Observing low-frequency decimeter hydrogen radio recombination lines (RRLs) with large single-dish telescopes, such as the Five-hundred-meter Aperture Spherical radio Telescope (FAST) in the L band, is a unique method for probing massive star formation on scales of hundreds of parsecs. This approach is particularly effective for detecting relatively weak and extended emissions from low-density gas ionized by massive stars. Deep, unbiased decimeter or centimeter RRL surveys with large single-dish telescopes can significantly enhance our understanding of the diffuse ionized gas along the Galactic plane. This, in turn, will improve our knowledge of the life cycle of matter in the interstellar medium and the dynamics of the Galaxy. In this context, we present a pilot project for such a blind L-band RRL survey targeting the Galactic plane and conducted using FAST. The results include the detection of RRL clumps and the identification of an off-arm active massive star-forming region near the Sagittarius-Carina arm. The ongoing and upcoming massive star formation in this region may be associated with the kink in the Sagittarius-Carina arm near 23$^ circ $ azimuth.
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