Laser-generated Shock Waves Research Articles

Propagation of Laser Generated Shock Waves through Heterogeneous Metallic Mediums

Propagation of Laser Generated Shock Waves through Heterogeneous Metallic Mediums

Simultaneous laser sintering and embedding of silver nanoparticles for highly flexible embedded electrodes

In manufacturing electronic devices embedded in flexible substrates, persistent technical challenges include process complexity, substrate damage, high surface roughness, and low mechanical flexibility. To address these challenges, this study proposes a method that involves simultaneously sintering silver nanoparticles (Ag NPs) and embedding them in polyethylene terephthalate (PET) substrates to fabricate flexible embedded electrodes. The proposed technique uses laser-generated high-intensity shock waves to compress Ag NPs coated on a PET substrate heated to its glass-transition temperature. The mechanical impact of the shock wave embeds the Ag NPs into the substrate while simultaneously sintering the particles. The thin-film Ag electrode fabricated using the proposed method exhibited outstanding electrical and mechanical properties. The electrical resistivity measured as low as 7.8 μΩ·cm, with a minimal increase of approximately 5 % after 2000 bending cycles at a bending radius of 1 mm. Furthermore, the fracture strength of the fully embedded electrode, as assessed through adhesive tape-peel tests, significantly surpassed that produced through conventional sintering methods. The proposed method has the potential to revolutionize conventional sintering methods in flexible substrate applications, offering a more efficient and reliable method for fabricating flexible embedded electrodes.

Microstructural Evolution and Surface Mechanical Properties of the Titanium Alloy Ti-13Nb-13Zr Subjected to Laser Shock Processing.

As a progressive surface-hardening technology, laser shock processing (LSP) can enhance the mechanical properties and extend fatigue life for metallic components through laser-generated high-pressure plasma shock waves. In this work, LSP was used to treat titanium alloy Ti-13Nb-13Zr experimental coupons, and the microstructural response and surface mechanical properties of the Ti-13Nb-13Zr experimental coupons were investigated. After the LSP treatment, the X-ray diffraction (XRD) peaks were shifted without any new phase formation. The surface roughness of the experimental coupons increased, which can be explained by the LSP-induced severe plastic deformation. The LSP treatment effectively enhanced the surface compressive residual stress of Ti-13Nb-13Zr. Meanwhile, the microhardness of the Ti-13Nb-13Zr was also obviously increased after the LSP treatment. The experimental results also showed that the number of shocks times is an important factor in the improvement of surface mechanical properties. LSP treatment with multiple shocks can lead to more severe plastic deformation. The surface roughness, surface compressive residual stress and microhardness of the Ti-13Nb-13Zr experimental coupons shocked three times are higher than those after one shock. What is more, grain refinement accounts for the mechanical properties' enhancements after the LSP treatment.

Characteristics of femtosecond laser-induced shockwaves in air.

Dynamic characteristics of femtosecond laser-generated shockwaves are investigated in ambient air. The experiments are performed using a 360-fs pulsed laser at a wavelength of 1.03 µm, with laser intensities up to 5 × 1014 W/cm2 (corresponding to about five times the air breakdown intensity threshold). Plasma and shockwave generation and propagation are visualized using a time-resolved transmission microscope. The maximum propagation velocity is in the order of Mach 30. By implementing a simple theoretical model, we find an initial pressure loading in the GPa range and shockwave pressure dropping down to MPa following propagation over few micrometers away from focus.

In-silico experimentations of multimode shock response of polyurea

Computational studies can supplement existing ultrahigh strain rate experimental techniques in the absence of invasive full-field measurement and visualization. In this study, a computational model is employed to elucidate various phenomena accompanying the generation, propagation, and interaction of multimode shock waves in a viscoelastic material. Specifically, a 4 mm diameter polyurea plug with a thickness of 0.5 mm was modeled as a linear viscoelastic solid, where the relaxation behavior of the shear modulus was described using a Prony series while the bulk modulus was assumed to be linear elastic based on the Poisson's ratio of polyurea. The results are presented in three case studies, where a different type of shock wave was emphasized in each case while focusing on the regions at the leading and trailing edges of the shock wavefront. Generally, the wavefront interacted with the accompanying and reflected waves, resulting in compromising the purity of the sought-after loading condition, especially during the return trip of the wave upon approaching the free surface. In Case Study I, the propagation of laser-induced pressure wave remained pure during the forward trip towards the free surface but was compromised by the accompanying shear wave and side spherical patterned pressure waves. Case Study II simulated the generation of surface waves by incorporating a ring-shaped loading site, where the release of a surface displacement was found to be focused and amplified at the central point. In the final case study, Case Study III, the applied shear wave at ultrahigh strain rate generated secondary pressure and horizontal shear waves at the edges of the loading site, which complicated the loading scenario but provided new insight into the interaction of laser-generated shock waves within the solid. The results can be used to improve the analysis of experimental data to quantify the accompanying deformation and failure mechanisms of polymers subjected to hypervelocity impacts.

Propagation of laser-generated shock waves in metals: 3D axisymmetric simulations compared to experiments

This work aims at demonstrating the ability of an acoustic linear code to model the propagation of a shock wave created by a laser impact over a metallic surface. In this process, a high pressure surface level is reached using a ns laser pulse that heats the surface of the material and generates a dense plasma expansion. The pressure reaches few GPa so shock waves are generated and propagate into the bulk of the material. Currently, shock wave propagation is modeled using continuity equations and an ad hoc equation of state for the illuminated material, very limiting because it is numerically intensive. Here, we propose to model the shock wave bulk propagation using a linear acoustic code. A nonlinear surface pressure term, resulting from the laser–matter interaction, is used as a boundary condition. The applied numerical scheme is based on the Virieux scheme, including a fourth order finite difference discretization of the linearized elastomechanical equations. The role of longitudinal and transverse waves and their origins are highlighted. The importance of considering 3D geometries is pointed out. Simulations are finally confronted with experimental results obtained with the Hephaistos Laserlab facility (energy up to 14 J at 532 nm wavelength laser; pulse duration: 7 ns). Illuminations up to the optical breakdown in water are easily achieved with laser focal spots of 5 mm width. Excellent agreement between experiments and simulations is observed for several sets of experimental parameters for titanium, a material of high elastic limit, while limitations are founded for aluminum. The code is available in the MetaData.

Safety of laser-generated shockwave treatment for bacterial biofilms in a cutaneous rodent model.

Bacterial biofilms are often found in chronically infected wounds. Biofilms protect bacteria from antibiotics and impair wound healing. Surgical debridement is often needed to remove the biofilm from an infected wound. Laser-generated shockwave (LGS) treatment is a novel tissue-sparing treatment for biofilm disruption. Previous studies have demonstrated that LGS is effective in disrupting biofilms in vitro. In this study, we aim to determine the safety threshold of the LGS technology in an in vivo rodent model. To understand the in vivo effects of LGS on healthy cutaneous tissue, the de-haired dorsal skin of Sprague-Dawley rats were treated with LGS at three different peak pressures (118, 296, 227 MPa). These pressures were generated using a 1064 nm Nd/YAG laser (pulse duration 5 ns and laser fluence of 777.9 mJ) with laser spot size diameters of 2.2, 3.0, and 4.2 mm, respectively. Following treatment, the animals were observed for 72 h, and a small subset was euthanized at 1-h, 24-h, and 72-h post-treatment and assessed for tissue injury or inflammation under histology. Each treatment group consisted of 9 rats (n = 3/time point for 1-h, 24-h, 72-h post-treatment). An additional 4 control (untreated) rats were included in the analysis, for a total of 31 animals. Gross injuries occurred in 21 (77%) animals and consisted of minor erythema, with prevalence positively correlated with peak pressure (p < 0.05). Of injuries under gross observation, 94% resolved within 24 h. Under histological analysis, the injuries and tissue inflammation were found to be localized to the epidermis and superficial dermis. LGS appears to be well tolerated by cutaneous tissue for the laser energy settings shown to be effective against bacterial biofilm in vitro. All injuries incurred, at even the highest peak pressures, were clinically mild and resolved within 1 day. This lends further support to the overall safety of LGS and serves to translate LGS towards in vivo efficacy studies.

Shock Waves in Laser-Induced Plasmas

The production of a plasma by a pulsed laser beam in solids, liquids or gas is often associated with the generation of a strong shock wave, which can be studied and interpreted in the framework of the theory of strong explosion. In this review, we will briefly present a theoretical interpretation of the physical mechanisms of laser-generated shock waves. After that, we will discuss how the study of the dynamics of the laser-induced shock wave can be used for obtaining useful information about the laser–target interaction (for example, the energy delivered by the laser on the target material) or on the physical properties of the target itself (hardness). Finally, we will focus the discussion on how the laser-induced shock wave can be exploited in analytical applications of Laser-Induced Plasmas as, for example, in Double-Pulse Laser-Induced Breakdown Spectroscopy experiments.

Laser-Induced Damage on Fused Silica With Photo-Acoustic Spectrum Analysis

Laser-induced damage on fused silica is studied with photo-acoustic spectrum. The damage characteristics are evaluated with the spectral analysis of photo-acoustic signal. The experimental results show that the damage threshold of fused silica samples is about 20.9 J/cm2 at 1-ON-1 condition at the wavelength of 1064 nm and the pulse duration of 10 ns. The damage morphology observed with confocal microscopy is gray haze, and the diameter and depth of the largest crater in gray haze are $6.7~\mu \text{m}$ and 200 nm, respectively. The reproducibility of photo-acoustic spectrum analysis and the characteristic spectral peak is discussed. Compared to the photo-acoustic method judged by signal amplitude, the photo-acoustic spectrum is more sensitive, which may provide an effective support for the study on laser-generated thermal explosion and shock wave propagation. Moreover, the photo-acoustic spectrum may provide a clue for early-damage judgment.

In‐depth analysis of antibacterial mechanisms of laser generated shockwave treatment

Background and Objectives Laser generated shockwave (LGS) is a novel modality for minimally invasive disruption of bacterial biofilms. The objectives of this study are to determine the mechanisms behind LGS treatment and non-biofilm effects on bacterial disruption, including (1) comparing bacterial load with and without LGS in its planktonic form and (2) estimating bacterial cell permeability following LGS. Study Design/Materials and Methods For the first study, planktonic S. epidermidis were treated with gentamicin (0, 8, 16, 32, 64 μg/ml) with and without LGS (1064 nm Nd:YAG laser, 110.14 mJ/mm2 , pulse duration 9 ns, spot size 3 mm, n = 8/group), and absorbances at 600 nm compared. For the second study, four samples of planktonic S. epidermidis were treated with LGS (same settings). Propidium iodide (PI) uptake via flow cytometry as a measure of cell permeability was measured at 0, 10, and 20 minutes following LGS. RESULTS: In comparing corresponding gentamicin concentrations within both LGS-treated samples and controls at 0 hours, there were no differences in absorbance (P = 0.923 and P = 0.814, respectively). Flow cytometry found modest PI uptake (10.4 ± 2.5%) immediately following LGS treatment, with time-dependent increase and persistence of the signal at 20 minutes (R2 = 0.449, P = 0.048). CONCLUSION: Taken together, LGS does not appear to have direct bacteriocidal properties, but rather by allowing for biofilm disruption and bacterial cell membrane permeabilization, both of which likely increase topical antibiotic delivery to pathogenic organisms. Insight into the mechanisms of LGS will allow for improved clinical applications and facilitate safe and effective translation of this technology. Lasers Surg. Med. © 2018 Wiley Periodicals, Inc.

Quantitative evaluation of the mechanical strength of titanium/composite bonding using laser-generated shock waves

Intense acoustic shock waves were applied to evaluate the mechanical strength of structural epoxy bonds between a TA6V4 titanium alloy and a 3D woven carbon/epoxy composite material. Two bond types with different mechanical strengths were obtained from two different adhesive reticulations, at 50% and 90% of conversion, resulting in longitudinal static strengths of 10 and 39 MPa and transverse strengths of 15 and 35 MPa, respectively. The GPa shock waves were generated using ns-scale intense laser pulses and reaction principles to a confined plasma expansion. Simulations taking into account the laser–matter interaction, plasma relaxation, and non-linear shock wave propagation were conducted to aid interpretation of the experiments. Good correlations were obtained between the experiments and the simulation and between different measurement methods of the mechanical strength (normalized tests vs laser-generated shock waves). Such results open the door toward certification of structural bonding.

Shock equation of state of LiH6 to 1.1 TPa

Using laser-generated shock waves, we have measured pressure, density, and temperature of LiH on the principal Hugoniot between 260 and 1100 GPa (2.6--11 Mbar) and on a second-shock Hugoniot up to 1400 GPa to near fivefold compression, extending the maximum pressure reached in non-nuclear experiments by a factor of two. We observe the onset of metal-like reflectivity consistent with temperature-induced ionization of the Li 2s electron, and no sign of additional changes in ionization up to the maximum pressure. Our measurements are in good agreement with gas gun, Z-machine, and underground test data and are accurately described by quantum molecular dynamics simulations. The results confirm the validity of equation of state models built on an average-atom description of the electron-thermal contribution to the free energy and a density-dependent Gr\uneisen parameter to describe shock response of LiH over this pressure range.

Amplitude-dependent shock wave propagation in three-dimensional microscale granular crystals

Ordered arrays of elastic spherical particles in contact, often referred to as granular crystals, have been used as a model system for understanding the dynamics of granular media and explored as a type of designer material for acoustic wave tailoring applications. Due to the Hertzian interactions between the particles, granular crystals composed of macroscale particles have been shown to support strongly nonlinear phenomena including shock and solitary waves. In this presentation, we will describe recent progress in our studies of laser-generated shock wave propagation in self-assembled three-dimensional microscale granular crystals, where adhesive forces between the particles play a major role. Specific features studied include the dependence of the shock wave velocities and absorption on excitation amplitude. Dynamic failure processes such as crater formation and spallation are also explored. The experimental measurements are compared with reduced-dimension discrete element model simulations. New under...

Laser-generated shockwaves enhance antibacterial activity against biofilms in vitro.

Bacterial biofilm formation within chronic wound beds, which provides an effective barrier against antibiotics, is a known cause of recalcitrant infections and a significant healthcare burden, often requiring repeated surgical debridements. Laser-generated shockwaves (LGS) is a novel, minimally invasive, and nonthermal modality for biofilm mechanical debridement which utilizes compressive stress waves, generated by photonic absorption in thin titanium films to mechanically disrupt the biofilm. Prior studies have demonstrated LGS monotherapy to be selectively efficacious for biofilm disruption and safe for host tissues. In this study, we sought to determine if LGS can enhance the antimicrobial activity and biofilm disruption capability of topical antibiotic therapy. Staphylococcus epidermidis biofilms grown in vitro on glass were treated with topical gentamicin (31, 62, and 124 μg/ml) with and without LGS (n = 3-11/treatment group). Mechanical shockwaves were generated with a 1,064 nm Nd:YAG laser (laser fluence 110.14 mJ/mm2 , pulse duration 5 ns, spot size 3 mm). Following a 24-hour incubation period, bacterial viability was assessed by determining the number of colony-forming units (CFU) via the Miles and Misra method. Residual biofilm bioburden was analyzed using the crystal violet biofilm assay. With gentamicin monotherapy, CFU density (CFU/mm2 ) at 31, 62, and 124 μg/ml were (282 ± 84) × 104 , (185 ± 34) × 104 , and (113 ± 9) × 104 , respectively. With LGS and gentamicin therapy, CFU density decreased to (170 ± 44) × 104 , (89 ± 24) × 104 , and (43 ± 3) × 104 , respectively (P = 0.1704, 0.0302, and 0.0004 when compared with gentamicin alone). Biofilm burden as measured by the assay in the gentamicin 31, 62, and 124 μg/ml groups was reduced by 80%, 95%, and 98% when LGS was added (P = 0.0102, >0.0001, and 0.0001 for all groups when compared with gentamicin alone). Furthermore, samples treated with LGS saw an increase in susceptibility to gentamicin, in terms of reduced biofilm bioburden and CFU densities. LGS enhances the efficacy of topical antibiotics in an in vitro model. This has significant implications for clinical applications in the management of chronic soft tissue infections and recalcitrant chronic rhinosinusitis. Lasers Surg. Med. 49:539-547, 2017. © 2017 Wiley Periodicals, Inc.

Laser-Generated Shockwaves as a Treatment to Reduce Bacterial Load and Disrupt Biofilm.

The goal of this paper is to demonstrate and evaluate the potential efficacy of laser-generated shockwave (LGS) therapy on biofilm infected tissue. To demonstrate proof of concept, Staphylococcus epidermidis was allowed to proliferate on ex vivo pigskin, until mature biofilm formation was achieved, and then subjected to LGS. Bacterial load between control and treated samples was compared using the swab technique and colony counting. Scanning electron microscopy (SEM) was then used to visualize the biofilm growth and resulting reduction in biofilm coverage from treatment. Images were false colored to improve contrast of biofilm, and percent biofilm coverage was computed, along with biofilm cluster size. LGS reduced bacterial load by 69% (p = 0.008). Imaging showed biofilm coverage reduced by 52% and significantly reduced average cluster size (p 0.001). LGS therapy reduced the burden of bacterial biofilm on ex vivo pigskin and can be visualized using SEM imaging. LGS therapy is a new treatment for infected wounds, allowing rapid disruption of biofilm to 1) remove bacteria and 2) increase susceptibility of remaining biofilm to topical antibiotics. This can lead to improved wound healing times, reduced patient morbidity, and decreased healthcare costs.

Laser-generated shock wave attenuation aimed at microscale pyrotechnic device design

To meet the rising demand for miniaturizing the pyrotechnic device that consists of donor/acceptor pair separated by a bulkhead or a thin gap, the shock initiation sensitivity in the microscale gap test configuration is investigated. For understanding the shock attenuation within a gap sample (304 stainless steel) thickness of 10∼800 μm, the laser-generated shock wave in water confinement is adopted. The shock properties are obtained from the free surface velocity by making use of a velocity interferometer system for any reflector (VISAR). Analytical models for plasma generation in a confined geometry and for evolution and decay of shock waves during the propagation are considered. The shape and amplitude of the laser-driven initial pressure load and its attenuation pattern in the gap are effectively controlled for targeting the microscale propagation distance and subsequent triggering pressure for the acceptor charge. The reported results are important in the precise controlling of the shock strength during the laser initiation of microscale pyrotechnic devices.

Improving the forming capability of laser dynamic forming by using rubber as a forming medium

Laser dynamic forming (LDF) is a novel high velocity forming technique, which employs laser-generated shock wave to load the sample. The forming velocity induced by the high energy laser pulse may exceed the critical forming velocity, resulting in the occurrence of premature fracture. To avoid the above premature fracture, rubber is introduced in LDF as a forming medium to prolong the loading duration in this paper. Laser induced shock wave energy is transferred to the sample in different forming stages, so the forming velocity can be kept below the critical forming velocity when the initial laser energy is high for fracture. Bulge forming experiments with and without rubber were performed to study the effect of rubber on loading duration. The experimental results show that, the shock wave energy attenuates during the propagation through the rubber layer, the rubber can avoid the premature fracture. So the plastic deformation can continue, the forming capability of LDF is improved. Due to the severe plastic deformation under rubber compression, adiabatic shear bands (ASB) occur in LDF with rubber. The material softening in ASB leads to the irregular fracture, which is different from the premature fracture pattern (regular fracture) in LDF without rubber. To better understand this deformation behavior, Johnson–Cook model is used to simulate the dynamic response and the evolution of ASB of copper sample. The simulation results also indicate the rubber can prolong the loading duration.

The Investigation on Mask and Plasticine Laser Shock Forming

A novel technology called mask and plasticine laser shock forming (MAPLSF) was introduced to manufacture micro-features on the surface of pure copper foil with the thickness of 40μm. In this process, the laser-generated shock wave and plasticine are used to replace the conventional rigid punch and die. The result showed that the shape of laser beam can be roughly manufactured on the surface of the workpiece and this mold-free laser shock forming process is a fast method to fabricate controlled micro-feature on the metallic foils. In this damage-free forming process, the workpicec can keep good surface, because the plasticine is softer than metal foils.

Experiment research on dynamic response of copper film at high strain rate by chirped pulse spectral interferometry

That the femtosecond laser pulses irradiate metallic materials thereby inducing ultrahigh strain rates, is an important experimental approach to studying the material behavior under extreme conditions. Femtosecond laser-generated shock waves in metal films have rise times of several picoseconds, the corresponding diagnostic technique is required to work with a higher time resolution, which makes the experimental measurements difficult. Chirped pulse spectral interferometry (CPSI) possesses capabilities of ultrafast time resolution and continuous measurement, thus it provides a diagnostic technique for studying the ultrashort shock wave. In this article, we carry out an experiment on femtosecond laser driven shock wave in copper film and the measurement by CPSI. Laser pulse of 25 fs duration at the central wavelength 800 nm is used, the tested samples are copper films of (5025) nm in thickness fabricated by electron beam sputtering deposition onto cover slip substrate of 180 m in thickness, pump beam focuses onto front surface of the copper film through the transparent substrate and this laser intensity is 2.31013 W/cm2. Chirped pulse spectral interferometry is used to detect the movements of the free rear surfaces of the copper films with temporal and spatial resolution. In the spectral interferometry, linearly chirped pulse is required and obtained by stretching the femtosecond laser pulse with a pair of gratings. The relation between frequency and time of the chirped pulse is accurately measured using asymmetric spectral interference method, which is required for explaining the experimental data. Since CPSI is a single shot diagnostic technique, we obtain the displacement and velocity history of the free rear surface with picosecond time resolution in a single measurement. From the results, the average shock velocity is calculated to be (5.60.2) km/s and the shock wave rise time is determined to be 6.9 ps. According to the shock wave relations, impact pressure and strain rate in the copper film are (57.18.8) GPa and 8109 s-1 respectively, the strain rate is so high that it is hard to achieve by long-pulse laser driven or other loading approaches. Additionally, experimental results also show that the free rear surface alternately experiences acceleration and deceleration, which indicates the spallation in the copper target. It is obvious that chirped pulse spectral interferometry is a reliable approach to studying ultrashort shock waves in metal films.

Analysis of flexible substrates for clinical translation of laser-generated shockwave therapy.

Bacteria biofilms in chronically infected wounds significantly increase the burden of healthcare costs and resources for patients and clinics. Because biofilms are such an effective barrier to standard antibiotic treatment, new methods of therapy need to be developed to combat these infections. Our group has demonstrated the potential of using Laser Generated Shockwaves as a potential therapy to mechanically disrupt the bacterial biofilms covering the wound. Previous studies have used rigid silica glass as the shockwave propagation medium, which is not compatible with the intended clinical application. This paper describes the exploration of five candidate flexible plastic films to replace the glass substrate. Each material measured 0.254 mm thick and was used to generate shockwaves of varying intensities. Shockwave characterization was performed using a high-speed Michelson displacement interferometer and peak stress values obtained in the flexible substrates were compared to glass using one-way nested Analysis of Variance and Tukey HSD post-hoc analysis. Results demonstrate statistically significant differences between substrate material and indicate that polycarbonate achieves the highest peak stress for a given laser fluence suggesting that it is optimal for clinical applications.