Large Radius Research Articles

Enhanced microwave absorption using multiple heterostructures derived from in-situ grown Sn-metal-organic framework on La-doped Fe3O4

As a representative magnetic oxide absorber, Fe3O4 has attracted considerable research attention owing to its remarkable magnetic saturation strength as well as semiconducting properties. Doping Fe3O4 with La3+ leads to 3d-4f magnetic coupling and ion distribution changes due to the unique electron configuration and large ionic radius of La3+, thereby greatly enhancing the magnetic performance. However, high density, low dielectric loss, and low permeability at high frequencies inhibit the electromagnetic wave absorption (EMWA) performance of ferrites. In this study, stick-shaped Sn metal-organic framework (MOF) is in-situ grown on La3+-doped Fe3O4 using a surfactant. After high-temperature annealing, the SnO2/porous carbon composites derived from Sn-MOF wrap the ferrite, forming a core-shell heterostructure, which not only prevents oxidation but also enhances the EMWA performance. Among the prepared LaxFe3-xO4/SnO2/C (LFSC) samples, LFSC-2 (with LaxFe3-xO4 to Sn-MOF ratio of 1:2) exhibits strong absorption performance with a minimum reflection loss (RLmin) of −44.1 dB. Furthermore, the gradient metamaterial based on LFSC-3 shows ultra-broadband EMWA with an effective absorption bandwidth (RLmin ≤ −10 dB) of 13.17 GHz. In addition, the LFSC-2 sample demonstrates excellent radar stealth capability in the radar cross section (RCS) far-field response, achieving an RCS reduction value of 20.4 dB·m2.

A Virgo Environmental Survey Tracing Ionised Gas Emission (VESTIGE)

We examine the prevalence of truncated star-forming discs in the Virgo cluster down to M* ≃ 107 M⊙. This work makes use of deep, high-resolution imaging in the Hα+[N II] narrow-band from the Virgo Environmental Survey Tracing Ionised Gas Emission (VESTIGE) and optical imaging from the Next Generation Virgo Survey (NGVS). To aid in the understanding of the effects of the cluster environment on star formation in Virgo galaxies, we take a physically motivated approach to define the edge of the star-forming disc via a drop-off in the radial specific star formation rate profile. A comparison with the expected sizes of normal galactic discs provides a measure of how truncated star-forming discs are in the cluster. We find that truncated star-forming discs are nearly ubiquitous across all regions of the Virgo cluster, including beyond the virial radius (0.974 Mpc). The majority of truncated discs at large cluster-centric radii are of galaxies likely on their first infall. As the intra-cluster medium density is low in this region, it is difficult to explain this population with solely ram-pressure stripping. A plausible explanation is that these galaxies are undergoing starvation of their gas supply before ram-pressure stripping becomes the dominant quenching mechanism. A simple model of starvation shows that this mechanism can produce moderate disc truncations within 1−2 Gyr. This model is consistent with ‘slow-then-rapid’ or ‘delayed-then-rapid’ quenching, whereby the early starvation mode drives disc truncations without significant change to the integrated star formation rate, and the later ram-pressure stripping mode rapidly quenches the galaxy. The origin of starvation may be in the group structures that exist around the main Virgo cluster, which indicates the importance of understanding pre-processing of galaxies beyond the cluster virial radius.

Atomistic first-principles modeling of single donor spin-qubit

Using an impurity atom in crystal silicon as a spin-1/2 qubit has been made experimentally possible recently where the impurity atom acts as a quantum dot (QD). Quantum transport in and out of such a donor QD occurs in the sequential tunneling regime where a physical quantity of importance is the charging (addition) energy, which measures the energy necessary for adding an electron into the donor QD. In this work, we present a first-principles method to quantitatively predict the addition energy of the donor QD. Using density functional theory (DFT), we determine the impurity states that serve as the basis set for subsequent exact diagonalization calculation of the many-body states and energies of the donor QD. Due to the large effective Bohr radius of the conduction electrons in Si, very large supercells containing more than 10 000 atoms must be used to obtain accurate results. For the donor QD of a phosphorus impurity in bulk Si, the combined DFT and exact diagonalization predicts the first addition energy to be 53 meV, in good agreement with the corresponding experimental value. For the donor QD of an arsenic impurity in Si, the first addition energy is predicted to be 44.2 meV. The calculated many-body wave functions provide a vivid electronic picture of the donor QD.

Cloud droplet size distributions governed by condensation, collision–coalescence, and sedimentation. Part 2: Analytical expressions for size distribution shape and asymptotic behavior for large-droplet tails

Abstract Droplet growth via condensation and collision-coalescence has been investigated in the limit of very weak coalescence growth: a collector-mode approximation emerges for coalescence growth that consists solely of droplets in the tail collecting droplets near the main mode of the cloud droplet size distribution, and that does not deplete the mode. In this second part, the approximation is formalized, leading to a simplified form of the collision-coalescence term in the equation governing the evolution of the droplet size distribution. This form allows for analytical solutions for transient growth and for steady-state distributions representing a balance between condensation, collision-coalescence growth, and removal by sedimentation. The solutions lead to an expression for the drizzle growth time, formally, the finite time in which a droplet approaches infinite size. The drizzle growth time is related to a transition radius at which droplet growth switches from condensation-dominated to coalescence-dominated. The solutions also provide a dimensionless group that governs the steady-state distribution shape, which is referred to as the drizzle number. The solutions are checked by comparing to a Monte Carlo model developed in Part 1, and it is found that the analytical solution is excellent when the drizzle number is much greater than unity, which is the typical situation for the microphysical conditions achievable in a convection-cloud chamber. The steady-state size distribution has the form of a modified gamma distribution, with a transition to power-law tail at sufficiently large radius. The solutions are formally valid for a convection-cloud chamber, but can also be extended to shallow, mixed-layer clouds such as mixing fogs.

Boosting K+‐Ionic Conductivity of Layered Oxides via Regulating P2/P3 Heterogeneity and Reciprocity for Room‐Temperature Quasi‐Solid‐State Potassium Metal Batteries

AbstractSolid‐state potassium metal batteries are promising candidates for grid‐scale energy storage due to their low cost, high energy density and inherent safety. However, solid state K‐ion conductors struggle with poor ionic conductivity due to the large ionic radius of K+‐ions. Herein, we report precise regulation of phase heterogeneity and reciprocity of the P2/P3‐symbiosis K0.62Mg0.54Sb0.46O2 solid electrolyte (SE) for boosting a high ionic conductivity of 1.6×10−4 S cm−1 at 25 °C. The bulk ionic conducting mechanism is explored by elucidating the effect of atomic stacking mode within the layered framework on K+‐ion migration barriers. For ion diffusion at grain boundaries, the P2/P3 biphasic symbiosis property assists in tunning the SE microstructure, which crystallizes in rod‐like particles with lengths of tens of micrometers facilitating long‐distance ion transport and significantly decreasing grain boundary resistance. Potassium metal symmetric cells using the modified SE deliver excellent cycling life over 300 h at 0.1 mA cm−2 and a high critical current density of 0.68 mA cm−2. The quasi‐solid‐state potassium metal batteries (QSSKBs) coupled with two kinds of layered oxide cathodes demonstrate remarkable stability over 300 cycles, outperforming the liquid electrolyte counterparts. The QSSKB system provides a promising strategy for high‐efficiency, safe, and durable large‐scale energy storage.

Boosting K+-Ionic Conductivity of Layered Oxides via Regulating P2/P3 Heterogeneity and Reciprocity for Room-Temperature Quasi-Solid-State Potassium Metal Batteries.

Solid-state potassium metal batteries are promising candidates for grid-scale energy storage due to their low cost, high energy density and inherent safety. However, solid state K-ion conductors struggle with poor ionic conductivity due to the large ionic radius of K+-ions. Herein, we report precise regulation of phase heterogeneity and reciprocity of the P2/P3-symbiosis K0.62Mg0.54Sb0.46O2 solid electrolyte (SE) for boosting a high ionic conductivity of 1.6×10-4 S cm-1 at 25 °C. The bulk ionic conducting mechanism is explored by elucidating the effect of atomic stacking mode within the layered framework on K+-ion migration barriers. For ion diffusion at grain boundaries, the P2/P3 biphasic symbiosis property assists in tunning the SE microstructure, which crystallizes in rod-like particles with lengths of tens of micrometers facilitating long-distance ion transport and significantly decreasing grain boundary resistance. Potassium metal symmetric cells using the modified SE deliver excellent cycling life over 300 h at 0.1 mA cm-2 and a high critical current density of 0.68 mA cm-2. The quasi-solid-state potassium metal batteries (QSSKBs) coupled with two kinds of layered oxide cathodes demonstrate remarkable stability over 300 cycles, outperforming the liquid electrolyte counterparts. The QSSKB system provides a promising strategy for high-efficiency, safe, and durable large-scale energy storage.

Assessing the robustness of the Galactic rotation curve inferred from the Jeans equations using Gaia DR3 and cosmological simulations

Several authors have recently applied Jeans modelling to -based datasets to infer the circular velocity curve for the Milky Way. These works have consistently found evidence for a continuous decline in the rotation curve beyond $ kpc $, which may indicate the existence of a light dark matter (DM) halo. Using a large sample of Gaia DR3 data, we aim to derive the rotation curve of the Milky Way using the Jeans equations, and to quantify the role of systematic effects, both in the data and those inherent to the Jeans methodology under the assumptions of axisymmetry and time independence. We used data from the Gaia DR3 radial velocity spectrometer sample, supplemented with distances inferred through Bayesian frameworks, to determine the radial variation of the second moments of the velocity distribution for stars close to the Galactic plane. We used these profiles to determine the rotation curve using the Jeans equations under the assumption of axisymmetry and explored how they vary with azimuth and position above and below the plane of the Galactic disc. We applied the same methodology to an N-body simulation of a Milky Way-like galaxy impacted by a satellite akin the Sagittarius dwarf, and to the Auriga suite of cosmological simulations. The circular velocity curve we infer for the Milky Way is consistent with previous findings out to $ 15$ kpc, where our statistics are robust. Due to the larger number of stars in our sample, we are able to reveal evidence of disequilibrium and deviations from axisymmetry closer in. For example, we find that the second moment of $V_R$ flattens out at $R kpc, and that the second moment of $V_ is different above and below the plane for $R kpc. Our exploration of the simulations indicates that these features are typical of galaxies that have been perturbed by external satellites. From the simulations, we also estimate that the difference between the true circular velocity curve and that inferred from Jeans equations can be as high as $15<!PCT!>$, but that it is likely of the order of $10<!PCT!>$ for the Milky Way. This is higher than the systematic uncertainties associated with the observations or those linked to most modelling assumptions when using the Jeans equations. However, if the density of the tracer population were truncated at large radii instead of being exponential as often assumed, this could lead to the erroneous conclusion of a steeply declining rotation curve. We find that steady-state axisymmetric Jeans modelling becomes less robust at large radii, indicating that particular caution must be exercised when interpreting the rotation curve inferred in those regions. A more careful and sophisticated approach may be necessary for precision measurements of the DM content of our Galaxy.

On the nature of the eccentric eclipsing binary star SY Phe with a pulsating γ Dor component

ABSTRACT Spectroscopic observations of the eccentric binary system SY Phe were made at the South African Astronomical Observatory in 2019, 2020, and 2021, and its mid-resolution spectra were obtained. The radial velocities of the component stars were measured using the cross-correlation method and Fourier disentangling of the spectra. The spectral type (hence the effective temperature) of the primary star was determined from a model-atmosphere analysis. The radial velocity and Transiting Exoplanet Survey Satellite (TESS) light curves of the system were analysed, and its absolute parameters were derived. A strong (5.2 mmag) periodic signal with a frequency typical of $\gamma$ Dor stars (1.169 cycles per day) dominates the Fourier spectrum of the light curve between the eclipses. Apsidal motion parameters of SY Phe were calculated by studying eclipse timing variations. The Geneva evolution models indicate an evolutionary age of 2 Gyr and solar metallicity for the primary component; however, although the position of the secondary component in the H–R diagram matches the isochrone of 2 Gyr, it appears to have a larger radius and higher effective temperature than expected for its determined mass. Here, the secondary component has too large a radius, which is in accordance with the radius discrepancy problem that has been encountered in other studies, especially in late-type dwarfs, and has not been solved for half a century.

A Novel Anion Receptor Additive for -40ºCSodium MetalBatteriesby Anion/Cation Solvation Engineering.

Sodium metal batteries, known for their high theoretical specific capacity, abundant reserves,and promisinglow-temperature performance, have garnered significant attention. However, the large ionic radius of Na+and sluggish transport kinetics across the interfacial structure hinder their practical application.Previous reviews have rarely regulated electrolyte performance from the perspective of anions; as important components of the electrolyte, the regulation mechanism is not well understood. Herein, a novel anion receptor additive, 4-aminophenylboronic acid pinalol ester (ABAPE), is proposed to weaken the coupling between anions and cations and accelerateNa+transport kinetics.The results of theoretical calculations and X-ray photoelectron spectroscopy with deep Ar-ion etching demonstrate thatthe introduction of this additive alters the solvation structure of Na+, reducesthe desolvation barrier and formsa stable and dense electrode-electrolyte interface. Moreover, ABAPE forms hydrogen bonds (-NH···O/F) with H2O/HF, effectively preventing the hydrolysis of NaPF6and stabilizing acidic species. Consequently, the Na||Na symmetric cell exhibits excellent long-cycle performance of 500 h at 1 mA cm-2 and 0.5 mAh cm-2. The Na||Na3V2(PO4)3(NVP) full cell with the addition of ABAPE maintains a capacity retention of 84.29% at 1 C after1200 cycles and presents no capacity decayover 150 cycles at -40°C.

Effect of the position of Mg replacing Ni on O3-NaNi1/3Fe1/3Mn1/3O2 on the structural stability of cathode materials

O3-NaNi1/3Fe1/3Mn1/3O2 (NaNFM) materials are susceptible to complex phase transitions during electrical cycling leading to poor structural, capacity retention and multiplicity properties. These drawbacks hinder the application of NaNFM in sodium-ion batteries. Here, Mg2+ with larger ionic radius was used to dope its transition metal layer Ni site. The effects of Mg2+ doped NaNFM crystal structure and transition metal valence states on its electrochemical properties were investigated by XRD, SEM, and XPS. The capacity retention of NaNMFM-0.02 (84.05 %) was higher than that of NaNFM (73 %) after 200 cycles of the material at 5C. In addition, NaNMFM-0.02 achieved a first discharge specific capacity of 146.5 mAh/g at high voltage. Based on structural and electrochemical analyses, this improvement is attributed to the fact that magnesium acts as a “pillar” to stabilize the crystal structure of NaNFM, while magnesium doping reduces the Jahn-Teller effect. As a result, the material has better electrochemical properties.

Nonlinear dynamics and effects of fast-ion driven instabilities in HL-2A NBI heating high-βN H-mode plasmas

High-performance plasmas had been obtained with hybrid scenarios on HL-2A in past several years, and the quality factor G=H89βN/q952 is around 0.3-0.4. In these high-βN H-mode plasmas with βN>2.5 and H98>1.2 Chen et al. (2022) [24], there are multiple energetic-ion driven instabilities, such as toroidal Alfvén eigenmode (TAE) and beta-induced Alfvén eigenmode (BAE), and there are complex magnetohydrodynamic (MHD) dynamics, e.g. nonlinear mode-mode and mode-particle interactions. The TAE amplitude increases explosively, and the frequency is fast chirping in the range of f=90−150 kHz. The TAE toroidal mode-number is n=3−4, and they localize in outer plasma region. The BAE amplitude also increases explosively, and the BAE frequency is fast chirping in the range of f=50−90 kHz. The toroidal mode-number of dominant BAEs is n=2, and these modes localize at q=2 rational surface where there is a large radius internal transport barrier (ITB). Generally, the energetic-ion fraction is low in outer plasma region. It indicates that thermal ions at large radius ITB location possibly provide additional drive and destabilize the BAE in company with energetic-ions. These TAEs/BAEs occur regularly in high-βN region and before large type-I ELM burst. To further illuminate the characteristics of these Alfvénic modes, the 2D and radial mode structures had been calculated by using a well-benchmarked general Alfvénic mode eigenvalue code (MAS). The experimental results suggest that these Alfvénic modes may have important effects on the pedestal transport and ELM-onset.

High-Performance Sodium-Ion Batteries with Graphene: An Overview of Recent Developments and Design.

Due to their low production cost, sodium-ion batteries (SIBs) are considered attractive alternatives to lithium-ion batteries (LIBs) for next generation sustainable and large-scale energy storage systems. However, during the charge/discharge cycle, a large volume strain is resulted due to the presence of a large radius of sodium ions and high molar compared to lithium ions, which further leads to poor cyclic stability and lower reversible capacity. In the past, researchers have devoted significant efforts to explore various anode materials to achieve SIBs with high energy density. Hence, as a promising anode material for SIBs, the two-dimensional (2D) materials including graphene and its derivatives and metal oxides have attracted remarkable attention due to their layered structure and superior physical and chemical properties. The inclusion of graphene and metal oxides with other nanomaterials in electrodes have led to the significant enhancements in electrical conductivity, reaction kinetics, capacity, rate performance and accommodating the large volume change respectively. Moreover, these 2D materials facilitated large surface areas and shorter paths for sodium ion adsorption and transportation respectively. In this review article, the fabrication techniques, structural configuration, sodium ion storage mechanism and its electrochemical performances will be introduced. Subsequently, an insight into the recent advancements in SIBs associated with 2D anode materials (graphene, graphene oxide (GO), transition metal oxides etc.) and other graphene-like elementary analogues (germanene, stanine etc.) as anode materials respectively will be discussed. Finally, the key challenges and future perspectives of SIBs towards enhancing the sodium storage performance of graphene-based electrode materials are discussed. In summary, we believe that this review will shed light on the path towards achieving long-cycling life, low operation cost and safe SIBs with high energy density using 2D anode materials and to be suitably commercialized for large-scale energy storage applications in the future.

Optimizing the crystal structure and electrochemical properties of Na4MnCr(PO4)3 by trace La doping

Na4MnCr(PO4)3, a manganese-based NASICON-type phosphate cathode material, is attracted considerable attention due to its high voltage and energy density. However, its practical application is hindered by poor electronic conductivity and inferior sodium ion diffusion kinetics. In this study, trace La3+ is utilized to optimize the lattice structure of Na4MnCr(PO4)3 due to its unique energy level structure. La3+ doping significantly enhances the local environment of the Mn-O bond and stabilizes the lattice structure by improving covalency, thereby mitigating Mn dissolution during charge–discharge cycles. Additionally, the large ionic radius of La3+ promotes the sodium ion transport kinetics by expanding the cell volume and facilitating rapid sodium storage. As a result, the optimal Na4MnCr0.995La0.005(PO4)3/C sample demonstrates an impressive initial discharge specific capacity of 124.5 mAh g−1 at 0.1C and superior cycling stability with a capacity retention of 70.2 % after 500 cycles at 5C. Furthermore, density functional theory calculations indicate that La3+ doping can enhance conductivity and reduce the energy barrier for sodium ion diffusion. This study presents an effective and cost-efficient doping strategy for modifying high-energy density NASICON-type phosphate cathode materials, showing promising potential in the field of sodium ion batteries.

Sr-Doping-Modulated Metal-Insulator Transition in NdNiO3 Epitaxial Films

Abstract Perovskite-structured nickelates, ReNiO3 (Re = rare-earth), have long garnered significant research interest due to their sharp and highly tunable metal-insulator transition (MIT). Doping the parent compound ReNiO3 compound with alkaline earth metal can substantially suppress this MIT. Recently, intriguing superconductivity has been discovered in doped infinite-layer nickelates (ReNiO2), while the mechanism behind A-site doping-suppressed MIT in the parent compound ReNiO3 remains unclear. To address this question, we grew a series of Nd1-x Sr x NiO3 (x = 0 ~ 0.2) thin films and conducted systematic electrical transport measurements. Our resistivity and Hall measurements suggest that Sr-induced excessive holes is not the primary reason for MIT suppression. Instead, first-principles calculations indicate that Sr cations, with larger ionic radius, suppress breathing mode distortions and promote charge transfer between oxygen and Ni cations. This process weakens Ni-O bond disproportionation and Ni2+/Ni4+ charge disproportionation. Such significant modulations in lattice and electronic structure convert the ground state from a charge-disproportionated antiferromagnetic insulator to a paramagnetic metal, thereby suppressing the MIT. This scenario is further supported by the weakened MIT observed in the tensile-strained NSNO/STO(001) films. Our work reveals the A-side doping-modulated electrical transport of perovskite nickelate films, providing deeper insights into novel electric phases in these strongly correlated nickelate systems.

Photometric properties of classical bulge and pseudo-bulge galaxies at 0.5 z<1.0

We compare the photometric properties and specific star formation rate (sSFR) of classical- and pseudo-bulge galaxies with $M_* odot $ at $0.5 z<1.0$, selected from all five CANDELS fields. We also compare these properties of bulge galaxies at lower redshift selected from MaNGA survey in previous work. This paper aims to study the properties of galaxies with classical and pseudo-bulges at intermediate redshift, to compare the differences between different bulge types, and to understand the evolution of bulges with redshift. Galaxies are classified into classical bulge and pseudo-bulge samples according to the S$ e $rsic index n of the bulge component based on results of two-component decomposition of galaxies, as well as the position of bulges on the Kormendy diagram. For the 105 classical bulge and 86 pseudo-bulge galaxies selected, we compare their size, luminosity, and sSFR of various components. At a given stellar mass, most classical bulge galaxies have smaller effective radii, larger $B/T$, brighter and relatively larger bulges, and less active star formation than pseudo-bulge galaxies. In addition, the two types of galaxies have larger differences in sSFR at large radii than at the central region at both low- and mid-redshifts. The differences between the properties of the two types of bulge galaxies are generally smaller at mid-redshift than at low-redshift, indicating that they are evolving to more distinct populations towards the local universe. Bulge type is correlated with the properties of their outer disks, and the correlation is already present at redshifts as high as $0.5<z<1$.

Investigation of a new group of low band-gap semiconducting double perovskite K2MgSnZ6 (Z = Cl, Br, & I) materials and their structural, electronic, mechanical, and optical behaviors via DFT study

This study focuses on potassium based double perovskite materials, specifically a series of K2MgSnZ6 (Z = Cl, Br, & I) halide materials. For the investigated materials, all primary calculations were performed using the Full-Potential Linearized Augmented Plane-Wave (FP-LAPW) method, supported by density functional theory (DFT), and implemented in the WIEN2k code. The Gold-Schmidt tolerance factor values confirm the structural stability of the compounds, while the negative values of formation energy indicate the feasibility of experimental synthesis of the studied materials. The lattice constants were observed to increase as the halide element at the ‘Z’ position was replaced by one with a larger ionic radius. The recorded band-gap values were 2.60 eV, 2.00 eV, and 1.37 eV for K2MgSnCl6, K2MgSnBr6, and K2MgSnI6, respectively. After calculating the elastic constants for all K2MgSnZ6 (Z = Cl, Br, & I) materials, it was found that they satisfy the primary conditions for Born stability required for cubic-phase materials: (1) C11 > B > C12, (2) C11 + 2C12 > 0, (3) C11 > 0, (4) C44 > 0, and (5) C11–C12 > 0. The optical parameters of the K2MgSnZ6 (Z = Cl, Br, & I) double perovskite materials suggest that these materials could play a significant role in practical applications such as solar cells, UV detectors, and various optoelectronic devices.

Safety Clearance and Artifact Testing of a Nitinol Breast Biopsy Clip in an Ultra-High Resolution (7 Tesla) Magnetic Resonance Imaging Environment

Abstract Background The lack of safety clearance of several metallic breast biopsy clips in 7 Tesla (T) poses a significant hurdle to using advanced magnetic resonance imaging (MRI) techniques in clinical management or cancer research. Aims This article assesses the Ultracor Twirl clip for safety and imaging artifacts in a 7T MRI scanner. Setting and Design This study can be categorized as a phantom study. Materials and Methods Tests for magnetic susceptibility (translational attraction and torque), MRI-related heating, and artifacts were conducted based on the American Society for Testing and Materials standards. The magnetic susceptibility tests evaluated the scanner's magnetic force that can cause clip movement and rotation. The heating test was conducted with customized MRI parameters of short TR and maximum echo-train length, designed to induce temperature change. The artifact test, using T1-weighted spin and gradient echo imaging sequences, evaluated potential image misrepresentations (localized signal loss) caused by the clip's metallic properties. Statistical Tests None. Results and Conclusion The magnetic susceptibility tests indicated no noticeable translational or rotational force exerted by the MRI scanner. The heating test indicated no significant temperature change (<0.3°C) in the testing gel when the clip was absent/present, both within the safety threshold (<1°C). The artifact test's clip images all contained an artifact (largest radius = 10.7 mm). These cumulative results indicate that this clip is safe in 7T scanners. Scanning at least 10.7 mm away from the clip avoids potential signal loss in the region of interest.

Active Fire Clustering and Spatiotemporal Dynamic Models for Forest Fire Management

Forest fires are increasingly destructive, contributing to significant ecological damage, carbon emissions, and economic losses. Monitoring these fires promptly and accurately, particularly by delineating fire perimeters, is critical for mitigating their impact. Satellite-based remote sensing, especially using active fire products from VIIRS and MODIS, has proven indispensable for real-time forest fire monitoring. Despite advancements, challenges remain in accurately clustering and delineating fire perimeters in a timely manner, as many existing methods rely on manual processing, resulting in delays. Active fire perimeter (AFP) and Timely Active Fire Progression (TAFP) models were developed which aim to be an automated approach for clustering active fire data points and delineating perimeters. The results demonstrated that the combined dataset achieved the highest matching rate of 85.13% for fire perimeters across all size classes, with a 95.95% clustering accuracy for fires ≥100 ha. However, the accuracy decreased for smaller fires. Overall, 1500 m radii with alpha values of 0.1 were found to be the most effective for fire perimeter delineation, particularly when applied at larger radii. The proposed models can play a critical role in improving operational responses by fire management agencies, helping to mitigate the destructive impact of forest fires more effectively.

Strategically Modulating Proton Activity and Electric Double Layer Adsorption for Innovative All-Vanadium Aqueous Mn2+/Proton Hybrid Batteries.

Aqueous Mn-ion batteries (MIBs) exhibit a promising development potential due to their cost-effectiveness, high safety, and potential for high energy density. However, the development of MIBs is hindered by the lack of electrode materials capable of storing Mn2+ ions due to acidic manganese salt electrolytes and large ion radius. Herein, the tunnel-type structure of monoclinic VO2 nanorods to effectively store Mn2+ ions via a reversible (de)insertion chemistry for the first time is reported. Utilizing exhaustive in situ/ex situ multi-scale characterization techniques and theoretical calculations, the co-insertion process of Mn2+/proton is revealed, elucidating the capacity decay mechanism wherein high proton activity leads to irreversible dissolution loss of vanadium species. Further, the Grotthuss transfer mechanism of protons is broken via a hydrogen bond reconstruction strategy while achieving the modulation of the electric double-layer structure, which effectively suppresses the electrode interface proton activity. Consequently, the VO2 demonstrates excellent electrochemical performance at both ambient temperatures and -20°C, especially maintaining a high capacity of 162mAhg-1 at 5Ag-1 after a record-breaking 20000 cycles. Notably, the all-vanadium symmetric pouch cells are successfully assembled for the first time based on the "rocking-chair" Mn2+/proton hybrid mechanism, demonstrating the practical application potential.

Microwave absorption properties of ytterbium substituted X-type ferrite in P-, L-, S-, and C-band

Ba1.5Sr0.5Zn2Fe28-xYbxO46 (x = 0.00, 0.07, 0.14, 0.21, and 0.28) hexaferrite were synthesized via sol-gel auto-combustion route to investigate the microwave absorption performance in different frequency bands. The structure has a single phase, and the variation in lattice parameter was observed due to Yb-content as host iron Fe3+ and substituted Yb3+ having different ionic radii. Microwave absorbing materials (MAMs) need to be lightweight, and the maximum crystallite size of prepared material is 41 nm. The physical properties vary with substitution, and the X-ray density value is higher than the bulk density, and the porosity of the prepared sample increases when the bulk density decreases. Micro-strain values are inverse to the crystallite size because Yb3+ has larger ionic radii than Fe3+. Rietveld refinement of the XRD patterns was conducted with a lower significance value. FTIR bands observed between 414 and 500 cm−1 are present due to iron-oxygen bond stretching and bending vibrations at octahedral and tetrahedral lattice sites. The cation distribution is highly responsible for the peak position of octahedral and tetrahedral sites—the dielectric constant increases with frequency because of dipole, interfacial, and electronic/atomic polarization. AC conductivity is very low, reflecting that the material can be used as a dielectric medium in the microwave frequency range's L, S, and C bands. The best MAM among all prepared materials is Ba1.5Sr0.5Zn2Fe27.72Yb0.28O46 which can be used for global positioning systems, weather radar, and satellite feeds as it has an excellent dielectric loss, remarkable tangential loss, and the reflection loss in P-, L-, S-, and C-bands. Other real-life application of all prepared materials are multi-layer chip inductor and longitudinal media recording.