Using a crossed electron beam–molecular beam scattering geometry and the relative-flow technique, ratios of elastic differential cross sections of SO2 to those of He have been measured at electron impact energies of 12, 20, 50, 100, 150, and 200 eV. At each energy, an angular range of 15° to 150° has been covered. These ratios have been multiplied by previously known He elastic differential cross sections to obtain elastic differential cross sections for SO2. From a knowledge of differential cross sections, integral and momentum transfer cross sections have been determined. Using the two-potential theory of e-molecule scattering, calculations were also performed and compared with the measurements.
Read full abstract