Island Arc Setting Research Articles

Geochemical characteristics of olivine and clinopyroxene in parental mafic–ultramafic rocks from the Yuanshishan Ni-Co laterite deposit in Qinghai Province, NW China

Yuanshishan is a Ni-Co laterite deposit that occurs in the Lajishan tectonic zone of the South Qilian orogenic belt, NW China. Ni–Co mineralization took place during the weathering of the parental mafic–ultramafic rocks. Little is known about the petrogenesis of these parent rocks. Therefore, field and petrographic investigations, together with in situ major and trace element analyses, were carried out on olivine and clinopyroxene from unweathered mafic–ultramafic rocks in the Yuanshishan Ni-Co deposit. The results show that olivine (Ni 963–2674 ppm, Co 52.7–245 ppm) is richer in Co and Ni than clinopyroxene (Ni 155–203 ppm, Co 23.1–32.5 ppm) in the Yuanshishan mafic–ultramafic rocks. The chromite (Ni 98.8–892 ppm, Co 836–1062 ppm) show higher Co and Ni than clinopyroxene, but has lower Ni but higher Co than olivine. Therefore, olivine and chromite are two main Co and Ni rich minerals in the parent rocks of Yuanshishan. A compositional comparison of olivine and clinopyroxene from the Yuanshishan deposit to those from other magmatic sulfide deposits reveals that the Yuanshishan parent magma is relatively poor in Ni and rich in Co. Olivine in the dunite of Yuanshishan has a quite high Fo value (95.2–98.3). The Yuanshishan olivine grains also show a positive correlation between Ni content and Ni/Co or Co content, and the correlation with Fo value is not obvious. The Co content shows a negative correlation with the Ni content and Fo value, which are consistent with the mantle olivine characteristics. Furthermore, the Li, Sc, V contents in olivine are lower than 10 ppm, indicating that the magma originated from the mantle. The Al, Si, Ti, Ca, and Na contents in clinopyroxene indicate that the original magma may have been subalkaline basaltic melt. Using an olivine-spinel thermometer, the Yuanshishan magma crystallization temperatures are calculated to be 1256–1376 °C. The AlⅣ:AlⅥ ratio (0.7–6.0) and Eu/Eu* value (0.9–1.4) of the clinopyroxene indicate that the Yuanshishan mafic–ultramafic rocks were formed under conditions of low to medium pressure and high oxygen fugacity. Moreover, the geochemical discriminant diagrams of clinopyroxene indicate that these rocks possibly formed in an island arc setting.

Pressure–temperature evolution, protolith characteristics and tectonic setting of granulite facies rocks from Laojinchang area in the Longgang Block, China

The Archean supracrustal rock series in the Laojinchang area of Jilin Province, China provide valuable insights into the Precambrian geological evolution of the North China Craton. This study presents new results on petrography, geochemistry, mineralogy, isotope geochronology and phase equilibrium modeling of the Laojinchang granulite facies metamorphic rocks. The protolith ages of garnet two-pyroxene granulite and amphibolite from Sidaolazihe Formation, and two-pyroxene granulite from Laoniugou Formation are 2565 ± 5.9 Ma, 2512 ± 17 Ma, and 2509.2 ± 8.6 Ma, respectively, with the metamorphic age recorded by amphibolite being 2475.6 ± 9 Ma. New geochemical data indicates that TTGs (tonalite-trondhjemite-granodiorite) weathering in an island arc environment formed the protolith of argillaceous gneiss of Sidaolazihe Formation. Basaltic andesite, formed under an island arc environment, was the protolith of garnet two-pyroxene granulite of Sidaolazihe Formation; while calc-alkaline basalt was the protolith of amphibolite from the same formation and two-pyroxene granulite from Laoniugou Formation. All these Archean supracrustal rocks exposed in the Laojinchang area have recorded nearly isobaric cooling (IBC) anticlockwise P-T paths with distinct prograde, peak and post-peak stages. The peak P-T conditions reached granulite facies, suggesting a heat source from underplated magmas. A tectonic model involving an island-arc setting is proposed for the evolution of these Neoarchean supracrustal rocks in Laojinchang area.

Two distinct early Paleozoic subduction zones in the eastern Central Asian Orogenic Belt: Evidence of subduction recycling and arc evolution

This paper presents zircon U–Pb dating and Hf isotopic, and whole-rock geochemical and Sr–Nd isotopic data for early Paleozoic igneous rocks as well as zircon U–Pb dating for the sedimentary rocks of the Songnen Massif within the eastern Central Asian Orogenic Belt (CAOB), aiming to reveal arc magma evolution process. The zircon U–Pb dating results of the siltstone of the Xiaojingou Formation yielded 450 Ma, 471 Ma, 502 Ma, 773 Ma, 818 Ma and 949 Ma age peaks, as well as multi-episodic Paleo-proterozoic ages (2486-1612 Ma), implying its deposition time is younger than ∼ 450 Ma. The zircon U–Pb dating results reveal that the Songnen Massif exists three episodes of volcanic rocks of the middle Cambrian (502 Ma), Middle Ordovician (453-449 Ma) and the Silurian (435-420 Ma). The middle Cambrian basalts are low-K tholeiitic to calc-alkaline series, weakly depleted εHf(t) and εNd(t) values. They were derived from the weakly depleted mantle metasomatized by slab fluid in an immature island arc setting. The Middle Ordovician to Silurian volcanic rocks show SiO2 of 49.4–58.1 wt%, plotting into high-K calc-alkaline series, which are also featured by higher Th/Nd and (Hf/Sm)PM ratios, together with moderate depleted εNd(t) values, suggesting their derivation of the depleted mantle wedge metasomatized by sediment-derived melt. In contrast, coeval early Paleozoic volcanic rocks in the eastern Xing’an Massif with the MORB-like εNd(t) values are characterized by an origin of the depleted mantle wedge and the distinct interaction of oceanic crust melt and mantle peridotite. Combined with the variation of calculated crust thickness, we suggested that there was a continental arc in the eastern Songnen Massif, which developed from immaturity to maturity during middle Cambrian to Silurian, while the early Paleozoic island arc in the eastern Xing’an Massif is characterized by ocean ridge subduction process.

River-fed basin-fill and hyperpycnites in an island-arc setting: The Silurian–Devonian Kekexiongkuduke Formation from Western Junggar, China

Sediments from land are primarily transported into basins through hyperpycnal flow, which plays a significant role in the process of basin filling. Various models of hyperpycnites have been proposed. This study examines a Silurian–Devonian basin-fill sequence in NW China to validate existing models and presents a visually compelling case demonstrating the process of basin filling through flood-dominated river discharge.The Utubulak Member of the Kekexiongkuduke Formation can be subdivided into three parts, representing basin floor, slope and shelf environments, collectively representing a regressive basin fill sequence. The lower part consists of flood-related turbidites contain or encompass material of terrestrial and marine origin, their sustained and pulsed velocity structures are similar to river discharge. These turbidites may result from basinal hyperpycnal flow or retrogressive failures of the shelf-edge (hyperpycnal) delta. The middle (slope deposits) contains bi-graded hyperpycnite bed interpreted commonly attributed to deposition by river floods exhibiting the classical waxing-waning configuration. Additionally, fine-grained deposits resulting from river-generated, dilute hyperpycnal or hypopycnal plumes are observed interbedded with the basin turbidites or slope background deposits. In the upper part, the presence of thick-bedded sandstones indicates that sustained hyperpycnal flow can transport sands to the shelf-edge/shelf, facilitating deep-water sand delivery. The vertical distribution of the various flood-related facies in basin floor, slope and shelf strata emphasize the complexity of hyperpycnites in different settings, and particularly highlighting challenges associated with their recognition in basin deposits.The investigated succession accumulated in an island-arc setting which provided a favorable condition for a river-fed turbidite system to develop. The narrow shelf facilitated transport of sediments by hyperpycnal flows directly into the basin, while erosion of high mountains promoted a high sediment supply for hyperpycnal flow. And a river-fed turbidite system commonly developed during the late stages of basin filling.

Insights into the indium enrichment of the Ashele VMS Cu-Zn deposit, Altay, NW China

Indium (In) is a critical metal used in the photovoltaic and semiconductor industries, which have exhibited extraordinary growth in demand. Indium is produced as a by-product of mining from different ore deposits (e.g., epithermal, sediment-hosted, and skarn). Volcanogenic massive sulfide (VMS) deposits are an important source of In; however, the mechanism of In enrichment is not fully understood. Here, we combine mineralogy with in situ trace element and S-Pb isotope geochemistry to reveal the enrichment of indium in the Ashele VMS Cu-Zn deposit (1.08 Mt. Cu, 0.43 Mt. Zn) located in Altay, NW China. The Ashele deposit is hosted in the metamorphosed Devonian felsic-bimodal volcanic rocks. This deposit consists of seafloor hydrothermal, metamorphic hydrothermal, and supergene stages. The seafloor hydrothermal stage comprises macro-scale Cu-rich bands (chalcopyrite, pyrite, and minor sphalerite) and Zn-rich bands (sphalerite, pyrite, and minor chalcopyrite). Indium is mainly hosted by chalcopyrite (mean 178 ppm) and sphalerite (mean 214 ppm) and occurs in the lattice. Mineral assemblages and trace element geochemistry suggest that the Cu-rich bands were deposited under high temperatures (> 300–350 °C) and sulfur fugacity (−7.2 to −4.9), whereas the Zn-rich bands were formed under lower temperatures (180–220 °C) and sulfur fugacity (−15.7 to −11.5). The interlayered Cu-rich and Zn-rich bands may reflect the oscillating temperature and sulfur fugacity variations. In situ S isotopic compositions of sulfides cluster within two ranges: 1–3 ‰ and 3–6 ‰, suggesting two endmembers: volcanic origin and reduced seawater sulfate. Pb isotopic ratios are similar to those of the host volcanic rocks, indicating that the metals may be derived from the felsic volcanic system. During metamorphism, the indium may be retained, but Cu contents of sphalerite become more homogeneous. Most In-rich VMS deposits worldwide are hosted by the felsic-dominant system in island arc and back-arc settings. These tectonic settings are conducive to the production of felsic volcanic systems, which are more likely to contain In mineralization. This study highlights the enrichment mechanism of indium in VMS deposits and suggests that the South Altay could become an important source of In.

Mineralogy and Geochemistry of Jasperoid Veins in Neoproterozoic Metavolcanics: Evidence of Silicification, Pyritization and Hematization

The Wadi Ranga sulfidic jasperoids in the Southern Eastern Desert (SED) of Egypt are hosted within the Neoproterozoic Shadli metavolcanics as an important juvenile crustal section of the Arabian Nubian Shield (ANS). This study deals with remote sensing and geochemical data to understand the mechanism and source of pyritization, silicification, and hematization in the host metavolcanics and to shed light on the genesis of their jasperoids. The host rocks are mainly dacitic to rhyolitic metatuffs, which are proximal to volcanic vents. They show peraluminous calc-alkaline affinity. These felsic metatuffs also exhibit a nearly flat REE pattern with slight LREE enrichment (La/Yb = 1.19–1.25) that has a nearly negative Eu anomaly (Eu/Eu* = 0.708–0.776), while their spider patterns display enrichment in Ba, K, and Pb and depletion in Nb, Ta, P, and Ti, reflecting the role of slab-derived fluid metasomatism during their formation in the island arc setting. The ratios of La/Yb (1.19–1.25) and La/Gd (1.0–1.17) of the studied felsic metatuffs are similar to those of the primitive mantle, suggesting their generation from fractionated melts that were derived from a depleted mantle source. Their Nb and Ti negative anomalies, along with the positive anomalies at Pb, K, Rb, and Ba, are attributed to the influence of fluids/melt derived from the subducted slab. The Wadi Ranga jasperoids are mainly composed of SiO2 (89.73–90.35 wt.%) and show wide ranges of Fe2O3t (2.73–6.63 wt.%) attributed to the significant amount of pyrite (up to 10 vol.%), hematite, goethite, and magnetite. They are also rich in some base metals (Cu + Pb + Zn = 58.32–240.68 ppm), leading to sulfidic jasperoids. Pyrite crystals with a minor concentration of Ag (up to 0.32 wt.%) are partially to completely converted to secondary hematite and goethite, giving the red ochre and forming hematization. Euhedral cubic pyrite is of magmatic origin and was formed in the early stages and accumulated in jasperoid by epigenetic Si-rich magmatic-derived hydrothermal fluids; pyritization is considered a magmatic–hydrothermal stage, followed by silicification and then hematization as post-magmatic stages. The euhedral apatite crystals in jasperoid are used to estimate the saturation temperature of their crystallization from the melt at about 850 °C. The chondrite (C1)-normalized REE pattern of the jasperoids shows slightly U–shaped patterns with a slightly negative Eu anomaly (Eu/Eu* = 0.43–0.98) due to slab-derived fluid metasomatism during their origin; these jasperoids are also rich in LILEs (e.g., K, Pb, and Sr) and depleted in HFSEs (e.g., Nb and Ta), reflecting their hydrothermal origin in the island arc tectonic setting. The source of silica in the studied jasperoids is likely derived from the felsic dyke and a nearby volcanic vent, where the resultant Si-rich fluids may circulate along the NW–SE, NE–SW, and E–W major faults and shear zones in the surrounding metavolcanics to leach Fe, S, and Si to form hydrothermal jasperoid lenses and veins.

Disputed tectonic setting for the late Silurian–early Carboniferous development of the northern New England Orogen: detrital zircon ages suggest a continental margin arc association

Devonian successions in the Calliope and Yarrol provinces of the northern New England Orogen in central to northern Queensland have a lithological assemblage and depositional environments indicative of a close association with a subduction-related volcanic arc. These rocks have been interpreted as related to island arc and backarc settings based on geochemical characteristics of magmatic rocks. We present new detrital zircon ages from the Devonian to lower Carboniferous successions of the Calliope and Yarrol province successions. Most samples have no or relatively few zircon grains extracted except for samples of quartz-rich sandstone in the Middle Devonian Erebus beds of Hunter Island, located 160 km north-northwest of Rockhampton and another sample in the Rockhampton district. The samples with abundant zircon, and some with less common zircon, have prominent peaks of mid Cambrian to Ordovician ages and are consistent with derivation from the northern Thomson Orogen where igneous rocks of this age are documented in the Charters Towers Province. These data indicate a connection between the Devonian arc-flank deposits of the northern New England Orogen and the Thomson Orogen, which had previously been well established for Carboniferous deep-marine sandstones of the subduction complex (e.g. Shoalwater Formation). These results favour an east-facing continental margin arc setting in the Devonian contra to intra-oceanic island arc settings previously proposed. Detrital zircon age spectra from sampled early Carboniferous units of northern New England Orogen association indicate a pulse of felsic magmatism of that age.

Proterozoic mafic dyke swarms of Bundelkhand Craton, North India: A connection to Columbia supercontinent

The present paper addresses petrography, geochemistry and Ar‐Ar geochronology of a significant number of mafic dykes from the Paleo‐ to Neoarchean Bundelkhand Craton in central India. The majority of the dykes are NW‐SE oriented (with a few NE‐SW and ENE‐WSW) with tholeiitic, sub‐alkaline and basalt to basaltic andesite composition. The trace element geochemistry of these dykes indicates an island arc setting during emplacement. The Ar‐Ar mineral dating (plagioclase) of three representative dykes reveals an emplacement age between 1.53 and 1.46 Ga. This finding and earlier reports (2.1–1.73 Ga) point to sustained mafic magmatism throughout the Bundelkhand Craton in a preferred structural orientation between 2.1 and 1.46 Ga. Mafic magmatism was episodic and can be linked to the perpetual subduction accretion processes between the central Indian Archean continents during the development of the Columbia supercontinent. The mafic dykes were emplaced at 45° to the maximum compression direction (E‐W), that is, along the line of no finite longitudinal strain. This time equivalent widespread NW‐SE and NE‐SW trending mafic dyke system is also relatable along the adjacent continents (Singhbhum, Bastar) and thus opened up a new paradigm for the dyke's emplacement across the Indian cratons.

Eocene to Miocene sediment provenance features and evolution history of the western slope area in the Xihu Sag of the East China Sea Continental Shelf Basin

Rift basins are commonly characterised by multiple sediment sources (e.g. transverse and longitudinal) that change over time during different rifting evolution stages. Therefore, tracing sediment provenance to decipher the sedimentary source-to-sink analyses processes in rift basins is important to predict sandy reservoirs. The Xihu Sag in the East China Sea Shelf Basin, particularly its western slope, features large-scale sand bodies of unclear origin. We used petrography, heavy minerals and geochemistry to study sediment provenance in the Eocene Baoshi to Miocene Longjing formations. Our work suggests there are three distinct areas (namely zones A, B and C) affected by different source areas. Zone A, influenced by the Hupijiao uplift, primarily contains metamorphic rock minerals; Zone B, affected by the Haijiao and Hupijiao uplifts, contains igneous and metamorphic rock minerals; and Zone C, dominated by the Haijiao uplift, features igneous with some metamorphic sources, which increase over time, indicating stronger sediment input from the northern Hupijiao uplift. Rare earth element analysis suggests a continental margin and island arc setting, primarily with intermediate–acid felsic rock sources. However, a Eu negative anomaly in Eocene upper Pinghu Formation to the Miocene Longjing Formation indicates some basic source contributions, possibly from a volcanic belt east of the South Yellow Sea. This intermediate–basic volcanic rock belt is located to the northwest of the Hupijiao uplift and may provide clasts for zones A and B through axial channels. These findings indicate that varied sediment sources in the different zones and basin evolution stages with a growing extra-basinal contribution from the Eocene to Miocene, which align with the tectonic shift from the rifting to post-rift period, are essential for understanding the sedimentary filling in this area.

Tectono-metamorphic evolution of the Central Bundelkhand Craton, India from geochemistry and bulk composition modelling of amphibolite enclaves

The Bundelkhand Craton (BuC) represents a significant Archean terrane within the northern Indian Craton and yet its tectono-metamorphic evolutionary history remains relatively understudied. Our investigation involves detailed petrography, geochemistry, and bulk composition modeling of both garnet-bearing and garnet-absent amphibolites with a two-fold objective: (i) to constrain the protolithic nature and tectonic settings involved in the genesis of these rocks, and (ii) to propose a tectono-metamorphic evolutionary history for the BuC. The BuC amphibolites originate from basalt and andesitic-basalt protoliths. Their trace element compositions reveal negative anomalies in Nb, Ta, and Ti, while their rare earth element (REE) normalized patterns indicate enrichment in light REEs over heavy REEs. The basaltic protolith is interpreted to have formed during orogeny in a compressional tectonic regime at the active margins of island arcs in a subduction-related setting. This interpretation is supported by various discrimination plots for amphibolites, such as Nb/Th vs Zr/Nb, Zr vs Zr/Y, and Th/Nb vs Ce/Nb, as well as high Th/Yb and low Nb/Yb contents— all of which suggest an island arc setting influenced by subduction. These amphibolites have undergone three distinct phases of metamorphism, as evidenced by petrography, mineral chemistry, and bulk composition modeling. This interpretation is further supported by geochemical discrimination diagrams which indicate that a subduction tectonic setting was active during peak metamorphism. During the pre-peak phase, the garnet-bearing amphibolites experienced pressure and temperature conditions ranging from 6.25 to 6.5 kbar and 580 to 590ºC, while the garnet-absent amphibolites underwent conditions from 5.0 to 5.8 kbar and 400 to 450ºC. Peak metamorphism was observed at pressures ranging from 6.8 to 7.4 kbar and temperatures from 760 to 805ºC for the garnet-bearing amphibolites, and at pressures from 7.0 to 7.4 kbar and temperatures from 785 to 810ºC for the garnet-absent amphibolites. The metamorphic retrograde conditions for the garnet-bearing amphibolites are defined by P-T conditions ranging from 4.45 to 4.75 kbar and 585 to 615ºC, while for the garnet-absent amphibolites, it ranges from 3.1 to 4.0 kbar and 620 to 710ºC. The mineral assemblages and P-T conditions delineate a clockwise P-T path for both, garnet-bearing and garnet-absent amphibolites from the Babina and Mauranipur regions. This suggests that the rocks underwent a burial process amid subduction tectonic settings in an arc-related environment, followed by a decompression stage that brought them to the surface.

Formation of deep arc root cumulates and implications for crustal growth in the southern Central Asian Orogenic Belt

Formation of ultramafic cumulate rocks at the arc root serves as a key process to understanding the deep evolution of arc magma and crustal growth. However, the arc root cumulates are easy to delaminate due to their high density, making limited field exposure. Here, we conducted comprehensive petrographic observations and geochemical analysis of typical ultramafic rocks (peridotites and pyroxenites) in an ophiolitic mélange from the central Beishan orogenic belt in the southern Central Asian Orogenic Belt (CAOB). Petrographic evidence shows that these rocks exhibit characteristic adcumulate and mesocumulate textures with intercumulus minerals such as olivine, orthopyroxene, and clinopyroxene. The mineral characteristics of ultramafic rocks, including olivine and orthopyroxene with lower NiO (0.10–0.33 wt% and 0.03–0.09 wt%, respectively) and Mg# (81–87 and 86–88, respectively), clinopyroxene with higher CaO (19.0–24.7 wt%), and spinel with lower Mg# (0–49), are distinct from those of mantle rocks but resemble cumulates. Both whole rock and calculated equilibrium melt exhibit the compositions of island arc magma characterized by enrichment in large ion lithophile elements (e.g., Cs, U, Pb, and Sr) and depletion in high field strength elements (e.g., Nb, Ta, Zr, Hf, and Ti). The covariation of high Mg# and low SiO2 in whole rocks is akin to typical arc root cumulates from classic island arcs (e.g., Kohistan and Talkeetna). The positive zircon εHf(t) values (+13 to +16) and calculated crystallization pressure of 0.9–1.1 GPa (∼30–40 km) support the formation of ultramafic cumulates in a juvenile island arc setting. These findings imply that most ultramafic rocks in the central Beishan orogenic belt are arc root cumulates instead of the mantle portion of an ophiolitic mélange. Fractional crystallization models suggest that arc root cumulate formation may have influenced the evolution of intermediate-felsic rocks in this area, and that the differentiation of hydrous arc magma played a crucial role in large-scale crustal growth in the southern CAOB during the early Paleozoic.

The mafic–ultramafic roots of a Mesoarchean microblock in southern India: Insights from petrochemistry and isotope geochronology of the Coorg Block

The Coorg Block in southern India is an archive of Paleo-Mesoarchean arc magmatism and continental building in the early Earth. Here we investigate a suite of mafic and ultramafic rocks and associated lithologies to characterize the roots of this microcontinent. We present petrologic, geochemical, as well as U-Pb and Lu-Hf data on zircon and U-Pb data on monazite from these rocks which provide insights into the petrogenesis of the rocks as well as the timings of magmatism and subsequent metamorphism. The geochemical features of the mafic granulites indicate that the rock suite was derived from the fractionation of a sub-alkaline tholeiite magma. Most of the rocks correspond to arc setting in a subduction-related tectonic regime. The rocks exhibit relative enrichment in LILE, Pb, and LREE with depletion in HFSE such as Nb and Ta suggesting partial melting of a metasomatized mantle wedge. Their high LILE/HFSE and LREE/HFSE ratios indicate slab dehydration and mantle wedge melting in typical island arc settings. The overall trace element and REE patterns of the rocks indicate that the source magma of the ultramafic and mafic rocks might have been derived from a refractory mantle source followed by the metasomatic enrichment of lithospheric mantle wedge by incompatible elements through the influx of subduction-derived fluids/melts. We present comprehensive zircon U-Pb data and Lu-Hf data on a suite of mafic granulite, garnet-bearing granulite, tremolite actinolite schist, charnockite, and anorthositic gabbro as well as monazite U-Pb data from a charnockite sample. Most zircon grains show cores with magmatic crystallization features and many grains are mantled by metamorphic rims. The age data show a prominent peak at 3.1 Ga for most of the rocks suggesting that the major crustal building in the Coorg Block occurred during the Mesoarchean. Rocks on the margins of the block were affected by the younger (Neoarchean) tectonothermal event in the surrounding blocks. The Lu-Hf isotopic data on zircon grains with ca. 3.1 Ga ages show εHf(t) values ranging from −4.4 to + 3.7 (average + 0.3). In the εHf(t) versus 207Pb/206Pb age diagram, the plots are distributed close to the CHUR line suggesting Paleo-Eoarchean juvenile magma sources. The voluminous mafic lower crust at the root of the Coorg Block is consistent with addition of mafic magmas through slab melting induced by high mantle potential temperatures in the Archean, as well as the interaction of fluids/melts with the mantle wedge.

Geochemical indicators to constrain weathering, provenance and tectonic setting of the Pisha Sandstone (Early–Middle Triassic) in Northeast Ordos Basin, China

The Pisha Sandstone is widely exposed in the northeastern margin of the Ordos basin. Since the Mesozoic the basin was subjected to uneven uplift several times, strong weathering and erosion have been occurring and a large amount of sediments derived from these erosional strata are input into the lower Yellow River, posing a fragile ecological environment along the river. However, the geochemical characteristics of the Pisha Sandstone have remained poorly understood. In this study, we focus on the Pisha Sandstone from Early–Middle Triassic Liujiagou, Heshanggou and Ermaying Formation, present a very first petrographic and geochemical data together with detailed field geological characteristics, aiming to place geochemical indicators on weathering, provenance and tectonic setting of the Pisha Sandstone. The results show that sandstones in Pisha Sandstone are classified as arkose, litharenite and wacke. The geochemical proxies including Chemical Index of Alteration (CIA = 67.2), Chemical Index of Weathering (CIW = 80.1), Plagioclase Index of Alteration (PIA = 75.6) and Index of Compositional Variability (ICV = 1.6) indicate Pisha Sandstone experienced first–cycle deposit and moderate to strong chemical weathering. Trace element and rare earth element concentrations together with their ratios (La/Sc, La/Co, Th/Sc, Th/Co, Cr/Th) reveal a felsic provenance, and source rock compositions are predominantly granodiorite and granite from the north margin of the Inner Mongolia Paleo–Uplift (IMPU), with a small amount of mafic or intermediate components. The geochemical signatures and tectonic discrimination diagrams display a collision setting for the Pisha Sandstone and further reveal the sediments had been deposited in a continental island arc setting. The results of this work may provide new theoretical basis for environmental protection in the Pisha Sandstone area.

Hadgarh Greenstone Belt: An extension of Tomka Daitari Greenstone Belt, Singhbhum Craton, India

Peripheral volcano sedimentary belts around the nucleus of Singhbhum-Granite-Complex are a part of one of the oldest continental crusts, known as the Singhbhum Craton (SC). Deciphering mutual relationship among these volcano-sedimentary packages offers considerable challenges. Badampahar-Gorumahisani Belt (BG Belt), Tomka Daitari Belt (TD Belt) and Bonai-Kendujhar Belt (BK Belt) draping Singhbhum-Granite-Complex as long linear belts from east, south and west, have some certain difference, primarily in terms of lithology. While the sedimentaries of BG Belt is mainly chemogenic, BK Belt is dominated by terrestrial sediments and TD Belt contains the both. Available data suggests the younger age of BK Belt than the rest couple of belts. Between TD Belt and BG Belt, another volcano sedimentary belt, commonly known as Hadgarh Belt, is present and it is less studied. The present study aims to characterize the Hadgarh Belt based on lithology and structure, which indicates its similarity with TD Belt. Almost identical lithologies are manifested by these two volcano sedimentary sequences barring the fact that the Hadgarh Belt has minor dominance of metasediments over metavolcanics, which is in subequal proportion in Tomka-Daitari and sensustricto BIF bands are absent in Hadgarh Belt. Both the belts have undergone uniform polyphase deformation and metamorphism. In both the belts, volcano sedimentary sequence of IOG is overlain by less deformed younger Mahagiri Quartzites and they are separated by an angular unconformity, marked by an impersistent conglomerate horizon. The intermediate area also sustains the similarities in depositional and deformational history with respect to the TD and Hadgarh belts on either side. Petrological studies also invoke similar mineral assemblage in the two belts, which is also in corroboration with the petrochemistry of the litho-units concerned. All the data thus generated, shows that the area, in totality, was evolved in an island arc setting varying from deep to shallow marine environments and sequence of deformations, intrusion of ultramafics followed by granite are also similar. In a nut shell, Hadgarh Belt can be referred as an extended part of the TD Belt.

Provenance of Conglomerate and Sandstone from Early Permian Shoushangou Formation in Xi Ujimqin, Inner Mongolia: Implications for Understanding Paleo‐Asian Ocean Subduction

AbstractDuring the Late Carboniferous to Early Permian, a rift was formed by post‐collisional extension after ocean closure or an island arc‐related basin formed by Paleo‐Asian Ocean (PAO) subduction in the Xi Ujimqin area. Nevertheless, the closure time of the PAO is still under debate. Thus, to identify the origin of the PAO, the geochemistry and U‐Pb age of zircons were analyzed for the extra‐large deep marine, polymict clastic boulders and sandstones in the Shoushangou Formation within the basin. The analyses revealed magmatic activity and tectonic evolution. The conglomerates include megaclasts of granite (298.8 ± 9.1 Ma) and granodiorite porphyry (297.1 ± 3.1 Ma), which were deposited by muddy debris flow. Results of this study demonstrated that the boulders of granitoids have the geochemistry of typical I‐type granite, characterized by low Zr + Nb + Ce + Y and low Ga/Al values. The granitoid boulders were formed in island arc setting, indicating the presence of arc magmatism in the area that is composed of the Late Carboniferous to Early Permian subduction‐related granitoid in southern Xi Ujimqin. Multiple diagrams for determining sedimentary provenance using major and trace elements indicate that Shoushangou sediments originated from continental island arc‐related felsic rocks. Detrital zircon U‐Pb age cluster of 330‐280 Ma was obtained, indicating input from granite, ophiolite, Xilin Gol complex, and Carboniferous sources to the south. The basin was geographically developed behind the arc during the Early Permian period because the outcropped intrusive rocks in the Late Carboniferous to Early Permian form a volcanic arc. The comprehensive analyses of source areas suggest that Shoushangou sediments developed in a backarc basin in response to the northward subduction of the PAO. The backarc basin and intrusive rocks, in addition to previously published Late Carboniferous to Early Permian magmatic rocks of arc unit in Xilin Gol, confirm the presence of an Early Permian trench‐arc‐basin system in the region, represented by the Baolidao arc and Xi Ujimqin backarc basin. This study highlights the importance and potential of combined geochemical and geochronological studies of conglomerates and sandstone for reconstructing the geodynamic setting of a basin.

Case study on Hangenberg Crisis equivalent deposits and associated conodont faunas including Siphonodella progenitors from late Devonian island arc settings (Indert Formation, Shine Jinst region, southern Mongolia)

Case study on Hangenberg Crisis equivalent deposits and associated conodont faunas including Siphonodella progenitors from late Devonian island arc settings (Indert Formation, Shine Jinst region, southern Mongolia)

Climato-tectonic evolution of siliciclastic sandstones on Puerto Rico: from lithic arenites to quartz-arenitic sands in an oceanic island-arc setting

Abstract Siliciclastic sandstone composition on the island of Puerto Rico, part of the Greater Antilles, was influenced by both tectonic setting and climate. Cretaceous through Eocene volcanic and plutonic rocks on Puerto Rico formed in an oceanic-arc setting. Sandstones deposited during arc volcanism are quartz-poor lithic and feldspatholithic arenites, whose geochemistry largely matches that of the oceanic-arc volcanic and plutonic rocks on Puerto Rico. After cessation of volcanism on Puerto Rico during collision of the Greater Antilles island arc with the Bahamas Bank, an Oligocene through Holocene overlap assemblage was deposited unconformably above the arc deposits in the North Coast and South Coast basins of Puerto Rico. The overlap assemblage consists of some siliciclastic material, but largely shallow-water carbonate deposits. Siliciclastic deposition in the overlap assemblage reflects the volcanic-arc source, plus quartz derived from plutons exposed during uplift. In the Pleistocene and Holocene (and possibly earlier), poorly consolidated quartz-arenitic sands with SiO2 values from 92 to 98% were deposited in the overlap assemblage. On geochemical tectonic-affinity diagrams, the lithic sandstones plot, as expected, in or near the fields for oceanic-arc provenance. However, the quartz-arenitic sands plot incorrectly in the passive-margin field when considering major elements, and correctly in or near the oceanic-arc field when considering trace elements. Trace elements in the quartz-arenitic sands are largely found in refractory minerals, whereas major elements in feldspars and lithic fragments are effectively removed by intense tropical weathering. Hence, future use of tectonic-affinity diagrams should rely on trace-element geochemistry. Sandstones derived from the Sierra Nevada continental arc in California have QFL quartz fractions below 60%, even though the source magmatic arc has significant modal quartz. This observation suggests a “climate cap,” which does not “allow” formation of more quartzose sediments. In contrast, tropical weathering on Puerto Rico removes this climate cap allowing the creation of quartz-arenitic sands from a source rock containing limited quartz. It is remarkable that quartz-arenitic sands occur on Puerto Rico, sourced from a provenance area containing extremely limited quantities of modal quartz (estimated at less than 5%) in an oceanic-arc environment bounded by two active subduction zones. Quartz-arenitic sands and sandstones are not uniquely continental or of cratonal origin; chemical weathering is fundamentally important for the origin of first-cycle quartz-arenitic sands.

The First Detrital Zircon Data on the Northwestern Precambrian Yenisei Ridge: Identification of the Continental–Arc Kiselikha Terrane

Northwestern segment of the Precambrian Yenisei Ridge contains ophiolite and is known in the literature as the Isakovka terrane or Isakovka domain. We suggest dividing it into two belts: the Kiselikha one (western) and Torzhikha (eastern), which differed in geodynamic regime during the late Neoproterozoic (~750–600 Ma). It is believed that the Kiselikha belt is composed mostly of volcanic rocks erupted at island arc setting in the second half of the Neoproterozoic, and that collision of this arc with Siberian continent formed the Yenisei Ridge orogen. This idea has not been sufficiently confirmed by geological and geochronological data. Dating of four detrital zircon samples extracted from sedimentary and volcanic-sedimentary rocks in the southern part of the belt revealed that the sampled strata belong to three different Precambrian levels: the Mesoproterozoic, the mid Neoproterozoic (800–750 Ma), and the end of the Neoproterozoic (620–600 Ma). Thus the authorized stratigraphic layout of the belt as well as its proposed island-arc origin require revision. By this paper we announce the identification of the Kiselikha terrane, which was a part of active margin of the Siberia paleocontinent at the beginning of the Neoproterozoic. Approximately in the middle of the Neoproterozoic, this block was rifted off Siberia and further evolved as a microcontinent bounded by an active margin from the outer side.

Genesis and Evolution of the Yolindi Cu-Fe Skarn Deposit in the Biga Peninsula (NW Turkey): Insights from Genetic Relationships with Calc-Alkaline Magmatic Activity

The current work investigates the impact of magmatic fluids and metasomatic processes on the Yolindi Cu-Fe skarn deposit in the Biga Peninsula, Turkey. It traces the stages of skarn evolution, from prograde to retrograde alterations, and investigates findings within a broader geological, mineralogical, and geochemical framework. Additionally, it assesses the evolutionary history of the Yolindi deposit in relation to calc-alkaline magmatic activity in an island-arc environment and compares its mineral compositions and genesis with other global and regional Cu-Fe skarn deposits. The Yolindi Cu-Fe skarn deposit in the Biga Peninsula was formed by the intrusion of Şaroluk quartz monzonite pluton into Upper Paleozoic Torasan Formation rocks such as phyllite, schists, hornfels, marble, and serpentinites. During skarnification, reactions between the magmatic fluids from the Şaroluk quartz monzonite pluton and the Torasan Formation produced skarn minerals associated with metals such as Fe and Cu. Initially, these reactions formed prograde skarn minerals such as augite-rich pyroxenes and andradite garnets with magnetite and pyrite. As the system cooled, these initial minerals underwent retrograde alteration, leading to the formation of minerals such as epidote, actinolite, and chlorite, as well as other copper and iron minerals including chalcopyrite, bornite, secondary magnetite, and specular hematite. Therefore, four main stages influenced the formation of the Yolindi Cu-Fe deposit: metamorphic bimetasomatic, prograde metasomatic, and retrograde metasomatic stages. Later, oxidation and weathering resulted in supergene minerals such as cerussite, malachite, and goethite, which serve as examples of the post-metamorphic stage. The mineralogical shifts, such as the andradite–grossular transition, reflect changing hydrothermal fluid compositions and characteristics due to the addition of meteoric fluids. Importantly, the formation of magnetite after garnet and clinopyroxene during the retrograde stage is evidenced by magnetite crystals within garnet. The mineral associations of the Yolindi Cu-Fe skarn deposit align with the global skarn deposits and specific Turkish skarns (e.g., Ayazmant Fe-Cu and Evciler Cu-Au skarn deposits). The Yolindi Cu-Fe skarn deposit, in association with ore-bearing solutions having magmatic origins, developed in an island-arc setting.

The isotope geochemistry of host rocks of the late Archean Guandi and Banshigou banded iron formations, southern Jilin Province: temporal and tectonic significance

The Guandi and Banshigou iron deposits of southern Jilin Province, China, are Algoma-type banded iron formations (BIFs) located in the Eastern Block of the North China Craton (NCC). LA–ICP–MS U–Pb dating shows the magmatic zircons in plagioclase amphibolite from the Guandi BIF (PA–GD) and plagioclase hornblende gneiss from the Banshigou BIF (PHG–BSG) were crystallised at 2556 ± 17 Ma and 2545 ± 27 Ma, respectively, representing the formation age of the BIFs. Metamorphic overgrowth zircons from both samples gave two U–Pb ages of 2452 ± 23 Ma and 2446 ± 70 Ma, indicating the age of metamorphism. The zircon εHf(t) values of PA–GD (–1.3 to +2.8) and PHG–BSG (–1.5 to +2.7) indicate that the magma source was derived from depleted mantle with contamination of crustal material. According to our study, the PA–GD and PHG–BSG were formed in an island arc setting and support previously proposed subduction zone tectonic models for the northeastern NCC during the Neoarchean.