Thermodynamic and transport properties of liquid and liquid mixtures have been used to understand the intermolecular interactions between the components of the mixture. The sound velocity, density and viscosity of binary liquid mixtures are important from practical and theoretical point of view to understand the liquid theory. In the present study sound velocity, density and viscosity have been measured of binary mixtures of 1, 3-dioxolane with pentanol, hexanol, heptanol, octanol, nonanol and decanol over the entire range of mole fraction at 298.15K, and atmospheric pressure. From these experimental measurements the excess molar volume (V<sub>m</sub><SUP>E</SUP>), excess viscosity (η<SUP>E</SUP>), acoustic impedance (Z<SUP>E</SUP>) and excess adiabatic compressibility (β<sub>ad</sub><SUP>E</SUP>), have been calculated. The excess molar volume (V<sub>m</sub><SUP>E</SUP>), excess viscosity (η<SUP>E</SUP>), acoustic impedance (Z<SUP>E</SUP>) and excess adiabatic compressibility (β<sub>ad</sub><SUP>E</SUP>), have been analyzed in terms of interactions arising due to structural effect, charge-transfer complexes and dipole-dipole interaction between unlike molecules. These deviations have been correlated by a polynomial Redlich-Kister equation. The excess properties are found to be eighter negative or positive depending on the molecular interactions and nature of the liquid mixtures. Excess properties provide important information in understanding the solute-solvent interaction in a solution. The excess molar volume (V<sub>m</sub><SUP>E</SUP>), excess viscosity (η<SUP>E</SUP>), acoustic impedance (Z<SUP>E</SUP>) and excess adiabatic compressibility (β<sub>ad</sub><SUP>E</SUP>), values have been interpreted to terms of the nature of intermolecular interactions between constituent molecules of mixtures.
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