Large Volcanogenic Massive Sulfide Deposits Research Articles

Geochronology and geochemistry of Neoproterozoic Hamamid metavolcanics hosting largest volcanogenic massive sulfide deposits in Eastern Desert of Egypt: Implications for petrogenesis and tectonic evolution

The Gebel Abu Hamamid area forms the middle part of Shadli Metavolcanics Belt of the South Eastern Desert, which hosts the largest volcanogenic massive sulfide deposits in Egypt. The host-rock succession belongs to the Younger Hamamid Metavolcanics (YHM) group, consisting of mafic and felsic lavas with variable volcaniclastics. Although several studies have attempted to clarify the crustal evolution of the Neoproterozoic basement rocks of the South Eastern Desert, researchers have yet to develop a deep understanding of the petrogenesis, tectonic setting, and ages of these host rocks. In the current study, we newly report whole-rock geochemistry, mineral chemistry, and in-situ U–Pb zircon dating from basaltic to rhyolitic rocks of the YHM group to describe their magmatic evolution. Results indicate that the mafic rocks are characterized by tholeiitic affinity and arc-like geochemical signatures with significantly enriched large-ion lithophile elements and depleted high field strength elements. The parental magma was likely generated by partial melting (~10–15%) of a spinel-lherzolite source mantle that was metasomatized by fluids from a former subduction event, followed by magma ascent under low pressure and low oxygen fugacity conditions. The felsic lavas (~695 Ma) are characterized by subduction-related geochemical characteristics with significant enrichments in Zr, Hf, and Sm. They formed from lithosphere-derived magma enriched by melts from the ancient subducted slab, and later experienced an assimilation-fractional crystallization (AFC) process. The YHM group was formed under extensional geodynamic conditions (back-arc basin setting). The zircon grains display hydrothermal overgrowth at the rims, most likely due to regional metamorphic and hydrothermal changes. This characteristic is likely the effect of hydrothermal fluids associated with the Jurassic-Cretaceous tectonothermal event in the South Eastern Desert.

Evidence for Remobilization of Barite Affecting Radiometric Dating Using 228Ra, 228Th, and 226Ra/Ba Values: Implications for the Evolution of Sea-Floor Volcanogenic Massive Sulfides

Samples of chimneys (black smokers) and other volcanogenic massive sulfide (VMS) mineralization were collected from hydrothermal vent fields associated with submarine arc and back-arc volcanoes in the western Pacific. Each specimen was dated using radiometric techniques to establish the frequency and duration of hydrothermal activity at that site, information that is vital when establishing the time elapsed to amass an ore deposit. In each case, the radiometric dating relied on the radium isotopes 228 Ra and 226 Ra with half-lives of 5.75 and 1,600 years, respectively, which coprecipitate with barite and then decay. We began dating VMS mineralization 15 years ago, knowing that the 226 Ra/Ba decreases with time, with the Ba and Ra assumed to be from a common source such that the initial 226 Ra/Ba value, i.e., the value at the onset of mineralization, was constant. Thus, the age of an “old” chimney (up to 15,000 yr) was calculated by comparing its 226 Ra/Ba value with the initial value established from nearby “young” chimneys ( 228 Ra. Since then, we have discovered that chimneys and other forms of sea-floor VMS mineralization can contain barite from two or more hydrothermal events. That is, older barite can be dissolved and reprecipitated (remobilized) from earlier mineralization deposited subseafloor, or earlier sea-floor mineralization overprinted (crosscut) by new. In many cases, the 226 Ra/Ba dating did not provide an absolute age for the older material but, rather, a difference in age between two samples that had incorporated varying proportions of older barite that was low or “dead” (i.e., >15,000 yr) with respect to 226 Ra, due to radioactive decay. Remobilizing of older barite is consistent with zone refining of metals in large VMS deposits, but we have only considered this recently. However, our investigations show that this can affect the initial 226 Ra/Ba values for VMS mineralization from arc and back-arc volcanoes, and also from mid-ocean ridges. Where sufficient samples contained 228 Ra, we estimated an age for the remobilized barite by plotting a 226 Ra/Ba versus 228 Ra/Ba mixing line for the VMS at the time of mineralization and found that hydrothermal activity has occurred at some arc volcanoes for >15,000 years. Such long histories of hydrothermal activity indicate the propensity for producing large metal-rich deposits on the seafloor.

Quantifying the release of base metals from source rocks for volcanogenic massive sulfide deposits: Effects of protolith composition and alteration mineralogy

This detailed study of the release of base metals during hydrothermal alteration from the sheeted dike complex of the Troodos ophiolite, Cyprus, aims to better understand the source of these elements in ore-forming hydrothermal fluids. The study area, ~10km2 between the villages of Spilia and Kannavia, has previously been recognized as a region in which the abundance of epidote in the altered sheeted dikes is higher than average — a so-called epidosite zone. The originally basaltic to andesitic sheeted dikes have been variably altered, but the secondary mineralogy is independent of the protolith composition. Four alteration facies have been identified in the epidosite zone. With progressively increasing modal epidote, decreasing modal amphibole, and decreasing bulk-rock Mg these are: (i) diabase, which is composed of amphibole+chlorite+albitic plagioclase±epidote±quartz, (ii) transitional diabase–epidosite, (iii) intermediate epidosite, and (iv) rare (<15% of the study area) end-member epidosite which consists largely of quartz+epidote. Comparing protolith base metal differentiation trends, defined by new analyses of cogenetic volcanic glass, with these altered samples indicates that the rocks originally contained 47–99ppm Zn, 1030–1390ppm Mn, 19–28ppm Co, 19–57ppm Cu and 7–50ppm Ni. The vast majority of the altered rocks within the epidosite zone studied have low Cu (averaging 3ppm) irrespective of alteration facies. This uniform and large depletion suggests that Cu was originally largely present in sulfides that were completely destroyed during hydrothermal alteration. With the exception of Co, the other base metals have substantially lower concentrations in the altered rocks than in their protoliths and show increasing base metal depletion with increasing modal epidote abundance. This suggests that breakdown of silicate minerals was important in controlling the release of these metals. Cobalt is enriched in the diabase and transitional diabase–epidosite alteration facies, and depleted in the end-member epidosite alteration facies, relative to protolith concentrations. This suggests that Co was redistributed within the sheeted dike complex rather than substantially leached out; the same is probably true of Mg. Mapping across the steep topography of the study area indicates that the Spilia–Kannavia epidosite zone has a volume of ~2km3. Based on this estimate, hydrothermal fluids leached ~369kt of Zn, ~52kt of Ni, ~3647kt of Mn and ~162kt of Cu. These Zn and Cu losses are similar to the masses of these metals present in the largest volcanogenic massive sulfide deposits on Cyprus. Based on the differences between protolith and altered rock compositions it is predicted that alteration of primitive protoliths will tend to produce fluids with higher ratios of Cu and Ni to Zn and Mn, whereas alteration of more evolved protoliths will produce fluids with lower ratios.

Hydrothermal precipitates associated with bimodal volcanism in the Central Bransfield Strait, Antarctica

Polymetallic sulfide-sulfate mineralization enriched in Pb-Ag-As-Sb-Hg occurs in the Bransfield Strait, a late Tertiary-Quaternary marginal basin close to the Antarctic Peninsula. The mineralization is associated with bimodal volcanism and pelagic and volcaniclastic sediment in rifted continental crust. Hydrothermal precipitates have been recovered from two shallow (1,050–1,000 m water depth) submarine volcanoes (Hook Ridge and Three Sisters) in the Central Bransfield Strait. Mineralization at Hook Ridge consists of polymetallic sulfides, massive barite, and pyrite and marcasite crusts in semilithified pelagic and volcaniclastic sediment. Native sulfur commonly infills void space and cements the volcaniclastic sediment. The polymetallic sulfides are dominated by sphalerite with minor galena, enargite, tetrahedrite-tennantite, pyrite, chalcopyrite, and traces of orpiment cemented by barite and opal-A. The presence of enargite at Hook Ridge, the abundance of native sulfur, and the low Fe content of sphalerite indicate a high sulfur activity of the hydrothermal fluids responsible for mineralization. The sulfur isotopic composition of Hook Ridge precipitates documents the complexity of the sulfur sources in this hydrothermal system with variable influence of biological activity and possibly magmatic contributions. Homogenization temperatures and salinities of fluid inclusions in barite and opal-A suggest that boiling may have affected the hydrothermal fluids during their ascent. The discovery of massive barite-silica precipitates at another shallow marine volcano (Three Sisters volcano) attests to the potential for hydrothermal mineralization at other volcanic edifices in the area. The characteristics of the mineralization in the Bransfield Strait with rifting of continental crust, the presence of bimodal volcanism, including highly evolved felsic volcanic rocks, the association with sediments, and the Pb-Ag-As-Sb-Hg enrichment are similar to the setting of massive sulfide deposits in the Okinawa Trough, and distinct from those of sediment-dominated hydrothermal systems such as Escanaba Trough, Middle Valley, and Guaymas Basin. The geological setting of the Bransfield Strait is also broadly similar to that of some of the largest volcanogenic massive sulfide deposits in the ancient record, such as the Iberian Pyrite Belt.

U-Pb zircon and geochemical evidence for bimodal mid-Paleozoic magmatism and syngenetic base-metal mineralization in the Yukon-Tanana terrane, Alaska

New SHRIMP (sensitive, high-resolution ion microprobe) U-Pb zircon ages and trace element geochemical data for mafic and felsic metaigneous rocks of the pericratonic Yukon-Tanana terrane in east-central Alaska help define the tectonic setting of mid-Paleo-zoic magmatism and syngenetic hydrothermal Zn-Pb-Ag mineralization along the ancient Pacific margin of North America. We compare data from similar greenschist-facies sequences of bimodal volcanic and subvolcanic rocks associated with carbonaceous and siliciclastic marine sedimentary rocks, in the Wood River area of the Alaska Range and the Salcha River area of the Yukon-Tanana Upland, and from amphibolite-facies augen gneiss and mafic gneiss (amphibolite) in the Goodpaster River area of the upland. Allowing for analytical uncertainties, igneous crystallization age ranges of 376–353 Ma, 378–346 Ma, and 374–358 Ma are indicated by 13 new SHRIMP U-Pb dates for the Wood River, Salcha River, and Goodpaster River areas, respectively. Bimodal magmatism is indicated by Late Devonian crystallization ages for both augen gneiss (371 ± 3 and 362 ± 4 Ma) and associated orthoamphibolite (369 ± 3 Ma) in the upland and by stratigraphic interleaving of mafic and felsic rocks in the Alaska Range. Metabasites in all three study areas have elevated HFSE (high field strength element) and REE (rare earth element) contents indicative of generation in a within-plate (extensional) tectonic setting. Within-plate trace element signatures also are indicated for peralkaline metarhyolites that host the largest volcanogenic massive sulfide deposits of the Bonnifield district in the Wood River area and for metarhyolite tuff interlayered with the carbonaceous Nasina assemblage, which hosts sedimentary exhalative sulfide occurrences in the Salcha River area. Most of the other felsic metaigneous samples from the Alaska Range and the Yukon-Tanana Upland have geochemical signatures that are similar to those of both average upper continental crust and continental-margin arc rocks generated in thick continental crust. Given the absence in our study areas of intermediate-composition magmatic products generally found in most arcs, and the presence of bimodal magmatism, the alkalic within-plate chemistry of the mafic rocks and some of the felsic rocks, and the widespread occurrence of interlayered carbonaceous sedimentary rocks indicative of deposition within a restricted marine basin or submerged continental margin, we consider it most likely that this prolonged Late Devonian to Early Mississippian magmatic episode resulted from attenuation of the ancient continental margin of western North America, rather than development of an arc, as proposed by many others.

High 18 O ore-forming fluids in volcanic-hosted base metal massive sulfide deposits; geologic, 18 O/ 16 O, and D/H evidence from the Iberian pyrite belt; Crandon, Wisconsin; and Blue Hill, Maine

High 18 O ore-forming fluids in volcanic-hosted base metal massive sulfide deposits; geologic, 18 O/ 16 O, and D/H evidence from the Iberian pyrite belt; Crandon, Wisconsin; and Blue Hill, Maine