Judd-Ofelt Analysis Research Articles

Role of WO3 on the conductivity, Judd-Ofelt and luminescence properties of 20K2O−xWO3−(78−x)TeO2−1Er2O3−1Yb2O3 glass system

Glasses with the composition of 20K2O−xWO3−(78−x)TeO2−1Er2O3−1Yb2O3 (x = 0–9 mol%) were prepared using the melt-quenching method. Tellurite-based glasses exhibit low phonon energy and when combined with high-density heavy-metal oxides like WO3, they show potentially promising applications in photonic devices. Therefore, this study aims to investigate the impact of WO3 on structural, DC conductivity, optical, and photoluminescence properties using FTIR, impedance, UV-Vis, and photoluminescence spectroscopies of the present glass system. The results revealed non-linear variations in non-bridging oxygens and optical band gaps, with DC conductivity reaching a maximum at 5 mol% WO3. Judd-Ofelt analysis indicated increased oscillator strength and Ω2 with a decrease at 5 mol%, attributed to enhanced multiphonon relaxation affecting Er3+ site asymmetry. Photoluminescence measurements revealed enhanced green (524 nm, 547 nm) and red (655 nm) emissions with maximum intensity observed at 7 mol% WO3, suggesting that these glasses are promising candidates for use in optical amplifiers and lasers.

Raman, Judd-Ofelt and Photoluminescence Analysis of Ho3+/Yb3+-Doped Borotellurite Glasses for Potential Laser Applications

In this study, glasses with the composition (79-x) B2O3-xTeO2-20Li2O-0.5Ho2O3-0.5Yb2O3 (x = 0 - 50mol%) were synthesized using the melt-quenching method to explore the spectroscopic effect of TeO2 and B2O3 as mixed glass formers. Raman spectroscopy indicated that increasing TeO2 content leads to depolymerization, characterized by a reduction in the relative area of TeO4 units. Absorption spectra revealed nine peaks related to transitions from 5I8 ground state to various excited states of Ho3+ ions, and one peak for the transition from the 2F7/2 ground state of Yb3+ ions. A negative bonding parameter suggests that there is primarily ionic interaction among Ho3+ and its ligands. However, the increase of Ω2 suggests that Ho3+ ions have relatively higher covalence and strong ligand polarizability, except at x = 40mol% due to the rivalry among TeO2 and B2O3. Decrease in Ω4 and Ω6 reflect reduced glass rigidity due to increased NBO content, weakening the glass structure. Luminescence spectra showed green (526nm) and red (642nm) emissions from Ho3+ transitions of 5F4 → 5I8 and 5F5 → 5I8. Intriguingly, a novel peak at 738nm associated with the 5F4 → 5I7 transition in Ho3+ ions, linked to energy transfer from Yb3+ to Ho3+. The stimulated emission cross section for the green and red emission were (0.324 – 0.347) × 10-20 cm2 and (0.387 – 0.423) × 10-20 cm2 respectively. These glasses demonstrate potential for advanced laser, green display, and photonic technology applications.

Synthesis, Down-Conversion Luminescence, and Judd-Ofelt analysis of Eu3+ ions activated in K2MgP2O7 nanophosphor

Synthesis, Down-Conversion Luminescence, and Judd-Ofelt analysis of Eu3+ ions activated in K2MgP2O7 nanophosphor

Spectroscopic properties of red-emitting Sr0.9Na0.2ZrO3:Eu3+ phosphors with potential applications in lasers and LEDs

A range of Sr0.9-yNa0.2ZrO3: Eu3+ (SNEZ) nanocrystalline phosphors with high color purity and exceptional laser properties were synthesized using sol-gel technique. The samples were characterized for structural and spectroscopic properties using methods including X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), diffuse reflectance spectroscopy, and photoluminescence (PL) spectroscopy. Structural analysis revealed orthorhombic phase with average crystallite size 28-19 nm, decreasing with increasing Eu3+ concentration. A low phonon energy of 455–495 cm−1 and wide (expanding) band gaps (5.0–5.3 eV) were obtained for the SNEZ phosphors. Under the excitation of 300 nm, the SNEZ phosphor emits strong red light at 614 nm, attributed to the 5D0 → 7F2 transition of the Eu3+ ion. Both XRD and Judd-Ofelt analysis revealed two sites for the Eu3+ ions. Additionally, the optimized SNEZ-7 phosphor achieves a PL internal quantum efficiency of 96 % under UV light at 300 nm excitation. Laser properties such as stimulated emission cross-section, gain bandwidth, branching ratio of the SNEZ phosphor is comparable to those of glasses, fluorides and other oxides for red light emitting laser applications. The CIE coordinate values of the synthesized red phosphor closely match those of commercially available red light-emitting phosphors, with a purity level of about 95 %. This suggests its suitability for various device applications, particularly in high-power white LEDs and lasers, as a red emitter.

Nanosized Eu3+-Doped NaY9Si6O26 Oxyapatite Phosphor: A Comprehensive Insight into Its Hydrothermal Synthesis and Structural, Morphological, Electronic, and Optical Properties.

Detailed analysis covered the optical and structural properties of Eu3+-doped NaY9Si6O26 oxyapatite phosphors, which were obtained via hydrothermal synthesis. X-ray diffraction patterns of NaY9Si6O26:xEu3+ (x = 0, 1, 5, 7, 10 mol% Eu3+) samples proved a single-phase hexagonal structure (P63/m (176) space group). Differential thermal analysis showed an exothermic peak at 995 °C attributed to the amorphous to crystalline transformation of NaY9Si6O26. Electron microscopy showed agglomerates composed of round-shaped nanoparticles ~53 nm in size. Room temperature photoluminescent emission spectra consisted of emission bands in the visible spectral region corresponding to 5D0 → 7FJ (J = 0, 1, 2, 3, 4) f-f transitions of Eu3+. Lifetime measurements showed that the Eu3+ concentration had no substantial effect on the rather long 5D0-level lifetime. The Eu3+ energy levels in the structure were determined using room-temperature excitation/emission spectra. Using the 7F1 manifold, the Nv-crystal field strength parameter was calculated to be 1442.65 cm-1. Structural, electronic, and optical properties were calculated to determine the band gap value, density of states, and index of refraction. The calculated direct band gap value was 4.665 eV (local density approximation) and 3.765 eV (general gradient approximation). Finally, the complete Judd-Ofelt analysis performed on all samples confirmed the experimental findings.

Judd-Ofelt analysis and temperature sensing properties of polyethylmethacrylate (PEMA) networks doped with CdNb2O6: Er3+/Yb3+ phosphors

Research on the sensitivity of temperature measurements and optical thermometry involving rare earth ions has been an area of interest in the field of photonics and materials science. Introducing polymer networks as a new host material has an important role due to their properties including a versatile and stable environment for rare earth ions and rapid response in temperature detection. In this work, linear and crosslinked polyethylmethacrylate (PEMA) networks doped with Er3+/Yb3+ (1.5 mol % Er3+, 2 mol% Yb3+) synthesized by free-radical crosslinking polymerization with 0.1 EMA (weight %) at 60 °C were used to investigate direct and indirect optical bandgap energies and Urbach energy from UV–Visible spectra. The Judd-Ofelt (JO) approach was employed to analyze parameters Ωt (t = 2,4,6), spontaneous transition probabilities (Α), branching ratios (β) and radiative lifetimes (τ) as a function of linear and crosslinked PEMA doped nano-crystalline CdNb2O6: Er3+/Yb3+. The stimulated emission cross-sections of the transitions 2H11/2⟶4I15/2, 2S3/2⟶4I15/2 and 2F9/2⟶4I15/2 of Er3+/Yb3+ were calculated by two different methods; Fuchtbauer-Ladenburg formula and modified theory, respectively. The gain bandwidth cross-section product for the 2H11/2⟶4I15/2 was found to be 162.06. 10−28cm3, 260.94. 10−28cm3 and 461.20. 10−28cm3 of Er3+/Yb3+ embedded in linear, low and high crosslinked PEMA samples, respectively. JO parameters and stimulated emission cross-sections increased; therefore, radiative lifetimes decreased by increasing crosslinking content. In addition, the temperature dependence of upconversion (UC) luminescence was monitored under 975 nm excitation. The fluorescence intensity ratio (FIR) method examined the temperature sensing under two thermally coupled levels at 525 and 548 nm. The maximum sensitivities obtained from the FIR technique within the 300–650 K temperature range shifted to lower temperatures with increasing crosslinker content. Hence, linear and crosslinked polymer hosts doped rare-earth ions can be candidates for remote temperature sensors across various fields.

Photoluminescence studies of Sr3P4O13: Eu3+ phosphor prepared by wet chemical method: Structural properties, charge compensation via alkali metal ions and Judd-Ofelt analysis

The Sr3P4O13:Eu3+ phosphors co-doped with alkali metal ions (A+ = Li+, Na+ and K+) were prepared by wet chemical method. The comparison with standard JCPDS data confirmed the formation of a triclinic crystalline phase with P-1(2) space group for the Eu3+ doped Sr3P4O13 phosphor and co-doped with alkali metal ions. The Li+ co-doped Sr3P4O13:Eu3+ phosphor has comparatively sharp and intense XRD patterns. The scanning electron microstructural analysis confirmed the formation of the particles size of 5 -50 μm. The comparative study of photoluminescence properties depicted that the peak positions were similar for all the prepared samples. The photoluminescence analysis of Sr3P4O13:Eu3+ phosphors show the emission in the red-orange region under the excitation of 394 nm (7F0→5L6) wavelength. Further, the charge compensation using alkali metal ions shows the larger photoluminescence intensity observed in the case of the Li+ co-doped Sr3P4O13:Eu3+ phosphors suggesting that the Li+ ion is better charge compensator among the studied alkali metal ions. Further, Judd-Ofelt (J-O) parameters were estimated for the Sr3P4O13:Eu3+ phosphors and co-doped with alkali metal ions in a series of samples. The comparison of Sr3P4O13:Eu3+ phosphors co-doped with alkali metal ions alongwith the J-O estimated parameters have been presented in the article.

Luminescence, temperature sensing and Judd-Ofelt analysis of Bi2Mo3O12:Eu3+ phosphors and the application in latent fingerprint visualization

Eu3+-activated materials have garnered significant attention due to their outstanding optical characteristics. In this work, the sol–gel method was successfully used to prepare Bi2Mo3O12 phosphors doped with different amounts of Eu3+. The generated samples were identified as orthorhombic Bi2Mo3O12 with a scheelite-like structure by X-ray diffraction analysis of the crystal structure. The sample’s morphology and size were examined using scanning electron microscopy and transmmission electron microscopy, which revealed irregular block morphology and tens to hundreds nanometers scale dimension. From the analysis of the concentration-dependent luminescence intensity of Eu3+, it was confirmed that the exchange interaction was responsible for the quenching of 5D0 fluorescence of Eu3+. When excited at 374 nm, the phosphor emitted brilliant red light, with the highest emission occurring at 616 nm (5D0→7F2 transition), and the calculated color coordinates of the sample were (0.663, 0.336). By examining the temperature dependence of the emission spectra, the temperature sensing performance of the sample and the thermal quenching behavior of Eu3+ luminescence was explored. Furthermore, the optical transition property of Eu3+ was investigated by using the emission spectra and fluorescence lifetime within the context of Judd-Ofelt theory. Ultimately, latent fingerprint visualization of the sample on various object surfaces was studied, thanks to the intense luminescence and small particle size of the Bi2Mo3O12:Eu3+ phosphor. The results indicated that the sample can clearly display the different hierarchical features of fingerprint on different object surfaces.

Physical, optical and spectral properties of Sm3+ and Eu3+ ions doped zinc boro-phosphate glass

This study focuses on the synthesis of Sm³⁺ and Eu³⁺ rare earth ions doped zinc boro-phosphate glasses and their physical, optical and spectral characterization. Photoluminescence was carried out through both steady-state and time-domain luminescence measurements. The glasses were prepared via the melt quenching technique, and they exhibit impressive mechanical strength and transparency. Judd-Ofelt analysis of the near-infrared absorption spectra revealed parameters Ω₂, Ω₄, and Ω₆, indicating low covalency and reduced site asymmetry for the rare earth ions compared to those in silicate-based glasses. When excited with violet light, the Sm³⁺-doped samples emitted bright orange luminescence, resulting from radiative relaxation from the ⁴G₅/₂ state to lower energy levels. The calculated branching ratios correspond well with the observed emission peak ratios. However, increasing the Sm³⁺ ion concentration resulted in reduced luminescence intensity and shorter fluorescence lifetimes, due to cross-relaxation effects. In the Sm³⁺/Eu³⁺ co-doped glasses, energy transfer from Sm³⁺ to Eu³⁺ ions was detected upon selective excitation of Sm³⁺ ions. This energy transfer efficiency was found to increase with higher concentrations of Eu³⁺ ions.

Optical characteristics, Judd-Ofelt analysis of enhanced luminescence by flux in thermally stable, novel Eu3+- doped BaZr(PO4)2 phosphor for indoor lighting applications

A series of novel single phased Eu3+ doped BaZr(PO4)2 phosphor were synthesized employing simple solid-state reaction route and studied the influence of different chlorides as fluxes (NH4Cl, KCl, LiCl and NaCl) on structural and photoluminescence properties. The structural characterization reveals pure phase formation of the as prepared phosphors with monoclinic crystal structure. The photoluminescence (PL) spectra recorded under 392 nm excitation depicts intense emission at 612 nm. Further, the concentration of Eu3+ ion was well tuned by carefully studying the PL spectra and the optimised amount of Eu3+ ion in BaZr(PO4)2 is found to be 3.0 mol%. The luminescence properties of phosphor with added aforementioned fluxes were also studied in detail. NH4Cl was found to be the best among all the fluxes taken and the photoluminescence intensity of phosphor gets enhanced by 1.43 times of without flux. The Judd-Ofelt theory was employed for determination of spectral parameters from photoluminescent emission spectra. The temperature dependent photoluminescent studies establishes stability of phosphor emission at operating temperatures. The CIE coordinates were evaluated that confirms the pure red emission under n-UV excitation. All the studies indicate the potential of the said phosphor in phosphor converted white light emitting diodes as red emitter and indoor lighting.

Judd-Ofelt analysis of dimeric europium carboxylates with gradually changing distortions of the crystal field around Eu3+ ion

Experimental and theoretical Judd-Ofelt intensity parameters Ωλ, rates of radiative Arad and nonradiative Anrad processes, and quantum efficiency of luminescence were calculated for a series of related aromatic and aliphatic carboxylates [Eu2(RCOO)6L2] (L - 1,10-phenanthroline or 2,2′-bipyridine) using the LUMPAC software. The behavior of these characteristics in the sequence of europium carboxylates with the gradually changing distortions of the crystal field, which is mainly caused by variation in the bond lengths of the bridging-cyclic COO− groups with Eu3+ ion, was analyzed. A correlation between the changes in the value of the Ω2 intensity parameter, the radiative rate Arad, and the ratio of metal-ligand bond lengths in the Eu coordination polyhedron was demonstrated. The dependence of the parameter Ω2 on the distribution of metal-ligand orbital overlap among Eu-ligand bonds of the compound was revealed. The higher Ω2 values in the set of aromatic carboxylates are associated with a more distorted nearest environment of the Eu3+ ion which is caused by the influence of the bulky R fragments. It is shown that the intensity of f-f transitions of the Eu3+ ion in the compounds under investigation is determined foremost by the dynamic coupling (DC) mechanism. The contribution of this mechanism to the parameters Ω2 and Ω4 is close to 100 %, its contribution to the Ω6 parameter is 85–92 %. The luminescence quantum efficiency for the studied europium carboxylates varies in the range of 52–74 %.

Photoluminescent and X-ray photoemission studies of Eu3+-doped kosnarite KZr2(PO4)3 nanophosphor and its Judd–Ofelt analysis

Photoluminescent and X-ray photoemission studies of Eu3+-doped kosnarite KZr2(PO4)3 nanophosphor and its Judd–Ofelt analysis

Photoluminescence emission enhancement in the LiSrVO4:Eu3+ vanadate phosphor by partial substitution of M+ ions (M+=Li+/Na+/K+); optical thermometry; and optical transition probabilities using Judd-Ofelt analysis

In solid state lighting (SSL), pcWLEDs gain more attention for various illumination applications. The Eu3+ activated LiSrVO4:xEu3+ (0–15 mol% in steps of 3) phosphors are prepared by the conventional solid state method and their phase formation is confirmed by PXRD. It suggest that the samples are in a monoclinic structure with P2/m space group. SEM results confirmed that the size of the prepared phosphor is in a micrometer range with an irregular spherical shape. The optical diffuse reflectance spectrum (DRS) consisted broad band absorption in the ultraviolet (UV) region (270–350 nm) and also, they are found to absorb strongly the NUV light (396 nm) and the blue light (466 nm). They exhibit the strongest emission at 617 nm for the samples under 326 nm excitation. The PL intensity of the phosphors are improved by co-doping. The optical transition probabilities of the LiSrVO4:9 mol% Eu3+ phosphor are also analyzed using the Judd-Ofelt theory. The optimized phosphor showed a good thermal stability and the lifetime values are in the millisecond range. The absolute and the relative sensitivities are obtained from the temperature dependent lifetime measurements. The LiSrVO4:9 mol%Eu3+ phosphor yielded CIE coordinates (x, y) of (0.5987, 0.4005), a low CCT of 1468K, and a color purity of 96.4 %. These results indicate the potential application of the LiSrVO4 based phosphors in WLEDs.

Optical, vibrational, and photoluminescence properties of holmium-doped boro-bismuth-germanate glasses.

Holmium (Ho3+)-doped boro-bismuth-germanate glasses having the chemical composition (30-x)B2O3 + 20GeO2 + 20Bi2O3 + 20Na2O + 10Y2O3 + xHo2O3, where x = 0.1, 0.5, 1.0, and 2.0 mol% were prepared by melt-quenching technique. The prepared glasses were examined for thermal, optical, vibrational, and photoluminescent properties. The prepared glasses were found to be thermally very stable. The optical bandgap and Urbach energies of 0.1 mol% Ho2O3-doped boro-bismuth-germanate glass were calculated to be 3.3 eV and 377 MeV, respectively, using the absorption spectrum. The Judd-Ofelt analysis was performed on the 0.1 mol% Ho2O3-doped glass and compared the obtained parameters with literature. The branching ratio (β) and emission cross-section (σem) of the green band were determined to be 0.7 and 0.24 × 10-20cm2, respectively. Under 450 nm excitation, a strong green emission around 550 nm was observed and assigned to the (5S2 + 5F4) → 5I8 (Ho3+) transition. Upon an increase of Ho2O3 content from 0.1 to 2.0 mol%, the intensities of all observed emission bands as well as decay time of the (5S2 + 5F4) → 5I8 transition have been decreased gradually. The reasons behind the decrease in emission intensity and decay time were discussed. The strong green emission suggests that these glasses may be a better option for display devices and green emission applications.

New Er3+-doped gadolinium borogermanate glasses for optical telecommunication

New Er3+-doped gadolinium borogermanate glasses were synthesized to investigate their physical, structural, optical, and luminescence properties in this work. The influence of Er2O3 concentration on those properties were studied to determine the optimum glass composition for photonics material. Glass density, molar volume, refractive index, polarizability, and field strength increase, while Er3+ inter-ionic distance decreases via adding Er2O3 concentration. From XRD and FTIR results, the tetrahedral BO4 and trigonal BO3 borates are the main structural units those connect in amorphous nature to form as a glass network. Glasses absorb the photons in ultraviolet, visible light and near-infrared region under Er3+ transitions. Glasses generate the strong infrared emission around 1.5 μm under the 4I13/2 → 4I15/2 transition of Er3+ ion. The 3.0 mol%-Er2O3 doped glass performs the highest emission intensity due to the concentration quenching effect. The luminescence decay time is shortened from ∼0.8 to ∼0.4 ms by adding Er2O3 content. Judd-Ofelt and MacCumber analysis indicate high potential of glass for using as an optical amplifier in telecommunication applications, due to its large luminescence bandwidth.

Preparation and Judd-Ofelt Analysis of Warm Red Luminescent Eu3+ Complexes for Semiconductor Lasing Devices.

Six novel red photoluminescent Eu3+ complexes with 3-formyl chromone as the primary sensitizer (L) were synthesized using the solution precipitation method. These complexes are [Eu(L3).X] where X is 2H2O (C1), phen (C2), neo (C3), bipy (C4), dmph (C5), and biquno (C6). These complexes were characterized by elemental analysis, EDAX analysis, SEM, FT-IR, thermo-gravimetric analysis (TGA/DTA) and photoluminescence spectra. The transition rates, quantum efficiency, and J-O intensity parameters were calculated using emission data and luminescence decay time (τ). Complexes exhibit a strong emission peak (5D0 → 7F2) of the Eu3+ ion in their luminescence emission spectra in solid and solution states, making them an effective emitter of the red color in OLEDs. The branching ratio of these complexes ranges from 80.67-82.92 in solid and 50.53-62.65 in solution state; CIE color coordinate of complexes falls in the red region. The color purity ranges [CP(%)] values for solid 95.26-97.27% and for solution ranges 85.11-93.43%. Correlated color temperature (CCT) of the complexes (C1-C6) ranged from 2710 to 3049K in the solid state and 1775 to 2450K in the solution state. These complexes are promising red emitters in OLEDs, semiconductors, and leasing devices.

Synergistic enhancement of optical properties in erbium-doped borate glasses through copper nanoparticle incorporation

The present study investigated the impact of incorporating copper nanoparticles (CuNPs) on the optical properties of erbium-doped borate glasses. Through melt-quenching and heat treatment techniques, glasses with varying Cu2O concentrations (x = 0–5 mol%) were synthesized. Physical and structural analyses revealed that Cu ions serve as effective network modifiers. They foster the formation of a greater proportion of BO4 tetrahedra and thus enhancing glass homogeneity. Optical absorption spectra demonstrate a distinct modulation of Er3+ absorption bands with Cu2O embedding, indicating the formation of CuNPs, as validated by the emergence of surface plasmon resonance bands. This structural evolution results in a noticeable reduction in the bandgap energy, signifying improved semiconducting behavior. Judd-Ofelt analysis highlighted the profound influence of CuNPs on hypersensitive transitions, thereby affecting oscillator strength. Photoluminescence measurements revealed amplified emission in the visible red and near infrared (NIR) region, attributed to the synergistic effects of CuNPs and Er3+ ions, with 5 mol % Cu2O exhibiting the highest emission intensity. Analysis of the radiative properties validates the enhancement of the emission cross-section, gain bandwidth, optical gain and radiative transitions. These enhancements contribute to a notable increase in the branching ratio from 0.91 % to 5.41 % accompanied by an increase in the quantum efficiency from ∼79 % to ∼90 %. Moreover, decay analysis revealed a notable enhancement in lifetime from 3.03 ms to 15.74 ms, which is indicative of enhanced radiative transitions. Overall, the incorporation of CuNPs into erbium-doped borate glasses facilitates significant enhancements in physical, structural, and optical properties. This positions them as promising materials for a wide array of optoelectronic applications. This comprehensive study sheds light on the complex interplay between CuNPs and erbium-barium borate glasses, offering valuable insights for the development of advanced optoelectronic materials with enhanced performance and functionality.

Judd-Ofelt analysis of Sm3+ doped Ca2LiMg2V3O12 phosphors: Unveiling luminescent and thermometric properties for multifunctional applications

This study investigated the luminescent and thermometric properties of pure and Sm³⁺-doped Ca₂LiMg₂V₃O₁₂ (CLMV) garnet-type vanadates synthesized by the solid-state reaction method. The synthesized materials, with varying Sm³⁺ concentrations (0.01–0.09 mol%), were comprehensively characterized using powder X-ray diffraction (PXRD) analysis to confirm their phase purity. Diffuse reflectance spectroscopy (DRS) measurements were employed to determine the band gap energy of both pure CLMV and CLMV:0.07Sm³⁺ samples. Photoluminescence (PL) excitation and emission spectra were recorded for the pure and Sm³⁺-doped CLMV phosphors using an excitation wavelength of 345 nm and monitoring the emission at 618 nm. These spectra revealed detailed information about the energy levels involved in light emission processes. An efficient energy transfer from the (VO₄)³⁻ groups to the Sm³⁺ ions was observed, exceeding 48%. This energy transfer process is crucial for achieving high-intensity luminescence in Sm³⁺-doped materials. Judd–Ofelt (J-O) theory was applied from the emission spectra and calculate the Judd–Ofelt intensity parameters, which govern the radiative properties of the Sm³⁺ ions. Based on the J-O analysis, the branching ratio (β) was estimated to be greater than 75%. This value, exceeding the threshold of 50% for display devices, signifies the suitability of the phosphor for solid-state lighting applications due to its efficient light emission. The thermal quenching behavior of both the Sm³⁺ ions and the (VO₄)³⁻ groups was further investigated to explore the optical thermometric characteristics of the Sm³⁺-doped CLMV phosphors. Notably, a maximum absolute sensitivity (Sa) of 0.35 K⁻1 and a relative sensitivity (Sr) of 2.55% K⁻1 were achieved, demonstrating the materials potential for non-contact optical temperature sensing applications. Lifetime decay analysis revealed double exponential decay behavior, indicating the presence of multiple luminescence centers within the phosphor. The average lifetime in the millisecond range further supports the suitability of these materials for practical applications. Finally, the CIE color coordinates, correlated color temperature (CCT), and color rendering index (CRI) values were also reported, providing insights into the colorimetric properties of the Sm³⁺-doped CLMV phosphors. These aspects are crucial for optimizing the materials for solid-state lighting applications.

Luminescence studies and Judd Ofelt parameterization of Dy3+ activated La2(WO4)3 yellow phosphor

The synthesis and detailed luminescence studies of a series of La2-xDyx(WO4)3 (x = 0.02, 0.1, 0.2, 0.4, 0.6, 0.8) phosphors synthesized via microwave-assisted co-precipitation technique is reported in this paper. The XRD analysis confirmed that the phosphors were crystalized in a monoclinic structure with space group C2/c and FTIR analysis identified the characteristic vibrational modes. Morphological studies were conducted using FESEM analysis, and the EDS technique substantiated the effective incorporation of Dy3+ ions in La2(WO4)3. The photoluminescence excitation and emission spectra of varying concentrations of Dy3+ ions were recorded and an optimum concentration of 10% exhibited the highest intensity. The emission spectra of all phosphors were dominated by peaks at 484 nm and 574 nm. The radiative properties were evaluated using Judd-Ofelt analysis and the JO intensity parameters followed the trend Ω2 > Ω6 > Ω4. The gradual decrease in the decay lifetime value of 4F9/2 excited level with an increase in doping concentration elucidates concentration quenching phenomena due to dipole – quadrupole interaction. The emission data were also analyzed by calculating CIE coordinates and concluded that Dy3+ doped La2(WO4)3 phosphors have potential applications in yellow light generation.

Web-based application software for Judd-Ofelt analysis of Eu3+ ion luminescence

This article reports on the development of a new Web-based application software for calculating Judd-Ofelt intensity parameters and derived quantities from the emission spectra of Eu3+ doped compounds. The application was entirely developed in JavaScript, and it is compatible with all major browsers. The web application can be accessed via the following link https://sciapps.sci-sim.com/judd_ofelt_analysis_Eu.html. Test samples of ZnO doped with different amounts of Eu3+ were synthesized using the combustion method, and their radiative properties and the chemical environment in the Eu surroundings were thoroughly investigated by Judd-Ofelt intensity and the derived parameters using the online application. In contrast to the tediousness and time-consuming process of these types of calculations, by using this online software, all intensity parameters and the derived quantities can be obtained within a short time.