Isotopic Characteristics Research Articles

Boron isotopes identify deep-slab serpentinite in the source of Aleutian arc magma

Seafloor lavas of the Western Aleutian arc have isotopically heavy boron (δ11B to +13.4‰) that is negatively correlated with B content (ppm). Endmember samples are primitive dacites and rhyodacites (δ11B > +10‰, SiO2 = 63%−70%, Mg# > 0.60) with adakitic trace-element and isotopic characteristics that require roles for residual garnet and rutile in their formation. The source of isotopically heavy B is likely serpentinite in the mantle section of the subducting plate, which dewaters into an inverted geothermal gradient and drives melting within the overlying volcanic section at depths where prior effects of seawater alteration were minimal. Most volcanic rocks from the Aleutian Island locations have 10−30 ppm B with an average δ11B of ∼+1.0‰ ± 1.3‰, reflecting a mixed source dominated by subducted sediment. A subset of island samples has B that is isotopically light (δ11B < −2.4‰) and at low concentrations (<11.0 ppm), which is typical of arc lavas globally from rear-arc settings where depth-to-slab is high, and where δ11B may be interpreted to reflect a source in dehydrated (isotopically light) altered oceanic crust. Mass balance modeling indicates that isotopically heavy B from deep-slab serpentinite is present in the Aleutian source arc-wide but is typically masked by sediment-derived B at volcanic centers outside of the westernmost segment of the arc.

Methane seepage activities in the Qiongdongnan Basin since MIS2

Gas hydrates are globally acknowledged as a significant strategic alternative energy source, and there is a consensus on the necessity to enhance their exploration. However, gas hydrates are highly prone to decomposition under variations in external environmental conditions, which can result in subsea methane seepage activities. Consequently, investigating subsea methane seepage activities holds substantial theoretical and practical significance for exploring gas hydrates. This paper evaluates the history of methane seepage activities in the Qiongdongnan Basin (QDNB) by analyzing the carbon and oxygen isotopic characteristics of benthic foraminifera and the geochemical properties of pore water from gravity sediment cores at sites QH-CL4 and QH-CL40. The results indicate that since the Marine isotope stage2 (MIS2), continuous micro-methane seepage activity has been present in the QDNB, characterized by a slight negative deviation in the carbon isotopes of benthic foraminifera. Methane seepage activity intensified during 14.6 ka BP and between 19.64–23.22 ka BP. This increase is thought to be associated with rising seawater temperature during the Bølling–Allerød interstadial and declining sea level during the Last Glacial Maximum, respectively. Moreover, current geochemical characteristics of pore water reveal strong methane seepage activity, with flux as high as 28.968 mmol·m-²·a-¹. This ongoing activity has led to gas hydrate formation within shallow layers while also causing negative deviations in pore water salinity.

Genetic relationship between W mineralization and granitic intrusion in Nanling Region, South China: Constraints from zircon and cassiterite u-pb age from new drill holes in Shangping deposit

The Nanling metallogenic belt is known for the widely development of typical quartz vein type W deposit. These quartz veins that contain wolframite are frequently located in close proximity to granitic intrusions. The genetic relationship between tungsten mineralization and the associated granitic rocks is still a subject of controversy. The Shangping deposit stands out as a historically significant W deposit with a quartz vein type in the region of Nanling. However, the specific time that W mineralization occurred remains enigmatic. Granitic intrusions are absent from the mine and only granite porphyry dike is exposed, so the link between tungsten mineralization and magmatic activity remains unclear. Fortunately, in recent years, a concealed granite intrusive has been exposed in drill holes in the southeastern of the Shangping W deposit. To comprehensively address the connection between granitic magma activity and W mineralization, it is vital to make up a relative deficiency of geochronological information on granite and ore mineral. Here, in order to get the first direct age constraints on the origin of the Shangping W deposit, we use a combination of different techniques, incorporating the Hf isotope geochemistry of zirconium and cassiterite U-Pb assessment using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Based on these robust data, we tentatively evaluated the connection between W mineralization and granitic intrusion.For the granite porphyry, the majority of representative U-Pb zircon assays establish a206Pb/238U age of 150.2 ± 0.5 Ma. An inferred emplacement age of ca. 151 Ma for the concealed granite in Kengweiwo is supported by a U-Pb isochron age from zircon. Combined with Hf isotopic characterization, it illuminates the mineralization potential of the Kengweiwo concealed granite. Cassiterite grains from hydrothermal quartz vein are subhedral to anhedral and have a lower intercept 206Pb/238U age of 153.9 ± 1.0 Ma. For the Shangping W deposit, all of these new geochronological dates provide well-constrained mineralization ages of 150–154 Ma. The dates of the concealed granite in the Kengweiwo area and the tungsten mineralization in the Shangping area are extremely concordant, indicating that they occurred roughly concurrently. The vein type tungsten mineralization in Shangping deposit may has a genetic link with crystallization of uncovered granite present at depth, which requires further investigation. These results emphasize the significance and potential of concealed granitic intrusion to host disseminated W mineralization in the deep part of Shangping deposit.

Water content drives distinct evolution trajectory of Early Cretaceous granitoids in inland and coastal southeast China

Water plays a crucial role in determining the crystallization sequence of magma, which subsequently influences the chemical compositions of magmatic rocks across different tectonic settings. In this study, we compared the evolutionary features of granitic rocks along the coast and inland areas of southeast China, aiming to identify the key factors influencing their evolution. Our work indicates that multiple granitic intrusions formed between 126 and 142 Ma in the coastal region of southeastern China, which is consistent with the formation ages of large-scale granitoids in the inland Gan-Hang Belt. Isotopic characteristics suggest that the granitic rocks in southern Fujian originated from the melting of juvenile crust, while those in northern Fujian and eastern Zhejiang were formed from the partial melting of ancient crustal rocks, incorporating mafic magma evolved from the mantle. Most of the granitoids from the coastal region of southeastern China exhibit low zircon saturation temperatures (680–800 °C) and Zr/Sr ratios (<1), suggesting their origin from a cold, wet magma reservoir. The porphyritic quartz diorite and porphyritic monzogranite represent the residual cumulate rocks of this hydrous magma reservoir, whereas the granitic porphyry and high-silica equigranular alkali feldspar granite evolved from the felsic melts extracted from the same reservoir. In contrast, most of the Early Cretaceous granitoids in the Gan-Hang Belt, located in the inland areas of southeast China, display high zircon saturation temperatures (800–900 °C) and Zr/Sr ratios (>1), indicating their origin from hot, water-poor magma reservoirs. The porphyritic granites in this region represent residual cumulate rocks formed in water-poor magma reservoirs, whereas the high-silica equigranular granites evolved from hot felsic melts extracted from similar magma reservoirs. In the Early Cretaceous, the coastal region of southeastern China was closer to the Late Mesozoic paleo-Pacific subduction zone, where crystal-melt segregation within cold, wet magma reservoirs predominantly influenced magma evolution. Conversely, the granitoids in the Gan-Hang Belt in the inland region, located farther from the Late Mesozoic paleo-Pacific subduction zone, were associated with a rift tectonic setting and formed through crystal-melt segregation within hot, water-poor magma reservoirs. Our study underscores the critical role of water content in magma reservoirs in shaping the chemical composition of granitic rocks through crystal-melt segregation, thereby deepening our understanding of crustal formation processes across diverse tectonic environments.

SOURCES OF MAGMAS OF PERMIAN GABBROS OF THE KHANGAI MOUNTAINS (Western Mongolia)

We present Sm–Nd and Rb–Sr isotope composition data on mafic–ultramafic massifs in the Khangai Mountains of Western Mongolia: Oortsog-Uul, Nomgon, and Yamaat-Uul. The U–Pb age of zircon and its Lu–Hf isotope and trace-element compositions were determined by LA–ICP–MS. New and previous geochronological data obtained by SIMS and LA–ICP–MS support the Permian age of the studied gabbros. The trace-element composition of zircon, characterized by strong HREE enrichment ((Lu/Gd)n &amp;gt; 7) and cerium positive (Ce/Ce* &amp;gt; 6.6) and europium negative (Eu/Eu* = 0.16–0.49) anomalies, indicates its magmatic genesis and the possibility of using isotope characteristics to assess the origin of mafic magmas. The formation of zircon from a residual mafic melt is inferred from the enrichment of zircon in U and Th with increasing Th/U, reflecting the accumulation of these highly incompatible elements in the residual melt, and from the crystallization temperature of zircon (810–880 °С). The geochemical characteristics of the rocks, their isotopic composition, the absence of xenogenic ancient zircons, and the lack of correlation between εNd(T) and major indices of crustal contamination indicate that crustal contamination did not influence the composition of the gabbros. Isotopic data on rocks and zircon indicate the involvement of two mantle sources in the formation of the mafic–ultramafic massifs of the Khangai Mountains: (a) depleted, predominant for the Nomgon and Yamaat-Uul massifs (εHf = 16.1–2.0; εNd = 4.5–0.0; and ISr = 0.70385–0.70537), and (b) enriched, predominant for the second phase of the Oortsog-Uul massif (εHf = 1.4–0.2; εNd = –3.6… –5.7; and ISr = 0.70704–0.70933).

Isotopic variability of short-tailed Albatrosses bone collagen (&lt;i&gt;Phoebastria albatrus&lt;/i&gt;) in the Bering Sea area during the holocene

The short-tailed Albatross (Phoebastria albatrus) is a rare bird species today, whose numbers declined significantly in the Holocene due to human fishing activities. Bone remains of albatrosses from archaeological sites of Chukotka, Kamchatka and Aleutian Islands, and from coastal sediments of the Commander Islands were used to analyze the content of stable carbon and nitrogen isotopes in bone collagen. Analysis showed that the isotopic niches of Aleutian and Commander albatrosses diverged during the Holocene. Short-tailed albatrosses of the Aleutian Islands are closer to Holocene albatrosses of Vancouver Island (Canada) by isotopic characteristics.

The Isotopic Characteristics, Sources, and Formation Pathways of Atmospheric Sulfate and Nitrate in the South China Sea

The Isotopic Characteristics, Sources, and Formation Pathways of Atmospheric Sulfate and Nitrate in the South China Sea

ISOTOPE COMPOSITION OF Pb AND Nd OF THE LATE NEOPROTEROZOIC–EARLY PALEOZOIC GRANITOIDS IN EASTERN TUVA (Case study of the Kaa-Khem batholith)

We present the results of Nd and Pb isotope studies of late Neoproterozoic–early Paleozoic granitoids of the Kaa-Khem batholith, which formed in different geodynamic settings within the early Caledonian structures of Eastern Tuva (Altai–Sayan sialic area). Based on the obtained isotope data, we assess the role of different source materials in the formation of melts for these granitoids and compare these rocks with coeval granitoids from the Lake Zone of Mongolia. The plagiogranitoid associations of the island arc stage of the Kaa-Khem batholith formation (572–562 Ma) are characterized by mantle Nd isotope values. In contrast, the Pb isotope characteristics of these intrusive associations correspond to an upper-crust source formed predominantly by terrigenous sediments. The granitoid associations of the accretion–collision stage of the Kaa-Khem batholith formation (512–450 Ma) have a less radiogenic primary Pb isotope composition as compared with the island arc granitoids. Evidently, during the magma formation at this stage, the relative role of terrigenous material decreased, while the role of depleted mantle material increased. At the same time, the decrease in ɛNd values in the granitoids as compared with the depleted mantle indicates that, along with the upper-mantle component, the role of the lower-crust component increased. These Nd and Pb isotope characteristics of the accretionary granitoids of the Kaa-Khem batholith indicate a significant contribution of the lower-crust source to their formation. This source is the crystalline basement of the Tuva–Mongolian microcontinent. The Pb isotope characteristics of the accretion–collision granitoids of the Kaa-Khem batholith are shifted to the upper-crust compositions relative to those of the Lake Zone granitoids. The reason is that the latter formed predominantly through the transformation of early Caledonian island arc complexes, which were generated with a higher portion of mantle component.

Isotopic signature of N2O produced during sulfur‐ and thiosulfate‐driven chemoautotrophic denitrification in freshwaters

AbstractChemoautotrophic denitrification plays an important role in nitrogen removal and the formation of a greenhouse gas (N2O) in aquatic environments. Natural stable isotopes support the tracing of nitrogen sources and the identification of biogeochemical processes in field research. However, the isotopic characteristics of N2O produced during chemoautotrophic denitrification have not been investigated so far. In this study, we analyzed isotopic signatures of nitrate and N2O in sulfur‐ and thiosulfate‐dependent denitrifying enrichments obtained from freshwater lakes. Chemoautotrophic denitrification exhibited a nitrate isotope pattern similar to heterotrophic denitrification: the 18ε/15ε‐nitrate followed a ratio close to 1. However, chemoautotrophic denitrification produced N2O with lower δ15N, δ18O, and higher site preference (SP = δ15Nα‐δ15Nβ) values, compared to heterotrophic denitrification. The SP value, approximately 5.1‰, was characteristic in detecting chemoautotrophic denitrification driven by different sulfur forms. δ18O varied with specific electron donors, around 20‰ and 40‰ during sulfur‐ and thiosulfate‐dependent denitrification, respectively. The unique N2O isotope characteristics were likely regulated by nitric oxide reductases of Burkholderiaceae populations during sulfur‐dependent denitrification and Sulfurovum during thiosulfate‐dependent denitrification. These findings improve our understanding of N2O production processes and have important implications for predicting N2O emissions at a greater spatial and temporal resolution.

B–Li differential enrichment of geothermal systems in the Da Qaidam and Gonghe–Guide Basin, northeastern Tibetan Plateau: Evidence from water chemistry and H–O–B–Li isotopes

Typical geothermal systems in the Da Qaidam (DQ) and Gonghe–Guide Basin (GGB) on the northeastern Tibetan Plateau (NETP) discharged different BLi contents. A widely accepted metallogenic model is that the salt–lake type BLi deposits in the TP are recharged by geothermal fluids with B–Li–rich, carried by rivers and enriched in the terminal salt lakes. The B–Li–rich geothermal water is the key source of mineralization in salt lakes, however, enrichment mechanism governing differential BLi contents in DQ and GGB geothermal systems remains ambiguous. This study systematically deciphers water chemistry and isotope characteristics (δD, δ18O, δ11B, δ7Li) of river waters, geothermal waters, sinters and surrounding rocks to discuss the enrichment process of BLi elements in the DQ and GGB geothermal systems. The δD and δ18O values of geothermal systems in the DQ (δD = −79.60 ∼ −82.40 ‰, δ18O = −10.97 ∼ −11.38 ‰) and GGB (δD = −64.00 ∼ −97.10 ‰, δ18O = −8.70 ∼ −13.00 ‰) are close to the GMWL and LMWL, indicating meteoric origin. The δD and high Cl− values (300–900 mg/L) of geothermal waters in the DQ and Qiabuqia, Qunaihai, Zhacangsi along Riyueshan of the GGB imply that these geothermal waters mixed by magmatic fluid and meteoric water. The hot springs in the DQ (B = 38.35–46.29 mg/L, Li = 3.11–3.72 mg/L) and GGB (B = 0.17–8.16 mg/L, Li = 0.08–10.49 mg/L) exhibit differential BLi geochemical characteristics. B and Li contents are higher in DQ hot springs and in hot springs along Riyueshan of the GGB, respectively. Comparison of the BLi contents and δ11B–δ7Li values of geothermal waters, sinters and host rocks reveals that BLi contents of geothermal waters are controlled by B–rich HP-UHP metamorphic rocks formed by metamorphism and Li–rich granites or pegmatites formed by magmatism in the Qilian Shan, respectively. Moreover, metamorphic and magmatic processes, combining with deep circulation reactivated by the thrust or strike–slip faults, create differential enrichment of BLi elements in the geothermal systems, such as DQ and GGB on the NETP. This study highlights into understanding the differential enrichment of BLi in the geothermal system on the TP. Furthermore, the resource elemental abundance of geothermal waters can be applied as an important prospecting indicator of endogenous BLi deposits.

Genesis of the Haopinggou breccia-hosted Au deposit, western Henan Province, China

Breccia-hosted Au deposits within the North China Craton (NCC) exhibit a complex genesis, with some breccias being genetically linked to Au mineralization and others unrelated. Understanding the origin of these breccias is crucial for elucidating the genesis of associated ore deposits and guiding exploration strategies. The Haopinggou deposit in the Xiong’ershan district, on the southern margin of the NCC, comprises quartz-carbonate vein-hosted Ag–Pb–Zn–Au deposits and related breccia pipe in metamorphic rocks of the late Archean to early Paleoproterozoic Taihua Group. The origin of the Haopinggou breccia is crucial to understand the Xiayu Ag-Pb-Zn-Au mineralization (5640 t Ag). In this study, we evaluate the genetic links between breccia and Ag-Pb-Zn-Au mineralization, with new insights obtained from the Haopinggou deposit characteristics, breccia characteristics, breccia-hosted Au mineralization, and isotopic data, which refine our understanding of Haopinggou Ag-Pb-Zn-Au hydrothermal systems and exploration models in discordant breccia pipes. Recent underground tunnel surveys and drill-core logging reveal a close spatial link between the breccia and hidden granite porphyry. Juvenile magmatic clasts (granite porphyry) and cement (K-feldspar and quartz crystallized from granite porphyry) are present in the breccia pipe above a granite porphyry apophysis, indicating that the breccia was formed by phreatomagmatic brecciation caused by emplacement of the granite porphyry. Fluidization at the cm- to 100-m-scale reveals that the movement direction of clasts inside the breccia pipe was from northwest to southeast after crypto-explosion, creating a northwest-trending breccia zone. Anhedral monazite (131.2 ± 7.6 Ma) encapsulated in pyrite from the breccia constrains the upper limit of brecciation. The δ34S values of pyrite in rock powder and hydrothermal cements range from 3.8 ‰ to 5.3 ‰ (mean: 4.8 ‰) and 2.7 ‰ to 7.5 ‰ (mean: 5.2 ‰), respectively, with δ34S-sphalerite in hydrothermal cement ranging from 5.7 ‰ to 6.1 ‰ (mean: 5.9 ‰) and δ34S-chalcopyrite ranging from − 0.9 ‰ to 5.6 ‰ (mean: 2.9 ‰). The S isotope characteristics of vein-hosted and breccia-hosted mineralization zones are consistent, with complete alignment of the sulfide assemblages and alteration features. These pieces of evidence collectively indicate that both vein- and breccia-hosted mineralization zones are products of magmatic activity. The metallogenic model for the Haopinggou breccia pipe underscores its unique formation mechanism, driven by pre-existing northwest-striking structural weaknesses and fluidization, indicative of a predominant northwest–southeast clast movement, and suggesting the potential for deep-seated porphyry-type Au mineralization.

Influences of the Stagnant Pacific Slab Beyond Its Westernmost Edge: Insights From the Cenozoic Alkaline Basalts in the Dariganga Volcanic Field, SE Mongolia

AbstractIt remains uncertain whether a stagnant slab in the mantle transition zone can affect the asthenospheric mantle beyond its leading edge. To address this question, we investigated Cenozoic alkaline basalts from the Dariganga volcanic field (DVF) in southeastern Mongolia. The DVF is located west of North–South Gravity Lineament (NSGL) in Eastern China, which is spatially coincident with the seismically detected stagnant Pacific slab front. Basalts from the DVF consist of nephelinite, basanite and alkali olivine basalt. These rocks have relatively high Nb/U (average = 58) and Nb/La (&gt;1) ratios and radiogenic Nd–Hf isotopic compositions. They also have high Ca/Al (0.60–1.13), Zn/FeT (13.5–16.5), and FeO/MnO (77–112) ratios as well as low δ26Mg (−0.42‰ to −0.26‰) values, reflecting an asthenospheric mantle source modified by carbonated eclogite‐derived melts. Pb–Nd–Hf isotope characteristics indicate that the carbonated eclogite‐derived melts likely originated from the stagnant Pacific slab. Although Cenozoic basalts from both the east of the NSGL (ENSGL) and DVF domains exhibit light δ26Mg values, basalts from the ENSGL nevertheless have lower δ26Mg values than those in the DVF domain. This suggests a gradual westward decline in the amount of carbonated melts/fluids derived from the stagnant Pacific slab. This variation trend, combined with a more fertile and oxidized asthenospheric mantle toward the ENSGL, indicates that the stagnant slab has affected the mantle and created a compositional aureole beyond its leading edge, which substantially contributed to the formation of the alkaline basalts in the DVF.

Oxygen and hydrogen isotope characteristics of different water bodies in the Burqin River Basin of the Altay Mountains, China

Oxygen and hydrogen isotope characteristics of different water bodies in the Burqin River Basin of the Altay Mountains, China

Indosinian magmatism in NE Vietnam: Petrogenesis and geodynamic implications of Triassic mafic suites from the Song Hien region

The Song Hien region is located at the southern margin of the South China Block and includes Early–Middle Triassic mafic suites. The petrogenesis and tectonic context of these rocks are important to comprehending one of the most challenging periods in the tectonic evolution of northern Vietnam related to the South China–Indochina collision. In the present study, we provide the first systematic examination of whole-rock geochemical and SrNd isotopic compositions of mafic suites from the NE Vietnam. The studied Early–Middle Triassic suites are dominated by basalts. The rocks are enriched in LILEs, U, and Th and depleted in Nb and Ta and show a wide range of geochemical and SrNd isotopic compositions ((La/Yb)CN = 0.4–4.6; Dy/Dy⁎ = 0.7–1.3; (87Sr/86Sr)i = 0.7053–0.7125; εNd(t) = (+3.7)–(−8.0)). They all originated from shallow melting of a subduction-modified lithospheric mantle, and the compositional diversity of these basalts is attributed mainly to geochemical and Nd-isotopic heterogeneity in the mantle source. The geochemical and SrNd isotopic features of the studied mafic suites indicate a negligible contribution of the asthenospheric mantle to magma generation and differ significantly from those of the Emeishan plume-related basalts. A model in which Early–Middle Triassic mafic magmatic activity in the NE Vietnam region is the result of decompression melting driven by convective thinning of the South China mantle lithosphere during the 250–240 Ma period is discussed in the study. This period corresponds to the South China–Indochina continental collision. In the NE Vietman region, the Early–Middle Triassic syn-collisional magmatism has an important metallogenic context, controlling NiCu sulfide and Sn(Cu) mineralizations.

Calcite U[sbnd]Pb dating and geochemical constraints on fracture opening in organic-rich shales

Gas-bearing, organic-rich shales commonly host numerous opening-mode fractures; however, their formation mechanism remains controversial, with competing arguments of tectonic-origin and/or hydrocarbon generation pressurization-origin. Here, we studied fracture fillings in shale reservoirs of the lower Silurian Longmaxi Formation in the Luzhou area, southern Sichuan Basin, SW China. Using in-situ UPb geochronology, rare earth elements (REEs) and C-O-Sr isotope geochemistry, and fluid inclusion analyses, we investigated the timing and geochemical attributions of fracture fills and identify the mechanism of fracture formation. The results show that, the cements that occupy fractures in the Longmaxi Formation shales contain mainly calcite and quartz. The calcite cements show crack-seal and fibrous textures, indicating that they are syn-kinematic mineral deposits. The 87Sr/86Sr values of the calcite cements essentially overlap with those of their proximal host shales. This result, combined with slight depletions in δ13CPDB and relatively uniform fluid δ18OSMOW isotopic features, indicate that the fluids from which the calcite precipitated were largely derived from their surrounding host shales. Abundant methane inclusions are present in fracture cements, with trapping pressures of 104.5–157.5 MPa and pressure coefficients of 1.92–2.43, suggesting they were trapped in an overpressurized fluid system. In-situ UPb dating of calcite cements yielded ages of ca. 160 Ma and ca. 110 Ma, which coincide with the timing of thermal cracking of oil to gas during burial. In combination with the overpressurized, geochemically closed fluid system, the fractures were most likely triggered by gas generation. Our study emphasizes that natural fracturing induced by hydrocarbon generation overpressurization is an essential mode of brittle failure in tectonically quiescent basins worldwide.

New Capabilities of the PAT Plutonium Analysis Program

The Plutonium Attribute Test (PAT) is a software program originally developed for determining the category of a plutonium sample. The premise for its development was that, to assign Pu samples to particular categories, it is not necessary to determine the abundance of all its isotopes. Rather, it is sufficient to determine only 239Pu abundance, which is universally used to establish a category assignment, i.e., >90 wt% 239Pu is low burnup (LBPu), <70 wt% is high burnup (HBPu), and the abundances in between could be considered medium burnup (MBPu) plutonium grade. In contrast to previous Pu isotopic analysis programs which analyze spectra taken with HPGe detectors, the algorithms developed in PAT analyses use spectra taken with medium resolution detectors such as LaBr3(Ce) and CZT detectors. As demonstrated by initial tests, PAT was found capable of not only assigning the material category, but also accurately determining 239Pu abundance, with several per cent typical relative combined standard uncertainty. Furthermore, an advanced algorithm (A-PAT) was added to allow full isotopic characterization of samples. This paper presents further enhancements of the PAT/A-PAT algorithms towards analysis of heavily shielded samples, samples with varied size and age, as well as mixed oxide (MOX) materials.

Enrichment Mechanism of Polymetallic Elements at the Base of the Niutitang Formation in Southeast Chongqing

Polymetallic enrichment layers are commonly found at the base of the Lower Cambrian and extensively distributed across the Upper Yangtze Platform, yet their genetic models remain controversial. This study systematically collected samples from a typical section in the southeastern Chongqing region for mineral, organic, and inorganic analyses. It investigates the relationship between the abundance of various trace metal elements and organic matter at the base of the Niutitang Formation, as well as the vertical distribution characteristics of organic carbon isotopes and organic matter features. The results indicate that the Niutitang Formation shale exhibits a distinct three-part structure from bottom to top. Various metal elements are enriched in the lower interval, showing a close correlation between the abundance of polymetallic elements and the carbon isotopes of shale organic matter. The middle interval contains the highest TOC value and the lowest Ti/Al ratio, while the upper interval shows a significant decrease in organic matter abundance, with a clear positive correlation between the excess silicon content and Ti/Al ratio. Additionally, the mixing effect of deep-sea upwelling is the primary control on the formation of polymetallic enrichment layers in the lower interval, followed by the adsorption of organic matter under anoxic conditions. The sedimentary environment of the upper interval of the Niutitang Formation trends toward oxidation, with paleoclimate shifting toward colder and drier conditions, exhibiting aeolian sedimentary features that are unfavorable for the enrichment of trace metal elements. Consequently, upwelling is a key factor in the enrichment and mineralization of trace metal elements at the base of the Lower Cambrian in the Upper Yangtze region.

Origin and Affinities of the Malmberget Iron Oxide-Apatite Deposit, Northern Sweden: Insights From Magnetite Chemistry and Fe-O Isotopes

European iron ore production is primarily sourced from magnetite dominated iron oxide-apatite ore deposits in the northern Norrbotten ore province of northernmost Sweden. The Malmberget iron oxide-apatite deposit is at present the largest iron ore resource in Europe and is an amphibolite facies grade analogue of the world-famous Kiirunavaara iron oxide-apatite deposit. The Malmberget rock association is characterised by multiple phases of deformation, metamorphism, and alteration that resulted in a geometrically and petrologically complex deposit that is genetically ambiguous. Primary ore textures and emplacement structures of the Malmberget iron oxide-apatite deposit have largely been recrystallised during metamorphic overprinting and now comprise dominantly medium- to coarse-grained granoblastic magnetite. However, isotopic characteristics are preserved and when combined with trace element chemistry, these can be used to understand magmatic vs. hydrothermal origin of the deposit. To unravel the primary origin of the Malmberget magnetite ore, we combined magnetite trace element chemistry and Fe-O stable isotopes to investigate the massive magnetite in the Fabian-Kapten and ViRi ore bodies of the Malmberget iron oxide-apatite deposit. Trace element correlations indicate a high-temperature magmatic to a transitional high-temperature magmatic-hydrothermal origin of the Malmberget iron oxide-apatite ore deposit, with data plotting into fields of clear magmatic affinity in trace element discrimination diagrams. Fe-O data fall into established magmatic fields regardless of subsequent metamorphic modifications, underlining a dominantly (ortho-)magmatic origin of the investigated deposits. Despite an overall magmatic to magmatic-hydrothermal origin for the two ore bodies studied, Fe-O isotope equilibrium calculations of the magnetite suggest a possible temperature discrepancy between the Fabian-Kapten ore body and the ViRi ore body, the latter showing a more pronounced magmatic character. These variations in trace element contents and Fe-O isotopes can be explained by the proximity of the more magmatic signatures to the centre of the ore forming magmatic system.

Geothermal distribution and evolution of fault-controlled Linyi geothermal system: Constrained from hydrogeochemical composition and numerical simulation

This study explores the Linyi geothermal field, located in Shandong Province, China, characterized by its non-magmatic, active fault-controlled geothermal system. Utilizing a combination of geochemical analyses, temperature measurements, and numerical simulations, a detailed genetic model of the geothermal system has been developed. The analysis included extensive water geochemical and isotopic characterization to determine reservoir temperature, depth, and origin of the geothermal waters. The thermal-hydro coupling model was integrated with these data to refine the thermal distribution and assess the evolutionary dynamics of the geothermal system. Our findings indicate that the geothermal anomalies in the Linyi field are predominantly controlled by hydrothermal convection within the Ordovician and Cambrian carbonate layers, facilitated by the high permeability of the Yishu Fault. The fault acts as a crucial conduit for meteoric water recharge, which undergoes significant heating due to the geothermal gradient in deeper rock formations. Isotopic analyses of hydrogen and oxygen revealed the meteoric origin of the geothermal waters, with recharge likely originating from the nearby Yimeng Mountains. Furthermore, the study established a conceptual evolutionary model to understand the mechanisms driving the geothermal resource development in the area. It was determined that the geothermal resources are typically fault-controlled, with significant potential for further exploration due to the identified hydrothermal anomalies at the fault's footwall. The model predicts the preservation of heated meteoric water in the reservoir rock for periods ranging from 10 to 50 thousand years, providing a sustainable source of geothermal energy. This comprehensive approach not only enhances the understanding of the heat accumulation mechanism but also highlights the potential for optimizing geothermal exploration strategies within fault-controlled geothermal systems.

Effect of CO2 and H2SO4 on the dissolution of a carbonate basement and alteration of silicates in a volcano-sedimentary system in central Mexico

This study explores the hydrogeochemical and isotopic characteristics of groundwater in the Irapuato Valley and Celaya Valley Aquifers in central Mexico, specifically focusing on the role of CO2 in mineral alteration during water-rock interaction. The study is grounded in the principles of hydrogeochemistry and stable isotope geochemistry, analyzing the impact of CO2 and H2SO4 on the weathering of carbonates and silicates. Hydrogeochemical analysis, including Piper diagrams, and isotopic measurements (δ13C, δ18O, δ2H), were conducted on water samples from wells in four municipalities (Irapuato, Salamanca, Villagrán, and Juventino Rosas). The data was statistically evaluated using Shapiro-Wilk tests to assess normality, skewness, and kurtosis, ensuring the reliability of the findings. The results indicate that HCO3− dominates the groundwater composition, with CO2 and H2SO4 significantly influencing mineral alteration processes. The isotopic data suggest that CO2 is primarily released from carbonate rock degassing, with slight isotopic enrichment in δ13C due to water-carbonate interaction. Hydrothermal fluids contribute to the geochemical evolution of the aquifer, leading to the formation of minerals such as tridymite, alunite, and kaolinite. Additionally, some groundwater samples exhibit evidence of thermalism and water-rock interactions, influencing their isotopic signatures and temperatures. These findings underscore the importance of CO2 in groundwater chemistry and highlight the need for further studies to understand regional flow dynamics and the potential impact of geothermal systems on water quality.