Assembling MXene nanofillers on a macroscopic carrier via the non-covalent bonding forces is one of the most efficient paths for preparing the MXene-based nanocomposites with multi functions and hierarchical structure. However, the frequently-used substrates, such as cotton fabric, synthetic textile, and polymer sponge are highly flammable, severely restricting the practical applications in some highly integrated scenarios. Herein, we report a facile design strategy that enables us to readily achieve the flame retardant MXene-based nanocomposites for highly efficient infrared stealth and strain sensing even when used in high-temperature environments. In particular, a phosphorus-nitrogen rich compound (HPTCP) was intercalated into the laminates of Ti3C2Tx-MXene to construct a hybrid flame retardant that was coated on the skeletons of melamine sponge by repeated dip-coating procedures. As a result of the synergistic effect among multicomponent, the Ti3C2Tx-HPTCP coated sponge displays excellent structural stability in real fire. In this case, flame treatment was adopted to create micro-/nano-scale cracks in the coated sponge and skeletons, significantly enhancing the sensitivity (∼0.20 kPa−1) and shortening the response time (69 ms) to strain. The burned sponge sensor can be employed for monitoring various human motions, from tiny throat vibrations and facial expressions to large-scale finger and knee bending. Besides, the burned sample still maintains the superior infrared stealth performance with a wide stealth temperature range, a large reduction in radiation temperature of 154 °C for the object temperature of 300 °C, and long-term working stability at high temperatures. Given the simple fabrication process, multilevel structural design, and stable performance, this work provides a promising strategy for addressing the flammability issue of template-based composite materials
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