in the other months. Overall, nutrient limitation in Lake Taihu and possibly other aquatic ecosystems worldwide may be more dynamic than what we thought before, which should be considered to eliminate eutrophication.

Seasonality of the Pacific Decadal Oscillation

Abstract The seasonality of the Pacific decadal oscillation (PDO) is examined using North Pacific sea surface temperature (SST) in observations and in a 480-yr simulation with the National Centers for Environmental Prediction (NCEP) Climate Forecast System (CFS) coupled model. The PDO, both in observations and in the CFS, shows similar seasonality, with increasing SST variance during spring and a maximum in late spring and early summer. The vertical structure of the ocean temperature anomaly associated with the PDO in the CFS displays a significant transition from a deep to a shallow structure during late spring, consistent with the seasonal variation of the mean ocean mixed layer depth (MLD). An analysis of atmospheric surface wind and SST anomalies from the CFS simulation indicates that there is a 1-month delay in the PDO-related SST response to the atmospheric wind forcing. The results based on the CFS simulation are generally consistent with observations, including both atmospheric data from the NCEP/Department of Energy (DOE) Global Reanalysis 2 (GR-2) and ocean data from the NCEP Global Ocean Data Assimilation System (GODAS). The 1-month delay together with the seasonal variation of the mean MLD tends to amplify the PDO-related SST response to the atmospheric surface wind in late spring to early summer, and the combination leads to the maximum variability of the PDO, which is a 3-month delay from the peak phase of the surface wind in February and March.

Variations in surface ozone at Nainital: A high‐altitude site in the central Himalayas

Surface ozone measurements have been made for the first time at Nainital (29.37°N, 79.45°E, 1958 m amsl), a high‐altitude site in the central Himalayas, between October 2006 and December 2008. Diurnal variations in ozone do not show the daytime photochemical build‐up typical of urban or rural sites. The seasonal variation shows a distinct ozone maximum in late spring (May; 67.2 ± 14.2 ppbv) with values sometimes exceeding 100 ppbv and a minimum in the summer/monsoon season (August; 24.9 ± 8.4 ppbv). Springtime ozone values in the central Himalayas are significantly higher than those at another high‐altitude site (Mt. Abu) in the western part of India. Seasonal variations in ozone and the processes responsible for the springtime peak are studied using meteorological parameters, insolation, spatial and temporal classifications of air mass trajectories, fire counts, and simulations with a chemical transport model. Net ozone production over the Northern Indian Subcontinent in regionally polluted air masses is estimated to be 3.2 ppbv/day in spring but no clear build‐up is seen at other times of year. Annual average ozone values in regionally polluted air masses (47.1 ± 16.7 ppbv) and on high insolation days (46.8 ± 17.3 ppbv) are similar. Background ozone levels are estimated to be 30–35 ppbv. Regional pollution is shown to have maximum contribution (16.5 ppbv) to ozone levels during May–June and is about 7 ppbv on an annual basis, while the contribution of long‐range transport is greatest during January–March (8–11 ppbv). The modeled stratospheric ozone contribution is 2–16 ppbv. Both the trajectory analysis and the model suggest that the stratospheric contribution is 4–6 ppbv greater than the contribution from regional pollution. Differences in the seasonal variation of ozone over high‐altitude sites in the central Himalayas (Nainital) and western India (Mt. Abu) suggest diverse regional emission sources in India and highlight the large spatial and temporal variability in ozone over the Indian region.

Biomass variation and reproductive phenology of Gracilaria gracilis in a Patagonian natural bed (Chubut, Argentina)

The biomass variation and the reproduction of the natural Gracilaria gracilis bed in Bahia Bustamante (Patagonia, Argentina) were analyzed for 2 years, with the aim of determining the present situation of the population for an updated status overview; establishing the relevant features of the temporal variation in both biomass and reproductive states in relation to environmental factors, epiphytes and associated algae; and assessing carpospore availability for future spore-culture development. Field measurements and sampling were performed monthly between March 2006 and February 2008. In both years, G. gracilis biomass presented marked seasonal variations, with a minimum in winter and a maximum in late spring and in summer. During both years, coexistence of the three life-cycle phases was found, with dominance of tetrasporophytes. Two data sets from individuals originated from sexual reproduction (tetraspores and carpospores) and from asexual reproduction by thallus fragmentation were analyzed separately. In the fragmentation fraction, tetrasporophyte frequencies remained higher than those for gametophytes. However, in the spore-originated fraction, a generation ratio close to 0.5 was observed. Female gametophytes bearing cystocarps were always present, with a maximum in summer and autumn. Biological data were related to environmental factors by means of canonical correspondence analysis (CCA). The first year was characterized by higher biomass values of G. gracilis and Undaria pinnatifida, lower epiphytism, larger Gracilaria thalli and greater proportion of mature tetrasporophytes and gametophytes. The second year was characterized by a high proportion of Gracilaria vegetative thalli and high epiphyte density. The best time to obtain spores from cystocarpic thalli would be in summer and early autumn.

IASI observations of seasonal and day-to-day variations of tropospheric ozone over three highly populated areas of China: Beijing, Shanghai, and Hong Kong

Abstract. IASI observations of tropospheric ozone over the Beijing, Shanghai and Hong Kong areas during one year (2008) have been analysed, demonstrating the capability of space-borne infrared nadir measurements to probe seasonal and even day-to-day variations of lower tropospheric ozone (0–6 km partial columns) on the regional scale of highly populated areas. The monthly variations of lower tropospheric ozone retrieved from IASI clearly show the influence of the Asian summer monsoon that brings clean air masses from the Pacific during summer. They exhibit indeed a sharp ozone maximum in late spring and early summer (May–June) followed by a summer minimum. The time periods and the intensities of the maxima and of the decreases are latitude-dependent: they are more pronounced in Hong Kong and Shanghai than in Beijing. Moreover, IASI provides the opportunity to follow the spatial variations of ozone over the surroundings of each megacity as well as its daily variability. We show here that the large lower tropospheric ozone amounts (0–6 km partial columns) observed with IASI are mainly downwind the highest populated areas in each region, thus possibly suggesting the anthropogenic origin of the large ozone amounts observed. Finally, an analysis of the mean ozone profiles over each region – for selected days with high ozone events – in association with the analysis of the meteorological situation shows that the high ozone amounts observed during winter are likely related to descents of ozone-rich air from the stratosphere, whereas in spring and summer the tropospheric ozone is likely enhanced by photochemical production in polluted areas and/or in air masses from fire plumes.

On detecting a trend in the residual circulation from observations of column HCl

Ground‐based measurements show that the HCl column at middle latitudes varies seasonally with a late spring maximum and a minimum in late summer. HALOE measurements of HCl profiles show that this seasonal cycle in the column is controlled by the seasonal variations of the mass and composition of the lowermost stratosphere. The seasonal maxima are produced by wintertime downward transport of stratospheric air. We hypothesize that the amplitude of the seasonal cycle is quantitatively related to the strength of the stratospheric residual circulation and stratosphere‐troposphere exchange (STE). We investigate this relationship using a multi‐decadal simulation from the GSFC Chemistry and Transport Model driven by output from a general circulation model in which an STE trend exists. We also examine the ground‐based record of HCl measurements at Jungfraujoch for evidence of a trend in the HCl seasonal amplitude that would be a signature of a long‐term change in the stratospheric circulation.

Diversity and seasonal dynamics of Actinobacteria populations in four lakes in northeastern Germany.

The phylogenetic diversity and seasonal dynamics of freshwater Actinobacteria populations in four limnologically different lakes of the Mecklenburg-Brandenburg Lake District (northeastern Germany) were investigated. Fluorescence in situ hybridization was used to determine the seasonal abundances and dynamics of total Actinobacteria (probe HGC69a) and the three actinobacterial subclusters acI, acI-A, and acI-B (probes AcI-852, AcI-840-1, and AcI-840-2). Seasonal means of total Actinobacteria abundances in the epilimnia of the lakes varied from 13 to 36%, with maximum values of 30 to 58%, of all DAPI (4',6'-diamidino-2-phenylindole)-stained cells. Around 80% of total Actinobacteria belonged to the acI cluster. The two subclusters acI-A and acI-B accounted for 60 to 91% of the acI cluster and showed seasonal means of 49% (acI-B) and 23% (acI-A) in relation to the acI cluster. Total Actinobacteria and members of the clusters acI and acI-B showed distinct seasonal changes in their absolute abundances, with maxima in late spring and fall/winter. In eight clone libraries constructed from the lakes, a total of 76 actinobacterial 16S rRNA gene sequences were identified from a total of 177 clones. The majority of the Actinobacteria sequences belonged to the acI and acIV cluster. Several new clusters and subclusters were found (acSTL, scB1-4, and acIVA-D). The majority of all obtained 16S rRNA gene sequences are distinct from those of already-cultured freshwater Actinobacteria.

Phytoplankton Assemblages and Their Dominant Pigments in the Nervion River Estuary

In the Nervion River estuary surface samples were taken from March to September 2003 at six sites covering most of the salinity range with the aim to know the biomass and taxonomic composition of phytoplankton assemblages in the different segments. Nine groups of algae including cyanobacteria, diatoms, dinoflagellates, chlorophytes, prasinophytes, euglenophytes, chrysophytes, haptophytes, raphidophytes and cryptophytes were identified by means of a combination of pigment analysis by high-performance liquid chromatography (HPLC) and microscopic observations of live and preserved cells. Diatoms, chlorophytes and cryptophytes were the most abundant algae in terms of cells number, whereas fucoxanthin, peridinin, chlorophyll b (Chl b) and alloxanthin were the most abundant auxiliary pigments. Based on multiple regression analysis, in the outer estuary (stations 0, 1, 2 and 3) about 93% of the chlorophyll a (Chl a) could be explained by algae containing fucoxanthin and by algae containing Chl b, whereas in the rest of the estuary most of the Chl a (about 98%) was accounted for by fucoxanthin, Chl b and alloxanthin containing algae. The study period coincided with that of most active phytoplankton growth in the estuary and fucoxanthin was by far the dominant among those signature pigments. Several diatoms, chrysophytes, haptophytes and raphydophytes were responsible for fucoxanthin among identified species. Besides, dinoflagellates with a pigment pattern corresponding to chrysophytes and type 4 haptophytes were identified among fucoxanthin-bearing algae. Cryptophytes were the most abundant species among those containing alloxanthin. The maximum of Chl b registered at the seaward end in April coincided with a bloom of the prasinophytes Cymbomonas tetramitiformis, whereas the Chl b maxima in late spring and summer were accounted for by prasinophytes in the middle and outer estuary and by several species of chlorophytes in the middle and inner estuary. Other Chl b containing algae were euglenophytes and the dinoflagellate Peridinium chlorophorum. Dinoflagellates constituted generally a minor component of the phytoplankton.

Simulation of the mineral dust emission frequencies from desert areas of China and Mongolia using an aerodynamic roughness length map derived from the POLDER/ADEOS 1 surface products

To determine the location of the potential dust source regions and to evaluate the dust emission frequencies over the arid and semiarid areas of China and Mongolia (35.5°N–47°N; 73°E–125°E), we established a map of Z0 from the composition of protrusion coefficient (PC) derived from the POLDER‐1 bidirectional reflectance distribution function (BRDF). Using a ° × ° resolution Z0 data set, we derived a map of the 10‐m erosion threshold wind velocity for the Chinese and Mongolian deserts. The retrieved erosion thresholds range from 7 m s−1 in the sandy deserts (Taklimakan, Badain Jaran, and Tengger deserts) to up to 20 m s−1 in the Gobi desert. They are comparable to the minimum wind velocity measured in meteorological stations during dust storms in the Taklimakan (6–8 m s−1) and in the Gobi desert (11–20 m s−1). These erosion thresholds were combined with surface wind fields, soil moisture, and snow cover to simulate the dust emission frequencies of the eastern Asian deserts over 3 years (1997–1999). The simulations point out the Taklimakan desert and the deserts of northern China as the most frequent sources of dust emissions. The simulated seasonal cycle is characterized by a maximum in late spring and a minimum in late autumn and winter. The comparison with climatologic studies of dust storms derived from synoptic observations confirms the importance of these two source areas and the reliability of the simulated seasonal cycle. It reveals an underestimation of the dust emission frequency in the Gobi desert, because of a low frequency of high wind velocities. Our results also suggest that soil moisture and snow cover are not the main factors controlling the seasonal cycle or the interannual variability of the dust emission frequencies. We finally compared the simulated dust event frequencies to occurrences of Total Ozone Mapping Spectrometer (TOMS) Absorbing Aerosol Index (AAI) higher than 0.7 over the Taklimakan desert, where mineral dust is expected to be the dominant absorbing aerosol. A very good agreement is obtained between the simulated frequencies and the TOMS AAI frequencies on monthly and seasonal timescales.

Effects of biogenic silica dissolution on silicon cycling and export production

Biogenic silica (bSiO2) dissolution plays an important role in the marine silicon cycle, diatom production and vertical export production. An ocean ecosystem model that incorporates dependency of bSiO2 dissolution on water temperature was used to examine the effects of bSiO2 dissolution on diatom production and bSiO2 export. Diatoms dominate with higher bSiO2 dissolution rates because of enhanced silicic acid supply for diatom production. Annual bSiO2 export does not change with bSiO2 dissolution rate, because of less bSiO2 production with lower rates and greater bSiO2 dissolution with higher rates. The ratio of bSiO2 export to production changes seasonally, with maximum in late spring. The contribution of spring diatom bloom to the annual bSiO2 export is 21–30%, smaller than observation‐based estimates. This suggests necessity for incorporating other factors controlling bSiO2 dissolution besides water temperature, such as difference in organic coating protections against bSiO2 dissolution between live and dead diatoms, in the model.

Organic nitrogen in precipitation across the United Kingdom

The concentration of water-soluble organic nitrogen (WSON) in precipitation has been measured at seven sites across the United Kingdom, over a period of 1–2 years, using protocols developed in a pilot study. Samples were collected over 1–2 weeks in continuously open funnels made of stainless steel, draining to a glass bottle, and were preserved during and after collection by the addition of thymol. After chemical analysis, samples were excluded from the long-term average if they showed signs of contamination (significant concentrations of K+ or PO43−). Two methods of measuring total dissolved N were used, persulphate oxidation and high-temperature chemiluminescence. The latter generally gave the larger values, and has been used to asses the organic component of dissolved N. The long-term data set confirms the original results from the pilot study - organic N contributes between 24 and 40% to the total annual wet deposition of dissolved N across the United Kingdom. The fraction of WSON was greatest at western sites, and was strongly correlated with ammonium concentrations. However, the seasonal pattern across all sites showed a late spring maximum for ammonium and nitrate, but a late summer maximum for WSON. The magnitude of the contribution of WSON to wet-deposited N has implications for the setting and assessment of critical loads for N deposition.

Linkages between Regional Trends in Monthly Maximum Flows and Selected Climatic Variables

The potential impact of climate change on the hydrologic regime is a crucial question for water resources management. This study explores regional trends in monthly maximum flows and their possible linkages to trends in selected climatic variables in a hydroclimatologically homogeneous region. Trends are identified using the Mann-Kendall nonparametric test, with a modification for autocorrelated data. The regional significance of trends identified at the local scale is evaluated by means of a regional bootstrap algorithm. A trend significance index that accounts for both local and regional significance levels is proposed as a convenient tool for quantification and visual comparison of different trend results. The index is also used for identifying potential linkages between trends in hydroclimatic records. The plausibility of identified linkages is explored by means of cross-correlation analysis applied on residuals that are obtained from the original records after subtracting all serially dependent components. An uncertainty in regional trend analysis resulting from different observation periods is presented and quantified by calculating trend significance indices for several scenarios of different locations and lengths of a common observation period shifted on a timescale. The results show significant changes in the intraannual flood regime in the case study area of southern British Columbia. A regionally, strongly significant increase in the spring air temperature shifts the timing of the snowmelt process, resulting in a significant increase in early spring maximum flows and a significant decrease in late spring maximum flows. An autumn decrease in flows is related to increasing air temperature in the preceding summer months, which tends to dry out catchments more intensively, and is also related to precipitation activity in the previous months. The regional trend results are highly sensitive to the location and length of a given regional observation period on a timescale. Possible sources of the uncertainty in a low frequency climatic variability such as the Pacific Decadal Oscillation are discussed.

Lagrangian estimate of global stratosphere‐troposphere mass exchange

Seasonal variations of the mass flux between the stratosphere and troposphere are investigated using a Lagrangian framework. Monthly three‐dimensional trajectories are calculated for 1996 and 1997 from the United Kingdom Meteorological Office assimilated data. Mass exchange shows nearly the same annual variations as previous Eulerian studies: (1) the northern net downward flux across the extratropical tropopause shows a primary maximum in late spring and early summer and secondary in winter, which is consistent with observational measurements, (2) the southern net downward flux has a peak only in winter, and (3) the extratropical and tropical air exchange across the upper boundary of the middleworld exhibits a pronounced annual variation with a wintertime maximum and summertime minimum. The occurrence of the largest downward flux over the western edges of the Pacific and Atlantic and near the Mediterranean suggests that tropopause folding and baroclinic disturbances in midlatitude storm tracks are the primary agent for the intrusion of stratospheric air into the troposphere. Tropical upward transport occurs in association with the monsoon anticyclones, and the greatest diabatic injection into the tropical stratosphere takes place over the summer hemisphere subtropics according to the seasonal variation of the Hadley circulation. Comparison of the Lagrangian flux estimate across the 100‐hPa surface with the estimate by the downward control mechanism using the residual mean meridional circulation shows reasonable correspondence.