Quantum networks that can perform user-defined protocols beyond quantum key distribution will require fully controllable entangled quantum states. To expand the available space of generated time-bin entangled states, we demonstrate a time-bin entangled photon source that produces qubit states |ψ〉=α|00〉+β|11〉\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$|{\\psi}\\rangle = \\alpha |{00}\\rangle + \\beta |{11}\\rangle $\\end{document} with fully controllable phase and amplitudes. Eight different two-photon states have been selected and prepared from arbitrary states on the reduced two-qubit Bloch sphere. The photon pairs encoded in the time-bin scheme were generated at 2.4 MHz with a visibility of V=0.9475±0.0016\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$V = 0.9475 \\pm 0.0016$\\end{document}, with a violation of the CHSH Bell’s inequality by 197 standard deviations. After entanglement distribution over 100 km of single-mode fibers, we obtained a visibility of V=0.9541±0.0113\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$V = 0.9541 \\pm 0.0113$\\end{document} with a violation of the CHSH Bell’s inequality by 6 standard deviations. The prepared states had an average fidelity of 0.9540±0.0016\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$0.9540 \\pm 0.0016$\\end{document} at the source and an average fidelity of 0.9353−0.0209+0.0100\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$0.9353 ^{+0.0100}_{-0.0209}$\\end{document} after entanglement distribution, which shows that the quantum states generated by our time-bin entangled photon source can be fully controlled potentially to a level applicable to long-distance advanced quantum network systems.