Laser Powder-bed Fusion Additive Manufacturing Research Articles

Laser Powder Bed Fusion Printing of CoCrFeMnNi High Entropy Alloy: Processing, Microstructure, and Mechanical Properties

AbstractEquiatomic CoCrFeMnNi high entropy alloy (HEA) powder was processed by laser powder bed fusion (LPBF) additive manufacturing (AM). The properties of the spherical pre-alloyed CoCrFeMnNi powder were characterized and its processability using LPBF AM was systematically investigated through the volumetric energy density (VED) based on the surface roughness, defects (micro-cracks and porosity) and densification. After optimization, LPBF processing at a VED of 104 J/mm3 achieved highly dense and crack-free vertical and horizontal test specimens with a porosity fraction lower than 0.01% and micro-pores having a mean size of, respectively, 25.9 μm and 13.4 μm, as determined from X-ray micro-computed tomography (μCT) inspection. Scanning electron microscope (SEM) analysis of the as-built (AB) CoCrFeMnNi processed at a VED of 104 J/mm3 showed a heterogeneous solidification microstructure, consisting of columnar grains with a cellular subgrain structure, and electron backscattered diffraction (EBSD) revealed a crystallographic texture mainly along the < 100 > direction. Post treatment with hot isostatic pressing (HIP) was effective in closing the remnant micro-pores in the bulk volume of the AB CoCrFeMnNi. Also, the cellular sub-grain structure in the AB CoCrFeMnNi completely disappeared after HIP and the resulting microstructure consisted of recrystallized equiaxed grains with annealing twins. The room temperature tensile response was anisotropic for AB CoCrFeMnNi with horizontally built specimens exhibiting higher strength and fracture strains (global and local) compared to vertically built ones; HIP reduced the anisotropy in the tensile properties and led to similar tensile strength with elongation values that were ~ 50% higher than in the AB condition. The HIPed CoCrFeMnNi also displayed higher Charpy impact toughness and absorbed energy at both room and liquid nitrogen temperatures compared to the AB material. Examination of the fracture surfaces after tensile and Charpy impact testing revealed ductile features with characteristic dimpled appearance and pointed to the important role of the remnant micro-pores on failure in the AB CoCrFeMnNi. Tribological assessments pointed to the superior low-stress abrasion resistance of AB and HIPed CoCrFeMnNi compared to 316L stainless steel (SS), which was included in this study to reinforce the analysis. SEM observations revealed that scratching and micro-fracture are the dominant wear mechanisms for the CoCrFeMnNi HEA, whereas ploughing and cutting parallel to the abrasive flow direction are the dominant mechanisms for 316L SS. To the authors’ knowledge, this study is the first to evaluate and report the low-stress abrasion resistance of any high entropy alloy. To understand the corrosion behavior, polarization curves of AB and HIPed CoCrFeMnNi were measured in 3.5 wt% NaCl and 1N H2SO4 solutions, and the results were compared to those of 316L SS. The findings indicate that AB and HIPed CoCrFeMnNi outperform 316L SS in a chloride-containing environment, but not in an acid-containing environment. Additionally, observations of hydrogen permeability revealed that AB CoCrFeMnNi permeates a lower volume of hydrogen atoms (by ~ 5 times) compared to 316L SS, despite its higher (by nearly 3 times) diffusion coefficient. Electrochemical hydrogen permeation data showed that the concentration of atomic hydrogen in the sub-surface of AB and HIPed CoCrFeMnNi was, respectively, about 32 and 26 times lower than in 316L SS. This study provides important material–structure–property data and indicates a promising outlook for LPBF of the CoCrFeMnNi HEA with high-performance.

Qualitative and quantitative characterization of powder bed quality in laser powder-bed fusion additive manufacturing by multi-task learning

Qualitative and quantitative characterization of powder bed quality in laser powder-bed fusion additive manufacturing by multi-task learning

Investigation of melt pool dynamics and solidification microstructures of laser melted Ti-6Al-4V powder using X-ray synchrotron imaging

Titanium alloy (Ti-6Al-4V) is widely used in additive manufacturing (AM) industry. However, as laser powder-bed fusion (PBF-L) additive manufacturing (AM) advances towards reliable production of titanium parts, a thorough understanding of the process-structure-properties (PSP) relationships remain to be fully understood. A study of the laser melting was paired with high-speed X-ray synchrotron imaging at the 32-ID beamline of the Advanced Photon Source at Argonne National Laboratory. Simultaneous melting and imaging was carried out on a Ti-6Al-4V powder layer held in a custom device designed to mimic single-track scans of the PBF-L process at different laser power levels, powder size distributions, and cover gas environments (Ar and He) on top of AM Ti-6Al-4V base metal. It was found that the thickness of the powder layer significantly affected the melt behavior: too much powder led to the formation of molten droplets that wetted the surface of the titanium, yet did not contribute to a uniform melting profile. Residual gas pores in the atomized powder were also observed to contribute to the pores observed in the melt pool, with the porosity of the powder (defined as volume of pores divided by total material volume) constant with powder size distribution (i.e., larger particles contained more entrapped gas, which increased final part porosity). When varying Ar or He through the same gas flow meter settings and nozzle, the difference in flow rates likely contributed more to the resultant porosity of the solidified material than did the thermal conductivity of the gasses, with He being the greater contributor to porosity. The microstructure of the heat affected zone contained α′, α, and an increased β phase fraction relative to the base material. The crystallographic texture of the melt pool region adopted that of the base metal.

Apparent properties of porous support structure with imperfections in metal additive manufacturing

In the laser powder bed fusion (L-PBF) additive manufacturing (AM) of metals, support structure is necessary for overhang shaped components. This support is porous with periodic 2D lattice microstructure. The purpose of this paper is to predict numerically the apparent properties of porous support made by titanium alloy, Ti-6Al-4V. One of the problems involved in L-PBF AM is the geometrical imperfections, which are also seen in the microstructure of the support. Micro-CT imaging revealed the variation in strut width and the disconnections. They were parameterized and statistically measured for two cases with different design parameter that determines the density of the 2D lattice microstructure. Based on the statistically measured data, three probabilistic microstructure models were generated per one design parameter. The asymptotic homogenization method was applied to calculate the apparent Young’s moduli, shear moduli and thermal conductivities assuming orthotropic material model. The calculated results were compared with those based on the CAD data without imperfections. Finally, the apparent properties were correlated with the design parameter so that they can be used in the process simulation in the design phase before manufacturing.

Solute segregation in a rapidly solidified Hastelloy-X Ni-based superalloy during laser powder bed fusion investigated by phase-field and computational thermal-fluid dynamics simulations

Solute segregation significantly affects material properties and is a critical issue in the laser powder-bed fusion (LPBF) additive manufacturing (AM) of Ni-based superalloys. To the best of our knowledge, this is the first study to demonstrate a computational thermal-fluid dynamics (CtFD) simulation coupled multi-phase-field (MPF) simulation with a multicomponent-composition model of Ni-based superalloy to predict solute segregation under solidification conditions in LPBF. The MPF simulation of the Hastelloy-X superalloy reproduced the experimentally observed submicron-sized cell structure. Significant solute segregations were formed within interdendritic regions during solidification at high cooling rates of up to 1.6 × 106 K s−1, a characteristic feature of LPBF. Solute segregation caused a decrease in the solidus temperature (TS), with a reduction of up to 38.4 K, which increases the risk of liquation cracks during LPBF. In addition, the segregation triggers the formation of carbide phases, which increases the susceptibility to ductility dip cracking. Conversely, we found that the decrease in TS is suppressed at the melt-pool boundary regions, where re-remelting occurs during the stacking of the layer above. Controlling the re-remelting behavior is deemed to be crucial for designing crack-free alloys. Thus, we demonstrated that solute segregation at the various interfacial regions of Ni-based multicomponent alloys can be predicted by the conventional MPF simulation. The design of crack-free Ni-based superalloys can be expedited by MPF simulations of a broad range of element combinations and their concentrations in multicomponent Ni-based superalloys.

Additive manufacturing of defect-free TiZrNbTa refractory high-entropy alloy with enhanced elastic isotropy via in-situ alloying of elemental powders

Laser powder-bed fusion (L-PBF) additive manufacturing presents ample opportunities to produce net-shape parts. The complex laser-powder interactions result in high cooling rates that often lead to unique microstructures and excellent mechanical properties. Refractory high-entropy alloys show great potential for high-temperature applications but are notoriously difficult to process by additive processes due to their sensitivity to cracking and defects, such as un-melted powders and keyholes. Here, we present a method based on a normalized model-based processing diagram to achieve a nearly defect-free TiZrNbTa alloy via in-situ alloying of elemental powders during L-PBF. Compared to its as-cast counterpart, the as-printed TiZrNbTa exhibits comparable mechanical properties but with enhanced elastic isotropy. This method has good potential for other refractory alloy systems based on in-situ alloying of elemental powders, thereby creating new opportunities to rapidly expand the collection of processable refractory materials via L-PBF.

Performance Improvement for the CuCrZr Alloy Produced by Laser Powder Bed Fusion Using the Remelting Process.

Owing to the high optical reflectivity of copper powder, the high-performance fabrication of copper alloys in the laser additive manufacturing (AM) field is problematic. To tackle this issue, this study employs the remelting process during laser powder bed fusion AM to fabricate defect-free and high-performance CuCrZr alloy. Compared to the non-remelting process, the remelting process yields finer grains, smaller precipitates, denser dislocations, and smaller dislocation cells. It realizes not only the dense molding of high laser reflectivity powders but also excellent mechanical properties and electrical conductivity (with an ultimate tensile strength of 329 MPa and conductivity of 96% IACS) without post-heat treatment. Furthermore, this study elucidates the influence of complex thermal gradients and multiple thermal cycles on the manufacturing process under the remelting process, as well as the internal mechanisms of microstructure evolution and performance improvement.

Perspectives on the unusual electrochemical corrosion of Nickel Aluminum Bronze (NAB) alloy fabricated through laser-powder bed fusion additive manufacturing

This research delves into the passivation and electrochemical corrosion response of as-printed and annealed L-PBF NAB, comparing their performance with wrought NAB counterparts. The results unveil that the interplay between microstructural uniformity, higher aluminum content, residual stress, and the presence of martensitic nanotwins substantially enhances the integrity of the corrosion film and improves the uniform corrosion resistance of as-fabricated NAB. Nonetheless, this combination adversely impacts the localized corrosion resistance. Remarkably, annealing, despite its detrimental effect on passivation and uniform corrosion behavior, ameliorates resistance to localized attacks. In contrast, the wrought equivalents exhibit inferior electrochemical corrosion performance across all experimental conditions.

Multimodal and multiscale strengthening mechanisms in Al-Ni-Zr-Ti-Mn alloy processed by laser powder bed fusion additive manufacturing

The unique thermokinetics of laser-powder bed fusion additive manufacturing (L-PBFAM) has been exploited for development of a novel high-strength Al-Ni-Ti-Zr-Mn alloy. The addition of 0.5 wt% Mn leads to extraordinary improvement in ultimate tensile strength (502 MPa) and work hardening due to the activation of two Mn-induced strengthening mechanisms. First, by a bimodal particle strengthening effect due to Al31Mn6Ni12 nano-quasi-crystal particles rejected in inter-dendritic spaces and fibrous Al3Ni eutectic dendritic channels, which predominately contributes to the strength improvement, and second by solid solution strengthening from remaining Mn entrapped in Al. These mechanisms supplement the particle strengthening effect imparted by coherent and incoherent Al3(Ti,Zr) co-precipitates present at melt pool boundaries, dislocation strengthening due to solidification induced strain, and Hall-Petch and backstress strengthening effect due to heterogenous grain size distribution occurring at various length scales. The solidification dynamics and hierarchical heat distribution that are associated with L-PBFAM resulted in complex spatial variations in these strengthening phenomena and were investigated via a high-throughput multiscale structure–property correlation that involved thermokinetic simulation, X-ray diffraction, high-resolution nanoindentation mapping, and site-specific transmission electron microscopy of the alloy.

Robust Superhydrophobicity through Surface Defects from Laser Powder Bed Fusion Additive Manufacturing.

The robustness of superhydrophobic objects conflicts with both the inevitable introduction of fragile micro/nanoscale surfaces and three-dimensional (3D) complex structures. The popular metal 3D printing technology can manufacture robust metal 3D complex components, but the hydrophily and mass surface defects restrict its diverse application. Herein, we proposed a strategy that takes the inherent ridges and grooves' surface defects from laser powder bed fusion additive manufacturing (LPBF-AM), a metal 3D printing process, as storage spaces for hydrophobic silica (HS) nanoparticles to obtain superhydrophobic capacity and superior robustness. The HS nanoparticles stored in the grooves among the laser-melted tracks serve as the hydrophobic guests, while the ridges' metal network provides the mechanical strength, leading to robust superhydrophobic objects with desired 3D structures. Moreover, HS nanoparticles coated on the LPBF-AM-printed surface can inhibit corrosion behavior caused by surface defects. It was found that LPBF-AM-printed objects with HS nanoparticles retained superior hydrophobicity after 150 abrasion cycles (~12.5 KPa) or 50 cycles (~37.5 KPa). Furthermore, LPBF-AM-printed ships with superhydrophobic coating maintained great water repellency even after 10,000 cycles of seawater swashing, preventing dynamic corrosion upon surfaces. Our proposed strategy, therefore, provides a low-cost, highly efficient, and robust superhydrophobic coating, which is applicable to metal 3D architectures toward corrosion-resistant requirements.

Fast-throughput simulations of laser-based additive manufacturing in metals to study the influence of processing parameters on mechanical properties

Laser-powder bed fusion additive manufacturing (LPBF-AM) of metals is rapidly becoming one of the most important materials processing pathways for next-generation metallic parts and components in a number of important applications. However, the large parametric space that characterizes laser-based LPBF-AM makes it challenging to understand what are the variables controlling the microstructural and mechanical property outcomes. Sensitivity studies based on direct LPBF-AM processing are costly and lengthy to conduct, and are subjected to the specifications and variability of each printer. Here we develop a fast-throughput numerical approach that simulates the LPBF-AM process using a cellular automaton model of dynamic solidification and grain growth. This is accompanied by a polycrystal plasticity model that captures grain boundary strengthening due to complex grain geometry and furnishes the stress-strain curves of the resulting microstructures. Our approach connects the processing stage with the mechanical testing stage, thus capturing the effect of processing variables such as the laser power, laser spot size, scan speed, and hatch width on the yield strength and tangent moduli of the processed materials. When applied to pure Cu and stainless 316L steel, we find that laser power and scan speed have the strongest influence on grain size in each material, respectively.

Non-destructive evaluation of bulk material zones and interfaces in powder bed fusion additive manufactured Ti6Al4V

Inconsistency of equipment and inappropriate design in the laser powder-bed fusion additive manufacturing (LPBF-AM) process are not tightly related to the technology development and are more challenging to avoid. Those processing-related factors can introduce sudden changes in the products' local mechanical properties by internal flaws or microstructure variation. The different property zones and their interfaces will accumulate stress and decrease lifetime. In this work, we applied ultrasound elastography and density profile to evaluate an LPBF Ti6Al4V sample with three property zones induced by different laser speeds to represent equipment errors or inappropriate designs. The elastography clearly distinguished three zones and their corresponding dynamic properties. The ultrasound estimated density profile conforms with profilometer-determined values. The interfaces in the Ti64 sample between the zones were further discerned experimentally by ultrasound to determine the spatial and contrast distributions with a subwavelength resolution based on numerical simulations. The spatial profile and the contrast ratio on the upper boundary of the interface showed the correlation between the interface thickness and the cooling condition during the manufacturing process. These interfacial contrasts in mechanical properties within the bulk 3D printed material are challenging to detect by conventional non-destructive techniques.

Analytical models for flow time estimation of additive manufacturing machines

The use of Additive Manufacturing (AM) technology has largely increased in the last years. Because of its large differences from conventional technologies, the use of AM in production systems might call for new strategies in production planning and control. To this aim, this paper proposes analytical models to predict aggregate performance measures such as flow time, work in process, and production throughput, for production systems characterised by Laser Powder Bed Fusion AM technology. These indicators could be used both in operations strategy development and in technology comparison. The proposed models differentiate for their detail of the analysis and the number of input parameters that need to be estimated. The results show that the level of detail of the model affects the analysis leading to quite different values of the performance measures, especially in the case of highly saturated systems. Also, a discussion about the applicability of the proposed model to other AM technologies show whether and to what extent the proposed models can be applied for modelling other AM technologies.

Laser-Powder Bed Fusion Additive Manufacturing of NiCrBSi Self-Fluxing Nickel Alloy, Material Health - Process Relationship

Laser Powder Bed Fusion (L-PBF) might be a promising solution for producing complex wear-resistant parts from NiCrBSi self-fluxing nickel alloys. This study investigates a large set of parameters with a baseplate heated up to 500 °C. Furthermore, laser remelting is also explored to further increase surface density and reduce cracking. Material health is deeply investigated by image analysis to quantify different defects (lack of fusion, porosity and cracks). Spatters likely induce lacks of fusion, while the low toughness and high hardness values cause cracks. The lack of fusion surface fraction and crack length decrease with the preheating temperature while the crack width increases. A surface density of 99 % is obtained with careful process optimisation leading to a laser power of 100 W, a laser speed of 750 mm.s-1 and a preheating temperature of 500 °C.

Effective Ti-6Al-4V Powder Recycling in LPBF Additive Manufacturing Considering Powder History

Laser powder bed fusion (LPBF) is an outstanding additive manufacturing (AM) technology that can enable both complicated geometries and desired mechanical properties in high-value components. However, the process reliability and cost have been the obstacles to the extensive industrial adoptions of LPBF. This work aims to develop a powder recycling procedure to reduce production cost and minimize process uncertainties due to powder degradation. We used a recycle index (R) to reuse Ti-6Al-4V powder through 10 production cycles. Using this recycle index is more reasonable than simply replying on recycle numbers as it incorporates the powder usage history. A recycling procedure with simple virgin powder top-up can effectively mitigate powder degradation and maintain stable powder properties, chemical compositions, and tensile properties. The experimental finding points to a sustainable recycling strategy of Ti alloy powders with minimal material waste and without noticeable detriment to observed mechanical performance through LPBF production cycles.

Developing a novel high-strength Mg-Gd-Y-Zn-Mn alloy for laser powder bed fusion additive manufacturing process

Laser powder bed fusion (LPBF) of Mg alloys mainly focuses on the traditional commercial casting Mg alloys such as AZ91D, ZK60 and WE43, which usually display relatively low tensile strengths. Herein we developed a novel high-strength Mg-12Gd-2Y-1Zn-0.5Mn (wt.%, GWZ1221M) alloy for the LPBF additive manufacturing process, and the evolution of microstructure and mechanical properties from the as-built state to LPBF-T4 and LPBF-T6 states was systematically investigated. The as-built GWZ1221M alloy exhibited fine equiaxed grains with an average grain size of only 4.3 ± 2.2 μm, while the as-cast alloy displayed typical coarse dendrite grains (178.2 ± 73.6 μm). Thus, the as-built alloy showed significantly higher tensile strengths than the as-cast counterpart, and its yield strength (YS), ultimate tensile strength (UTS) and elongation (EL) were 315 ± 8 MPa, 340 ± 7 MPa and 2.7 ± 0.5 % respectively. Solution treatment transformed hard and brittle β-(Mg,Zn)3(Gd,Y) phase into basal X phase and lamellar long period stacking ordered (LPSO) with better plastic deformability, leading to the improvement of EL. Then peak-aging heat treatment introduced numerous nano-sized prismatic β′ precipitates inside grains, resulting in the enhancement of YS. Finally, the LPBF-T6 alloy achieved appreciably high strength with YS, UTS and EL of 320 ± 3 MPa, 395 ± 4 MPa and 2.1 ± 0.4 % respectively. Both as-built and LPBF-T6 GWZ1221M alloys showed remarkably higher tensile strengths than the as-cast counterparts and as-built commercial Mg alloys, highlighting the great potential of high-strength as-built Mg-Gd based alloys for structural applications.

On the nanoscale oxide dispersion via in-situ atmospheric oxidation during laser powder bed fusion

In-situ oxidation during laser additive manufacturing (AM) is considered a more economical approach to producing AM oxide dispersion-strengthened (ODS) alloys. However, there is very few success in making AM ODS alloys with oxide density comparable to commercial ODS alloys made by conventional means. To explore the key mechanisms that prevent the high-density dispersion of nanoscale oxides during in-situ reactive AM, we investigated oxide dispersion by in-situ gas-phase reaction during laser powder bed fusion (LPBF) with respect to oxygen gettering elements with different oxygen affinity, getter concentration, atmospheric oxygen level, and laser parameters. Our results show that in-situ oxidation in a high-oxygen printing atmosphere during LPBF AM cannot effectively produce good-quality ODS steels, even when the amount of oxygen pick-up from the atmosphere into the melt pool is comparable to the oxygen level in commercial ODS alloys. We found that surface oxidation and oxide agglomeration in the melt pool prevent the high-density dispersion of nanoscale oxides. In addition, oxide agglomeration also contributes to a higher amount of manufacturing defects. Powder spattering plays a secondary impact on oxygen loss.

Assessment of self-lubricating coated cutting tools fabricated by laser additive manufacturing technology for friction-reduction

Dry cutting acting as a green machining technology is a promising manufacturing process in industrial applications; however, severe friction under dry cutting conditions aggravates tool wear and reduces tool life. Self-lubricating cutting tools exhibit excellent benefits in improving cutting properties and that can be used in sustainable machining. The complex process, low efficiency and thin coating thickness limit the production and use of present self-lubricating cutting tools with traditional methods. To enhance the lubricating effect and motivate the development of fabrication methods for self-lubricating cutting tools, Ni-based powders dispersed with MoS2 and Al2O3 particles were preset on the tool substrate; afterward, the self-lubricating coatings were deposited by laser powder-bed fusion additive manufacturing (AM) with a nanosecond fiber laser for cutting application. The self-lubricating coatings were characterized, and the friction and cutting performances of the AM self-lubricating coated tools (SLCs) were evaluated by sliding friction and dry machining tests. The results show that the developed SLC tools reduced the friction coefficient by 8.8–11.7%, cutting forces by 17.6–29.6%, and cutting power by 17.3–22.0% compared to conventional high-speed steel cutting tools (HSS). Built-up edge formation and tool wear were also significantly reduced. The observed mechanisms were attributed to the release of MoS2 particles from the coatings forming a lubricating film at the tool-chip interface, while the Al2O3 particles enhanced surface hardness. The results revealed the practicability of self-lubricating coated cutting tools fabricated by laser-based AM for friction-reduction, and that provide a cleaner process for dry cutting applications.

Simultaneous optimization of topology and process parameters for laser-powder bed fusion additive manufacturing

Simultaneous optimization of topology and process parameters for laser-powder bed fusion additive manufacturing

Quantification and Analysis of Residual Stresses in Braking Pedal Produced via Laser-Powder Bed Fusion Additive Manufacturing Technology.

This study focuses on the experimental verification of residual stress (RS) in a 3D-printed braking pedal using the Powder Bed Fusion (PBF) method with SS316L material. The RS was measured at two representative locations using the hole drilling method (HDM) and the dividing method, which are semi-destructive and destructive methods of RS measurement, respectively. The finite element method (FEM) was used with Ansys Workbench 2020R2 and Simufact Additive 2021 software to determine the magnitude of RS. The results provide insights into how RS is incorporated into metal 3D-printed components and the available tools for predicting RS. This information is essential for experts to improve the accuracy and functionality of SLM parts when post-subtractive or additive manufacturing processes are used. Overall, this study contributes to the advancement of knowledge on the effects of RS on 3D-printed metal components, which can inform future research and development in this area.