Laser-induced Fluorescence Technique Research Articles

On the effects of walking speed, crowd density and human-to-source distance on pollutant dispersion in indoor spaces

The effects of walking speed, crowd density and human-to-source distance on pollutant dispersion in two scaled room models are investigated using simultaneous planar laser-induced fluorescence and particle-image velocimetry techniques. For a small 3 m high room, where the length-scales of the people and room are comparable, the walking motions significantly influenced the macro room mean flow patterns. This has a strong effect on the scalar dispersion properties as the magnitudes of the advective scalar fluxes are often comparable or larger than the turbulent scalar fluxes. As such, the scalar dispersion properties are case specific. For a large 9 m high room, the walking motion influenced only the local mean flow field. The increase in walking speed and crowd density improves the efficiency in which the scalar is transported and mixed with fresh ambient fluid out of the measurement plane (i.e. along the direction of the motion), leading to scalar-free zones observed on the opposite side of the room from the ventilation outlet. The area of the scalar-free zone increases with an increase in the walking speed and crowd density. The advective scalar fluxes are more sensitive to the human motion than the turbulent components, and as the mixing efficiency improves, the advective fluxes show a greater weakening with increased distance from source. The concentration PDFs in the near-source region can be described by the exponential function where the expected value at the 99% percentile can be derived as C99/crms′=4.61, which agreed well with the experimental measurements of 4.1 to 5.9.

An Experimental Study on the Distribution of Grease in Cylindrical Roller Bearings

The lubrication performance of bearings is greatly influenced by the distribution of the lubricant. In this study, a cylindrical rolling bearing test rig was constructed and presented. The distribution of grease and lubricating oil along the contact region was examined using the laser-induced fluorescence technique, and the thickness of the layer was determined. The lubricating oil and grease layer thickness distribution map was acquired. The effects of supply amount, thickener content, and speed on grease distribution were examined. Mechanisms for replenishing the line contact area were investigated.

Absolute density measurement of hydrogen radicals in XUV induced plasma for tin contamination cleaning via laser-induced fluorescence

Effective cleaning of tin contamination on the collecting mirrors in extreme ultraviolet source is one of the key techniques to improve throughput and cost performance of extreme ultraviolet lithography. Hydrogen radicals produced in hydrogen plasma that is induced by wideband extreme ultraviolet radiation are expected to be utilized for in situ tin contamination cleaning in extreme ultraviolet sources. In this Letter, we clarified absolute density and cleaning ability of the hydrogen radicals produced by intense extreme ultraviolet pulse through ground state population density measurement by laser-induced fluorescence technique. The experimentally obtained radical parameters coincided well with simulation results and collisional radiative model. It was found that the extreme ultraviolet induced plasma was in quasi-steady state with abundant amount of hydrogen radicals in ground state. Further, it was found that the in situ tin contamination cleaning in extreme ultraviolet lithography source would become more practical with increase in operational parameters, such as extreme ultraviolet emission intensity, gas pressure, and radical production cross section.

Bubble ring entrapment during a water drop impact on viscous oil films

Air entrapment during the drop impact on a liquid surface is crucial to the ocean–atmosphere mass transfer process. Herein, we report a new mechanism of air entrapment. When a water drop impacts a highly viscous oil film, a bubble ring with a volume of approximately 2% of that of the initial drop is entrapped and disintegrated into multiple bubbles underneath the spreading lamella, which eventually float and burst to emit singular jets near the free surface. The reconstructed profile of the deformed oil film by the laser-induced fluorescence technique reveals the formation of the ridge and valley, which leads to the bubble ring entrapment between the two layers. The effect of the impact velocity on the annular ridge structure and bubble volume is discussed. The onset of the bubble ring disintegration is theoretically predicted, which agrees well with experimental data. Finally, the parameter space of bubble ring entrapment is presented in the regime maps, where three parameters including the impact Weber number, the dimensionless oil viscosity, and film thickness are considered.

Experimental Branching Fractions, Transition Probabilities, and Oscillator Strengths in Sm ii

Branching fractions (BFs) of Sm ii for 71 lines from 12 excited levels ranging from 31,638.79 to 35,463.91 cm−1 were determined for the first time based on the Fourier transform spectra available from the National Solar Observatory database. New transition probabilities and oscillator strengths for these lines were derived by combining the determined BFs with reliable lifetimes measured using a time-resolved laser-induced fluorescence technique. Furthermore, BFs for 38 lines from five levels included in earlier studies were also determined for comparisons. The new results reported in this work will be useful in many fields, especially for astrophysics.

In Situ Measurement of Oil Reservoir and Oil Layers by Fluorescence Technique in a Ball-on-Disc Test Rig

Abstract The major oil supply for the ball-on-disc contact is provided by the lubricating oil reservoir and the oil ridges; however, the regularity of their changes has not been thoroughly investigated. In this study, the laser-induced fluorescence technique was adopted to determine the film distribution of the oil reservoir and the layer thickness of the oil ridges on the free surface. It clearly depicts the changes in the oil reservoir and reveals the mechanism of the oil reflow surrounding the contact region under various driving actions. The results may give a new perspective and a fuller understanding of the lubricating oil supply by revealing additional information about the oil supply surrounding the contact region.

Characterizing turbulent non-premixed flame structure and pollutant formation of cracked ammonia jet flames using simultaneous NH and NO PLIF

The combustion of cracked ammonia is crucial for enhancing flame stability and reducing pollutant emissions in ammonia-based combustion systems. This study investigated the flame structure and pollutant formation in cracked ammonia jet flames (CAJFs) to improve our understanding of the turbulence-chemistry interactions in ammonia combustion. A simultaneous NH and NO planar laser-induced fluorescence (PLIF) technique was employed to analyze the flame structure of turbulent non-premixed CAJFs, emulated using ammonia-hydrogen–nitrogen mixtures. Experimental measurements were conducted across a range of pressures (1–5 bar) and cracking ratios (7 %-28 %). The results revealed the significant influence of the cracking ratio on the chemical reactivity and NH-layer characteristics of ammonia-hydrogen flames. NH effectively marked the heat release layer of CAJFs. Reducing the cracking ratio from 28 % to 7 % resulted in increased local extinction-induced NH-layer fragmentation and reduced reaction area. The reaction layer thickness exhibited low sensitivity to the cracking ratio and pressure, while the broadening of the NH layer displayed a slowdown pattern with increasing height, differing from premixed flames. The pollutant NO rapidly formed within the reaction zone, persisting in the outer hot products until reduced by turbulent mixing. The fragmented flame structure promoted decreased NO formation and potentially lower NO concentration. A novel approach of multiplying NH and NO was proposed to reflect the formation characteristics of another important pollutant N2O. The effect of turbulent disturbances on N2O formation needs to be considered in turbulent CAJFs because N2O formation is strongly suppressed when turbulent transport reduces local NO concentration. This research enhances understanding of turbulence-chemistry interactions in cracked ammonia combustion, benefiting ammonia flame stability and pollutant emission control.

An investigation of flow regimes and mixing in a novel arrow-shaped jet reactor

Fluid mixing plays a vital role in the industry of chemical engineering. In this work, a novel arrow-shaped jet reactor by varying the angle of fluid impingement in the inlet channel was investigated. Flow field visualization experiments using Planar Laser-Induced Fluorescence (PLIF) technique were carried out to study various flow regimes and mixing performance. Results show that differentiated flow patterns of engulfment flow regimes appear within the arrow-shaped jet reactor. Particularly, vortex ring shedding was found in the unsteady engulfing flow regime, which promoted the mixing significantly. Besides, the mechanism of the variation of fluid impinging angle on mixing in an arrow-shaped jet reactor was investigated by numerical simulation. The results indicate that the transformation from double-leg vortex to single-leg vortex and the increase of the volume of vortex clusters caused by vortex ring shedding are the main reasons for the improvement of the mixing of engulfment flow regime.

An experimental study of the dynamics and mass transfer of a rising bubble

In this work, the rise characteristics of shrinking CO2 and non-shrinking N2 bubbles in distilled water for a wide range of bubble sizes in ellipsoidal and wobbly regime (deq = 1.5 mm to 6.5 mm) have been investigated. For these bubbles, their size, trajectory, and rise velocity have been measured using a moving camera system, while the dissolved CO2 is qualitatively studied using a planar laser-induced fluorescence (P-LIF) technique. We explore the interplay between hydrodynamics and mass transfer using well-studied regimes in bubble behaviour. Our results show that the interrelation between mass transfer and bubble rise dynamics is quasi-steady in nature and strongly dependent on wake-induced effects: shape and path oscillations. Based on an analogy of the two phenomena, we conclude that the behaviour of smaller bubbles (<2 mm) as immobile spheres from a mass transfer perspective is not related to the mobility of the interface, but a lack of surface renewal of dissolved gas at the interface. We propose a mechanistic correlation for calculating the mass transfer coefficient, kL, in this regime of bubble size, using the knowledge of the drag coefficient.

A novel laser-induced fluorescence concept for thermometry measurements in machining lubricoolants

This study investigates a two-colour laser-induced fluorescence (LIF) technique for thermometry in cooling lubricants (CL) for machining. The diagnostic technique should enable a simultaneous determination of cooling film thickness and film temperature, which is relevant for typical machining processes like turning and milling processes. The temperature determination is based on a temperature-sensitive fluorescence intensity ratio of a special dye determined in suitable spectral regions representing common band pass filters. For this purpose, two CL emulsions CL6 (6 vol.% CL, 94 vol.% water; normal machining) and CL10 (10 vol.% CL, 90 vol.% water; heavy machining) and its individual components were doped with the fluorescence dye Eosin-Y. Temperature dependent spectral LIF intensities were recorded in the range of 273–313 K, which are relevant for milling and cutting operations. Furthermore, absorption spectra were analysed as well. The temperature-dependent fluorescence measurements revealed a temperature limit for the emulsion stability. The emission peaks of Eosin-Y are shifted with increasing temperature towards longer wavelengths. The sensitivities of CL10 (1.88%/K) and CL6 (1.58%/K) are comparable to or even higher than the sensitivities of other LIF dyes provided in the literature. The literature-based dyes were however not determined in those CL. The measurements showed, that the investigated tracer-CL/water emulsions mixed with the dye enable a reliable temperature determination.

Reaction Rates of OH Radicals with CH3OCF2CHFCF3 and CHF2CF2OCH2CF2CHF2: Measurements and Estimation Using Neural Network Method.

The reaction rates of OH radicals with CH3OCF2CHFCF3 (k1) and CHF2CF2OCH2CF2CHF2 (k2) were measured over a temperature range of 250-430 K. Kinetic measurements were performed using the flash and laser photolysis methods combined with a laser-induced fluorescence technique. The Arrhenius rate parameters were determined as k1 = (2.52 ± 0.25) × 10-12·exp[-(1390 ± 30)/T], k2 = (1.83 ± 0.20) × 10-12·exp[-(1420 ± 35)/T] cm3 molecule-1 s-1. The infrared absorption spectra of the two hydrofluoroethers were measured at approximately 298 K in 760 Torr of N2. The atmospheric lifetimes of CH3OCF2CHFCF3 and CHF2CF2OCH2CF2CHF2 have been estimated as 2.5 and 3.8 years, respectively, and their global warming potentials were determined as 245 and 405, respectively. Additionally, a method, using a three-layered feed-forward neural network, for estimating the rates of the reaction of the OH radicals with alkanes, ethers, and alcohols was investigated. The ratios of the calculated reaction rates to the observed ones agreed within a factor of 2. The ability of the neural network method to predict reaction rates was examined by using a leave-one-out test.

Absolute calibration of the ratio of Xe/O two-photon absorption cross-sections for O-TALIF applications

The paper presents a calibration of the ratio of two-photon absorption cross-sections, σXe(2)/σO(2) , necessary for the absolute O-atom density measurements by two-photon absorption laser-induced fluorescence (TALIF) technique. To calibrate the ratio of the cross-sections, a special discharge with 100% dissociation of molecular oxygen, and so with a known ‘reference’ density of O-atom [O] ref=2⋅ [O2] was suggested. This is a nanosecond capillary discharge in N2:O2 mixtures with a few percent of oxygen at a reduced electric field of a few hundred of Townsend and specific deposited energy of about 1 eV mol−1. Voltage at the electrodes, electrical current in the plasma, longitudinal electric field and energy delivered to the gas were measured with 0.2 ns synchronisation. Additionally, radial distribution of emission of excited nitrogen molecules and gas temperature in the discharge and afterglow were obtained experimentally. Detailed 1D kinetic modeling was suggested to confirm complete O2 dissociation and to analyse the main reactions. By comparing the data measured by TALIF technique with the ‘reference’ density of oxygen atoms [O] ref , the ratio of the two-photon absorption cross-sections σXe(2)/σO(2) was determined.

Understanding heat transfer and flow characteristics of additively manufactured pin fin arrays through laser-induced fluorescence and particle image velocimetry

This article investigates the thermal and hydrodynamic performance of three distinct additively manufactured fin array configurations in a cooling channel: cylindrical, optimized, and perforated fin. The optimized fin design was achieved through the application of a genetic algorithm (GA) to enhance heat transfer efficiency. Experimental assessments were conducted to quantify the heat transfer characteristics and pressure drop across these fin configurations where water is the working fluid and the Reynolds number ranges from 1100 to 5100, along with visualization using Laser-Induced Fluorescence (LIF) and Particle Image Velocimetry (PIV) techniques. Results reveal that the optimized fin array, generated through genetic algorithm optimization, demonstrates a notable enhancement in heat transfer coefficient, exhibiting an improvement of up to 44 % when compared to the traditional cylindrical fin configuration. Furthermore, the perforated fined array showcases a 63 % enhancement in heat transfer performance compared to the cylindrical fin array without apparent increase of pressure drop. The utilization of LIF and PIV techniques offers insights into the heat transfer and fluid velocity distributions within the cooling channel. These visualization methods provide a profound understanding of the flow patterns, flow mixing phenomena, and heat exchange associated with the pin fin designs, facilitating a deeper comprehension of the underlying heat transfer mechanisms.

Spectroscopic detection of the gallium methylene (GaCH2 and GaCD2) free radical in the gas phase by laser-induced fluorescence and emission spectroscopy.

GaCH2, a free radical thought to play a role in the chemical vapor deposition of gallium-containing thin films and semiconductors, has been spectroscopically detected for the first time. The radical was produced in a pulsed discharge jet using a precursor mixture of trimethylgallium vapor in high pressure argon and studied by laser-induced fluorescence and wavelength resolved emission techniques. Partially rotationally resolved spectra of the hydrogenated and deuterated species were obtained, and they exhibit the nuclear statistical weight variations and subband structure expected for a 2A2-2B1 electronic transition. The measured spectroscopic quantities have been compared to our own abinitio calculations of the ground and excited state properties. The electronic spectrum of gallium methylene is similar to the corresponding spectrum of the aluminum methylene radical, which we reported in 2022.

Experimental investigation of scalar dispersion in indoor spaces

The scalar dispersion from point sources in indoor spaces is experimentally investigated using simultaneous particle–image velocimetry and planar laser-induced fluorescence techniques in a 20:1 and a 60:1 full-to-model scale room model. The ventilation inlets dominate turbulence production, with magnitudes of the velocities and Reynolds stresses observed to increase with air changes per hour (ACH). Mean concentration maps show a dependence on the ACH and source location which is attributed to the flow field at the near-source region. The peak-to-mean concentration shows a weak dependence on the mean concentration and concentration variance maps, indicating risk for toxic chemicals may be underpredicted if based only on these information. The concentration PDFs are generally well-described by exponential distributions with C99/crms′ values never exceeding 5.0. The magnitudes of the advective and turbulent scalar fluxes are strongly dependent on the ACH and source location, neither of which are able to dominate the other by more than an order of magnitude. The eddy diffusivity tensor was measured and a conditional-averaging based method is proposed to approximate it to an isotropic eddy diffusion coefficient, K. For real applications where K is used to estimate magnitudes of the turbulent scalar flux using the gradient transport model, the assumption of isotropic turbulence can introduce an uncertainty of around 17.8%.

Buoyant miscible viscoplastic displacements in vertical pipes: Flow regimes and their characterizations

We experimentally study miscible displacement flows of a light Newtonian fluid by a heavy viscoplastic fluid, in a vertical pipe with a large aspect ratio (δ−1≫1). We use camera imaging, laser-induced fluorescence, and ultrasound Doppler velocimetry techniques, to capture and process data. Four dimensionless parameters, namely, the Reynolds (Re), Bingham (B), viscosity ratio (M), and densimetric Froude (Fr) numbers (or their combinations), mainly govern the flow dynamics. We identify and characterize three distinct flow regimes, including plug, separation, and mixing regimes, while we describe each regime's dynamics in detail, particularly in terms of the velocity and concentration fields as well as the displacement front velocity. In addition, we analyze the plug regime concerning the residual wall layers, the separation regime in terms of the separation dynamics, spatiotemporal separation zone, and viscoplastic layer thinning, and the mixing regime regarding the mixing index and macroscopic diffusion. Finally, we develop a simplified model to help delineate the flow regime classification, in the plane of Re/Fr2 and M.

Investigating discrepancies between jet and plume in mean and turbulent flow of 45o inclined dense jets

Rapid expansion in the desalination industry in the last few years has led to the release of substantial quantities of concentrate and highly saline wastewater (brine) into marine environments. To mitigate the environmental consequences, the flow is discharged in depth from single or multi-port diffusers with inclined jets. This technique is used to enhance flow mixing and entrainment in the receiving water. To study flow turbulent characteristics along the jet-to-plume transition zone, a Laser Induced Fluorescence technique has been used. The dynamics of concentration fluctuations in the 45o inclined dense jets were investigated, and the extent of entrainment into the jet core or the length of the non-zero intermittency zone was identified. Intensity and intermittency of the fluctuations across the flow path together with energy spectrums at different points were plotted. The results show that turbulence kinetic energy spectrums resemble the −5/3 power law of Kolmogorov theory for the inertial subrange.

Axial and azimuthal development of disturbance waves in annular flow in a horizontal pipe

Transformation of gas-liquid flow in a horizontal pipe is investigated during the transition from stratified to annular flow pattern. Using Brightness-Based Laser-Induced Fluorescence technique, spatiotemporal evolution of liquid film thickness is analyzed over the downstream distance range of about 900 mm (45 pipe diameters), starting from the inlet. The measurements are carried out for three values of azimuthal angle θ: 0 (pipe bottom), 90°, and 180°, to track the circumferential spreading of liquid film and disturbance waves. At large gas velocities, thin liquid film is dragged upwards before the formation of large waves. The disturbance waves are created at the pipe bottom and spread circumferentially as they propagate downstream, over the already-wetted pipe walls. At large enough liquid flow rates, the spreading disturbance waves reach the pipe ceiling and form full rings around the circumference. The frequency and velocity of the disturbance waves eventually become the same around the pipe circumference; the disturbance wave amplitude and the base film thickness decrease with θ. The base film is more uniform around the circumference compared to the wave amplitude. At lower liquid flow rates, the disturbance waves cover only a part of pipe circumference. Their edges demonstrate oscillatory circumferential spreading, which ends by deceleration and decay of the edges. The upper part of the pipe may be wetted by a thin base film layer, covered only with ripples, or remain dry. At low gas speeds and large liquid flow rates, occasional splashing of large waves over the pipe ceiling without pre-wetting by the thin film is possible; however, the remaining film drains downward and no stable annular film is maintained. Liquid droplets, entrained from the pipe bottom and depositing in the upper parts of the pipe, are gathered in trains of creeping pendant droplets at the very top part of the pipe; no continuous wetting is achieved due to droplet deposition.

Modeling of wavy water film by application of artificial neural network - a state of art study

Nowadays, artificial intelligence (AI) tools have attained a state of maturity and have advanced at a quick rate of achievement in various fields of study. Thus, the predictive and classification of artificial intelligence AI capabilities in manufacturing, commercial, and scientific research applications have resulted in remarkable success. It is widely known that two-phase flow is such a complex problem, and it has a vital state of study due to its importance and wide range of applications. Such as water film phenomena are critical for various industries, including nuclear protection, energy generation, absorption processes, internal combustion engines, chemical reactors, and spray cooling. The present study presented a realistic model for a particular two-phase flow problem of water film thickness. Also, we used neurotic networks for prediction and classification, such as the conventional neural network (CNN) and Long Short-Term Memory (LSTM). The proposed model was evaluated using various raw data, including the input liquid Reynolds number, the Reynolds gas number, the angle of inclination, and the thickness of the water film. The water film thickness was determined using a planar laser-induced fluorescence (PLIF) technique on the various inclination platforms. The current experimental work's inclination angle varied between 0 and 50 degrees. However, when the Reynolds number of the input water changed from 175 to 435, the thickness of the water film was determined; Reynolds gas numbers range from 6950 to 34800.The current study findings indicate an effective alternative method for detecting and forecasting water films on a sloping plate. Nash-Sutcliffe Efficiency (NSE) affected 99 %, 97 %, and 94 % of forecasts, respectively. The findings show tremendous improvement when deep learning uses both LSTM and CNN. The gravitational pressure and air share tension push the water film.

Sources and Destinations of Oil Leakage through TPOCR Based on 2D-LIF Observation and Modeling Analysis

The Three-Piece Oil Control Ring (TPOCR) is becoming a viable option for heavy duty gas and hydrogen engines due to the low particle concentration in these engines. Although direct oil leakage from the gap is not likely to happen with the misalignment of the upper and lower rail gaps, there exist other less-apparent oil leaking mechanisms through the TPOCR. This work is targeted at understanding the oil leakage’s source and destination through the rail and liner interfaces across the whole cycle. The 2D Laser Induced Fluorescence technique was applied on an optical engine to study the oil transport behavior. Combined with a TPOCR model for dynamics and lubrication, the mechanisms that cause rail twist and oil scraping by the upper rail were analyzed. It was found that the symmetrical rail can scrape the oil up in the up-strokes. The scraped oil first accumulates in the clearance between the upper rail and groove, as well as at the upper corner of the rail Outer Diameter before being transferred to both the third land and liner when the piston changes direction at Top Dead Center. Rails with an asymmetrical profile can reduce or enhance these effects depending the orientation of the rails. This study provides findings that could help design the engine to better control Lubricate Oil Consumption and properly lubricate the Top Dead Center’s dry region at the same time.