Langanite Research Articles

SAW Parameters on Y-cut Langasite Structured Materials

This paper presents results and investigations of several new, man-made piezoelectric single crystal, Czochralski-grown substrate materials for surface acoustic waves (SAW) applications. These materials, langanite (LGN), langatate (LGT), Sr3TaGa3Si2O14 (STGS), Sr3NbGa3Si2O14 (SNGS), Ca3TaGa3Si2O14 (CTGS), and Ca3NbGa3Si2O14 (CNGS), have the same structure as langasite (LGS) and are of the same crystal class as quartz. These compounds are denser than quartz, resulting in lower phase velocities. They also have higher coupling. Unlike quartz and lithium niobate, there is no degradation of material properties below the material melting points resulting in the possibility of extreme high-temperature operation (> 1000 degrees C). This paper gives a summary of extracted SAW material parameters for various propagation angles on Y-cut substrates of the six materials. Parameters included are electromechanical coupling, phase velocity, transducer capacitance, metal strip reflectivity, and temperature coefficient of frequency. Using previously published fundamental material constants, extracted parameters are compared with predictions for LGT and LGN. In addition, power flow angle and fractional frequency curvature data are reported for propagation angles on CTGS and CNGS Y-cut substrates that exhibit temperature compensation near room temperature. Detailed descriptions of the SAW parameter extraction techniques are given. A discussion of the results is provided, including a comparison of extracted parameters and an overview of possible SAW applications.

Luminescence properties of piezoelectric single crystals with langasite structure

Luminescence properties of single crystals of langasite (LGS), langataite (LGT), and langanite (LGN) are investigated at 5 K by using synchrotron radiation as an exciting light source. Two emission bands are observed at 420 and 500 nm in LGS, at 410 and 460 nm in LGT, and at 500 and 535 nm in LGN. The origin of these bands is discussed by reference to the electronic structure of LGS.

Force-frequency effect of Y-cut langanite and Y-cut langatate.

Most recently, langasite and its isomorphs (LGX) have been advanced as potential substitutes for quartz, owing to their extremely high-quality (Q) factors. At least twice higher Q value of LGX than that of quartz has been reported. High Q translates into potentially greater stability. In order to make such materials practical, the environmental sensitivities must be addressed. One of such sensitivities is the force-frequency effect, which relates the sensitiveness of a resonator to shock and vibration via the third-order (non-Hookean) elastic constants. In this paper, we report measured force-frequency coefficients of a Y-cut langanite (LGN) resonator and a Y-cut langatate (LGT) resonator as a function of the azimuthal angle, which is the angle between the crystalline x-axis of a resonator plate and the direction of in-plane diametric force applied to the periphery of the resonator. It was found that the LGN and the LGT behave like AT-cut quartz in the polarity of the frequency changes and the existence of zero-coefficient angle. The maximum magnitudes of the coefficients of the LGN and the LGT are five and seven times smaller than that of stress-compensated cut (SC-cut) quartz, respectively (or, 7 and 10 times smaller comparing to AT-cut quartz). The coefficients of planar-stress, which represent the superposition of a continuous distribution of periphery stresses, also were obtained as 0.52 X 10(-15) m x s/N and 0.38 X 10(-15) m x s/N for the LGN and the LGT, respectively.

Amplitude-frequency effect of Y-cut langanite and langatate.

Amplitude-frequency effect of a Y-cut langanite (LGN) resonator and a Y-cut langatate (LGT) resonator were measured. The frequency shifts from the baseline frequency with 1 mA were measured as a function of drive currents up to 28 mA. High-drive current shifted the frequency, but it also heated the crystal locally, causing temperature-related frequency changes. The local heat transfer and its influence on the frequency were analyzed. The amplitude-frequency shift was effectively measured, and was not affected by the temperature-related frequency changes. The 3rd, 5th, and 7th overtones (OT's) were found to behave as soft springs, i.e., resonant frequency decreases as drive current increases. The drive sensitivity coefficients of the 3rd and 5th OT's are in the vicinity of -2 ppb/mA2 for both resonators. The 7th OT's are higher than the other OT's: -5 approximately -7 ppb/mA2. The lowest drive sensitivity is -1.2 ppb/mA2 on the 5th OT of the LGT.

LGX pure shear horizontal SAW for liquid sensor applications

This paper reports predicted and measured properties of the pure shear horizontal (SH) mode for the LGX family of crystals, which includes langasite (LGS), langanite (LGN), and langatate (LGT). These crystals are of the trigonal class 32 group, as quartz, and they exhibit the SH symmetry type uncoupling for the Euler angles (0/spl deg/, /spl theta/, 90/spl deg/). This surface acoustic mode, also known as surface transverse wave (STW), is especially attractive for liquid sensing due to the moderate damping observed in liquid or viscous environments. Numerical and experimental propagation data presented for the SH mode on LGX (0/spl deg/, /spl theta/, 90/spl deg/) includes phase velocity (v/sub p/), electromechanical coupling coefficient (K/sup 2/), temperature coefficient of delay (TCD), fractional change in frequency with respect to temperature (/spl Delta/f/fo), penetration depth, metal strip reflectivity, and excitation of spurious plate modes as a function of /spl theta/. High electromechanical coupling and zero temperature coefficient of delay (TCD) along LGX Euler angles (0/spl deg/, /spl theta/, 90/spl deg/), /spl theta/ between 10/spl deg/ and 25/spl deg/, with penetration depths comparable to surface acoustic wave (SAW) devices are disclosed. In particular, along LGT (0/spl deg/, 13.5/spl deg/, 90/spl deg/), the experimental results reported with resonators and delay line structures verify the high electromechanical coupling (0.8%) for a SH SAW mode, about 10 times stronger than the 36/spl deg/ Y rotated quartz SH orientation, and the existence of zero TCD around 140/spl deg/C. The phase velocity of 2660 m/s is within 0.2% of the calculated value, which is about 55% below the phase velocity of 36/spl deg/ Y quartz, thus leading to smaller STW devices. The penetration depth of 6.5 wavelengths is eight times more shallow than 36/spl deg/ Y quartz, thus providing significant SH mode energy trapping close to the surface. With such positive predicted and measured coupling and propagation characteristics, these orientations are appropriate for the fabrication of high coupling, zero TCD, smaller, and highly sensitive STW devices for filtering, frequency control, and liquid sensor applications.

Investigation on recent quartz-like materials for SAW applications

Recent progress in growing and characterizing quartz-like materials of the trigonal system class 32 has been reported by several groups. The promising perspective for bulk acoustic wave frequency control applications indicates the potentiality of employing these materials for SAW applications as well. This paper reports results of investigations focused on SAW orientations of langasite (LGS), gallium phosphate (GaPO(4)), and langanite (LGN), both singly and doubly rotated cuts. Among the characteristics explored, major attention is paid to the temperature coefficient of delay (TCD), the electromechanical coupling coefficient (K(2)), and the power flow angle (PFA). Contour graphs are plotted based on our calculated results and show the regions in space in which low TCD and high K(2 ) can be obtained; they also exhibit the associated PFA and phase velocity characteristics. The influence of different sets of material constants is addressed. The spatial investigation performed shows that there are promising orientation regions in these materials at which zero or reduced TCD (<10 ppm/ degrees C) and PFA are obtained. Additional attractive characteristics for SAW applications have been observed: values of K(2) a few times higher than the K(2) of quartz ST-X, thus finding applications in larger bandwidth devices; variation of the TCD with respect to temperature, which is comparable to the variation found for quartz ST-X and less than that for zero TCD Li (2)B(4)O(7) cuts like 45 degrees X-Z and (0 degrees 78 degrees 90 degrees ); and phase velocity values circa 13 to 26% smaller than the phase velocity of quartz ST-X thus allowing a reduction in size for intermediate frequency device applications.