Water Age Research Articles

Watershed hydrology mediates the recovery of an arsenic impacted subarctic landscape

A holistic understanding of the chemical recovery of lakes from arsenic (As) pollution requires consideration of within-lake biogeochemical cycling of As and processes occurring in the surrounding catchment. This study used a watershed mass balance approach, complemented by experimental sediment incubations, to assess the mobility and transport of As within a subarctic watershed (155 km2) impacted by more than 60 years of atmospheric mining emissions. The period of record spanned a transition from drought to high streamflow between September 2017 and September 2019, which yielded insights into the interacting effects of hydrology and within-lake biogeochemical cycling of As. Internal loading of As from contaminated lake sediments (25–46 kg As year−1) and contributions from terrestrial sources (16–56 kg As yr−1) continue to negatively impact lake water quality (19–144 μg As L−1), but the relative importance of these loads varies seasonally and inter-annually in response to changing hydrological conditions. Wet conditions resulted in greater transport of As from terrestrial reservoirs and upstream areas, shorter lake water retention time, and increased the downstream export of As. During dry periods, the lake was disconnected from the surrounding watershed resulting in limited terrestrial contributions and longer lake water residence time, which delayed recovery due to the greater relative influence of internal loading from contaminated sediments. This study highlights that changing hydroclimatic regimes will alter trajectories of chemical recovery for arsenic impacted lakes through the coupling of within-lake and watershed transport processes.

Using oxygen isotopes in phosphate to assess biological phosphorus cycling in a small and shallow freshwater lake system

AbstractReducing excess phosphorus (P) loads that cause eutrophication in aquatic systems is essential for meeting water quality standards. The oxygen isotopic composition of phosphate (δ18Op) is a powerful tool for tracking P sources and cycling in diverse natural ecosystems. Here, we use δ18Op distribution in a small freshwater body (a lagoon–lake system) with high biological activity. We report δ18Op values seasonally along the water flow path in lagoon–lake system adjacent to Lake Biwa, Japan. The δ18Op values of inflowing water originating as agricultural runoff were constant throughout the study period at +16.3‰ ± 0.2‰. The δ18Op values in the system were generally offset from temperature‐dependent isotopic equilibrium with the surrounding water, ranging from +11.1‰ to +17.8‰. The δ18Op values of the lake water approached equilibrium values in July and October, when dissolved inorganic P (DIP) retention rates were high, consistent with extensive biologically mediated phosphate cycling. A δ18Op two end‐member mixing model, involving inflowing P and biologically recycled P, suggests that P turnover rates in the lagoon–lake system were high during the productive seasons. In contrast, the longer lake water residence time in the non‐irrigation season (winter) allowed δ18Op values to deviate toward lower values relative to both equilibrium and agricultural source δ18Op values, suggesting that P metabolism was dominated by extracellular/ecto‐enzymatic hydrolysis of dissolved organic P under low DIP concentrations. This work highlighted the utility of δ18Op for understanding P dynamics in shallow lake ecosystems.

Repeated failures of the giant Beshkiol Landslide and their impact on the long-term Naryn Basin floodings, Kyrgyz Tien Shan

Landslides are major hazards that lead to cataclysmic changes in regional physiography. Their consequences are particularly significant when they affect a river system, forming dammed-lake upstream that represents a high flood threat for the downstream region. The Naryn River is the largest river in the Kyrgyz Tien Shan and is of great economic importance. The Beshkiol Landslide, the largest one in Central Asia but of unknown age, has most likely blocked the Naryn River in the past during the Late Pleistocene, with evidence of thick lacustrine deposits as well as numerous paleo-shorelines preserved upstream. In this study, a detailed geomorphological and sedimentological analysis combined with luminescence and 14C dating provides a strong chronological framework to refine the dynamics between the Beshkiol landslides and dammed-lakes in the Naryn Basin. We propose that the Beshkiol Landslide was first triggered 51.9 ± 4.4 kyrs ago, with a 410 m-high dam that blocked the Naryn River. A first lake with a total volume of 121 ± 50 km3 lasted for >37.0 ± 5.1 kyrs, one of the longest landslide-dammed lake residence time ever documented in the world. Our sedimentological observations highlight a catastrophic lake outburst flood between 15.6 and 14.1 kyrs cal BP, likely related to a landslide dam breach. A short-lived phase of fluvial erosion impacted the whole Naryn Basin followed by a second landslide activation (280 m- high dam) and subsequent flooding by a second lake of 27 ± 10 km3. This second lake had a minimum residence time of 7.7 ± 1.3 kyrs before its final gradual drainage that was followed by a fluvial erosional phase still active today in the Naryn Basin. We also suggest that the distal unconsolidated part of the Beshkiol Landslide could be remobilized in the event of an earthquake and/or extreme rain episode, causing a potentially dam of the Naryn River, which would have strong regional economic impacts.

A global compilation of diatom silica oxygen isotope records from lake sediment – trends and implications for climate reconstruction

Abstract. Oxygen isotopes in biogenic silica (δ18OBSi) from lake sediments allow for quantitative reconstruction of past hydroclimate and proxy-model comparison in terrestrial environments. The signals of individual records have been attributed to different factors, such as air temperature (Tair), atmospheric circulation patterns, hydrological changes, and lake evaporation. While every lake has its own local set of drivers of δ18O variability, here we explore the extent to which regional or even global signals emerge from a series of paleoenvironmental records. This study provides a comprehensive compilation and combined statistical evaluation of the existing lake sediment δ18OBSi records, largely missing in other summary publications (i.e. PAGES network). For this purpose, we have identified and compiled 71 down-core records published to date and complemented these datasets with additional lake basin parameters (e.g. lake water residence time and catchment size) to best characterize the signal properties. Records feature widely different temporal coverage and resolution, ranging from decadal-scale records covering the past 150 years to records with multi-millennial-scale resolution spanning glacial–interglacial cycles. The best coverage in number of records (N = 37) and data points (N = 2112) is available for Northern Hemispheric (NH) extratropical regions throughout the Holocene (roughly corresponding to Marine Isotope Stage 1; MIS 1). To address the different variabilities and temporal offsets, records were brought to a common temporal resolution by binning and subsequently filtered for hydrologically open lakes with lake water residence times < 100 years. For mid- to high-latitude (> 45° N) lakes, we find common δ18OBSi patterns among the lake records during both the Holocene and Common Era (CE). These include maxima and minima corresponding to known climate episodes, such as the Holocene Thermal Maximum (HTM), Neoglacial Cooling, Medieval Climate Anomaly (MCA) and the Little Ice Age (LIA). These patterns are in line with long-term air temperature changes supported by previously published climate reconstructions from other archives, as well as Holocene summer insolation changes. In conclusion, oxygen isotope records from NH extratropical lake sediments feature a common climate signal at centennial (for CE) and millennial (for Holocene) timescales despite stemming from different lakes in different geographic locations and hence constitute a valuable proxy for past climate reconstructions.

Understanding Lake Residence Time Across Spatial and Temporal Scales: A Modeling Analysis of Lake George, New York USA

AbstractWhole lake residence time has been associated with various water quality parameters, including harmful algal blooms. Despite observations of spatial variability in commonly measured lake water quality parameters, little attention is given to the spatial variability of residence time in lakes. In this paper we use water age as a surrogate for residence time and we examine its spatial and temporal distribution in 10 bays of varying size in Lake George, New York (USA). Using a validated hydrodynamic model against observations of water temperature and water currents, and using simulated water age, we show that the average residence time in most of the bays is less than 3 days. Timeseries of bay‐average water age shows that it can sharply decrease within 1 day due to a strong wind event. The average spatial distribution is shown to be non‐uniform, with only a small section of the bottom layer of the bays having a substantially greater age, which may be more than 1 week in certain bays. Snapshots of water age transects indicate that strong wind events substantially change the vertical distribution of water age in some bays, even to the extent of inverting the distribution. The substantial decreases of water age in the bays were associated with the shallowing and deepening of the thermocline. Our results highlight how variations in water residence times within lakes could introduce substantial variation in water quality attributes. Whole lake residence times may serve as a poor proxy to understand the dynamics of water masses, especially in large and morphologically complex waterbodies.

Effect of Aging on Hardness of Glass Ionomer, Resin-Modified Glass Ionomer, Giomer and Compomer Dental Restorative Materials

Objective: To assess deionized water's aging effect on the hardness of four direct tooth colored dental filling materials i.e., Glass Ionomer Cement, Resin Modified Glass Ionomer, Giomer and Compomer.Study Design: An in vitro experimental study performed in triplicates.Place and Duration of Study: The study was carried out at PG Laboratory, Department of Science of Dental Materials, Army Medical College, Rawalpindi, Pakistan from February 2023 to August 2023.Methods: Three disc-shaped samples (n=3) of 10 mm diameter and 1 mm thickness of each restorative material were prepared using stainless steel molds per manufacturer's instructions. These disc-shaped samples were then suspended in a 15 mL conical centrifuge tube containing 10 mL deionized water, followed by incubation in a Forced Convection Laboratory Oven at 37 C where these were allowed to age over a period of 1-2 years. Vickers Hardness of each sample was then checked at two-time intervals, i.e., after 24 h setting and after 2.5 years of ageing through the Micro Vickers Hardness Tester calibrated at 1Kgf (9.80 N) with dwell time of 10 seconds and light intensity 10. Results: After one day (24 h) aging in deionized water, maximum mean Vickers hardness number (VHN) was exhibited by Compomer (539.83±58.08 VHN) and least by GIC (175.75±24.47 VHN). After aging the sample for 912 days, maximum mean VHN was observed for GIC (420.67±99.66 VHN) and least by Compomer (354.33±9.22 VHN). Conclusion: RMGIC sustains its hardness on aging, hardness of GIC increases while that of Giomer and Compomer decreases upon aging.
 How to cite this: Gul H, Nayyer M, Junaid Y, Pasha M, Ejaz T, Liaqat U, Hassan SH. Effect of Aging on Hardness of Glass Ionomer, ResinModified Glass Ionomer, Giomer and Compomer Dental Restorative Materials. Life and Science. 2023; 4(4): 438-444. doi: http://doi.org/10.37185/LnS.1.1.437

Mixing Process Evaluation Due to Sea Level Rise in Babitonga bay, Brazil

The Babitonga bay, located in the state of Santa Catarina, Brazil, is an estuarine system of great social and economic importance, that can be highly affected by climate changes effects. These effects include the water level increasing due to Sea Level Rise (SLR) that can be impact the circulation of the bay. In this work, effects in the circulation and mixing processes in the Babitonga bay due to SLR are evaluated. The Water Renewal Rate (WRR) and the Water Age (WA) are used as indicators for the evaluation of the effects. A hydrodynamic model was calibrated and validated for the year 2019, taken as a baseline scenario, and two representative scenarios of SLR due climate change, defined by the Inter-Governmental Panel for Climate Change (IPCC), for the year 2100, were analyzed. WRR and WA were calculated for the Summer and Winter periods for the year 2019, and also for four different projected scenarios for the year 2100. The renovation process is more efficient in the Summer because of the influence of the freshwater discharge. The results showed a reduction in the WRR for the year 2100, and, consequently, an increase in the WA, using the 2019 as the comparison scenario.

The Potential Use of Global Evapotranspiration Products and Models to Estimate Lake Residence Time at Large Scale

AbstractWater residence time (WRT) is an important lake attribute that influences almost all in‐lake nutrient processes. However, information on WRT is often missing or outdated, especially in regions lacking lake inflow or outflow observations. Recent advances in global precipitation and evapotranspiration (ET) products and calibration‐free ET models provide the possibility of estimating lake WRT at large scales using estimated runoff from the water balance over the lake catchment. Here, we tested four global ET products and two calibration‐free ET models for estimating the mean annual lake outflow and WRT of 67 globally distributed lakes using precipitation inputs from four global precipitation products. The results show that the WRT estimated using the water balance method and global ET estimates generally correlates well with reference WRT (R = 0.90 ∼ 0.99) when using reliable precipitation inputs and is slightly more accurate than the estimates from the existing global WRT dataset and methods (R = 0.79 ∼ 0.94). Despite the large relative error (RE) in the estimates of the WRT, the RE of the phosphorus retention derived from the estimated WRT is acceptable (RE < ±30%). The simplicity and versatility of this approach underline its potential applications to large‐scale studies that require a fair estimation of WRT.

Filter feeders are key to small microplastic residence times in stratified lakes: A virtual experiment

Microplastic (MP) is potentially harmful to lake ecosystems, with its uptake into the food web largely controlled by its residence time in the lake water column. Here we combine laboratory and virtual experiments to quantify residence times of small MP (<15 μm) in two contrasting model lakes; Lake Constance (large lake) and Esthwaite Water (a small lake). We compare MP residence times in a purely physical system with MP transport controlled by sinking and mixing to a model where, in addition to physical processes, zooplankton package MP into faecal pellets that are then egested into the water column. The laboratory experiments showed that MP settling velocities increased from ~5 × 10−6–10−3 mm s−1 for pristine MP to ~1 mm s−1 for MP embedded faeces. Modeled lake residence times for the 0.5 and 5 μm particles were >15 years in the abiotic models, while in the biotic simulations they were reduced to ~1 year. There was little difference between abiotic and biotic simulations for the 15 μm particles. The ratio of the MP zooplankton uptake velocity to the sinking velocity (v_up/vs_epi) was used to classify biological vs. physical transport pathways. For the 0.5 and 5 μm particles v_up/vs_epi was ≫1 in all cases for both lakes, while for the 15 μm MP there was a transition between biological and physical processes dominating residence times depending on zooplankton numbers. Our results suggest that packaging of small MP in faecal pellets by zooplankton will control its residence time in lakes. Moreover, the majority of small MP will cycle through organisms before reaching the sediment, increasing the likelihood of negative ecological effects and transfer in the food web.

Seasonal variations in residence time and water age in the Mundaú-Manguaba Estuarine Lagoon System, AL (Brazil)

The Characteristic Hydraulic Times (CHT), called Residence Time (RT) and Water Age (WA), were analyzed in the Mundaú-Manguaba Estuarine Lagoon System (MMELS – AL, Brazil), using the SisBaHiA® – Environmental Hydrodynamics Base System, for two scenarios: wet season, from May to July 2018; and dry season, from October to December 2018. The hydrodynamic modelings appropriately represented water level variations measured in the lagoons. The analysis of residual currents revealed how hydrodynamic circulation was affected by seasonal variations, and provided essential information to understand the results of the RT and WA simulations. This study deepened the knowledge regarding the RT of the water masses inside the lagoons, and reinforced how river discharges significantly influence their export, which resulted, considering the spatial scope, in much smaller RT in the wet season compared to the dry season. The WA analysis added new and significant knowledge about water renewal, from a different perspective, and as yet little-explored in the study region. Among the results obtained, the most relevant refer to the dry season, in which it was found that the “oldest” waters in the Mundaú L. occurred near the southeast region, while in the Manguaba L., in the vicinity of the central region. Both regions were confirmed as the places that present the most critical trophic state index in each lagoon, showing that WA is a CHT that indicates the regions most conducive to more critical trophic states.&#x0D; Keywords: Mundaú-Manguaba lagoons, residence time, water age.

Effects of a Volcanic-Fluid Cycle System on Water Chemistry of a Deep Caldera Lake: Lake Tazawa, Akita Prefecture, Japan

Lake Tazawa, the deepest lake (423.4 m depth at maximum) in Japan underwent drastically changed water quality in 1940, because volcanic water from two active volcanos was then drawn into the lake for power generation and irrigation. Thereby, the pH of lake water decreased from 6.7 to 4.2, which exterminated a land-locked type of sockeye salmon, Oncorhynchus nerkakawamurae (locally called Kunimasu trout). Additionally, the mean residence time of lake water changed from 195 years to 8.9 years by rapidly increasing the outflow for power generation and irrigation. In this study, long-term chemical fluxes controlling lake water chemistry were obtained, and a groundwater water cycle system between the lake and the volcano was explored by estimating hydrological and chemical budgets of the lake. In the chemical budget estimate, two ionic species, SO42− and Cl−, in volcanic fluids were chosen and each mass conservation equation was yielded. The hydrological budget estimate gave us the net groundwater inflow at −1.36 m3/s on average over three periods in 2020–2021, and then the simultaneous equation coupled with the chemical budget equation allowed us to separate into groundwater inflow and outflow at 6.01 m3/s and 7.37 m3/s, averaged over the three periods, respectively. The evaluated groundwater inflow and outflow were compared with those of the other crater or caldera lakes. The linear relationship between the lake volume and the magnitude of groundwater inflow or outflow suggests that the groundwater cycle scale in such a lake increases with the magnitude of the volcanic eruption to have formed the lake.

A novel approach for accurate quantification of lake residence time — Lake Kinneret as a case study

Water residence time, which is affected by increasing water demands and climate change, plays a crucial role in lakes and reservoirs since it influences many natural physical and ecological processes that eventually impact the water quality of the waterbody. Thus, accurate quantification of the water residence time and its distribution is an important tool in lake management. In this study we present a novel approach for assessing the residence time in lakes and reservoirs. The approach is based on the Leslie matrix model that was originally developed for the analysis of age-structured biological population dynamics. In this approach the water in the lake is divided into different age classes each representing the time since the “parcel” of water entered the lake and provides an overall picture of the water age structure. The traditional approach for calculating residence times, which relies only on the lake volume and annual inflow or outflow volumes thereby disregarding any previous information, is very sensitive to large interannual variation. While the proposed approach produces the fraction and volume distribution curves of all age classes within the lake for each simulated timestep. Thus, in addition to mean residence time, the fraction of young water (FYW), quantifying the “young” fraction of water in the lake can be analyzed. The same is true for any other age class of water.The approach was applied to Lake Kinneret (Sea of Galilee) historical data collected over 32 years (1987-2018) and for prediction of long-term time series based on several future scenarios (inflows and outflows). It offers a more accurate quantification of the mean residence time of water in a lake and can easily be adapted to other waterbodies. Comparison of simulation results may serve as basis for determining the lake's management policy, by controlling the inflows and outflows, that will affect both the mean residence time and the fraction of “young/old” age classes of water.

The potential use of global evapotranspiration products and models to estimate lake residence time at large scale

The potential use of global evapotranspiration products and models to estimate lake residence time at large scale

The potential of using global evapotranspiration products and models to estimate lake residence time at large scale

The potential of using global evapotranspiration products and models to estimate lake residence time at large scale

The potential of using global evapotranspiration products and models to estimate lake residence time at large scale

The potential of using global evapotranspiration products and models to estimate lake residence time at large scale

Measurement of microplastic settling velocities and implications for residence times in thermally stratified lakes

AbstractMicroplastics residence times in lakes are currently poorly understood. In this work, settling experiments with pristine and biofilm‐colonized microplastic particles were combined with model calculations to evaluate settling velocities, particle distributions, and residence times in the epilimnion, metalimnion, and hypolimnion of a hypothetical stratified lake broadly based on Upper Lake Constance. Settling velocities of various biodegradable and nonbiodegradable polymers of various shapes, sizes, and biofilm colonization were measured in a settling column. The settling velocities ranged between ~ 0.30 and ~ 50 mm s−1. Particle sizes and polymer densities were identified as primary controls on settling rates. Microplastic particles that had been exposed to a lake environment for up to 30 weeks were colonized by a range of biofilms and associated extracellular polymeric substances; surprisingly, however, the settling velocity did not vary significantly between pristine and colonized microplastic particles. Simulated microplastic residence times in the model lake varied over a wide range of time scales (10−1 to 105 d) and depended mainly on the size of the particles and depth of the lake layer. Long residence times on the order of 105 d (for 1‐μm microplastic particles) imply that for small microplastic particles there is a high probability that they will be taken up at some stage by lake organisms. As the lake retention time (~ 4.5 years) is considerably shorter than the residence time of small microplastics, negligible quantities of these microplastic particles should be found in the lake sediment unless some other process increases their settling velocity.

A multi-isotope and modelling approach for constraining hydro-connectivity in the East African Rift System, southern Ethiopia

During the last African Humid Period (AHP; 15–5 ka), many lakes in the East African Rift System (EARS) experienced pronounced lake-level variations that dramatically transformed the hydrological landscape. Currently dry, saline or marshy-wetland terminal lakes became vast waterbodies, interconnected via overflow sills resulting in the formation of a several thousand-kilometre-long chain of lakes in the EARS. A quantitative, process-based understanding of these hydrological systems can advance our interpretation of past hydroclimate variability from proxy records. Here, we provide a critical modern hydrological dataset for the data-sparse Lake Chew Bahir basin in southern Ethiopia. Driven by modern data, an isotope-enabled hydro-balance model was developed to assess how increases in rainfall modulate δ18O and 87Sr/86Sr variability. Considering a terminal Lake Chew Bahir scenario, humid conditions resulted in higher lake δ18O (∼+14‰) due to increased evaporation and longer water residence times. At the same time 87Sr/86Sr decreased from 0.7064 to 0.7061 due to an increased riverine Sr flux characterised by lower, unradiogenic 87Sr/86Sr ratios. In a modelling scenario where Lake Chew Bahir became a flow-through system with interconnectivity between lakes Abaya, Chamo, Chew Bahir and Turkana, higher lake δ18O (∼+12‰) relative to present was found, but δ18O was lower than in the terminal lake scenario. The lake water 87Sr/86Sr ratios (<0.7061) were also slightly lower. A moderate concomitant change in rainfall input δ18O of −1‰ in step with hydrological reorganisation resulted in the lowest lake δ18O (∼+5‰). Modelled δ18O values were similar to the δ18O range of endogenic carbonates from sedimentary cores from Lake Chew Bahir at the onset of the AHP, supporting the validity of our model, and suggesting that evaporation and the lake water residence time strongly influence lake water δ18O. However, the reported 87Sr/86Sr of fossil carbonates from Lake Chew Bahir during the AHP (0.7065–0.7060) could not be reproduced by our modelled scenarios without adjusting the surface-water-to-groundwater ratio, highlighting the potential role of groundwater as a water source in semi-arid regions. These results demonstrate the insights that can be gained from applying a process-based approach using O and Sr isotope hydro-balance modelling to aid interpretation of past hydro-balance and lake interconnectivity from lacustrine sedimentary records.

Five New Year's Resolutions

Welcome to 2022! It's time to make the proverbial New Year's resolutions. So, let's think big—bigger than just losing 10 pounds (and I don't mean upping it to 15 pounds). Why not stretch? To me, this is water's moment and now is the time to be bold. Big moves often find their roots in the past, so, before getting to my proposed 2022 resolutions for the water sector, let's get into the way-back machine and visit the era of bell bottom jeans, VW buses, and rivers on fire. Fifty years ago—1972—the federal government took an unprecedented step forward for America's water. That was the year the Clean Water Act was passed. This was possible because two years prior, in 1970, President Richard Nixon created the US Environmental Protection Agency (USEPA) by executive order. During his 1970 State of the Union address, President Nixon placed the importance of his decision to create the USEPA for the purpose of protecting the environment as “. . . a subject which, next to our desire for peace, may well become the major concern of the American people in the decade of the seventies.” President Nixon's statement about our desire for peace and protecting the environment still rings true 50 years later, of course. It is worth noting that this decision also reflected the long-pent-up desire of the people for a clean sustainable environment—not one where rivers caught on fire. In a bit of Hollywood-type drama and what for some might seem like a contradiction, President Nixon vetoed the bill in October 1972 to create the Clean Water Act and prevent pollution discharges into America's water. The president, however, was countered by votes in both the Senate and House to override his veto and make the Clean Water Act a law. With the passing of the Clean Water Act came the sizable price tag of US$24.7 billion, most of which was in the form of grants to states for the construction of wastewater treatment plants. In October 2021 things again changed positively for water's future when the US Congress and President Biden made water infrastructure a priority by enacting the Infrastructure Investment and Jobs Act. With the $55 billion for water infrastructure and programs included in this act, the federal government is helping states and local water providers to spur on critical water projects. Now is certainly another great moment for water, and in many ways it, too, is a long-awaited response to the two decades AWWA and its members have spent working to draw attention to the concern of water's aging infrastructure. This was first formally signaled in AWWA's 2001 Dawn of the Replacement Era report and then, a decade later, more formally quantified in AWWA's 2012 Buried No Longer report. Collectively, these resolutions are all achievable and, in this moment for water, we can make positive, meaningful steps on each. A good friend of mine likes to say, in solving problems three things are needed: talent, money, and time, and usually you have only two of these. In this case, we have all three, as long as we act without undue delay. Achieving these goals may not be the same magnitude as achieving world peace, but they definitely are part of the legacy we can leave for people 50 years from now. Certainly, it is a more meaningful gift to the future than losing 10 pounds.

Can reductions in water residence time be used to disrupt seasonal stratification and control internal loading in a eutrophic monomictic lake?

Anthropogenic eutrophication caused by excess loading of nutrients, especially phosphorus (P), from catchments is a major cause of lake water quality degradation. The release of P from bed sediments to the water column, termed internal loading, can exceed catchment P load in eutrophic lakes, especially those that stratify during warm summer periods. Managing internal P loading is challenging, and although a range of approaches have been implemented, long-term success is often limited, requiring lake-specific solutions. Here, we assess the manipulation of lake residence time to inhibit internal loading in Elterwater, a shallow stratifying lake in the English Lake District, UK. Since 2016, additional inflowing water has been diverted into the inner basin of Elterwater to reduce its water residence time, with the intention of limiting the length of the stratified period and reducing internal loading. Combining eight years of field data in a Before-After-Control-Impact study with process-based hydrodynamic modelling enabled the quantification of the residence time intervention effects on stratification length, water column stability, and concentrations of chlorophyll a and P. Annual water residence time was reduced during the study period by around 40% (4.9 days). Despite this change, the lake continued to stratify and developed hypolimnetic anoxia. As a result, there was little significant change in phosphorus (as total or soluble reactive phosphorus) or chlorophyll a concentrations. Summer stratification length was 2 days shorter and 7% less stable with the intervention. Our results suggest that the change to water residence time in Elterwater was insufficient to induce large enough physical changes to improve water quality. However, the minor physical changes suggest the management measure had some impact and that larger changes in water residence time may have the potential to induce reductions in internal loading. Future assessments of management requirements should combine multi-year observations and physical lake modelling to provide improved understanding of the intervention effect size required to alter the physical structure of the lake, leading to increased hypolimnetic oxygen and reduced potential for internal loading.

Characteristics of Dissolved Organic Carbon in Boreal Lakes: High Spatial and Inter‐Annual Variability Controlled by Landscape Attributes and Wet‐Dry Periods

AbstractConcentration and chemical composition of dissolved organic carbon (DOC) influence several lake functions; greenhouse gas exchange, nutrient cycling, food webs, and water treatability. To assess spatial and inter‐annual controls on DOC characteristics, 34 lakes were sampled annually for 8 years on the Boreal Plains, Western Canada—a region with heterogeneous surficial geology, and a sub‐humid climate with pronounced inter‐annual wet‐dry periods. Large spatial variability in long‐term average DOC concentration (10–49 mg C L−1) and aromaticity (SUVA254: 1.2–3.9 L mg−1 C m−1) among lakes was found. Higher DOC concentrations and aromaticity were associated with lakes in watersheds with fine‐textured surficial geology and with relatively large contributions through shallow, organic‐rich flow paths. Lake DOC aromaticity was also higher in lakes with lower evaporative enrichment, regardless of surficial geology, indicating shorter lake water residence times and less within‐lake degradation of allochthonous DOC. High inter‐annual variability for both DOC and aromaticity was observed, with coefficients of variation at 10.9 ± 4.6% and 11.1 ± 2.5% among lakes, respectively. Inter‐annual variability in DOC concentrations had low synchronicity among lakes, with patterns of variability linked to surficial geology and primarily responsive to short‐term cumulative precipitation. Conversely, inter‐annual variability in aromaticity had high synchronicity among lakes, driven by longer‐term cumulative precipitation and shifts in lake water residence times. Our study shows it is necessary to consider lake hydrogeomorphic setting and climate to understand spatial and inter‐annual variability in lake DOC characteristics and associated lake functions, and that Boreal Plains lakes have high climate sensitivity.