Abstract Hydrocarbon dust is one of the dominant components of interstellar dust, which mainly consists of polycyclic aromatic hydrocarbons and aliphatic hydrocarbons. While hydrocarbon dust is thought to be processed in interstellar radiation fields or shocks, detailed processing mechanisms are not completely understood yet. We investigate the processing of hydrocarbon dust by analyzing the relation between the luminosities emitted by hydrocarbon dust and the total infrared luminosities $(L_{\mathrm{IR}})$ for 138 star-forming galaxies at redshift $z \lt 0.3$. Using near-infrared 2.5–5$\, \mu {\rm m}$ spectra obtained with AKARI, we derived the luminosities of the aromatic hydrocarbon feature at 3.3$\, \mu {\rm m}$ ($L_\mathrm{aromatic}$) and the aliphatic hydrocarbon feature at 3.4–3.6$\, \mu {\rm m}$ ($L_\mathrm{aliphatic}$). We also derived $L_\mathrm{IR}$ and the radiation field strength by modeling the spectral energy distributions of the 138 galaxies with AKARI, WISE, and IRAS photometry data. We find that galaxies with higher $L_\mathrm{IR}$ tend to exhibit lower $L_\mathrm{aliphatic}/L_\mathrm{aromatic}$ ratios. Furthermore, we find that there is an anti-correlation between $L_\mathrm{aliphatic}/L_\mathrm{aromatic}$ ratios and the radiation field strength, and also that the galaxies with low $L_\mathrm{aliphatic}/L_\mathrm{aromatic}$ ratios are dominated by merger galaxies. These results support the suggestion that hydrocarbon dust is processed through photodissociation in strong radiation fields and/or shocks during merging processes of galaxies; the $L_\mathrm{aliphatic}/L_\mathrm{aromatic}$ ratio is likely to decrease in such harsh interstellar conditions since the aliphatic bonds are known to be chemically weaker than the aromatic bonds.