Expressions for the amplitude reflection and transmission coefficients for light incident on a dielectric thin film that is biaxially anisotropic and situated on an isotropic substrate are presented for the special case where one of the principal axes of the film is parallel to the surface of the film and perpendicular to the plane of incidence of the light. This is one of a few special cases for reflection from anisotropic materials that contains no cross-coupling between the p and s polarizations of the light.