Kadowaki Woods Research Articles

Evidence of multi-band superconductivity in non-centrosymmetric full Heusler alloy LuPd2Sn

In this work, evidence of multi-band superconductivity and presence of mixed parity states in full Heusler alloy LuPd2Sn is investigated using the x-ray diffraction, temperature and field dependent resistivity, temperature dependent magnetization, and heat capacity measurements. Our studies reveal that LuPd2Sn is a type II superconductor and undergoes superconducting transition below 2.5 K. Above 2.5 K, the temperature and field dependence of resistivity indicate to the presence of multiple bands and inter-band phonon assisted scattering. The upper critical field, H C2 (T) exhibits linear behaviour and deviates from Werthamer, Helfand and Hohenberg model over the measured temperature range. Additionally, the Kadowaki–Woods ratio plot supports the unconventional superconductivity in this alloy. Moreover, a significant deviation from the s-wave behaviour is noted, which is studied using phases fluctuation analysis. It indicates the presence of spin triplet along with spin singlet component arising due to antisymmetric spin orbit coupling.

Ginzburg–Landau Analysis on the Physical Properties of the Kagome Superconductor CsV3Sb5

The kagome lattice consisting of corner-sharing triangles has been studied in the context of quantum physics for more than seventy years. For the novel discovered kagome superconductor CsV3Sb5, identifying the pairing symmetry of order parameter remained an elusive problem until now. Based on the two-band Ginzburg–Landau theory, we study the temperature dependence of upper critical field and magnetic penetration depth for this compound. All theoretical results are consistent with the experimental data, which strongly indicates the existence of two-gap s-wave superconductivity in this system. In addition, it is worth noting that the anisotropy of effective masses in the band with large (or small) gap is about 70 (or 2.4). With the calculation of the Kadowaki–Woods ratio as 0.58×10−5μΩ cm mol2 K2 mJ−2, the semi-heavy-fermion feature is suggested in the compound CsV3Sb5.

Wide-range T 2 resistivity and umklapp scattering in moiré graphene

We argue that the unusually strong electron–electron interactions in the narrow bands in moiré superlattices originate from compact Wannier orbitals. Enhanced overlaps of electronic wavefunctions, enabled by such orbitals, result in a strong el–el superlattice umklapp scattering. We identify the umklapp scattering processes as a source of the strong temperature-dependent resistivity observed in these systems. In a simple model, the umklapp scattering predicts a T-dependent resistivity that grows as T 2 with a numerical prefactor that grows as the Wannier orbital radius decreases. We quantify the enhancement in el–el scattering by the Kadowaki–Woods (KW) ratio, a quantity that is sensitive to umklapp scattering but, helpfully, insensitive to the effects due to the high density of electronic states. Our analysis predicts anomalously large KW ratio values that clearly indicate the importance of the umklapp el–el processes and their impact on the T-dependent resistivity.

Anisotropic Fermi Surfaces, Electrical Transport, and Two-Dimensional Fermi Liquid Behavior in Layered Ternary Boride MoAlB

We report a study of fermiology, electrical anisotropy, and Fermi liquid properties in the layered ternary boride MoAlB, which could be peeled into two-dimensional (2D) metal borides (MBenes). By studying the quantum oscillations in comprehensive methods of magnetization, magnetothermoelectric power, and torque with the first-principle calculations, we reveal three types of bands in this system, including two 2D-like electronic bands and one complex three-dimensional-like hole band. Meanwhile, a large out-of-plane electrical anisotropy (ρbb /ρaa ∼ 1100 and ρbb /ρcc ∼ 500, at 2 K) was observed, which is similar to those of the typical anisotropic semimetals but lower than those of some semiconductors (up to 105). After calculating the Kadowaki–Woods ratio (KWR = A/γ 2), we observed that the ratio of the in-plane A a,c /γ 2 is closer to the universal trend, whereas the out-of-plane A b /γ 2 severely deviates from the universality. This demonstrates a 2D Fermi liquid behavior. In addition, MoAlB cannot be unified using the modified KWR formula like other layered systems (Sr2RuO4 and MoOCl2). This unique feature necessitates further exploration of the Fermi liquid property of this layered molybdenum compound.

On the Origin and the Amplitude of T‐Square Resistivity in Fermi Liquids

AbstractIn 1937, Baber, Landau, and Pomeranchuk postulated that collisions between electrons generates a contribution to the electric resistivity of metals with a distinct T2 temperature dependence. The amplitude of this term is small in common metals, but dominant in metals hosting either heavy carriers or a low concentration of them. The temperature dependence is set by the size of the scattering phase, but the microscopic source of dissipation is not straightforward. To explain how electron–electron collisions lead to momentum leak, Umklapp events or multiple electron reservoirs have been invoked. This interpretation is challenged by several experimental observations: the persistence of T‐square resistivity in dilute metals (in which the two mechanisms are irrelevant), the successful extension of Kadowaki–Woods scaling to dilute metals, and the observation of a size‐dependent T‐square thermal resistivity () and its WiedemannFranz correlation with T‐square electrical resistivity. This paper argues that much insight is provided by the case of normal liquid 3He where the T‐square temperature dependence of energy and momentum diffusivity is driven by fermionfermion collisions. The amplitude of T‐square resistivity in 3He and in metals share a common scaling. Thus, the ubiquitous T‐square electrical resistivity ultimately stems from the Fermi‐liquid temperature dependence of momentum diffusivity.

Superconductivity with a Violation of Pauli Limit and Evidences for Multigap in η-Carbide Type Ti4Ir2O

We report the synthesis, crystal structure, and superconductivity of Ti4Ir2O. The title compound crystallizes in an η-carbide type structure of the space group (No. 227), with lattice parameters a = b = c = 11.6194(1) Å. The superconducting temperature T c is found to be 5.1–5.7 K. Most surprisingly, Ti4Ir2O hosts an upper critical field of 16.45 T, which is far beyond the Pauli paramagnetic limit. Strong coupled superconductivity with evidences for multigap is revealed by the measurements of heat capacity and upper critical field. First-principles calculations suggest that the density of states near the Fermi level originates from the hybridization of Ti-3d and Ir-5d orbitals, and the effect of spin-orbit coupling on the Fermi surfaces is prominent. Large values of the Wilson ratio (R W ∼ 3.9), the Kadowaki–Woods ratio [A/γ 2 ∼ 9.0 × 10−6 μΩ⋅cm/(mJ⋅mol−1⋅K−1)2], and the Sommerfeld coefficient (γ = 33.74 mJ⋅mol−1⋅K−2) all suggest strong electron correlations (similar to heavy fermion systems) in Ti4Ir2O. The violation of Pauli limit is possibly due to a combination of strong-coupled superconductivity and large spin-orbit scattering. With these intriguing behaviors, Ti4Ir2O serves as a candidate for unconventional superconductor.

A successive multi-phase transitions in polycrystalline BaFe2As2: Emergence of C4 phase

We report magnetization and resistivity studies on polycrystalline BaFe2As2 prepared by solid-state reaction, in the temperature range of 5–350 K, upto the field of 9 T. Low-field susceptibility exhibits multi-phase transitions with two new magnetic phase transitions beside the well-known transition at [Formula: see text] K from paramagnetic/antiferromagnetic-tetragonal/orthorhombic transitions. The phase at [Formula: see text] K is attributed to the phase transition from antiferromagnetic-orthorhombic (C2-phase) to antiferromagnetic-tetragonal phase (C4-phase), while the phase transition at higher temperatures remains unsolved. Making an analogy to the antiferromagnetic nanosized particles, we suggest that BaFe2As2 consists of smaller but similar nanosized clusters. We have analyzed the magnetization data using the modified Langevin function on the basis of thermally activated induced uncompensated spins (thermoinduced moments). The nanosized clustering in this compound is evidenced by the exchange bias and coercivity stemming from the exchange coupling interactions between weak ferromagnetic bulk magnetization in clusters and spin-glass-like phase interface layers surrounding the clusters. We also observe that annealing enhances the superconductivity, similar to the effect of pressure on the superconductivity. We find that an exponential term well describes the resistivity of this compound due to magnon-assisted interband electron–phonon scattering between the bands with [Formula: see text] and [Formula: see text] orbitals forming two-hole pockets around the zone center and one electron pocket around the zone corner. We have also obtained the Kadowaki–Woods ratio ([Formula: see text] cm (K mol/mJ)[Formula: see text] and the Sommerfeld–Wilson ratio ([Formula: see text]) for BaFe2As2, both ratios are much larger than those ([Formula: see text]/[Formula: see text] cm (K mol/mJ)2, [Formula: see text]) for Kondo lattice systems, indicating the existence of a weak ferromagnetic correlation between Fe moments. It appears that magnon-mediated pairing is responsible for superconductivity. Finally, we observe zero resistance at [Formula: see text] K in amorphous BaFe2As2, which gives a new insight into the superconductivity under very high pressure.

CeAu2In4: A candidate of quasi-one-dimensional antiferromagnetic Kondo lattice* *Project supported by the National Natural Science Foundation of China (Grant Nos. 11774404 and 52088101), the National Key R&D Program of China (Grant No. 2017YF A0303100), and the Chinese Academy of Sciences through the Strategic Priority Research Program (Grant No. XDB33000000).

Needle-like single crystals of CeAu2In4 have been grown from In flux and characterized as a new candidate of quasi-one-dimensional Kondo lattice compound by crystallographic, magnetic, transport, and specific-heat measurements down to very low temperatures. We observe an antiferromagnetic transition at T N ≈ 0.9 K, a highly non-mean-field profile of the corresponding peak in specific heat, and a large Sommerfeld coefficient γ = 369 mJ⋅mol−1⋅K−2. The Kondo temperature T K is estimated to be 1.1 K, being low and comparable to T N. While Fermi liquid behavior is observed deep into the magnetically ordered phase, the Kadowaki–Woods ratio is much reduced relative to the expected value for Ce compounds with Kramers doublet ground state. Markedly, this feature shares striking similarities to that of the prototypical quasi-one-dimensional compounds YbNi4P2 and CeRh6Ge4 with tunable ferromagnetic quantum critical point. Given the shortest Ce–Ce distance along the needle direction, CeAu2In4 appears to be an interesting model system for exploring antiferromagnetic quantum critical behaviors in a quasi-one-dimensional Kondo lattice with enhanced quantum fluctuations.

Weak itinerant ferromagnetism and non-Fermi liquid behavior in Ni-TM (TM = Cr, Nb) alloys near critical concentration

We report a comprehensive study on the magnetic, electrical and thermal properties of Ni100−x TM x (TM = V, Cr, Nb,) alloys around their critical concentration. Analysis of field and temperature dependence magnetization data suggests a weak itinerant ferromagnetic behavior in x = 8 and 10 compositions and the ferromagnetic ordering suppresses in the concentration range 10 < x < 12. Further, the temperature dependence of specific heat shows an unusual low temperature variation with an enhanced Sommerfeld coefficient, γ, with a signature of non-Fermi-liquid (NFL) behavior close to critical concentration. Further, the enhancement in Kadowaki–Woods ratio suggests it to be a strongly correlated electron system near critical concentration. Present analysis of experimental data consistently revealed that the NFL behavior is caused by spin fluctuations near critical concentration. The temperature dependencies of the electrical resistivity, the magnetization and linear term of the electronic specific heat appear to follow the theoretical predictions of a quantum phase transition and it is tempting to suggest that the presently studies Ni-rich alloys can be candidates for the observation of Griffith phase.

Intercalation of van der Waals layered materials: A route towards engineering of electron correlation**Project supported by the National Key Basic Research Program of China (Grant Nos. 2013CBA01603, 2016YFA0300600, and 2016YFA0300903), the National Natural Science Foundation of China (Grant Nos. 11574005, 11774009, 11222436, and 11574283), and the National Postdoctoral Program for Innovative Talents of China (Grant No. BX201700012) funded by China

Being parent materials of two-dimensional (2D) crystals, van der Waals layered materials have received revived interest. In most 2D materials, the interaction between electrons is negligible. Introducing the interaction can give rise to a variety of exotic properties. Here, via intercalating a van der Waals layered compound VS2, we find evidence for electron correlation by extensive magnetic, thermal, electrical, and thermoelectric characterizations. The low temperature Sommerfeld coefficient is 64 mJ⋅K−2⋅mol−1 and the Kadowaki–Woods ratio rKW ∼ 0.20a0. Both supports an enhancement of the electron correlation. The temperature dependences of the resistivity and thermopower indicate an important role played by the Kondo effect. The Kondo temperature TK is estimated to be around 8 K. Our results suggest intercalation as a potential means to engineer the electron correlation in van der Waals materials, as well as 2D materials.

Unconventional superconductivity in CuxBi2Se3 from magnetic susceptibility and electrical transport

Although the Cu doped Bi2Se3 topological insulator was discovered and intensively studied for almost a decade, its electrical and magnetic properties in normal state, and the mechanism of ‘high-Tc’ superconductivity regarding the relatively low-carrier density are still not addressed yet. In this work, we report a systematic investigation of magnetic susceptibility, critical fields, and electrical transport on the nominal Cu0.20Bi2Se3 single crystals with = 4.18 K, the highest so far. The composition analysis yields the Cu stoichiometry of x = 0.09(1). The magnetic susceptibility shows considerable anisotropy and an obvious kink at around 96 K was observed in the magnetic susceptibility for H∥c, which indicates a charge density anomaly. The electrical transport measurements indicate the two-dimensional (2D) Fermi liquid behavior at low temperatures with a high Kadowaki–Woods ratio, A/γ2 = 30.3a0. The lower critical field at 0 K limit was extracted to be 6.0 Oe for H∥ab. In the clean limit, the ratio of energy gap to Tc was determined to be Δ0/kBTc = 2.029 ± 0.124 exceeding the standard BCS value 1.764, suggesting Cu0.09Bi2Se3 is a strong-coupling superconductor. The in-plane penetration depth at 0 K was calculated to be 1541.57 nm, resulting in an unprecedented high ratio of Tc/λ−2(0) ≅ 9.86. Moreover, the ratio of Tc to Fermi temperature is estimated to be = 0.034. Both ratios fall into the region of unconventional superconductivity according to Uemura’s regime, supporting the unconventional superconducting mechanism in CuxBi2Se3. Finally, the enhanced Tc value higher than 4 K is proposed to arise from the increased density of states at Fermi energy and strong electron–phonon interaction induced by the charge density instability.

Electronic properties in itinerant ferromagnet SrRu1−xTixO3

Here, we study the electrical transport and specific heat in 4d based ferromagnetic material SrRuO3 and its Ti substituted SrRu1−xTixO3 series (x ⩽ 0.7). The SrRuO3 is a metal and shows itinerant ferromagnetism with transition temperature Tc ∼ 160 K. The nonmagnetic Ti4+ (3d0) substitution would not only weaken the active Ru–O–Ru channel but is also expected to tune the electronic density and electron correlation effect. A metal to insulator transition has been observed around x ∼ 0.4. The nature of charge transport in paramagnetic-metallic state (x ⩽ 0.4) and in insulating state (x > 0.4) follows modified Mott’s variable range hopping model. In ferromagnetic-metallic state, resistivity shows a T2 dependence below Tc which though modifies to T3/2 dependence at low temperature. In Ti substituted samples, temperature range for T3/2 dependence extends to higher temperature. Interestingly, this T3/2 dependence dominates in whole ferromagnetic regime in presence of magnetic field. This evolution of electronic transport behavior can be explained within the framework of Fermi liquid theory and electron–magnon scattering mechanism. The negative magnetoresistance exhibits a hysteresis and a crossover between negative and positive value with magnetic field which is connected with magnetic behavior in series. The decreasing electronic coefficient of specific heat with x supports the increasing insulating behavior in present series. We calculate a high Kadowaki–Woods ratio (x ⩽ 0.3) for SrRuO3 which increases with substitution concentration. This signifies an increasing electronic correlation effect with substitution concentration.

Study of Nb0.18Re0.82 non-centrosymmetric superconductor in the normal and superconducting states

We examine the evidence for multiband superconductivity and non s-wave pairing in the non-centrosymmetric superconductor (NCS) Nb0.18Re0.82, using electrical transport, magnetization and specific heat measurements. In the normal state, the evolution of electrical resistivity with temperature and magnetic field support the phonon-assisted interband scattering and multiband picture. In the superconducting state, the temperature dependence of the upper critical field, , is found linear and cannot be described within the Werthamer, Helfand and Hohenberg model over the whole temperature range measured. In addition, the observed exceeds the Pauli limit, suggesting non-s-wave pairing. Interestingly, the Kadowaki–Woods ratio and Uemura plot reveal a behavior in Nb0.18Re0.82 which is similar to that found in unconventional superconductors. The normalized superfluid density (ρs), estimated using the temperature dependence of the lower critical field, , is well explained with the help of the multiband description. Phase fluctuation analysis conducted on the reversible magnetization data, reveals a significant deviation from the mean-field conventional s-wave behavior. This trend is interpreted in terms of a non s-wave spin-triplet component in the pairing symmetry as might be anticipated in a NCS where anti-symmetric spin–orbit coupling plays a dominant role. Recently, time reversal symmetry breaking observed in Nb0.18Re0.82 supports this picture.

Polaronic Nonmetal–Correlated Metal Crossover System β′-CuxV2O5 with Anharmonic Copper Oscillation and Thermoelectric Conversion Performance

The crystal structures and electronic properties of β′CuxV2O5 are explored through measurements of X-ray four-circle diffraction, electrical resistivity, thermoelectric power, thermal conductivity, magnetization, and electron paramagnetic resonance. For various compositions with 0.243 ≤ x ≤ 0.587, the crystal structures are redetermined through the anharmonic approach of the copper displacement factors, where the anharmonicity is reduced with increasing Cu concentration. The electron transport for x ≤ 0.45 is nonmetallic due to polaron hopping and the random potential of Cu ions, while for x = 0.60, a correlated Fermi-liquid state appears with a Wilson ratio of 1.3 and a Kadowaki–Woods ratio close to the universal value for heavy-fermion systems. At around x = 0.50, the polaronic bandwidth may broaden so that the Hubbard subbands caused by the electron correlation will overlap. The nonmetallic composition in the proximity of the nonmetal–metal crossover shows a dimensionless thermoelectric power factor of...

Specific heat and Hall effect of the ferromagnetic Kondo lattice UCu0.9Sb2

We have investigated the electrical resistivity ρ, specific heat Cp and Hall coefficient RH on a single crystal of a ferromagnetic Kondo lattice UCu0.9Sb2. The experimental , Cp(T) and data evidence a bulk magnetic phase transition at K, and additionally exhibit an unexpected bump located in the temperature range TC/10–TC/3. UCu0.9Sb2 has an enhanced electronic specific heat coefficient mJ molK−2, corresponding to Kondo temperature K. An analysis of the Hall effect data for j//(a, b)-plane and H// c-axis reveals that the low-temperature ordinary Hall coefficient R0 is positive, suggesting that p-type electrical conductivity is dominant. The density of the carriers at 2 K is about 0.6 holes f.u.−1, which may categorize the studied compound into class of low carrier density compounds. Combined γ and R0 data divulge an effective mass of charge carriers 27 me. This finding together with quite low Hall mobility cm2 Vs−1 and Kadowaki–Woods ratio cm (mol K2 mJ−1)2, manifest the development of heavy-fermion state in the ferromagnetic UCu0.9Sb2 compound at low temperatures.

Superconductivity in a new layered nickel selenide CsNi2Se2

The physical properties of CsNi2Se2 were characterized by electrical resistivity, magnetization and specific heat measurements. We found that the stoichiometric CsNi2Se2 compound undergoes a superconducting transition at Tc = 2.7 K. A large Sommerfeld coefficient (∼77.90 mJ/mol K−2) was obtained from the normal state electronic specific heat. However, the Kadowaki–Woods ratio of CsNi2Se2 was estimated to be about 0.041 × 10cm(mol K2/mJ)2, indicating the absence of strong electron–electron correlations. In the superconducting state, we found that the zero-field electronic specific heat data, Ces(T) (0.5 K T < 2.7 K), can be fitted well with a two-gap BCS model, indicating the multi-gap feature of CsNi2Se2. The comparison with the density functional theory (DFT) calculations suggested that the large in these nickel selenide superconductors may be related to the large density of states (DOS) at the Fermi surface.

‘Hard’ crystalline lattice in the Weyl semimetal NbAs

We report the effect of hydrostatic pressure on the magnetotransport properties of the Weyl semimetal NbAs. Subtle changes can be seen in the profiles with pressure up to 2.31 GPa. The Fermi surfaces undergo an anisotropic evolution under pressure: the extremal areas slightly increase in the - plane, but decrease in the -() plane. The topological features of the two pockets observed at atmospheric pressure, however, remain unchanged at 2.31 GPa. No superconductivity can be seen down to 0.3 K for all the pressures measured. By fitting the temperature dependence of specific heat to the Debye model, we obtain a small Sommerfeld coefficient mJ (mol·K2)−1 and a large Debye temperature, K, confirming a ‘hard’ crystalline lattice that is stable under pressure. We also studied the Kadowaki–Woods ratio of this low-carrier-density massless system, cm mol2 K2 J−2. After accounting for the small carrier density in NbAs, this indicates a suppressed transport scattering rate relative to other metals.

Cooperative magnetic behaviour in the new valence fluctuating compound Ce2Rh3Ge

In this study we report the physical properties of the new ternary compound Ce2Rh3Ge that crystallizes in the rhombohedral, triple hexagonal MgCu2-type of structure. The electronic ground state properties of Ce2Rh3Ge were characterized by magnetic susceptibility, specific heat, electrical resistivity and thermal transport measurements. The results indicate the presence of short range magnetic interaction, probably of ferromagnetic origin below TC = 4 K. The shape of χ−1(T) deviates from the Curie–Weiss behavior with a broad minimum at about = 450 K reminiscent of valence fluctuating cerium systems. At T = 10 K, the magnetic part of the resistivity ρ4 f (T) exhibits a shallow minimum followed by increase of resistivity ρ(T) −lnT, which hints at a substantial Kondo screening effect. Ce2Rh3Ge belongs to a small group of strongly correlated cerium compounds in which the two competing effects of Kondo and RKKY interactions produce long-range magnetic order from strongly hybridized and intermediate-valent 4 f spins. At sufficiently low temperatures Ce2Rh3Ge scales well with the Kadowaki–Woods ratio A/γ2 and the value of the Wilson ratio χ(T → 0)/γ found for this compound classifies it as a mixed-valence compound. The presence of valence fluctuation and magnetic order it is rare for these attributes to be found simultaneously in same compound, in same temperature range. In our opinion a novelty of presented results of Ce2Rh3Ge is that this compound adds a new member to a small but growing class of systems bearing a strongly mixed- or intermediate-valent 4 f magnetic moment, but in which the lattice of spins nevertheless end up finding it possible to order magnetically.

High pressure synthesis of a new phase of YbAg2: Structure, valence of Yb and properties

The new phase of YbAg2 was obtained using high-pressure and high-temperature reaction. YbAg2 crystallizes in the MgZn2 structure (the space group P63/mmc space group, No 194) with a = 5.68153(3) Å and c = 9.31995(7) Å and the unit cell volume V = 260.54(3) Å3. The XANES analysis showed that the valence state of Yb is +2.8. The low-temperature dependences of the electrical resistivity and magnetic susceptibility can be adequately described by a T2 term that supports the Fermi-liquid picture. The Kadowaki–Woods relation gives a low value of the degeneracy (N = 2).

Low-temperature properties of theS=12spin systemYb3Ru4Al12with a distorted kagome lattice structure

We have synthesized single crystals of ternary intermetallic ${\mathrm{Yb}}_{3}{\mathrm{Ru}}_{4}{\mathrm{Al}}_{12}$ with a distorted kagome lattice structure, and investigated the low-temperature resistivity, specific heat, magnetization, and magnetic phase transitions. ${\mathrm{Yb}}_{3}{\mathrm{Ru}}_{4}{\mathrm{Al}}_{12}$ is the first $4f$ system that has a ${\mathrm{Gd}}_{3}{\mathrm{Ru}}_{4}{\mathrm{Al}}_{12}$-type crystal structure where antiferromagnetic interaction acts on the spin. The crystal electric field (CEF) ground state of this compound is determined as a well isolated twofold degenerate state that is subjected to a strong easy-plane-type magnetic anisotropy. In the present study, the spin system of ${\mathrm{Yb}}_{3}{\mathrm{Ru}}_{4}{\mathrm{Al}}_{12}$ is regarded as an AFM $XY$ model of $S=1/2$. This compound undergoes successive magnetic phase transitions at 1.5 and 1.6 K, and the resistivity exhibits ${T}^{2}$ behavior below 1 K. The ratio of the coefficient of the ${T}^{2}$ term in the resistivity $A$, and that of the electronic specific heat coefficient ${\ensuremath{\gamma}}_{0}$, deviates from the Kadowaki-Woods (KW) law. The successive phase transitions and low-temperature properties of ${\mathrm{Yb}}_{3}{\mathrm{Ru}}_{4}{\mathrm{Al}}_{12}$ where geometrical frustration and heavy fermion behavior occur are discussed.