Large Emission Research Articles

Tm3+-doped barium antimony germanate glass fibers for achieving 1.8–2 µm lasers

Near- and mid-infrared fiber lasers at the ∼2µm wavelength range are essential for applications such as medical diagnostics, environmental monitoring, and military confrontation. However, developing materials that provide both anti-crystallization stability and high gain in this range remains challenging. This study presents the development of high-gain Tm3+-doped barium antimony germanate (BaO−Sb2O3−GeO2, abbreviated as BSG) glass fiber, designed to achieve laser emission at 1.8–2 µm. Based on the glass-forming region, the composition of BSG bulk glass is optimized, and it exhibits a high Tm3+ doping concentration (N=3.3×1020ions/cm3), excellent anti-crystallization stability (ΔT=250∘C), and a large emission cross-section (σ e =8.4×10−21cm2). Tm3+-doped BSG optical fibers are fabricated using a melting–quenching method with a large full width at half-maximum of up to 200 nm in their amplified spontaneous emission spectra. Such Tm3+-doped BSG fibers produced gain coefficients of 6.48 dB/cm at 1950 nm and 6.03 dB/cm at 1867 nm when pumped at 1570 nm, respectively. Furthermore, laser outputs of 1862 nm and 1964 nm are achieved using a 2 cm long Tm3+-doped BSG glass fiber, highlighting the potential of BSG glass fibers in near- and mid-infrared laser applications.

Modelling long-term Greenhouse Gas mitigation pathways for Mongolia

Abstract Mongolia’s faces substantial challenges to reduce its Greenhouse Gas (GHG) emissions due to a reliance on coal to meet electricity, heat and other energy demand and large livestock emissions. Despite this, Mongolia has committed to reduce GHG emissions by 22.7% in 2030 compared to a baseline emission scenario. Greenhouse gas mitigation assessments for Mongolia have focussed on actions to achieve emission reductions by 2030, but not on the potential for further reduction over the longer-term. This study addresses this gap through the development of long-term (2050) GHG emission pathways for Mongolia. From a technical mitigation potential perspective, these pathways aim to inform what level of GHG reduction targets Mongolia could commit to for the period after its current target expires. Greenhouse gas emissions are quantified for historic years (2010-2019) for all major GHG emitting source sectors, and projected to 2050 based on the population and socioeconomic development outlined in Mongolia’s Sustainable Development Vision 2050. Finally, mitigation scenarios that model implementation of 49 specific mitigation measures are developed, to quantify their emission reduction potential. Without mitigation, GHG emissions were estimated to increase by 67% and 139% in 2030 and 2050, respectively, compared to 2019 levels (39 million tonnes CO2-eq emissions). Implementation of the 49 mitigation measures could reduce GHG emissions by 40% in 2050 compared to the baseline. This study highlights that post-2030, Mongolia could increase its climate change mitigation ambition. Renewable Electricity generation, and energy efficiency were the measures that could achieve the majority of these additional emission reductions. However, despite the achieve emission reductions in excess of those within current commitments, there remains a substantial gap between the emission reduction potential of technically feasible measures currently being considered in Mongolia’s climate change mitigation planning, and full decarbonisation.

Large solar energetic particles and solar radio emissions during Cycle 25. A comparative analysis of trends and characteristics with cycles 23 and 24

Solar energetic particles (SEPs) affect space weather in both the heliosphere and on Earth. The present study investigates the occurrences of large SEP events focusing on their influence on the Earth, as well as their correlation with solar radio bursts (SRBs). The velocity dispersion analysis (VDA) is used to calculate the release times of large SEP events from their launch locations, as well as their apparent path length that connects them to interplanetary magnetic fields lines. According to the study, 122 large SEP events impacted the planet Earth from 1997 to 2024. The comparison of occurrence rates with previous solar cycles (SCs) suggests that SC 25 will peak with greater solar activity than the cycle 24 in terms of large SEP occurrences since large SEP events correlate well with the pattern of the sunspot cycle progression. In general, a few (35 out of 122) large SEP events are typically released from the Sun at times that coincide with the peak of associated solar flares and the onsets of corresponding SRBs indicating no delay while the rest have delayed in the release. The projected apparent lengths (L) range from 1.0 to 3.0 AU, with L exceeding 1.5 AU due to particle scattering and launch site pitch angles. The majority (115/122) of SEP occurrences are accelerated by shock waves from solar flares, CMEs, and fast plasma flow in the magnetic reconnection regions. Relevant SRBs for space weather study as they precede large SEP events diagnose the properties of particle populations propelled by solar flares and CMEs. This study finds that 90% of the large SEP events are preceded by solar radio emissions of type II, III and IV; and WAVES/STEREO revealed ∼76% of SRBs have continuation in IP medium indicating the dynamics of associated shocks and electron beams traveling along open and quasi-open magnetic field lines. Thus, SRB monitoring continues to be a valuable tool for studying space weather and understanding physical phenomena in the solar corona and IP medium, such as particle populations that cause large SEP occurrences.

Insights into the Solution Processing of Non-van der Waals Boron Carbide.

Exfoliation of non-layered materials is crucial to unleash their enormous potential in wide range of applications. However, the presence of strong non-van der Waals interactions in all three dimensions makes exfoliation challenging. Boron carbide (B4C), known for its high hardness, holds great potential for diverse applications. In this work, B4C is exfoliated in 29 solvents to determine its Hansen solubility parameters (HSP) and understand the dispersion stability. The experimentally determined HSP values are 19.6, 15.3 and 15.1 MPa1/2 for dispersive interactions (δD), polar interactions (δP) and hydrogen bonding interactions (δH), respectively. Subsequently, in situ dispersion stability is analyzed qualitatively and quantitatively from the space-time resolved extinction profiles employing an analytical centrifuge. The sedimentation kinetics of B4C dispersions are analyzed using instability index, integral extinction and sedimentation velocity. B4C dispersions in solvents like ε-caprolactone, isopropyl alcohol, propylene carbonate and formamide exhibited excellent stability. Additionally, B4C nanosheets are utilized to investigate their field emission properties. These nanosheets exhibit a turn-on electric field of 3.35 V/μm at an emission current density of 1 μA cm-2, and it delivered a large emission current density of ~ 375 μA cm-2 at an applied electric field of 5.7 V/μm.

Satellite‐Based Identification of Large Anthropogenic NMVOC Emission Sources

AbstractNonmethane volatile organic compounds (NMVOCs) emitted in excess from anthropogenic sources significantly contribute to the formation of harmful pollutants, thereby degrading air quality. While satellite measurements have become valuable tools for tracking anthropogenic emitters, they have primarily targeted inorganic species and methane (). This study demonstrates the potential of infrared atmospheric sounding interferometers (IASI) to detect anthropogenic NMVOC point sources on a global scale. Using an advanced oversampling technique, we enhance the spatial resolution of IASI measurements to identify emitters of three major NMVOCs: methanol (OH), acetylene (), and propylene (). These point sources are primarily associated with chemical and petrochemical facilities, coal‐burning activities, metallurgy, pharmaceutical manufacturing sites, and megacities. We also highlight the value of combining IASI measurements of NMVOCs with those of the inorganic species, such as sulfur dioxide () and ammonia (), to aid in the identification of anthropogenic point sources.

A Novel Colon-Targeting Ratiometric Probe with Large Emission Shift for Imaging Peroxynitrite in Ulcerative Colitis.

Ulcerative colitis (UC) is an inflammatory disease that leads to the overexpression of peroxynitrite (ONOO-). Up to now, it has been a challenge to design a colon-targeted fluorescent probe with a large emission shift that can detect and image ONOO- in UC mice. Here, a fluorophore (pyran-coumarin) is linked with cholic acid to develop a colon-targeted fluorescent probe (CPC) for the detection of ONOO-. The fluorescent probe showed strong near-infrared emission at 725 nm. After reacting with ONOO-, it can be observed that the fluorescence intensity at 725 nm decreases obviously, and the signal at 490 nm increases clearly with an obvious emission shift (235 nm). This response mechanism causes the probe to have good sensitivity and selectivity. Additionally, the probe CPC shows good targeting ability for the cells with overexpressingTGR5 receptors and displays good results for detecting exogenous and endogenous ONOO- in the cells. More importantly, the probe CPC can be especially assembled in the colon site to distinguish normal and UC mice and provide significant information for the diagnosis of UC.

Energy Transfer for Constructing Circularly Polarized Luminescence Materials: Recent Progress and Future Prospects

AbstractCircularly polarized luminescence (CPL) materials hold significant promise in multidisciplinary fields such as circularly polarized organic light‐emitting diodes, biological probes, data storage, and information encryption. However, these cutting‐edge applications also put forward higher requirements for the design of CPL materials, requiring large dissymmetry factor and high emission quality. For this purpose, diverse approaches have been explored to generate and enhance CPL emission. Among them, energy transfer (ET) strategy stands out as it can be readily implemented in a wide range of CPL materials. The present work overviews latest advances in energy transfer for generating and modulating CPL, involving small organic molecules, polymers, metal complexes, liquid crystals, as well as new‐emerging chiral luminescent materials. It is anticipated that the review article will garner increased attention toward energy transfer systems and facilitate the advancement of CPL materials.

Characteristics of Volatile Organic Compounds Emissions and Odor Impact in the Pharmaceutical Industry

Volatile Organic Compounds (VOCs) are not only essential precursors for the formation of ozone and PM2.5, but also hazardous to human health and responsible for unpleasant odors. The pharmaceutical industry has become an important industrial source of VOCs due to China’s large emissions and complex emission chains. In total, 245 VOCs samples were collected and analyzed from 11 typical pharmaceutical companies in Zibo City of the North China Plain, in order to investigate the VOCs emission characteristics and odor impacts. The emission factor for the pharmaceutical industry was 7.97 ± 8.21 g/kg pharmaceuticals, while the main emission links were chimney emissions, equipment sealing leakage, and so on. Finally, considering both purifying efficiency and economic benefits, the multistage absorption (AB) method is most effective for VOCs concentrations below 100 mg/m3, while UV photo-oxygenation combined with adsorption (UVA) is more suitable for concentrations below 300 mg/m3. The Regenerative Thermal Oxidizer (RTO), Catalytic Oxidizer (CO), and Condensation + Adsorption (CA) technologies demonstrated greater stability and efficiency, particularly in the treatment of complex organic pollutants, highlighting their advantages in both VOCs and odor removal at higher concentrations.

Dual-Mode Stretchable Emitter with Programmable Emissivity and Air Permeability.

Materials with anisotropic emission characteristics have attracted considerable attention for thermal management. Although many dual-mode emitters have been developed for this purpose in the form of textiles, multilayer films, and photonic structures, multiple functionalities are essential for their versatile applications. Herein, a highly stretchable dual-mode emitter with programmable emissivity and air permeability is presented. The emitter comprises a planar Ge2Sb2Te5 (GST) cavity on one side of a perforated elastomer substrate and an infrared-reflecting metal layer on the other side. With a laser-induced phase transition from amorphous to crystalline GST, the emitter exhibits a large emissivity difference of 0.52 between both sides. The dual-mode emitter remains highly stable without mechanical failure after repeated stretching cycles to a strain of 50%. This air-permeable and stretchable emitter can be attached to any curved surface, including the human body. The GST-side emissivity can be programmed into an arbitrary emissivity pattern using a spatially modulated laser beam, ultimately enabling the printing of mutually independent visible and thermal images in a single emitter. This study provides a promising structure for multispectral optical security as well as thermal management.

Supression of shielding effect of large area field emitter cathode in radio frequency gun environment

Abstract Utilisation of large area field emitters (LAFE) cathodes for rf gun injector hold promise for delivering compact, high power and high brightness electron beam for advanced accelerator technologies. LAFEs subjected to DC electric fields posses significant challenges due to the shielding effect which restricts emission from central emitters and decreases the overall current density. Mitigating the shielding effect of LAFE in rf gun environment is essential for meeting the desired beam quality requirement in an accelerator. The current distribution of LAFE under DC conditions depend on its various geometrical parameters such as emitter height, inter-emitter distance, aspect ratio, number of emitters. Additionally, in rf gunsetup, LAFEs are subjected to variable macroscopic electric field at different emitter position which can potentially alter the current distribution compared to DC fields. In this work, we have systematically studied the shielding effect properties of LAFE in rf gun environment under the influence of various LAFE parameters. A semi-analytical approachhas been adopted to estimate the current distribution which combines the analytically calculated field enhancement factor (γ) and numerically calculated applied rf field values. This new methodology was first validated using COMSOL simulation and then employed for field emission performance estimation of a LAFE cathode integrated in a½ cell S-band (2856 MHz) rf gun. The simulation results reveals that under favourable conditions, a Gaussian spatial distribution of beam can be obtained from LAFE thus countering the shielding effect typical in DC fields. By optimizing the LAFE parameters, the desired current and beam distribution pattern can be achieved. This study highlights the adoption of a promising approach for designing LAFE cathodes suitable for rf gun which can lead to advancement of field emission technologies for accelerator-related applications.

Experimental Investigation on Rock Failure Characteristics of Large-Span Goafs Using Digital Image Correlation Analysis and Acoustic Emission Monitoring

Rockmass in deep mining is highly susceptible to large-scale collapses under high stress and blast-induced disturbances, leading to casualties and economic losses. To investigate the evolution characteristics of goaf instability and the types of seismic sources that induce instability, an experiment on goaf instability was designed under uniaxial compression conditions based on actual mining operations. The entire experimental process was monitored using digital image correlation analysis and acoustic emission monitoring. By calculating the digital speckle field on the surface of the rock specimen during the experiment, the evolution characteristics of the deformation and strain fields from the beginning of loading to complete failure were analyzed. The study explored the dynamic behavior of cracks from initiation to propagation and eventually inducing large-scale collapse. The results show that the instability process of the goaf begins with the formation of tensile cracks. As stress increases, shear cracks occur in the specimen, leading to macroscopic failure. Furthermore, based on the differences in overall microfracture types measured by RA-AF characteristic parameters during specimen failure, large amplitude acoustic emission events corresponding to the formation of dominant macroscopic cracks were selected, and the focal mechanisms of these events were inverted. The results indicate that shear failure sources are significantly more prevalent than tensile failure sources in acoustic emission events leading to goaf instability. These findings can provide useful guidance for the support design and the prevention and control of rockmass instability disasters.

Europium-Infused Polystyrene Nanoparticles for Enhanced Bacterial Labeling in Microscopic Imaging

Luminescence microscopic imaging has become an indispensable tool in diagnostics and therapeutics. Lanthanide luminescent complexes (LLCs) have proven to be invaluable in this endeavor due to certain attractive characteristics such as long decay times, large Richardson shifts and narrow emission bands. However, the insolubility of these complexes and the negative effects of the aqueous environment on their photophysical properties still restrict their biological applications. By embedding luminescent Eu3+ complexes into polystyrene nanoparticles (NPs), these complexes can not only maintain their photophysical properties, but even enhance them. This leads to exceptionally high quantum yields (> 90 %) and decay times ( >800 μs). In addition, the surfaces of the NPs described here are covered with primary amine groups, which may be exploited for various interesting bioconjugation chemistries. In the present application, they were modified with N-hydroxysuccinimide (NHS) esters and then coupled either electrostatically or covalently to both, Gram-positive and Gram-negative bacteria, labeling them for luminescence microscopic imaging. This, to the best of our knowledge, is the first report of polymer NPs infused with LLCs for bacteria labeling.

IPCC Emission Factor Overestimates N2O Emissions from Agricultural Ditches.

Agricultural ditches emit disproportionate amounts of nitrous oxide (N2O), but their contributions to regional or global N2O emissions remain unclear due to limited data. The Intergovernmental Panel on Climate Change (IPCC) recommends using emission factors (EFs) to estimate indirect N2O emission, but the EF for ditches (EF5g) is categorized as groundwater, which potentially introduces a significant bias. This study conducted a regional-scale campaign in the North China Plain, one of the world's most intensive agricultural regions, and calculated the EF5g values from agricultural ditches by the concentration method (N2O-N/NO3--N). The results found that the regional-scale mean EF5g value (0.0028) was less than half of the IPCC default value (0.006), illustrating that the current IPCC methodology significantly overestimates N2O emissions from agricultural ditches. Despite the relatively small EF5g values, agricultural ditches exhibited a high mean N2O concentration (3.36 μg L-1) and a large regional emission (1.14 ± 0.86 Gg N2O-N yr-1), which is equal to 3.8 ± 2.9% of direct N2O emission from the croplands in the North China Plain. Since ditches are ubiquitous in agricultural regions and are likely to expand under climate change, refining EF5g is crucial to accurately assess their contribution to global N2O budgets.

Coal Phase-Out and Carbon Tax Analysis with Long-Term Planning Models: A Case Study for the Chilean Electric Power System

Large CO2 emissions constitute a significant problem today due to their effect on climate change, and the need to design appropriate energy policies to mitigate their consequences and reduce emissions requires a detailed analysis of one of the main sources of such emissions: the electricity system. Thus, this paper presents a study on the effects of energy policies on decarbonization by comparing the detailed phase-out of coal-fired power plants across a range of cases with the implementation of a carbon tax to meet Nationally Determined Contributions (NDCs). The case study focuses on the Chilean electricity system, using a long-term generation and transmission expansion planning model (GTEP) that incorporates a wide range of generation technologies. The study examines the long-term effects of these policies, including costs, investments, and CO2 emissions, as well as their impact on consumer prices reflected in the marginal costs of the system. The transmission system modeling covers various regions of Chile and significant projections for renewable energy sources. It evaluates three economic scenarios based on generation technology costs, fuel prices, and electricity demand under four different closure schemes and fourteen different carbon tax levels. The results indicate that implementing a carbon tax can be more cost-effective for the system than the implementation of a phase-out schedule for coal plants, taking the form of reduced CO2 emission and overall system costs, with an optimal carbon tax value of 37 USD/tCO2. Additionally, the study reveals significant effects on consumer prices, showing that a carbon tax as an energy policy leads to lower prices compared to a phase-out scheme.

Infrared thermochromic antenna composite for self-adaptive thermoregulation

Self-adaptive thermoregulation, the mechanism living organisms use to balance their temperature, holds great promise for decarbonizing cooling and heating processes. This functionality can be effectively emulated by engineering the thermal emissivity of materials to adapt to background temperature variations. Yet, solutions that marry large emissivity switching (Δϵ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\varDelta \\epsilon$$\\end{document}) with scalability, cost-effectiveness, and design freedom are still lacking. Here, we fill this gap by introducing infrared dipole antennas made of tunable thermochromic materials. We demonstrate that non-spherical antennas (rods, stars and flakes) made of vanadium-dioxide can exhibit a massive (~200-fold) increase in their absorption cross-section as temperature rises. Embedding these antennas in polymer films, or simply spraying them directly, creates free-form thermoregulation composites, featuring an outstanding Δϵ~0.6\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\varDelta \\epsilon \\sim 0.6$$\\end{document} in spectral ranges that can be tuned at will. Our research paves the way for versatile self-adaptive heat management solutions (coatings, fibers, membranes, and films) that could find application in radiative-cooling, heat-sensing, thermal-camouflage, and other.

Realizing Near-Unity Photoluminescence Efficiency in Antimony-Doped Indium-Based Halides Induced by Strong Electron-Phonon Coupling.

Exploring a zero-dimensional (0D) hybrid halide with a large Stokes shift and efficient broad-band emission is highly desirable due to its enormous potential for solid-state lighting (SSL) application. However, it is still challenging to develop a highly emissive 0D hybrid halide with low toxicity and remarkable stability. Herein, we developed a novel indium-based metal halide A5In2Cl16·4H2O (A = doubly protonated 1,4-diaminobutane) whose inorganic octahedrons are completely isolated by the organic cations to form the 0D structure. Experimental and theoretical studies confirmed that Sb-doped A5In2Cl16·4H2O exhibits broad yellow emission with a photoluminescence quantum yield (PLQY) of up to 98%. The intense yellow emission can be attributed to the radiative recombination of triplet self-trapped excitons (STEs) in [SbCl6]3- octahedrons caused by the strong electron-phonon coupling. Benefiting from the excellent stability and photoluminescence performance, A5In2Cl16·4H2O:15%Sb was used as the yellow phosphor to prepare a white-light-emitting diode (WLED) device with a color rendering index of 87.8 and a luminous efficiency of up to 36.18 lm/W, demonstrating its potential in SSL applications. This work provides a guidance for developing environmentally friendly, efficient, and stable ultraviolet (UV)-excited broad-band emission materials.

Unraveling Urban NOx Emission Sources in Polluted Arctic Wintertime Using NO2 Nitrogen Isotopes

AbstractNitrogen (N) isotopic fractionation during nitrogen oxides (NOx) cycling and conversion into atmospheric nitrate alters the original N isotopic composition (δ15N) of NOx emissions. Limited quantification of these isotopic effects in urban settings hampers the δ15N‐based identification and apportionment of NOx sources. δ15N of nitrogen dioxide (NO2) measured during winter in downtown Fairbanks, Alaska, displayed a large temporal variability, from −10.2 to 24.1‰. δ15N(NO2) records are found to be driven by equilibrium isotopic fractionation, at a rate in very close agreement with theoretical predictions. This result confirms that N isotopic partitioning between NO and NO2 can be accurately predicted over a wide range of conditions. This represents an important step for inferring NOx emission sources from isotopic composition measurement of reactive nitrogen species. After correcting our δ15N(NO2) measurements for N fractionation effects, a δ15N‐based source apportionment analysis identifies vehicle and space heating oil emissions as the dominant sources of breathing‐level NOx at this urban site. Despite their large NOx emissions, coal‐fired power plants with elevated chimney stacks (>26 m) appear to make a small contribution to surface NOx levels in downtown Fairbanks (likely less than 18% on average). The combined uncertainties of the δ15N of NOx from heating oil combustion and of the influence of low temperatures on the δ15N of NOx emitted by vehicle exhaust prevent a more detailed partitioning of surface NOx sources in Fairbanks.

Coordination-driven molecular switch on the base of an ESIPT-capable pyrimidine ligand: Synthesis, fine-tuning of emission by the halide anion and theoretical studies

ESIPT-based materials (ESIPT = Excited State Intramolecular Proton Transfer) find diverse applications in optoelectronics and biomedicine owing to the peculiarities of their luminescence properties. Here, an ESIPT-capable compound 2-(3,5-dimethyl-1H-pyrazol-1-yl)-4-(2-hydroxyphenyl)pyrimidine (HL4,2,Me) featuring a short O–H⋅⋅⋅N intramolecular hydrogen bond and two N,N-sites for metal binding has been synthesized. HL4,2,Me is the first reported molecule which can act as an ESIPT molecular switch triggered by metal ion coordination without its deprotonation. Drastic changes in the HL4,2,Me conformation in the [Zn(HL4,2,Me)X2] (X = Cl, Br,I) complexes significantly alter the photoluminescence response compared to the free ligand. In the solid state, HL4,2,Me exhibits barrierless ESIPT and large Stokes-shifted yellow-orange emission due to the interplay of anti-Kasha S2 → S0 fluorescence and Kasha-like T1 → S0 phosphorescence radiative channels. The violation of Kasha’s rule for HL4,2,Me is justified by an extraordinarily large S2 – S1 energy gap (ca. 0.9 eV), slowing down the rate of S2 → S1 internal conversion. The photoluminescence behavior of the ESIPT–incapable zinc(II) coordination compounds strongly depends on the halide anion: the chlorido complex exhibits only fluorescence, the bromido complex displays a minor phosphorescence channel in addition to a major fluorescence channel, while the iodido complex exhibits predominantly phosphorescence. As a result, the emission color of the [Zn(HL4,2,Me)X2] complexes changes gradually from blue for X = Cl to orange for X = I, providing a platform for the fine-tuning of emission by the halide anion.

Intramolecular Charge Transfer Inhibition Strategy toward a Desired Solvatochromic Fluorescent Platform: Visualization of Duple Organelles and Detection of Carbon Dioxide.

Solvatochromic fluorescent probes are crucial molecular tools to investigate and aggregate proteins' fold, visualize fine structures in biomembranes, and label different organelles in dual emission colors. However, solvatochromic fluorogens often displayed a weak emission at high polarity, hindering their bioimaging applications. To resolve this problem, herein, we propose an intramolecular charge transfer (ICT) inhibition strategy. The probe was designed with a single electronic donor and two acceptors in order to split and inhibit the ICT procedure. As a result, the probe displayed an intense emission at both low and high polarities and showed a large emission shift (84 nm) upon polarity change. Using the probe, we successfully imaged lipid droplets and the endoplasmic reticulum in different fluorescence colors. Moreover, the different degrees of lipid accumulation by oleic acid, stearic acid, and cholesterol (oleic acid > stearic acid > cholesterol) have been revealed. The lipid accumulation induced by the three lipids could be rapidly consumed under lipid-less conditions, and the lipids with stearic acid were the most difficult to be consumed. The biological results could facilitate the understanding and treatment of lipid accumulation and obesity. Furthermore, utilizing the polarity increase of diethylamine after the reaction with CO2, the ratiometric detection of CO2 has been achieved for the first time with the probe.

Offshore carbon storage from power plants based on real option and multi‐period source‐sink matching: A case study in the eastern coastal China

Carbon capture utilization and storage (CCUS) emerges as a pivotal strategy for CO2 reduction in the power sector, particularly focusing on the overlooked domain of offshore storage along China's east coast. In spite of the potential high costs, irreversible investments, and lengthy development, offshore storage can still be prospective. Considering autonomous decision-making among emission sources, this study pioneers a CO2 offshore storage investment decision model tailored for coal-fired and gas-fired power plants. Innovating an offshore storage source-sink matching model with a real options model and introducing a pipeline network optimization model allows a realistic source-sink matching strategy to be explored under optimal investment timing. According to the results, among 154 large stationary emission sources in Zhejiang Province, offshore storage could reduce CO2 emissions by 4.59 Gt, utilizing the Qiantang, Minjiang, and Fuzhou depressions. It is economically feasible to implement offshore storage with a whole-process unit cost of 368.8 CNY/tCO2, mainly dominated by capture costs. A hybrid carbon tax-subsidy policy promotes carbon reduction and economic benefits, offering a more effective incentive for emission sources to invest in offshore storage than a single policy. At a hybrid policy price of 250 CNY/tCO2, all 27 selected emission sources are projected to invest in offshore storage by 2048, with a preference for the Qiantang depression as the storage site. Practically, this study provides important technical support and guidance for the large-scale deployment of offshore storage.