IRSL Signal Research Articles

Luminescence dating of the MIS 6 glaciation of the Pamir mountains (Central Asia)

The Pamir Mountains are one of the highest mountain systems in the world; they act as sources of fresh water for the main rivers of Central Asia: the Amudaria and Syrdaria. Throughout the Quaternary, the Pamirs played a major role in controlling atmospheric circulation and land-surface processes, and provided great volumes of terrigenous sediments for transport by large rivers to the depressions in the Aral and Caspian regions. These ultimately provided broad aeolian cover in the sandy deserts, and finer dust for the widely distributed loess-palaeosol sequences. The glaciation history of this highly dynamic region provides an important basis for understanding climate change, sediment source and landscape evolution in Central Asia during the Quaternary. The question of the number, distribution, extent and timing of Pleistocene glaciations in the Pamir is debated. One of the main obstacles to research, together with difficulties of access and severity of current climate, is the varying degree of preservation of traces of previous glaciations in the western and eastern Pamir. As a result of a geological survey, we for the first time identified a thick lacustrine deposit at high altitudes in a tributary of the Panj – the valley of the Sary-Shitharv River – this records the damming of the Panj River valley by a large glacier. Luminescence measurements were undertaken to obtain the age of the Sary-Shitharv glacially-dammed lake. As often in mountain catchments the quartz OSL signal was unsuitable for dose estimation, and so the chronology of the Sary-Shitharv section is based entirely on post-IR IRSL signals from K-rich feldspar. We used pIRIR50,290 and pIRIR200,290 protocols and obtained indistinguishable ages from both protocols. Given the high sedimentation rates deduced from the structure of lacustrine deposits, the entire sequence must have been accumulated rather quickly, over a period of no more than a few thousand years. The average age over the whole series of dates is 165 ± 11 ka. This places the existence of the glacially-dammed lake at Sary-Shitharv in late MIS 6, a result that fits well with the general course of the glacial history of the Pamirs.

Exploring the use of averaged thermal kinetic parameters in luminescence thermochronometry

In luminescence thermochronometry, the thermal stability of feldspar minerals is conventionally constrained from isothermal decay experiments. However, despite recent refinement of the measurement protocol, measurements take several days and are routinely done for each individual sample. Following that most other thermochronometric methods usually use only a single reference set of thermal kinetic parameters, and that recent studies on direct physical probing of feldspar sample properties have shown that trap depth and band-tail width are broadly similar despite large variations in chemical composition, we sought to optimise luminescence thermochronometry measurements by exploring whether a single set of thermal kinetic parameters can describe luminescence thermal decay in feldspar. We explored the effect of using averaged thermal kinetic parameters rather than sample-specific thermal kinetic parameters to model luminescence signal accumulation under different thermal conditions. A set of K- and Na-feldspar minerals extracted from all over the world were analysed after being measured with a multi-elevated temperature protocol, comprising four different IRSL signals at 50, 100, 150, and 225 °C. Comparisons were done between the thermal kinetic parameters of each IRSL signal depending on different variables such as geographic region, transect, lithology, or mineralogy of the analysed feldspar grains. Even though it is not possible to generalise the thermal kinetic parameters between IRSL signals measured at different temperatures, the variance between the thermal kinetic parameters of different samples measured at the same IRSL temperature is consistent with the uncertainties on the individual parameters (i.e., <2–10%), suggesting that averaged, rather than sample-specific values may be appropriate. We then explored the effect of using these averaged parameters to model luminescence signal accumulation under different synthetic and natural thermal conditions. For our dataset, results show minimal impact on the obtained cooling histories and exhumation rates. We therefore propose the use of averaged rather than sample-specific thermal kinetic parameters for rapid investigation of luminescence thermochronometry samples. Based on careful initial characterisation of a few samples to verify the validity of using averaged thermal kinetic parameters, this would reduce measurement times by ca. 50% (i.e., 3–4 days per sample), allowing higher resolution sampling and measurement.

Direct dating of an ancient stone causeway at Karlslunde, Sjælland, Denmark: A combined approach using luminescence from the surfaces of granitic cobbles and coarse grains from disaggregated heated rocks

In 2017 part of an ancient stone causeway was uncovered at Karlslunde on the island of Sjælland, Denmark. With no artefacts found at the site, optically stimulated luminescence dating of coarse grains, grains derived from disaggregated rocks, and surficial rock chips obtained directly from granitic road cobbles were used to determine the time of construction. Some granitic road cobbles were visibly disaggregating at the time of excavation, and laboratory measurements revealed surprising strong fast component dominated quartz sensitivity from these samples. It was concluded that some of the rocks used in the causeway had been heated, presumably prior to incorporation in the structure. Dose recovery plateau experiments using sedimentary quartz and quartz grains recovered by gently disaggregating heated rocks suggested the use of a 220/180 °C preheat/cut-heat combination (DR ratio 0.999 ± 0.018; n = 40); this reduced the risk of thermal transfer in these young samples. IRSL signals were used for rocks that could not be disaggregated. The L/T burial profiles obtained from two unheated rocks (1 granite, 1 felsic gneiss) indicated they had been exposed for sufficient time for us to be confident of obtaining accurate IRSL ages. The post-IR IRSL180 signals were also measured in these two cobbles; the bleaching front was shallow and the signal was only sufficiently reset to allow accurate determination of De on one rock. After subtracting a residual, the dose recovery ratio results for the unheated rocks post-IR IRSL180 and IR50 were 1.006 ± 0.012 (n = 10) and 0.937 ± 0.007 (n = 10), respectively. In total 8 ages were accepted; 4 coarse grained sediment quartz ages from an unexcavated part of the road surface, 2 fading corrected IR50 ages from surface slices from non-disaggregated cobbles, and 2 quartz ages from disaggregated (apparently heated) cobbles. IRSL signals from the sedimentary and heated samples were used primarily to assess the degree of resetting of the quartz blue-stimulated OSL; both the post-IR IRSL and IR50 signals significantly over-estimated the quartz age. However, the sedimentary quartz ages, the heated cobble quartz ages and the fading corrected IR50 ages from the unheated road cobbles, are consistent and likely reflect a construction age of ∼2ka ago.

Combined different luminescence dating approaches on fluvial gravel deposits from the southern upper Rhine graben

In recent years, luminescence dating has witnessed significant advancements to overcome its traditional boundaries. However, methodological challenges persist when dating high-energy fluvial gravel deposits in proglacial settings, because partial bleaching and the scarcity of sand lenses complicate luminescence age estimation through conventional approaches. To address these issues, using rock surfaces of large clasts may overcome the limited availability of sand layers in some deposits and allow clast specific assessment of luminescence signal resetting at the time of deposition through the analyses of bleaching profiles. The Hartheim gravel pit in the southern Upper Rhine Graben of southwest Germany features a sedimentary succession deposited by distal braided river meltwater streams reworked during the late Pleistocene. Different luminescence approaches have been applied to sand lenses, the sandy matrix of gravel deposits and crystalline cobbles. Quartz optically stimulated luminescence (OSL) ages range between ∼19 and 22 ka, which represents the time just after the last glaciation maximum in the region. The OSL ages of the sandy matrix of ∼24–27 ka are in an agreement with the previous estimates, as these are from a stratigraphic lower position. However, post-IR infrared stimulated luminescence (pIRIR) ages of sand layer and sandy matrix both are some 3–6 ka older than the OSL ages, despite being internally very consistent. Luminescence depth profiles show that the signal was deeply reset in some cobbles, whereas in others only the IRSL signal in the surface layer appears to have been reset. The cobble IRSL ages show a relatively large spread, and it remains uncertain, if this is caused by incomplete bleaching or it reflects dosimetric issues. Nevertheless, overall, our results underscore the potential of rock surface luminescence dating to date fluvial deposits from the Upper Rhine Graben and similar settings.

Do attenuation coefficients based on luminescence bleaching fronts reflect true light attenuation in rocks?

The emerging technique of rock surface luminescence dating employs a double-exponential fitting dating model based on the Bouguer-Lambert law. The accuracy of exposure age determination is sensitive to the light attenuation coefficient, μ, which is usually derived from fitting the luminescence profile as a function of depth into the rock. Alternatively, μ might be determined by direct measurement using a spectrophotometer. However, their directly measured values of μ were significantly larger than those estimated from field luminescence bleaching data. Here, we aim to confirm these previous results by measuring the luminescence-depth profiles of both IRSL and IRPL signals from granite rock exposed to different light sources, including sunlight, SOL2 and IR LEDs under controlled conditions. We also measured monochromatic light (blue LED: (470 ± 30) nm, green LED: (520 ± 30) nm, and infrared LED: (850 ± 30) nm) attenuation in granite rock slices of varying thickness (0.62–2.60 mm) using a high-sensitivity photodiode. Finally, we use a camera-based measurement system and a Risø Luminescence Imager to investigate spatial variation in transmitted light as a function of slice thickness. The spatial correlation between direct light transmission and luminescence emission is then investigated, to investigate the underlying reasons for the difference between direct measurement and luminescence-based estimates of μ. We find that light attenuation through a granite rock slice is very heterogeneous; most light penetrates through localized low attenuation light paths corresponding to transmission through the most transparent grains, presumably quartz. The light penetration and escape into the surrounding matrix are assumed to be influenced by the surface area of quartz grains. As a result, transmissive light paths result in a significant area of feldspar grains at depth in the slice being exposed to more light than might be expected from average attenuation measurement. When the incident light predominantly travels through feldspar minerals, simultaneously stimulating luminescence from within any potassium feldspar (K-feldspar), the attenuation coefficients derived from the luminescence-depth profiles tend to be smaller than the average of 1.18 ± 0.07 (n = 79) irrespective of the kinetic model used for fitting. Thus, luminescence-based attenuation coefficient estimates appear to be affected by the distribution of light attenuation across and within the rock slice, making such estimates preferable to directly measured (average) estimates of light attenuation coefficients. These insights are important for our understanding of the significance of light attenuation coefficients in rock samples; they contribute to the reassessment of parameters and measurement methods in dating models and so to improvements in accuracy of rock surface luminescence dating techniques.

The sensitisation of quartz extracted from andesite

Low quartz sensitivities have been reported in several studies in Iran, and in part this is presumed to be a result of the volcanic provenance of many of the sediments in the study areas. In this study we test experimentally whether a quartz sample, extracted from an andesitic rock and showing an insensitive fast component in the Optically Stimulated Luminescence (OSL) signal, can be sensitised using optical and thermal methods.The luminescence characteristics of quartz extracted from a rock sample from a landslide in Iran (Rudbar-Manjil) are compared to those of a well-characterised quartz sample. We find that very few of aliquots prepared from extracted quartz grains show any sensitivity of the most easily stimulated part of the OSL signal, but that ∼23% of aliquots give detectable initial signals after repeated dosing and bleaching. Surprisingly, a large fraction of the most easily stimulated quartz OSL is removed by infra-red stimulation, even though there is no significant IRSL signal in the UV. However thermal annealing at 700 °C gives rise to a test-dose response that is unaffected by IR. This annealing sensitises all aliquots to some degree and induces a signal which is stable up to 260 °C, in contrast to that following optical sensitisation, which begins to decrease when heated to 140 °C. The implications of these observations are discussed, both in terms of luminescence process and potential for dating.

Sedimentary facies and chronological study for a Late Pleistocene sand layer with swash cross bedding within a sand hill at north of Poyang Lake, as inferred from sedimentary structure and optical dating of K-feldspar and quartz grains

Poyang Lake is the largest freshwater lake in China. Currently, there are several sand hills around Poyang Lake and they were mainly interpreted to be formed by aeolian process. However, by field investigation, it is found that several sand/silt layers with parallel bedding, horizontal bedding and swash cross bedding were preserved within sand hills around Poyang Lake. Compared with recent highest water level in Poyang Lake since 1949, the sand/silt layers with parallel bedding, horizontal bedding and swash cross bedding are higher than 22.63m from several meters to more than 10 m. From the view of sedimentary structure, the sand/silt layers mentioned above should be treated as water-lain sediments. In this study, one sand layer with swash cross bedding at elevation of ∼47.5m within a sand hill at north of Poyang Lake was targeted. The bleaching of K-feldspar IRSL signals and quartz OSL signals during their deposition were further investigated by using optical dating techniques. It is found that both K-feldspar IRSL signals and quartz OSL signals were partially bleached and such phenomenon is very different from typical aeolian sediments. The partially bleaching of both K-feldspar IRSL signals and quartz OSL signals is consistent with interpretations by sedimentary structure of the targeted sand layer, i.e. the sand layer with the swash cross bedding within the sand hill should be interpreted as hydraulic sediments and they were not formed by aeolian process. The OSL ages of targeted sand layer were then analyzed by three different methods, i.e. single aliquot MET-pIRIR dating of K-feldspar, single aliquot OSL dating of quartz as well as single grain OSL dating of quartz. The OSL ages of three methods were all consistent with each other and the age results show that the targeted sand layer was formed during MIS 3a. Although previous studies suggested that previous Poyang Lake (Pengli Ze) was initially formed during mid-Holocene, our study indicates that previous Poyang Lake (Pengli Ze) already existed during MIS 3a and it might experience extremely high water level phase at that time.

Zeroing of IRSL signals in cobbles surfaces from a modern river floodplain in the Manas river, Tian Shan

A newly developing method, rock surface luminescence dating, provides a novel means of constraining the burial age of fluvial gravel and unveiling the transport and exposure-burial process of fluvial bed-load. A crucial requirement for successful age determination in luminescence dating of buried rock surfaces is that a sufficiently thick surficial layer was reset to a near-zero level of signal prior to deposition and burial. However, little such effort has been made on modern fluvial gravels from various depositional environments to provide a sound justification for the use of luminescence dating in such settings. In this study, we reported an investigation of daylight bleaching in modern cobbles with different sizes and shapes at a modern river floodplain from the Manas River, Tian Shan, to test the reliability and applicability of fluvial cobble optical dating. Four multi-elevated-temperature post-infrared infrared (MET-pIRIR) stimulated luminescence signals of rock slices were measured using a modified MET-pIRIR protocol to establish residual luminescence-depth profiles. The residual does of pIRIR and MET-pIRIR signals of sub-surface rock slices were also estimated using different modified SAR protocols. The results showed that the high temperature IRSL signal could be reset to ∼2–3 mm depth into cobbles surface and flat cobbles seem easier to bleach than spherical cobbles. The residual doses of sub-surface rock slices of cobbles from modern river floodplain was ∼0.4 Gy and ∼1.1 Gy for the IR50 and the pIRIR170 signal respectively, suggesting a residual age of ∼0.1 ka and ∼0.2 ka. The residual ages of MET-pIRIR signals of sub-surface rock slices of cobble MNS2-5 were ∼0.5–1 ka at higher stimulation temperature. Our results show that the fluvial cobble optical dating techniques have great potential for providing reliable chronologies for river floodplain gravel and other fluvial depositional events.

MET-post-IR IRSL luminescence dating of cobbles buried in fluvial terraces in the Northern Chinese Tian Shan

Cobbles can be used as an alternative to the conventionally employed sand-sized mineral luminescence dating. In piedmont environments, cobbles are much more abundant than sand-sized material. The IRSL 50 signal has been widely used in previous studies due to its greater sensitivity to exposure events. However, it is well known that the low temperature IRSL signal is more prone to fade than elevated temperature post-IR IRSL signal. In this study, to test the reliability and applicability of cobble sub-surface elevated temperature IRSL luminescence dating, six light-color granite cobbles and two sand-sized samples from silty sand lens were collected from a high terrace of Manas River on the northern piedmont of Chinese Tian Shan. A modified multi-elevated-temperature post-infrared infrared stimulated luminescence (MET-post-IR IRSL) protocol was applied. The age-temperature (A-T) plateau of MET-post-IR IRSL measurement was combined with the conventional age-depth (A-D) plateau in luminescence-depth profile to evaluate the resetting and fading of MET-post-IR IRSL signals. Uncertainties of grain-sizes of K-feldspar within solidified slices were also explored by μ-XRF mapping of potassium content. The A-T plateau was identified between MET-post-IR IRSL 170 and MET-post-IR IRSL 225 signals of one cobble, which suggested completeness of bleaching before burial and negligible anomalous fading during burial. This cobble yielded MET-post-IR IRSL 225 ages of 15.8 ± 2.6 ka and 19.0 ± 3.2 ka for top and bottom side, respectively. These MET-post-IR IRSL 225 ages were consistent with independent coarse-grained quartz MAM OSL ages (15.7 ± 3.6 ka and 14.8 ± 2.6 ka) of two sand-sized samples. The MET-post-IR IRSL 225 age of 16.0 ± 1.2 ka for the bottom side of another cobble was also consistent with the independent age, even without the A-T plateau. It was inferred to be caused by anomalous fading of MET-post-IR IRSL signals other than that stimulated at 225 °C by refering to the A-D plateau observed. Our results show that MET-post-IR IRSL measurement can be employed to determine the burial ages of cobbles. The A-T plateau, complemented with the A-D plateau, could be used to assess the reliability of burial ages of cobble luminescence dating from the view of bleaching and fading. • MET-post-IR IRSL measurement has advantages in judgement of fading and bleaching of rock slices. • Constraining the terrace ages using fluvial cobbles has great potential and prospects. • Evaluating the uncertainty of internal dose related to grain sizes variation of K-feldspar.

Luminescence chronology of fossiliferous fluvial sediments along the middle Atbara River, Sudan

Fluvial sediments of the middle Atbara River Valley, eastern Sudan, contain abundant vertebrate fossils and stone tools. Previous work described two sedimentary units, the Butana Bridge Synthem (BBS) and the Khashm El Girba Synthem (KGS), with three divisions each (BBS1-3 and KGS1-3, from bottom to top, respectively). 230 Th/U dating on bivalve shells suggested an age of ∼126 and ∼92 ka for the basal KGS2 and basal KGS3, respectively, and mammalian biochronology in combination with magnetostratigraphy suggested an age of late Early to early Middle Pleistocene for the underlying BBS. To establish a detailed chronology of this fluvial sedimentary sequence, we collected 17 luminescence samples from both sides of the Atbara River close to the Butana Bridge. Quartz OSL dating was applied to samples from the upper part of the profile (upper KGS2 and KGS3), but the signal reached saturation within the upper ∼10 m of the sequence. To select a suitable feldspar signal to date older samples beyond the limit of the quartz OSL, a comparison of the quartz OSL, feldspar post-IR IRSL at 225 and 290 °C, and pulsed IRSL signal at 50 °C was conducted for a sample from KGS3. The result showed that only the fading corrected pulsed IRSL yielded an age consistent with the quartz OSL, and the post-IR IRSL signals (both at 225 and 290 °C) overestimated the quartz age significantly. We therefore selected the pulsed IRSL signal to date the older deposits. The luminescence ages indicate that the entire BBS - KGS sequence was deposited between 224 ± 23 ka and <17 ± 1 ka, corresponding to marine isotope stages (MIS) 7–2, significantly revising previous conclusions.

Luminescence dating of shoreline sediments indicates a late deglacial lake-level rise of Selin Co on the central Tibetan Plateau

The palaeo-shorelines around the lakes on the Tibetan Plateau can be used to reconstruct water level variations, which serve as sensitive indicators of hydroclimate change. Extensive studies have been carried out to constrain the Holocene lake level fluctuations by dating shorelines with a variety of methods (e.g., luminescence, 14C, 10Be and U–Th series). In comparison, the timing of the lake level variations during the last glacial and subsequent deglaciation periods has been rarely studied. The driving factors of such changes, therefore, remain elusive. In this study, we performed a detailed luminescence dating investigation on six samples taken from a nearshore sedimentary outcrop in the south of Selin Co basin. The post-IR IRSL signals measured at 225 °C (pIRIR225) on sand-sized K-feldspar grains demonstrated a generally good behavior and yielded reliable chronologies, while the optically stimulated luminescence (OSL) signals of quartz showed systematical age underestimation, which was attributed to anomalous fading. Six pIRIR225 ages ranging from 15 to 10 ka suggested that the lake level of Selin Co during the last deglaciation reached up to 40–45 m high above the modern lake level. In view of the regional precipitation and temperature proxy records, we consider that the glacier meltwater supply has likely been the primary contributor to the lake highstands during the last deglaciation.

Rock and sediment luminescence dating of an ancient circular stone-walled enclosure at Sønnebøe, northern Scania, Sweden

Dating agricultural artefacts such as field walls and clearance cairns using radiocarbon can be challenging, especially since the association with datable material may be poor. Rock surface burial dating using luminescence offers an alternative. Here we report on the luminescence dating of a medieval circular stone-walled enclosure at Sønnebøe, northern Scania, Sweden, using both buried rocks and sediments. Luminescence burial profiles from IRSL signals measured at 50 °C (IR 50 ) indicated significant prior light exposure in 7 of the 8 samples tested (5 granite, 2 felsic gneiss), in some cases multiple exposure burial cycles were indicated. These rock surfaces had apparently been exposed for sufficient time to allow accurate IRSL ages for the most recent burial event. In contrasts, no useful post-IR IRSL profiles were obtained indicating that this signal was not sufficiently reset to allow accurate determination of the burial dose on any of these rocks. IR 50 fading corrections (typically ∼50%) were derived by comparing field saturation with that induced in the laboratory. Quartz extracted from sediments surrounding the rocks gave an average measured to given dose ratio of 1.03 ± 0.01 (n = 90), and these sediment samples were then dated using multigrain aliquots; the corresponding feldspar dose recovery ratio obtained using rock samples was 0.98 ± 0.05 (n = 28). A total of 15 ages were derived; 8 quartz OSL ages from the disturbed coarse grained sediments surrounding the structure, and 7 fading corrected IR 50 ages from the surfaces of rocks (2–3 mm chips, ∼1 mm thick) used in the construction of the structure itself. The exposure events preserved by the ring enclosure stones unequivocally show wall building taking place at the site between 800 and 300 years ago. • Direct dating of stone walled structures. • Rock surface burial dating using IR 50 luminescence bleaching profiles. • Comparison of dating results obtained from sand sized sedimentary grains and granitic rocks. • Application of improved modelling of infinite matrix beta and gamma dose rates in rocks.

A method to evaluate the degree of bleaching of IRSL signals in feldspar: The 3ET method

In addition to dating, IRSL luminescence signals can preserve information about erosional, transport, and depositional histories of a population of grains. Knowledge of the degree of bleaching can be useful in understanding the processes that occurred during previous depositional events, as certain transport conditions result in a well bleached signal, while others result in grains retaining an inherited signal from prior events. This information can be accessed by making single-grain IRSL measurements across successively increasing temperatures, thereby isolating signals from traps of different bleachabilities. A new approach offers a way to evaluate the completeness of bleaching of a grain by testing patterns of equivalent dose (D E ) values measured at three elevated temperatures (3ET), 50, 125, and 225 °C. Consistent D E estimates across two or more temperatures suggest a single bleaching event of sufficient duration to fully depopulate the traps involved. Incompletely bleached grains with inconsistent D E values across temperatures will lack a 3ET “plateau.” Modes in the distribution of D E values for fully bleached grains can suggest depositional ages, subject to assessment of fading. We developed a Python code in a Jupyter Notebook environment for data analysis and visualization to expedite processing the large data sets produced by the 3ET protocol. The 3ET protocol was tested on a radiocarbon dated sequence of playa samples from California, USA and on a set of fluvial terraces in the Marlborough region of New Zealand as part of a larger project to reconstruct regional seismic history. Where standard pIRIR apparent ages can be inconsistent or ambiguous, 3ET age estimates produce generally consistent apparent ages. Modes of 3ET plateaus can be used to infer the most recent and prior events that resulted in a sub-population of grains being fully bleached. These initial results suggest that the 3ET method can be useful to characterize both the age and degree of bleaching of depositional events.

Isolating quartz-dominated OSL signal of rock slice by using pulsed stimulation: Implications for dating burial age of cobbles

Although the OSL signal sourced from quartz is expected to be more stable and bleached more rapidly than the IRSL signal sourced from feldspar in a general sense, the former is much less investigated than the latter for rock surface related luminescence dating. It is mainly due to the difficulty in isolating quartz-dominated OSL signals from rock slices, and the low sensitivity and non-fast component dominated OSL signals for quartz in most of rocks. In merit of the sub-conduction band transition of trapped electrons of feldspar under both green light stimulation and IR stimulation at elevated temperature (Jain and Ankjӕrgaard, 2011), it is expected that the contribution of feldspars to the green light stimulated luminescence could be substantially reduced by a prior IR stimulation at elevated temperature. Meanwhile, more fast-component dominated quartz OSL signal (if there is any) could be obtained by green light stimulation (Bailey et al., 2011). Therefore, in this study, we investigated the feasibility of using the post-IR pulsed green stimulation, which is performed at 25 °C (PGLSL 25 ) following two IR stimulations (IR 50 IR 225 ), to isolate the quartz-dominated OSL signals from rock slices of granite cobbles for burial dating. The decay characteristics of stimulation curve, characteristic saturation dose and thermal stability of the pIR 50 IR 225 PGLSL 25 signal suggest that this signal is quartz-dominated, but still not fast-component dominated. We tentatively validated the equivalent dose (D e ) measurement protocol by dose recovery experiment. The luminescence-depth profiles show that the bleaching depths of pIR 50 IR 225 PGLSL 25 signals are slightly smaller than or close to that of the IR 50 signals, while they are much shallower for the pIR 50 IR 225 signals. The pIR 50 IR 225 PGLSL 25 procedure enables multiple D e values determined from luminescence signals, with different bleachabilities and stabilities, from both feldspars and quartz in one measurement, which is of potential for buried age dating of cobbles. • The pIR 50 IR 225 PGLSL 25 method could be used to isolate the quartz-dominated signal from rock slice. • The bleaching depth of the pIR 50 IR 225 PGLSL 25 signalis slightly less than or close to that of the IR 50 signal. • The pIR 50 IR 225 and the pIR 50 IR 225 PGLSL 25 D e values could be obtained in one measurement.

A simplified multiple aliquot regenerative dose protocol to extend the dating limit of K-feldspar pIRIR signal

The post-infrared infrared stimulated luminescence signal (pIRIR) from K-feldspar shows significantly less athermal fading than the conventional IRSL signal, thus it has been widely used for dating Quaternary deposits. With the single aliquot regenerative dose (SAR) protocol, the test dose signal is influenced by the preceding regenerative dose, and the characteristic saturation dose (D0) of the pIRIR signal is mostly in the range of 200–600 Gy, depending on the size of the test dose. According to the D0 value, the dating range of pIRIR is restricted to <300 ka with the SAR protocol. Here we present a multiple aliquot regenerative dose (MAR) protocol using low-temperature thermoluminescence (TL) signal for inter-aliquot normalisation. The multiple-elevated-temperature (MET) pIRIR signals up to 290 °C are investigated. The D0 increases to 850–1300 Gy with this protocol, which should represent the intrinsic D0 of IR or pIRIR signals of K-feldspar. Based on the higher D0, this protocol has the potential to date samples with equivalent doses (Des) up to 2000 Gy, i.e. up to ∼600 ka considering a dose rate of ∼3.5 Gy·ka−1. Applications of this MAR protocol on two loess samples from the Chinese Loess Plateau provide ages consistent with expected ages up to 350 ka, with the MET-pIRIR signal at 290 °C. However, tests on three fluvial and alluvial samples show age overestimation with the new MAR protocol as well as SAR protocol, which may result from the hard-to-bleach property of the high-temperature pIRIR signals. Simulations of fading correction indicate that the age will be over-corrected when the laboratory dose response curve has a D0 smaller than the true D0 of the signal. Caution should be taken in fading corrected ages measured with the conventional SAR protocol, as the D0 values are always underestimated in this case.

Using Infra-red stimulated luminescence and phototransferred thermoluminescence to investigate electron trapping and charge transport in feldspars

Previous studies have observed mineral specific variations in the ratios of IRSL signals stimulated at the different discrete wavelengths of lines corresponding to Xe lamp emission lines, which fall within the broad excitation spectrum of IRSL. Meanwhile recent accounts of IRSL have referred to single trapping systems within the excitation band, and modelled excitation spectra as continuous gaussian distributions. A simple single trap model should not result in variations in the ratio of IRSL intensities produced at different wavelengths. In the study reported here 22 different feldspar samples, which have all been characterised by SEM and x-ray analysis, were measured using a portable OSL instrument equipped with 890 nm and 940 nm diode arrays to confirm and extend the previous observations of variations in IRSL intensity ratios. Of the samples investigated the sensitivity varied over 3–4 orders of magnitude. Albite samples in this selection showed consistently high responses. The plagioclase samples show significant variations, and the microcline and K-feldspar samples produced a large range of responses. Excitation ratios of 940 nm–890 nm show mineralogically linked variations which together with the earlier Xe lamp data point to distributions of trapping systems within the variable environments of these minerals. These results do not readily fit simple single trap models for luminescence from feldspars; instead, they suggest multiple traps or a series of similar traps which are significantly perturbed by their local lattice structural environments. Post Stimulation Phosphorescence (PSP) was observed for all samples, and phototransferred thermoluminescence (PTTL) has also been confirmed following IR stimulation suggesting that recombination mechanisms involve charge mobility and interactions with shallow traps in band-tail states rather than primarily being associated with direct quantum tunnelling recombination. The relative proportions of PSP to prior IRSL also varied between the two stimulation wavelengths which further emphasises the physical differentiation between processes influencing different subpopulations of the trapping states associated with IRSL and their local lattice environments.

Dating Neolithic rubble layers from Ba'ja and Basta sites in southern Jordan using luminescence

There is considerable evidence of widespread damage in the 7th millennium habitation sites across Jordan. The origins of this damage are unknown, but the most widely accepted hypothesis associates the resulting rubble and gravel deposits with the Holocene Rapid Climate Change. One way of testing the various hypotheses is to provide a more reliable chronology for the event(s) in question. In this study, we used quartz OSL and feldspar IRSL signals to date accumulative rubble layers at two archaeological sites in Southern Jordan; Ba'ja and Basta. By comparison with the OSL ages, the IRSL ages demonstrate that most of the quartz samples were sufficiently well bleached at deposition to provide accurate ages. Quartz ages show that deposition of the rubble layers took place in different episodes starting around 8.5 ka and 6.0 ka. Ages from Ba'ja site agree with the archaeological expectations of time of deposition. However, the results from Basta are younger than the archaeological expectations, which are based mainly on architectural style and stratigraphy.

Sea-level changes in the Bohai Sea, northern China, constrained by coastal loess accumulation over the past 200 ka

Loess sequences are widely distributed in semi-arid regions around the world, and are sometimes also located in coastal zones. The accumulations of coastal loess provide a valuable record of both climate and sea-level changes. Here we report sedimentological and high sampling resolution luminescence dating evidence for such changes from two loess sequences from the Shandong Peninsula and Miaodao Archipelago near the coast of Bohai Sea in northern China. Both the quartz optically stimulated luminescence (OSL) and K-feldspar post-infrared IRSL (pIRIR290) signals show consistent and satisfactory luminescence characteristics up to ∼100 ka, while the K-feldspar pIRIR290 ages provide age control up to ∼200 ka and are in stratigraphic order. With this fully independent age model, our results reveal that coastal loess accumulation is episodic with a high variability in apparent accumulation rates. After comparing with global and regional sea-level records, we find that the intervals with high accumulation rates coincide with global low sea-level stages, and that the loess sedimentary hiatuses indicated by nearly zero or very low accumulation rates at one site mainly correspond to global high sea-level stages, indicating the dominant role of global sea-level changes on coastal loess accumulation in the study area. We therefore conclude that regional marine regression mainly occurred during MIS 6, and MIS 5b to MIS 2, with extremely low regional sea levels possibly around 150 ka, 70–60 ka and 37–24 ka, while high sea-levels occurred during MIS 5e–5c and MIS 1. This study implies that coastal loess deposits with a good chronology could be used to constrain the timing of regional sea level change.

Investigating the resetting of IRSL signals in beach cobbles and their potential for rock surface dating of marine terraces in Northern Chile

Inactive shorelines represent valuable records for sea level change, shoreline variations and tectonics if we can constrain the timing of their formation. Where the associated beaches are cobble dominated, luminescence rock surface dating is a promising alternative to established dating approaches, since unlike other techniques it offers the potential to identify clasts unaffected by inherited ages. While luminescence rock surface dating has successfully been used on Holocene and Late Pleistocene beach ridges previously, in this study the potential of IRSL rock surface dating is evaluated for the magmatic cobbles of uplifted Pleistocene terraces along the tectonically active coast of northern Chile. Cobbles from an active beach were used to investigate the influence of cobble lithology on IRSL signal properties and the effectiveness of IRSL signal resetting in the rock. While alkaline and andesitic cobbles yield low IRSL intensities and limited signal resetting due to strong light attenuation, more favourable characteristics for dating were observed for some diorite and granite cobbles. Their IRSL signals were well reset in the uppermost few mm without any systematic difference between upper and lower surface. Some of them revealed bleaching plateaus with inherited ages close to zero after correction for laboratory residuals. For dating, cobbles from three Pleistocene marine terraces, for which new uranium‑thorium and ESR control ages on molluscs provide age control, were targeted. None of the associated IRSL rock surface burial ages agrees with the MIS 5 control ages of the terraces. Most of the selected cobbles are either too dark to allow for effective signal resetting or yield IRSL properties unsuitable for dating. Only one of the targeted cobbles shows both signs of signal resetting at its surface and sensitive IRSL signals, but its signal was already in field saturation due to dose rates >6 Gy/ka. In conclusion, our data indicate that beach cobbles with granitic to dioritic lithology combine appropriate IRSL properties and sufficient IRSL signal resetting for dating Holocene landforms. Last interglacial terraces may already be beyond the limit of IRSL dating for most cobbles of this lithology since they show large dose rates compared to IRSL sediment dating.

The Bleaching of Different K-Feldspar pIRIR Signals of Source Materials of Lacustrine Sediment – A Case Study from Bosten Lake Basin in Arid Central Asia

Abstract The residual ages and bleaching of K-feldspar post-IR IRSL (pIRIR) signals (pIR50IR170, pIR50IR290, and pIR200IR290) for a variety of modern sediment sources to the Bosten Lake basin in the southern Tian Shan of arid central Asia were assessed to identify the most appropriate facies to sample for ascertaining well-bleached, depositional ages associated with Quaternary paleolake development. Results indicate pIR50IR290 residual ages for pluvial fan, fluvial, and eolian sediments cluster at 40–6, 6–3, and 2–1 ka, respectively, and are depositional ages. Residual ages of pIR200IR290 signals are twice that of pIR50IR290 signals, while residual ages of pIR50IR170 signals are similar to that of pIR50IR290 signals for all samples. Eolian and fluvial samples show well-bleached, coarse-grained (90–125 μm) K-feldspar and poorly-bleached coarse grained K-feldspar from pluvial samples. High residual doses in fluvial and pluvial samples indicate it may not be advisable to apply pIRIR dating utilising different pIRIR signals to Holocene lacustrine samples. However, the residual ages measured for eolian deposits are small and can allow precise and robust assessment of paleolake development by targeting the K-feldspar pIR50IR170 signal to date Holocene samples and the pIR200IR290 and pIR50IR290 signals to date Pleistocene samples.