A long-standing challenge in exploring the dynamics of large-scale atmospheric or oceanic motions is to find more appropriate theoretical models. This paper aims at the mechanisms of nonlinear Rossby waves by a new obtained nonlinear evolutionary equation hierarchy approach. The multiple scales method and weak nonlinear perturbation method are adopted based on the quasi-geostrophic potential vorticity conservation law for large scale atmospheric or oceanic motions. It is the first time that a Quartic Korteweg–de Vries model equation is derived to describe the propagation of nonlinear Rossby waves amplitude, which provides a new acceptable theoretical model for the study of atmospheric blocking phenomena. Qualitative and quantitative analysis for the new Quartic KdV model are finished to disclose the evolutionary mechanisms of nonlinear Rossby waves. The corresponding results declares that the β effect, topographic features and detuning parameter are all important factors on the nonlinear Rossby waves.