The increasingly rapid development of technology has given rise to simulation methods used in circuit specifically in dynamic electricity. One of them is the NI-Multisim application which is useful for determining current and voltage values efficiently and effectively with a circuit design that is built first in the application. Research activities were carried out by simulating Khirchoff's law on NI Multisim by building a circuit scheme based on the circuit composition, namely resistance, voltage source and using voltage measuring instruments and current measuring instruments which are all arranged in such a way by referring to electrical circuit theory. The results of this research are that there is a difference in the total resistance value between the values in the circuit kit module practice and the use of Multisim. However, the difference is very small with an error of around 7.83% for the series-parallel circuit. The current value for each resistance which is connected in a mixed manner can be seen that the practical and theoretical values have an error value of 0% to 24.24% respectively located at R3 at the 6V voltage source and R2 at 12V. The current in I3 is equal to the sum of the current in I2 and the current in I1 for each specified voltage variation. The measurement values with the Khirchoff kit module are different from the NI Multisim simulation, but the differences are still relatively small, ranging from 6% to 28%.