Laser Surface Melting Research Articles

Effect of laser surface melting on microstructure and hardness of Mg–4Y–2Zn–1Zr-0.6Ca alloy

To improve the performance of magnesium and enhance its mechanical properties and microstructure, a laboratory-scale Mg alloy with the composition Mg–4Y–2Zn–1Zr-0.6Ca was developed. Subsequently, the alloy was subjected to homogenization and extrusion processes to reduce casting defects and the microstructure refinement. Additionally, surface modification was performed using a pulsed Nd:YAG laser. The findings of the experiment indicate that by controlling the laser processing parameters, it was possible to attain a microstructure devoid of any defects. Moreover, an examination of the microstructure and secondary phases was conducted through the utilization of characterization techniques such as the Optical Microscope (OM), Field Emission Scanning Electron Microscope (FESEM) equipped with Energy Dispersive Spectroscopy (EDS), and X-ray Diffraction (XRD). Furthermore, the micro hardness of the samples was evaluated using the Vickers micro hardness testing method. Consequently, the microstructures of all specimens exhibited equiaxed grains, predominantly composed of (α-Mg), (Mg24Y5+α-Zr), and the W-phase (Mg3Y2Zn3). In addition, the laser-melted surface revealed a noteworthy refinement of the grain structure, with an evolution in grain morphology from the top to the bottom of the melted area. Equiaxed grains were present in the centerline, whereas columnar grains were observed in the fusion line. Additionally, as the scanning speed increased, a finer microstructure was observed. Due to the rapid heating and cooling involved in the laser surface melting (LSM) process, the secondary phase (Mg3Y2Zn3) dissolved in the microstructure, and the (Mg24Y5+α-Zr) phase was uniformly distributed throughout the LSMed area. Ultimately, the micro hardness showed a significant increase due to the dual influence of grain refinement and the homogeneous dispersion of the secondary phase.

Level-Set Method Based Predictive Modeling to Track the Evolution of Surface During Pulsed Laser Surface Melting

Abstract The objective of this study is to investigate the evolution of surface geometry during pulsed laser surface melting (pLSM) via level-set method-based interface tracking numerical framework. Existing models to track surface geometry are inaccurate and computationally expensive. Therefore, they have limited use in gaining understanding of the surface evolution during pLSM. A numerical model, integrating the level-set approach, fluid flow, and heat transfer dynamics, is detailed in this paper. The multi-phase numerical model achieves accurate tracking of interface for a single pulse by implementing the volumetric laser heat source on the moving interface by modifying Beer–Lambert's law. The accuracy of the single pulse model is confirmed by comparing its peak-to-valley height (PVH) to the experimental data. The deviation in PVH is limited to about 15%, with a maximum root mean square error of ∼0.24 µm, highlighting the model's reliability. Additionally, the evolved surface of a single pulse from the model is replicated over an area with dedicated overlaps to generate the predicted textured surface with reasonable accuracy. Some inaccuracies in the predicted surface roughness values were observed because the textures were generated based on a single pulse geometry computed on an initially flat surface. Nonetheless, the results highlight a significant development in numerical frameworks for pLSM and can be used as a tool to gain deeper insights into the process and for process optimization.

Effect of laser surface melting on superficial morphology and properties of the electrochemical polishing Ti6Al4V alloy

Effect of laser surface melting on superficial morphology and properties of the electrochemical polishing Ti6Al4V alloy

تأثير استعمال ليزر النيوديميوم ياك (Nd-YAG) على البنية الدقيقة وصلابة سطح الفولاذ AISI1012

The unique characteristics of the laser beam such as directionality, monochromaticity, and brightness make it a very important tool in the surface treatment engineering. The concentrated heat in the laser beam can be precisely directed toward the processed region on the surface. The laser beam power, beam size, and scanning velocity are easily controlled during the different processing methods. Laser surface modifications of metallic materials, such as laser surface melting, laser surface alloying, and laser cladding are some of the most important methods to improve the mechanical properties of the processed layer on the surface. A pulsed Nd-YAG laser surface melted specimens of low carbon steel with a maximum power of 90W at different processing parameters. The rapid melt and solidification of the treated layer produced a refinement in the microstructure. The original microstructure of this steel (Ferrite + Pearlite) has been transformed to new phases of martensitic and bainitic structures. The melted layer consists of the melted pool, the heat affected zone, and the substrate. The maximum hardness of the laser melted layer is more than 400 HV. The effect of different lasers such as high power CW CO2 laser on the mechanical properties and corrosion resistance of steel alloys will be carried out in future studies. Keywords: Nd-Yag Laser, Laser surface treatment, Microstructure and hardness of AISI1012 steel

Beyond symmetry: Investigating asymmetric melt pool evolution in multi-pulse laser surface melting

A numerical investigation is carried out to explore the intricacies of multi-pulse pulsed laser surface melting (pLSM) to understand its impact on surface evolution. A finite-element-based multi-phase model with temperature-dependent properties is employed to track the interface for multiple laser pulses. Examining various overlap spacings and conducting a comparative analysis of the number of pulses, the study focuses on the exclusive influence of overlapping in surface texture generation. Notably, the assumption of an initially flat surface eliminates the effects of the initial surface roughness to provide unique insights completely based on multi-pulse dynamics. While the first pulse on a flat initial surface resulted in a symmetric surface evolution, asymmetric melt pools were observed in the second pulse and subsequent pulses. The asymmetry results from non-uniform cooling and melt pool flows influenced by the surface evolved in the first pulse. The topography-driven surface tension from the first pulse made the trailing peak solidify slower than the leading peak. The asymmetry was significant for smaller overlaps between the two pulses and reduced as the overlap increased. Further, an increase in the number of laser pulses promotes the generation of identical asymmetric surface features. In conclusion, the study demonstrates the importance of the developed model in accurately predicting the surface evolution influenced by topography-driven surface tension and that single pulse axisymmetric models are insufficient.

The impact of LSM pretreatment on the growth behavior, electrical insulation and corrosion resistance properties of PEO coating on 6061 aluminum alloy

This work reported the influence of laser surface melting (LSM) pretreatment on the growth behavior, electrical insulation and corrosion resistance of plasma electrolytic oxidation (PEO) film on 6061 aluminum alloy. It is found that the LSM pretreatment refines the surface structure of original Al metal, generating defects that store excessive energy, thereby enhancing reaction kinetics and phase transition during the PEO process. By LSM pretreatment, uniform electrical discharge and film growth can be obtained, resulting in fewer defects and lower porosity in PEO layers. Additionally, a large amount of columnar crystals comprising of SiO2 phase are observed, which transformed from the SiO32− deposited on the surface, and the LSM pretreatment significantly improves the electrical insulation, corrosion resistance, and substrate adhesion of following PEO layer. Under the same PEO treatment duration, the breakdown voltage of coating increased by 100 V, and icorr decreased from 3.26 × 10−4 to 9.13 × 10−6 A cm−2. It is expected that the combination of LSM and PEO processes can not only enhance the surface properties of Al metal, but also expand the practical application of aluminum alloy in high-power electronic devices and related fields.

Enhancing Bactericidal Properties of Ti6Al4V Surfaces through Micro and Nano Hierarchical Laser Texturing.

Orthopedic and dental implants made from Ti6Al4V are widely used due to their excellent mechanical properties and biocompatibility. However, the long-term performance of these implants can be compromised by bacterial infections. This study explores the development of hierarchically textured surfaces with enhanced bactericidal properties to address such challenges. Hierarchical surface structures were developed by combining microscale features produced by a microsecond laser and superimposed submicron features produced using a femtosecond laser. Microscale patterns were produced by the pulsed laser surface melting process, whereas submicrometer laser-induced periodic surface structures were created on top of them by femtosecond laser processing. Escherichia coli bacterial cells were cultured on the textured surface. After 24 h, a staining analysis was performed using SYTO9 and PI dyes to investigate the samples with a confocal microscope for live dead assays. Results showed bacterial colony formation onto the microscale surface textures with live bacterial cells, whereas the hierarchical surface textures display segregated and physically damaged bacterial cell attachments on surfaces. The hierarchical surface textures showed ∼98% dead bacterial cells due to the combined effect of its multiscale surface features and oxide formation during the laser processing steps. The efficacy of hierarchical surface textures in enhancing the antibacterial behavior of Ti6Al4V implants is evident from the conducted research. Such laser-based surface treatments can find potential applications in different industrial sectors.

The effect of laser surface melting on the microstructure, microsegregation and solidification path of service-aged ECY768 cobalt-based gas turbine nozzle

In this study, the laser surface melting of cobalt-based superalloy ECY768, which has been in service for 40,000 h at a temperature of 1000 °C, has been investigated. Subsequently, laser surface welding and post-welding heat treatment is performed on the samples. This study was conducted in order to restore the microstructure of the damaged service-aged gas turbine nozzle to as-cast state. The results showed that by performing laser surface remelting, the microstructure of as-cast state can be approached. Also, the results of this study have investigated the weldability, microsegregation and solidification path of this superalloy, and it can be used in the repairing this superalloy in the industry. Laser surface melting was performed using a continuous wave fiber laser at various speeds of 10, 12, 14, 20, 50, and 70 mm/s. The microstructure and phase characteristics of the samples were examined using optical and scanning electron microscopes. Upon analyzing the macrostructure of the weld metal, it was observed that the depth of the melt zone at the speed of 12 mm/s is 585 ± 40 μm. In the investigating the microstructure of the solidification modes, namely planar, cellular, columnar dendritic, and equiaxed dendritic, it was observed that microsegregation occurs during laser welding of the samples due to the presence of heavy elements such as tantalum and tungsten. The solidification distribution coefficient for tantalum was calculated to be 0.37, which increased to 0.60 after the solution annealing heat treatment, resulting in an improved segregation behavior. Characterizing the surface hardness profiles of laser-melted samples it was observed that the hardness in the melt zone significantly increased compared to the base metal. The results of the current research indicate that the weldability (resistance to various welding defects, especially hot cracks) of the cobalt-based superalloy ECY768 is acceptable, and this process can be used for rejuvenating service-aged ECY768 cobalt-based gas turbine nozzle.

Influence of discrete laser surface melting on hot cracking behavior and mechanical properties of Q235 steel

Modern industries demand higher mechanical properties from components. Traditional heat treatment methods often suffer from drawbacks such as high production costs, time-intensive processes, and labor-intensive procedures. The integration of bionic engineering with laser surface melting has given rise to Discrete Laser Surface Melting (DLSM) technology, effectively mitigating these shortcomings. Previous research has substantiated the capability of this technology to significantly enhance various metal properties. This study employed an Nd:YAG pulsed laser for the DLSM treatment of Q235 steel. The discrete laser surface melted (DLSMed) units were prepared on Q235 steel samples. Subsequent analysis utilized scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy-dispersive spectroscopy (EDS) to examine the microstructure and chemical composition of the DLSMed samples. Surface profilometry, hardness testing, and X-ray stress testing were conducted to measure surface roughness, microhardness, and residual stress, respectively. Mechanical properties were evaluated using tensile and impact testing machines. Experimental findings revealed that the DLSMed sample's surface could be divided into three regions: the melting zone, the heat-affected zone (HAZ), and the substrate. The microstructure of the melting zone consisted of refined martensite. The depth and width of the DLSMed units exhibited a certain regularity with variations in the defocus distance. Increasing the defocus distance positively impacted grain refinement and hardness but also led to an increase in surface roughness. Residual stress increased within a specific defocusing range, but beyond this range, its variation lost regularity. Hot cracking behavior within the DLSMed unit encompassed four stages: crack nucleation, propagation, healing, and decomposition. Different defocusing distances and the distribution of DLSMed units significantly affected the tensile strength and impact toughness of the samples. As the defocusing distance increased, the tensile and yield strength of DLSMed samples with transverse units gradually decreased. In contrast, samples with longitudinal units showed a trend of first decreasing and then increasing in tensile and yield strength. The distribution of DLSMed units played a significant role in improving the tensile properties of Q235 steel. The contribution of three factors to the impact performance of DLSMed samples was ranked from high to low as hardness, grain size, and yield strength ratio. The soft phase (substrate) could absorb impact energy and convert it into strain energy stored in the DLSMed sample. Only when the distribution of DLSMed units (hard phases) aligned with the tensile direction could they effectively limit the plastic deformation and enhance the mechanical properties of Q235 steel. However, an increase in defocusing distance led to increased brittleness, deteriorating the mechanical properties of the DLSMed samples. Finally, this study unveiled the strengthening mechanisms of DLSMed samples, providing valuable insights for future applications in enhancing the mechanical properties of metals.

Microstructure evolution and grain growth characteristics of IN625 in laser surface melting: Effects of laser power and scanning speed

This study investigated the effects of laser power and scanning speed on the microstructure evolution and grain growth characteristics of IN625 in laser surface melting. Laser powers of 400 W, 600 W and 800 W at scanning speeds from 200 mm/min to 800 mm/min were employed to melt the surface of as-cast IN625 using a continuous Yb-doped fibre laser. The microstructure from the surface to the melt pool boundary was characterised by scanning electron microscopy (SEM) and electron backscattered diffraction (EBSD). It was shown that a cellular structure was developed at low energy densities (≤ 240 J/mm2), since low energy densities resulted in more rapid solidification. A coarse grain region was found near the surface after melting and a columnar grain growth region was formed close to the melt pool boundary at increasing laser power. Large angle grain boundaries were eliminated and medium angle grain boundaries exhibited an area fraction of 90 % after laser surface melting. This was due to the fact that the twinned grains were fully melted in the melt pool and no twins were formed after solidification. An analytical approach was proposed to the estimate the melt pool depth and good agreement between experimental and calculated melt pool depth was obtained at laser power of 400 W and 600 W.

Influence of discrete laser surface melting on scuffing resistance of W6Mo5Cr4V2 steel gear

The gear transmission system is advancing towards high-speed and heavy-duty applications. Among the main failure modes of the system, tooth surface scuffing due to increased tooth surface temperature has emerged as a prominent concern in mechanical transmission. Addressing the enhancement of gear scuffing resistance has thus become an urgent challenge in this field. This paper utilized discrete laser surface melting (DLSM) treatment to create discrete laser surface melted (DLSMed) units on the surface of W6Mo5Cr4V2 steel gears, resembling the radial ribs found on the surface of Limaria basilica. The paper investigated the size, hardness, residual austenite content, and residual stress of the DLSMed units at varying current intensities and laser frequencies. Microstructural observations were conducted on the DLSMed units, followed by gear scuffing experiments performed on the Forschungsstelle für Zahnräder und Getriebebau (FZG) testing machine. The experimental findings revealed that the change in laser frequency had a clearly weaker impact on the size of the DLSMed unit compared to current intensity. The DLSMed unit consisted of two parts: the melting zone (MZ) and the heat-affected zone (HAZ), with equiaxed and dendritic microstructures, respectively. Both zones exhibited refinement with increasing current intensity and laser frequency. Moreover, the microhardness of the DLSMed unit showed significant improvement compared to that of as-received gears. The scuffing resistance of DLSMed gears was found to be closely linked to their initial surface roughness. Residual stress formation in DLSMed gears was attributed to thermal stress and microstructural stress. The distribution pattern of DLSMed units had varying effects on the scuffing load-carrying capacity of DLSMed gears. Specifically, DLSMed gears with transverse distribution of DLSMed units demonstrated a 12.5% improvement in anti-scuffing performance compared to those with longitudinal distribution. Finally, this paper elucidated the mechanism through which DLSM enhances the scuffing resistance of W6Mo5Cr4V2 steel gears.

A comparative study of laser fluence effect on surface modification and hardness profile of austempered ductile iron

The impact of laser transformation hardening (LSH) and Laser surface melting (LSM) on an austempered ductile iron (ADI) alloy was investigated. Various laser fluences (J mm−2) were irradiated on the ADI specimens, obtained by different beam powers and scanning speeds to reach the optimum parameters to attain a surface with a good combination of high hardness and deep hardened depth, together with obtaining minimal distortion and crack-free surface. ADI surfaces were treated by means of high-power Nd:YAG laser in continuous wave mode. A detailed investigation of the obtained microstructure was characterized via optical and scanning electron microscopy attached to an EDX analyzer as well as X-ray diffraction analysis. Such a wide laser fluence range has a considerable effect on the achieved microstructure. A process parameter map was established which indicated that three different laser treatments were induced under such values of laser fluences: a laser transformation hardening, a partial laser melting, and a complete laser melting. The results revealed that to produce a hardened microstructure, specimens have to be operated within a very small range of laser fluence from 9.6 up to 29 J mm−2, achieving surface hardness values around 900 HV0.1 and depths of approximately 184–700 μm, respectively. Meanwhile, partial melting of the treated layer took place at a medium energy density range from 37 to 112 J mm−2, by a further increase in laser fluence (120–360 J mm−2), complete melting occurred which resulted in a deeper treated layer that reached 3.5 mm with an increase in microhardness value to almost 1100 HV0.1 at 360 J mm−2. The obtained microstructure in case of low laser fluence consisted of an austenite dendritic structure with undissolved graphite nodules, however, at medium and high laser fluence, the microstructure contains large cementite plates, iron-silicon carbides, a small area of ledeburite structure, and some retained austenite. The quantitative amounts of such phases directly depend on the applied laser fluence. Such phases were identified by means of EDX analysis.

Data Sets Formation on the Physical Properties of Oxide Scale Components for Theoretical Assessment of Efficiency Parameters of Laser Cleaning of Carbon Steels and Related Processes

There is a need in machine-building industries nowadays to automate technologies, in particular, laser ones, to remove surface oxide layers – mill scale, rust – from steel products/pieces in order to improve the energy effectiveness of processing. Herewith, a theoretical assessment method for the intensity of heating of the oxide layer and the phase transition in it can be used to optimize laser cleaning (LC) of the steel surface. To realize this, it is possible to use some calculation and modeling procedures that require, as a first step, the data collection and verification on the temperature-dependent properties of iron-containing condensed phases, as possible components contained, in particular, in scale, which is typically widespread into various metal products. In this regard, the formation of database for characteristics of oxide scale components by the way of selection of information on thermophysical (including optical) properties of the components mentioned and of steel base, which are required for a reliable calculation of the thermal efficiency parameters of the technology for laser cleaning of carbon steels, as well as such actively developed related technologies as laser cutting, drilling, coating remelting, etc., was chosen as the task of our research. An analytical overview of published experimental data made it possible to systematize information on a number of transport and other physical properties of iron-containing components at ambient pressure, including thermal conductivity (k) and diffusivity (a), density ρ, irradiation absorptance and integral emissivity in the temperature range from T ≈ 298 K to the melting temperatures of oxide and metal phases and above them. At the same time, a preliminary thermochemical estimation shows (on the calculated data) the existence of such thermodynamically stable forms of the condensed phase in the heating spot of scale layers during its LC at the melting point and above it, as Fe3O4, FeO, and Fe, which is consistent with known experimental data. Comparison of the values of a calculated by us (using the published values of k, ρ and molar heat capacity and using extrapolation in the high-temperature region) for the types of scale components under consideration with a set of experimental values of this parameter in current literature revealed the presence of differences for both oxide and metal phases. These new values make it possible to fill in a gap in the temperature range T = 1600–1800 K that existed in the data on the thermal diffusivity. The value of a = (0.83–0.92)·10–6 m2/s was also calculated for liquid iron oxide for the T ≈ 1800 K, which was not measured experimentally, that, obviously, prevented modeling of not only laser surface processing, melting and cleaning of steels, but also calculations in the field of metallurgical and other technologies, which are characterized by the presence of iron oxide melts during heating.

Comparison of the Erosive Wear Resistance of Ductile Cast Iron Following Laser Surface Melting and Alloying

This article presents research results on the influence of the laser surface melting and alloying processes on the erosive wear resistance of ductile cast iron. For the research, an EN-GJS 350-22 ductile cast iron surface was laser-melted and laser-alloyed with titanium powder in an argon and nitrogen atmosphere. Solid-particle erosion tests were carried out on the laser-melted and -alloyed surface layers and the base material according to the ASTM G76-04 standard with 30° and 90° impingement angles. The erosive wear resistance results were correlated with Vickers hardness and microstructural test results with the use of SEM (scanning electron microscopy), TEM (transmission electron microscopy), EDS (energy dispersive spectroscopy), and XRD (X-ray diffraction). The mechanisms of erosive wear were also analyzed for the laser-treated surface layers and the base material. The research showed that the laser melting and alloying processes with titanium powder had a positive effect on the hardness and erosive wear resistance of the ductile cast iron surface due to microstructure modification. Moreover, despite the lower hardness of the laser-alloyed surface layers, their composite microstructure had a positive impact on the erosive wear resistance in comparison to the laser-melted surface layers.

Effects of Different Oxidation Methods on the Wetting and Diffusion Characteristics of a High-Alumina Glass Sealant on 304 Stainless Steel.

Glass-to-metal seals are a very important element in the construction of vacuum tubes, electric discharge tubes, pressure-tight glass windows in metal cases, and metal or ceramic packages of electronic components. This paper presents the influence of different pretreatment methods on the high-temperature wettability of 304 stainless steel by high-alumina glass sealing. The pretreatment of the steel included laser surface melting and pre-oxidizing. The bonding characteristics of glass and stainless steel directly depend on the wettability in terms of the measured wetting angle, the type of oxide formed at the stainless steel surface, and the microstructural changes during the manufacturing process. The oxide film thickness on the stainless steel surface was evaluated to determine the optimal parameters. The film was wetted with high-alumina glass powder at different temperatures. The results showed that pre-oxidation decreased the wetting angle from 56.2° to 33.6°, while for the laser-melted surface, the wetting angle decreased from 49.8° to 31.5°. Scanning electron microscopy (SEM) revealed that the oxide film on the laser-melted surface was thicker and denser than that formed on the pre-oxidized surface. The present work shows that laser surface melting has a greater beneficial influence on the wetting and diffusion characteristics of 304 stainless steel sealed by high-alumina glass.

The effect of shot peening on the contact fatigue performance of C40 steel gears after laser surface melting

In this paper, shot peening (SP) was employed as a post-processing technique for the laser surface melted (LSMed) gear. The aim was to improve the contact fatigue performance of laser surface melting+shot peened (LSMSPed) gears. The microstructure, surface roughness, residual stress, microhardness of C40 steel gears before and after SP treatment were characterized using scanning electron microscopy, x-ray diffraction stress analyzer, contour measuring instrument, and hardness tester. Fatigue test of gear was carried out with a Forschungsstelle für Zahnräder und Getriebebau (FZG) testing machine. Following the laser surface melting (LSM) treatment, a molten layer was observed on the gear teeth surface. The experimental results indicated that SP induced a hardened layer with a certain thickness and plastic deformation on the surface of LSMed gears. Importantly, as the SP parameters increased, there’s a corresponding reduction in both the average grain diameter and the maximum grain diameter. The reduction was most pronounced when the shot diameter reached its maximum value. It’s worth noting that once the optimal threshold for SP parameters is surpassed, the residual compressive stress and microhardness on the LSMSPed gear surface do not exhibit a continuous growth trend. Furthermore, the rise in SP parameters resulted in a gradual increase in the surface roughness of LSMSPed gears, albeit to varying degrees. In light of the combined effects of grain refinement, residual compressive stress, microhardness, and surface roughness, the contact fatigue performance of LSMSPed gears improved with increasing SP parameters. Notably, when comparing the contact fatigue life of LSMed gears with that of LSMSPed gears, we observed a substantial enhancement. However, it’s essential to highlight that when the shot diameter reaches its maximum value, the contact fatigue life of the LSMSPed gear, somewhat unexpectedly, decreased. It emphasized to a certain extent the influence of surface roughness on the contact fatigue performance of LSMSP gears.

Effects of heat treatment on the nano-indentation, corrosion and cavitation erosion behavior of 17-4PH stainless steel by laser surface melting

The effects of heat treatment on the microstructure, residual stresses, nano-indentation behavior, the resistance to the corrosion and cavitation erosion (CE) of 17-4PH stainless steel (17-4PH SS) by laser surface melting (LSM) were thoroughly investigated. Experimental results showed that the samples were mainly composed of martensite phase, and the NbC precipitations formed after heat treatment. The distribution of NbC precipitations was more uniform in the sample (S3) after solution treatment 3 h at 1040 °C + aging treatment 3 h at 480 °C. The grain size was increased for the samples after heat treatment. This heat treatment processing significantly reduced the residual stresses generated from the LSM process, and the nano-indentation behavior of the LSM samples after heat treatment was improved compared to that of the LSM sample without heat treatment. The S3 sample displayed the highest corrosion resistance as indicated by the low corrosion current density (icorr), high pitting potential (Epit) and high polarization resistance (Rp). The CE resistance of samples after heat treatment in 3.5 wt% NaCl solution was higher than that of the sample without heat treatment. Among them, the S3 sample exhibited the highest CE resistance, and its CE mass loss was only 59.5 % of the sample without heat treatment. The excellent CE resistance resulted from the appropriate combination of mechanical properties, corrosion resistance and self-recovery ability of the passivation film.

Comparison of the corrosion and cavitation erosion behaviors of the cast and surface-modified manganese-aluminum bronzes in sodium chloride solution

Modified layers with refined and homogenized microstructure were obtained on a cast manganese aluminum bronze (MAB) by friction stir processing (FSP) and laser surface melting (LSM). In 3.5% NaCl solution, a much more protective film was formed and uniform corrosion occurred for the two surface-modified MABs. The corrosion rate of the cast sample was reduced by a factor of 29.73% after FSP and 51.35% after LSM. The cavitation erosion (CE) rate of the cast MAB was about 1.83 and 3.07 times larger than that of the FSP and LSM samples, respectively. The CE resistance increment was highly attributed to the improved hardness and enhanced nano-indentation behavior after FSP or LSM. For each MAB, the CE resistance decreased with extended pre-immersion time. Compared with the result of the correspondingly freshly-prepared sample, the CE rate was raised by a factor of 36.22%, 42.97% and 44.00% after 30 days’ pre-immersion for the cast, FSP and LSM MABs, respectively. For the cast and FSP MABs, mechanical impact was the leading factor accounting for CE degradation. For the pre-corroded samples, corrosion damage at the β and κ phases weakened the mechanical properties and thus triggered more grievous material exfoliation under CE. For the LSM MAB, CE-corrosion synergy dominantly gave rise to the CE damage. Corrosion at grain boundaries after pre-immersion also deteriorated the CE performance. The LSM MAB possessed the highest corrosion and CE resistances because the fine single-phase microstructure reduced the galvanic corrosion effect and crack propagation tendency under CE impact.

Microstructural and electrochemical behaviour of severely surface-deformed 316L steel manufactured by conventional and selective laser melting routes

This study thoroughly examines the influence of conventional and selective laser melting (SLM) routes and surface mechanical attrition treatment (SMAT) on the microstructural and electrochemical properties of 316L steel. Compared to wrought specimens, the SLM specimens exhibit significantly smaller grains (∼41 vs. ∼83 µm) and higher dislocation density (∼7.2 × 1013 vs. ∼3.7 × 1012 m−2). Both specimens show nearly doubled surface hardness after SMAT, with the SLM surface displaying a ∼30 nm grain size and minimal α’ phase. The microstructure significantly influences passivation and corrosion behaviour. The SLM specimens exhibit superior electrochemical characteristics to wrought counterparts in SMATed (0.00299 mmpy) and non-SMATed (0.00771 mmpy) conditions. SMAT effectively eliminates surface porosity, enhancing the passivation and corrosion resistance of SLM steel.

Microstructure, wear resistance, corrosion behavior, and cytotoxicity of Mg-Zn-Ca amorphous coatings fabricated by laser surface melting

To address the issues of rapid degradation rate in biodegradable magnesium alloys, which seriously restricts their clinical application, this study employed laser surface melting (LSM) on Mg-Zn-Ca alloys. The impact of the LSM process on the microstructural characteristics of magnesium alloy was examined. Subsequently, an assessment was conducted to analyze the hardness, corrosion resistance, friction and wear properties, as well as cytotoxicity of amorphous coatings applied on magnesium alloy for potential use in biodegradable implants. When the laser scanning power was set at 500 W and scanning speed was adjusted to 90 mm/s, the LSM alloy exhibited good comprehensive of properties, with a microhardness of 540 HV and a friction coefficient of 0.2024. Electrochemical analysis conducted in simulated body fluid (SBF) solution revealed that the LSM sample demonstrated favorable resistance to corrosion, as evidenced by a corrosion potential of -1.3346 V, corrosion current density of 0.0199 mA/cm2, and corrosion rate of 0.455 mm/y. Both the cast and LSM alloys exhibited non-toxicity towards SaOS2 cells, with the LSM alloys displaying slightly superior biocompatibility than the as-cast alloys.