The main goal of the work was to develop phosphorescent coating for investigations of surface temperature distribution resulted from short duration and high energy thermal events such as small rocket engine testing. For that purpose, we developed thermal history paint with upconverting Gd2O3: Er3+, Yb3+, Mg2+ nanopowder. The developed paint was heated by Joule effect with precise control over temperature and heating time. Photoluminescence signal of cooled samples was excited with 980 nm laser and collected in automatic manner with use of an optical fibre probe connected to photospectrometer. The results show that irreversible changes of paint emission are temperature and heating time specific for calcination temperatures from 700 °C to 1150 °C. Calibration curves were prepared for heating times of 10, 60 and 180 seconds. Finally, 2D surface temperature samples were determined with use of upconverting thermal history paint and compared to IR camera and pyrometric measurements. The results indicate that uncertainty of temperature measurement below 10 °C was achieved for temperatures above 1000 °C. It has been demonstrated that developed thermal history paint allows for measurements of 2D surface temperature distribution with high spatial resolution and good agreement to standard measurements techniques like thermal camera and pyrometer.