We introduce quaternary modified four μ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\mu $$\\end{document}-circulant codes as a modification of four circulant codes. We give basic properties of quaternary modified four μ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\mu $$\\end{document}-circulant Hermitian self-dual codes. We also construct quaternary modified four μ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\mu $$\\end{document}-circulant Hermitian self-dual codes having large minimum weights. Two quaternary Hermitian self-dual [56, 28, 16] codes are constructed for the first time. These codes improve the previously known lower bound on the largest minimum weight among all quaternary (linear) [56, 28] codes. In addition, these codes imply the existence of a quantum [[56, 0, 16]] code.