Over the past few years, there has been a revitalized emphasis on comprehending the shifts in land cover and their implications for a range of environmental factors. This investigation seeks to analyze how changes in land surface temperatures (LST), normalized difference vegetation index (NDVI), normalized difference built-up index (NDBI), and alterations in land cover intersect within the lower Kharun catchment area. The primary dataset utilized in this study is for 2001 and 2021 Landsat 7 and 8, part of the Landsat program managed by the United States Geological Survey (USGS), offer essential Earth observation data using their multispectral and thermal sensors which are designed to detect thermal radiation emitted from the Earth's surface. When these bands are properly processed, they enable accurate temperature measurements. Visual interpretation was conducted on these images, categorizing them into five specific classes of land cover these were vegetation, open land, settlement, waterbodies, and cultivation. Following this, spectral indices like NDVI and NDBI were calculated, and LST was derived using a single-channel algorithm. Subsequently, correlation analysis was utilized to explore the interconnectedness or mutual relationship among the spatial distribution of these parameters. Over the period from 2001 to 2021, the most significant changes in land use were observed in the settlement area and cultivation, which increased by 6.92 and 6.23 sq. km, respectively. Conversely, open land, vegetation, and waterbodies experienced decreases of 7.13, 5.56, and 0.46 sq. km, respectively. The patterns in which LST, NDBI, and NDVI are distributed, exhibited corresponding variations following changes in land cover. The observed alterations in LST, NDBI, and NDVI are believed to be primarily influenced by the expansion of built-up areas. A noticeable association suggests that as built-up areas increase, both NDBI and LST values typically rise.Furthermore, a correlation observed between LST with NDVI was negative, suggesting an inverse relationship between these parameters. On the other hand, the correlation of LST with NDBI observed was positive, indicating that these parameters exhibit a direct relationship. Overall, these findings seem to be complex and highlight the interactions between changing land cover and environmental parameters, underscoring the importance of understanding these relationships for effective land management and environmental monitoring.