Ions In Collisions Research Articles

High external quantum efficiency photodetector based on Ga2O3/CH3NH3PbI3

In this paper, Ga2O3/CH3NH3PbI3 photodetector (PD) with high external quantum efficiency (EQE) was successfully prepared by spin coating CH3NH3PbI3 on the film surface of Ga2O3/Au MSM PD. Compared with Ga2O3 film device, the dark current of heterojunction device decreased from 5.20 to 0.09nA, and the responsivity increased from 0.18 to 14.01 A/W at 40 V bias. It is worth noting that under the same bias voltage (40 V), the EQE of Ga2O3/CH3NH3PbI3 PD is as high as 6686 %, which is 78 times of Ga2O3/Au PD (85.89 %). The high EQE is attributed to collision ionization doubling caused by the effect of an applied electric field. In addition, the construction of heterojunction speeds up the response speed of PD. This work has important implications for the selection of heterogeneous materials and the construction of PDs to optimize device performance.

Breit interaction overtaking Coulomb force at low energies: an unexpectedly efficient mechanism for ionization in slow collisions

Abstract It is generally assumed that ionization in slow collisions of light atomic particles, whose constituents (electrons and nuclei) move with velocities orders of magnitude smaller than the speed of light, is driven solely by the Coulomb force. Here we show, however, that the Breit interaction—a relativistic correction to the Coulomb interaction between electrons—can become the main actor when the colliding system couples resonantly to the quantum radiation field. Our results demonstrate that this ionization mechanism can be very efficient in various not too dense physical environments, including stellar plasmas and atomic beams propagating in gases.

Effects of anode evaporation process on the anode sheath characteristics in vacuum arc plasma

Abstract The anode sheath of vacuum arc plasma plays a key role in the generation of anode plasma, but the effects of anode evaporation on the anode sheath remains unclear. In this paper, a theoretical model of a collisional sheath for multi-component plasma coupled with anode evaporation is developed, and the spatial evolution of the anode sheath at different anode surface temperatures is investigated. The results indicate that the distribution of charged particles density and potential in the anode sheath monotonically decreases in the absence or reduction of anode evaporation. When the anode surface temperature exceeds 1900K, a potential hump appears within the sheath. This is due to enhanced anode evaporation increasing the metal vapor density, which intensifies electron impact ionization and charge exchange collisions, resulting in a higher net space charge density. Finally, the effects of various collision reactions and electron temperatures on the potential hump are analyzed. These findings are meaningful for understanding the anode plasma generation mechanism and regulating the anode plasma parameters.

Establishing criteria for the transition from kinetic to fluid modeling in hollow cathode analysis

Hollow cathodes for plasma switch applications are investigated via 2D3V particle-in-cell simulations of the channel and plume region. The kinetic nature of the plasma within the channel is dependent on the thermalization rate of electrons, emitted from the insert. When Coulomb collisions occur at a much greater rate than ionization or excitation collisions, the electron energy distribution function rapidly relaxes to a Maxwellian and the plasma within the channel can be described accurately via a fluid model. In contrast, if inelastic processes are much faster than Coulomb collisions, then the electron energy distribution function in the channel exhibits a notable high-energy tail, and a kinetic treatment is required. This criterion is applied to hollow cathodes from the literature, revealing that a fluid approach is suitable for most electric propulsion applications, whereas a kinetic treatment can be more critical to accurate modeling of plasma switches.

Influence of different factors on gap breakdown process with hot electrode and high temperature gas medium in low voltage circuit breaker chamber based on particle-in-cell/Monte-Carlo collision simulation

Different factors such as gas composition inside the low voltage circuit breaker (LVCB) chamber and the residual plasma in the post-arc stage affect the breakdown process, which in turn affects the breaking capacity of LVCBs. In this paper, the effects of non-parallel electrode structure, gas temperature and pressure, electrode temperature, and gap distance on gap breakdown of hot electrode under high temperature gas conditions were studied, for which a particle-in-cell/Monte-Carlo collision simulation model has been established, which takes into account the effects of high-temperature gas components, cathode electron thermal emission, electron collision ionization and other effects, and simulation studies have been conducted. The simulation results show that the increase in gap gas temperature, the decrease in air pressure, and the increase in electrode temperature will lead to the gap breakdown more easily. With the increase in the gap length, the breakdown voltage increases, but the average electric field intensity required for breakdown decreases. In the non-parallel electrode structure, the breakdown occurs first at the position with the shortest gap distance, then the cathode sheath forms and extends along the electrode surface to other areas, and finally, the entire gap breaks down.

Ionization by radiative energy transport vs. impact ionization in energetic atomic collisions

Abstract We explore a mechanism for ionization in high-velocity (but not yet relativistic) collisions of light atomic particles, one of which being initially in an excited internal state. This mechanism is driven by the generalized Breit interaction and proceeds via radiative energy transport between the colliding particles which has an extremely long range. A comparison of this mechanism with those which are ‘standard’ for high-velocity collisions shows that it can play a noticeable role in collisions with excited target atoms.

Doubly differential cross sections for ionization in proton collisions with atomic hydrogen: Energy and angular distribution of emitted electrons

Doubly differential cross sections for ionization in proton collisions with atomic hydrogen: Energy and angular distribution of emitted electrons

Ruling out a saddle-point mechanism of ionization in intermediate-energy ion-atom collisions

Ruling out a saddle-point mechanism of ionization in intermediate-energy ion-atom collisions

Photoproduction of K^{+}K^{-} Pairs in Ultraperipheral Collisions.

K^{+}K^{-} pairs may be produced in photonuclear collisions, either from the decays of photoproduced ϕ(1020) mesons or directly as nonresonant K^{+}K^{-} pairs. Measurements of K^{+}K^{-} photoproduction probe the couplings between the ϕ(1020) and charged kaons with photons and nuclear targets. The kaon-proton scattering occurs at energies far above those available elsewhere. We present the first measurement of coherent photoproduction of K^{+}K^{-} pairs on lead ions in ultraperipheral collisions using the ALICE detector, including the first investigation of direct K^{+}K^{-} production. There is significant K^{+}K^{-} production at low transverse momentum, consistent with coherent photoproduction on lead targets. In the mass range 1.1<M_{KK}<1.4 GeV/c^{2} above the ϕ(1020) resonance, for rapidity |y_{KK}|<0.8 and p_{T,KK}<0.1 GeV/c, the measured coherent photoproduction cross section is dσ/dy=3.37±0.61(stat)±0.15(syst) mb. The center-of-mass energy per nucleon of the photon-nucleus (Pb) system W_{γPb,n} ranges from 33 to 188GeV, far higher than previous measurements on heavy-nucleus targets. The cross section is larger than expected for ϕ(1020) photoproduction alone. The mass spectrum is fit to a cocktail consisting of ϕ(1020) decays, direct K^{+}K^{-} photoproduction, and interference between the two. The confidence regions for the amplitude and relative phase angle for direct K^{+}K^{-} photoproduction are presented.

Reaction mechanism investigation on Plasma-Assisted steam reforming of toluene based on emission spectrum analysis and kinetic simulation

Plasma-enhanced reforming has been widely studied as an efficient technology for online tar removal. By combining reforming experiments with kinetic modeling and in-situ optical emission spectrometry (OES) analysis, interaction mechanism and coupling rules of plasma/thermal reactions during plasma-assisted steam reforming of toluene were well explored in this study. A chemistry model was innovatively developed for plasma-assisted steam reforming of toluene, and predicted experimental results under different operations conditions with superb agreements. The rate of production and sensitivity analysis implied that OH, H and N2* mainly contributed to primary toluene conversion, while the electronic attachment dissociation of H2O, H addition onto benzene ring and benzyl oxidation by OH were the most enhancing-sensitive reactions. Resultantly, toluene conversion was greatly increased with steam addition before VfH2O = 10 %, but after which VfH2O increase deteriorated the reforming performance due to the inhibition of E-N2 collision by high VfH2O. As temperature increased, plasma and thermal synergistically promoted reforming performance before 300 °C, at which > 60 % toluene was converted into small molecules such as CO, H2 and C2H2, with yields of 23.6 %, 9.4 % and 16.3 % correspondingly at 12 kJ/L, but further temperature increase would not benefit due to the reduced discharge field strength at higher temperatures, being confirmed by the decreased relative intensity of OH, CN feature bands on OES. It was initially proposed that non-thermal plasma governed the reforming process at T < 300 °C, and thermal reactions predominated at T > 500 °C after a transition region (300 ∼ 500 °C). Increase of input energy caused higher discharge field strength, promoted the electronic collision ionization or dissociation of N2 and H2O, thus enhanced toluene conversion and gas yields. A detailed reaction pathway has also been clarified.

Investigation of the cross sections for electron collision ionization of complex molecules

AbstractAn accurate and computationally efficient determination of the cross sections for electron collision ionization of molecules has various applications, such as plasma physics and atmospheric science. In the case of large molecules, ab initio calculations are often difficult and time‐consuming. Here, we develop a feed forward neural network to predict the electron impact ionization cross sections of complex molecules. The training (predicting) set in the method consists of a series of theoretical ionization cross sections for small (large) molecules obtained from the combined model, which integrates the Binary‐Encounter‐Bethe and Deutsch‐Märk models. Several complex systems or targets involving electron collision ionization are evaluated, including molecules such as CH, CH, CH, CH, C, CHO, and CHO. The root mean square errors of the trained and predicted cross sections by the neural network (compared to the values from the combined model) are found to be approximately .0086 and .0930 (in 10 cm), respectively, (using the CHO molecule as an example), indicating our results are very high accuracy. The excellent agreement between the predicted values and the actual values indicates that the neural network is a practical and powerful tool for determining the electron collision ionization cross sections of complex molecules and can provide valuable insights into the dynamics process. Apart from its fundamental importance, this study has far‐reaching implications for gas discharge, low‐temperature plasmas, and fusion edge plasmas and so forth.

Visualization of electrical interaction among close-packed atmospheric pressure plasma jets

Plasma jet arrays can flexibly generate large-scale plasma in ambient air for surface treatment. Close arrangement of plasma jets inevitably induces a complex electrical interaction, which reshapes plasma plumes and destabilizes the treatment process. Understanding electrical interaction is a prerequisite for optimizing parameters in surface treatment. In this study, we employ a linear electro-optic technique to visualize the electrical interaction on the cross section perpendicular to plume trajectories. The strength of the interaction is featured by the density of the deposited surface charge. Results show that plasma jet arrays can simultaneously deposit like-charged groups onto the substrate. However, the electrical interaction is proven to behave with a tendency toward convergence rather than the repulsion caused by electrostatic interaction. It is inferred that electrons at the head of ionization waves (IWs) shield electrostatic repellence between positive charge groups. The collision ionization by electrons in the interval guides the coalescence of adjacent IWs. This study clarifies the electrical interaction between multiple jets, which is instructive for stable control of large-scale non-thermal plasmas for surface treatment.

Study on stray electrons ejecting from a long-pulse negative ion source for fusion

The negative ion based neutral beam injection is a desirable plasma heating and current drive method for the large-scale magnetic fusion devices. Due to the strict requirements and difficult development of the negative ion source for fusion, a long-pulse negative ion source has been developed under the framework of the Comprehensive Research Facility for Fusion Technology in China. This negative ion source consists of a single radio frequency (RF) driver plasma source and a three-electrode accelerator. The typical extraction and acceleration voltage are 4–8 kV and 40–50 kV, respectively. During one shot of the long-pulse (∼100 s) beam extraction, the gas pressure in the vacuum vessel increased sharply and the temperature of the cryopump rise from 8 K to 20 K. Moreover, the vessel wall appeared a high temperature after several long-pulse shots. A self-consistent simulation of beam-gas interaction revealed that the heat loads on the vessel wall should be caused by the stray electrons ejecting from the accelerator. Those stray electrons are mainly generated via the stripping or ionization collisions and strongly deflected by the downstream side of the deflection magnetic field for the co-extracted electron. The location of hot spots measured by infrared thermography is consistent with the simulation results. To solve this problem, a series of electron dumps are designed to avoid the direct impinging of the ejecting electrons on the cryopump and the vessel wall. And the results suggest that the hot spots are almost eliminated.

Effect of desorbed gas on microwave breakdown on vacuum side of dielectric window

The gas desorbed from the dielectric surface has a great influence on the characteristics of microwave breakdown on the vacuum side of the dielectric window. In this paper, the dielectric surface breakdown is described by using the electromagnetic particle-in-cell-Monte Carlo collision (PIC-MCC) model. The process of desorption of gas and its influence on the breakdown characteristics are studied. The simulation results show that, due to the accumulation of desorbed gas, the pressure near the dielectric surface increases in time, and the breakdown mechanism transitions from secondary electron multipactor to collision ionization. More and more electrons generated by collision ionization drift to the dielectric surface, so that the amplitude of self-organized normal electric field increases in time and sometimes points to the dielectric surface. Nevertheless, the number of secondary electrons emitted in each microwave cycle is approximately equal to the number of primary electrons. In the early and middle stages of breakdown, the attenuation of the microwave electric field near the dielectric surface is very small. However, the collision ionization causes a sharp increase in the number density of electrons, and the microwave electric field decays rapidly in the later stage of breakdown. Compared with the electromagnetic PIC-MCC simulation results, the mean energy and number of electrons obtained by the electrostatic PIC-MCC model are overestimated in the later stage of breakdown because it does not take into account the attenuation of microwave electric field. The pressure of the desorbed gas predicted by the electromagnetic PIC-MCC model is close to the measured value, when the number of gas atoms desorbed by an incident electron is taken as 0.4.

Cold electrons at a weakly outgassing comet

ABSTRACT Throughout the Rosetta mission, cold electrons (&amp;lt;1 eV) were measured in the coma of comet 67P/Churyumov–Gerasimenko. Cometary electrons are produced at ∼10 eV through photoionization or through electron-impact ionization collisions. The cold electron population is formed by cooling the warm population through inelastic electron–neutral collisions. Assuming radial electron outflow, electrons are collisional with the neutral gas coma below the electron exobase, which only formed above the comet surface in near-perihelion high-outgassing conditions (Q &amp;gt; 3 × 1027 s−1). However, the cold population was identified at low outgassing (Q &amp;lt; 1026 s−1), when the inner coma was not expected to be collisional. We examine cooling of electrons at a weakly outgassing comet, using a 3D collisional model of electrons at a comet. Electron paths are extended by trapping in an ambipolar electric field and by gyration around magnetic field lines. This increases the probability of electrons undergoing inelastic collisions with the coma and becoming cold. We demonstrate that a cold electron population can be formed and sustained, under weak outgassing conditions (Q = 1026 s−1), once 3D electron dynamics are accounted for. Cold electrons are produced in the inner coma through electron–neutral collisions and transported tailwards by an E × B drift We quantify the efficiency of trapping in driving electron cooling, with trajectories typically 100 times longer than expected from ballistic radial outflow. Based on collisional simulations, we define an estimate for a region where a cold electron population can form, bounded by an electron cooling exobase. This estimate agrees well with cold electron measurements from the Rosetta Plasma Consortium.

Theoretical analysis of the electronic structure and electron collision ionization process in a strongly coupled semi-classical plasma environment

In this work, we propose a distorted wave method in the relativistic framework to analyze the electron collision ionization process under the influence of strongly coupled semi-classical plasmas. A pseudopotential is used to represent the screened interactions between the core and outer electron, together with solving the Dirac equation to take care of the relativistic effects. This potential characterizes the plasma in terms of the Debye screening length and the de Broglie wavelength, which takes into account both the quantum mechanical effects of diffraction (short distance) and the collective effects (long distance). With this method, the traditional central-field potential is modified, the bound- and continuum-electron wavefunctions and the collision matrix elements are estimated under a relativistic Dirac–Coulomb framework. The strongly coupled semi-classical plasma effects on the energies, transition rates, and the electron impact ionization cross sections are investigated in detail, using the hydrogen atom as an example. Our results agree well with other available theoretical data. The reported results and the computational scheme are not only of interest to the communities such as atomic and plasma physics, but also have implications for many other areas, including astrophysical objects, inertial confinement fusion plasmas, etc.

Particle-in-cell/Monte Carlo collision simulation on gap breakdown characteristics of under the conditions of hot-electrode and high-temperature gas medium in low-voltage circuit breaker chamber

The gas composition inside the low-voltage circuit breaker (LVCB) chamber and the residual plasma in the post-arc stage affect the breakdown process, which in turn affects the breaking capacity of LVCBs. In this paper, the back-arc breakdown and post-arc re-breakdown phenomena occurring inside the LVCB chamber are categorized as the breakdown in the case of high-temperature gas gap of hot electrodes, for which a particle-in-cell/Monte Carlo collision simulation model has been established, which takes into account the effects of high-temperature gas components, cathode electron thermal emission, electron collision ionization, and other effects, and simulation studies have been conducted. The simulation results show that the gap breakdown is mainly caused by the high-temperature hot free background gas and the cathode thermal electron emission. A plasma sheath layer is formed at the cathode during the breakdown process, and the electric field strength in the sheath layer is higher than that in other regions. With the development of the streamer to the cathode, the thickness of the sheath layer becomes narrower and the electric field strength increases, and finally, a discharge plasma channel is formed in the gap.

High-temperature properties of dry air used as arc quenching medium and its mixture with vaporized C2F4 : reaction products and critical reduced electric field strength at 300–3000 K

Recently, electric power equipment manufacturers released a joint statement with the aim of developing high-voltage electrical equipment completely free of fluorinated gases such as fluoroketones and fluoronitriles, which are considered as alternatives to SF6 and artificially produced compounds of F. This paper considers air as a typical gas present naturally in the environment to investigate its high-temperature properties, including an air mixture with C2F4 vapor injected from a polytetrafluoroethylene nozzle, for application as an arc-quenching medium in a high-voltage circuit breaker equipped with a nozzle. Chemical composition results for the reaction products at 300–3000 K show that the admixture of C2F4 vapor causes a decrease in the molar number of O2 contained in the air, owing to the production of O-containing compounds such as CO2 and CO . Additionally, the results reveal that the admixture of C2F4 vapor lead to the production of CF4 as the predominant F-containing compound. Furthermore, the boundary condition for O2 production in terms of O2 molar number XO2 and C2F4 molar number XC2F4 is formulated. Such evaluation of the mixture composition enables the determination of a reduced effective collision ionization coefficient αˉ/N and a critical reduced electric field strength Ecr/N , resulting in αˉ/N = 0. The strength Ecr/N for the mixture with 30%–100% C2F4 molar fraction rises to approximately 150 Td (1 Td = 1 ×10−21 V m2) over 300–3000 K, which is 20–50 Td higher than that for high-temperature air unmixed with C2F4 vapor. The variation in Ecr/N is discussed in terms of predominant electron impact processes and the electron energy distribution function in the mixture.

A novel optical emission spectroscopy method for diagnostics of contribution of different ionization mechanisms and flux of ions in different valences in discharge channel of a Hall thruster

The mass application of Hall thrusters poses the need for a diagnostic method of ionization mechanism in the discharge channel to boost the iteration and optimization of thruster design. This work presents an Optical Emission Spectroscopy (OES) method for diagnostics of the contribution of different ionization mechanisms and the flux of ions in different valences in the discharge channel of a Hall thruster. The emission spectra in the discharge channel are analyzed by jointly utilizing a collisional-radiative model, an ionization-excitation model, and a flux-conservation model. It is found that the intensities of some spectral lines can be converted into the reaction rates of collision processes, e.g., electron-induced excitation and ionization processes. The latter can further be used to determine the evolutions of particle fluxes by utilizing the conservation law of matter. The novel method is demonstrated on a kilo-watt Hall thruster. The evolutions of several parameters are determined using this method along the discharge channel, including the ionization rates of different mechanisms, particle fluxes, particle densities, and particle velocities. This novel method can be further developed by being jointly utilized with spectral imaging and tomography techniques, enabling diagnostics of multi-dimensional distributions of the above-mentioned parameters in the discharge channel and near-field plume.

Electron transport characteristics in water under electrostrictive effect

The transport characteristics of electrons are crucial for the initiation and development of pulse discharge in water. In this work, we develop a physical model of electron transport that consides elastic and inelastic collision cross sections. The purpose of this study is to investigate frequency variations of elastic collisions, ionization and excitation collisions with different initial electron energy values, and to explore the characteristic of electron energy loss in water. The Monte Carlo method is employed to track structure characteristics of electron transmission and scattering under varying energy values. The results show that the electrons of lower energy (~20 eV) are significantly impacted by the water molecule scattering, hence their transmission capacities are weakened. When the incident energy of electron reaches 100 eV, the scattering deviation distance is roughly equivalent to the transmission depth, about 6–8 nm, and the maximum deviation angle &lt;i&gt;θ&lt;/i&gt;&lt;sub&gt;shift&lt;/sub&gt; ~ 60°. When the electron incident energy is in a range of 10–1000 eV, the number of elastic collisions is much greater than the number of excitation and ionization collisions, and the number of ionization collisions and excitation collisions increases significantly with the increase of electron energy. The higher the electron incident energy, the greater the energy loss is. However, the energy loss decreases sharply with the extension of penetration distance. For the ionization collision, the average ionization energy loss, &lt;i&gt;W&lt;/i&gt;, decreases rapidly with the increase of electron energy, and ultimately maintains at a level of 20–30 eV, which is consistent with the experimental results reported.