With the economic and social transformation, corporate social responsibility has become an important factor affecting the enterprises performance. In this paper, we make an empirical analysis of the relationship between corporate social responsibility and organizational performance by using structural equation model. The result shows that CRS has an impact on the human resource management practice and organizational performance, at the same time, the HRM system has played an intermediary role. Enterprises to fulfill corporate social responsibility will significantly enhance the efficiency of human resource management, and obtain recognition of employees. So that it is necessary for enterprises to undertake the social responsibility in the long-term, and CRS will provide potential value for enterprises' competitive advantage. With the transformation of China's economic and social, enterprises take the initiative to take social responsibility in practice is very important. In particular to take the subject of corporate social responsibility of a company, enterprise or organization, from the perspective of system, resources and competitive advantage, the enterprise bear the social responsibility is not only necessary and to the survival and development of enterprises and competitive advantage are potential value. The relationship between corporate social responsibility and corporate financial performance of long debate and research still continues, with the stakeholder theory is put forward, and were more likely to enterprise stakeholders (1). The construct, and enterprise staff is enterprise key stakeholders, is the important resources of enterprises, business objectives or performance is obviously affect employee goals and can be influenced by the employee, the enterprise must on today's human resource issues active response, and to obtain the legitimacy of enterprise operation, coordination of the enterprise and employee relations, taking the way of harmonious relationship between employees and organizations to realize the sustainable development of enterprises. Enterprises to the human resources and social issues management, into the enterprise human resources management policy and practice operation, affect employee behavior and attitude to meet the demand of human resources and obtain competitive advantage and organizational performance. Carol put forward the Pyramid model of corporate social responsibility; corporate social responsibility is divided into economic responsibility, legal responsibility, and ethical responsibility. Many disputes about corporate social responsibility mainly focus on enterprise, such as principal -agent theory, property rights theory, from the perspective of the nature of these enterprises to find the main body of social responsibility (2). Corporate social responsibility from the