Interstellar Medium Research Articles

MALS discovery of a rare H I 21 cm absorber at z ∼ 1.35: Origin of the absorbing gas in powerful active galactic nuclei

We report a new, rare detection of H I 21 cm absorption associated with a quasar (only six quasars are known at 1 < z < 2) toward J2339−5523 at zem = 1.3531, discovered through the MeerKAT Absorption Line Survey (MALS). The absorption profile is broad (∼400 km s−1 ), and the peak is redshifted by ∼200 km s−1 from zem. Interestingly, optical/far-UV spectra of the quasar from the Magellan-MIKE/HST-COS spectrographs do not show any absorption features associated with the 21 cm absorption, despite the coincident presence of the optical quasar and the radio core inferred from a flat-spectrum component with a flux density of ∼65 mJy at high frequencies (> 5 GHz). The simplest explanation would be that no large H I column (N(H I) > 1017 cm−2) is present toward the radio core and the optical active galactic nucleus. Based on the joint optical and radio analysis of a heterogeneous sample of 16 quasars (zmedian = 0.7) and 19 radio galaxies (zmedian = 0.4) with H I 21 cm absorption detection and matched in 1.4 GHz luminosity (L1.4 GHz), a consistent picture emerges according to which quasars primarily trace the gas in the inner circumnuclear disk and cocoon created by the interaction of the jet with interstellar medium. They (i.e., quasars) exhibit a L1.4 GHz – ΔVnull correlation and a frequent mismatch of the radio and optical spectral lines. The radio galaxies show no such correlation and likely trace the gas from the cocoon and the galaxy-wide interstellar medium outside the photoionization cone. The analysis presented here demonstrates the potential of radio spectroscopic observations to reveal the origin of the absorbing gas associated with active galactic nuclei that may be missed in optical observations.

Tracing Prebiotic Molecules: Rotational Spectroscopy of Deuterated Glycolaldehyde and (Z)-1,2-Ethenediol.

Glycolaldehyde, an important prebiotic molecule, along with its monodeuterated species and its higher energy tautomer, (Z)-1,2-ethenediol, has been detected in the interstellar medium. Although the elemental D/H ratio in the universe is only ∼1.6 × 10-5, the deuterium relative abundance in interstellar molecules might be by far larger than this. As such, it provides a remarkable and almost unique diagnostic tool. In particular, it might help elucidate the reaction mechanisms that lead to the formation of the so-called complex organic molecules. It is therefore crucial to extend the census of the interstellar deuterated molecules. To this aim, in this work, we present for the first time a spectroscopic investigation of the rotational spectra of the CHDOD-CHO bideuterated variant of glycolaldehyde and of mono- and bideuterated species of (Z)-1,2-ethenediol (CHOD═CHOD, CHOD═CHOH, and CHOH═CHOD rotamers). For each species, more than a hundred transitions have been assigned. Their analysis led to the accurate determination of all rotational constants as well as quartic and sextic centrifugal distortion terms, thus providing spectroscopic line catalogs suitable for supporting astronomical searches. In addition, the rotational constants of the bideuterated glycolaldehyde isotopologue studied in this work allowed us to improve the semiexperimental equilibrium structure determination for this molecule.

Heating of the interstellar gas by cosmic rays and warm transparent ionized plasma observed by pulsar dispersions

Electron densities in different locations of our galaxy are obtained in pulsar astronomy by dividing the dispersion measure (DM) by the distance of the pulsar to Earth. The properties of the interstellar plasma are related to its heating by cosmic rays. Following the present analysis, DM’s measurements are obtained with different properties of the corresponding plasmas at different temperatures. (1) For relatively low temperatures (around and below 10,000 (K)), the state of molecular, atomic and ionized hydrogen is analyzed by the interstellar medium model with partially ionized plasma. In this region, various spectroscopic effects are obtained. (2) For temperatures above this limit, the interstellar gas is found to be a completely ionized medium, and this plasma is defined as warm ionized medium (WIM) plasma. We show in the first part of the paper that this plasma is transparent, as obtained from the solution of Saha’s equation. The index of refraction of the WIM plasma is real, but the plasma can be observed by dispersion measurements. (3) For very high temperatures (around 1 million (K)), the plasma is defined as hot ionized medium, where X-rays are obtained. We concentrate in the present work on the analysis of WIM plasma. We calculate the mass densities of this plasma and compare it with dark matter mass densities, which are found to be larger. But some factors which may reduce this difference are discussed.

Proton Transfer Processes in 2-Butenenitrile Dimer Cation Studied by Mass-Selective Infrared Spectroscopy.

2-Butenenitrile (2-Bu) is a recently discovered crucial interstellar molecule. Herein, an abnormal NH band was observed in the infrared spectrum of the 2-Bu dimer cation, suggestive of a proton transfer reaction within the cluster. Through a comprehensive theoretical analysis of the IR spectrum of (2-Bu)2+, we discovered not only the formation of a new C-N bond through the attachment of one 2-Bu to another but also the occurrence of a proton transfer reaction in the cluster. This proton was identified as originating from the methyl group of the attaching 2-Bu in the cluster based on the analysis of IR spectra of (2-Bu)+ and [2-Bu-acrylonitrile (AN)]+. Furthermore, the detailed reaction process of this ion-molecule reaction is examined with theoretical calculation. This finding contributes significantly to our deeper understanding of ion-molecule reactions in the gas phase and the formation of nitrogen-containing prebiotic molecules in the interstellar medium.

Investigating H-atom reactions in small PAHs with imperfect aromaticity: A combined experimental and computational study of indene (C9H8) and indane (C9H10).

Polycyclic aromatic hydrocarbons (PAHs) are widely recognized as catalysts for interstellar H2 formation. Extensive exploration into the catalytic potential of various PAHs has encompassed both theoretical investigations and experimental studies. In the present study, we focused on studying the reactivity of an imperfect aromatic molecule, indene (C9H8), and its hydrogenated counterpart, indane (C9H10), as potential catalysts for H2 formation within the interstellar medium. The reactions of these molecules with H atoms at 3.1K were investigated experimentally using the para-H2 matrix isolation technique. Our experimental results demonstrate that both indene and indane are reactive toward H atoms. Indene can participate in H-atom-abstraction and H-atom-addition reactions, whereas indane primarily undergoes H-atom-abstraction reactions. The H-atom-abstraction reaction of indene results in the formation of the 1-indenyl radical (R1) (C9H7) and H2molecule. Simultaneously, an H-atom-addition reaction forms the 1,2-dihydro-indene-3-yl radical (R2) (C9H9). Experiments also reveal that the H-atom-abstraction reaction of indane also produces the R2 radical. To the best of our knowledge, this study represents the first reporting of the infrared spectra of R1 and R2 radicals. The experimental results, combined with theoretical findings, suggest that indane and indene may play a role in the catalytic formation of interstellar H2. Furthermore, these results imply a quasi-equilibrium between the investigated molecules and the formed radicals via H-atom-addition and H-atom-abstraction reactions.

Hierarchical hub-filament structures and gas inflows on galaxy-cloud scales

Abstract We investigated the kinematics and dynamics of gas structures on galaxy-cloud scales in two spiral galaxies NGC5236 (M83) and NGC4321 (M100) using CO (2–1) line. We utilized the FILFINDER algorithm on integrated intensity maps for the identification of filaments in two galaxies. Clear fluctuations in velocity and density were observed along these filaments, enabling the fitting of velocity gradients around intensity peaks. The variations in velocity gradient across different scales suggest a gradual and consistent increase in velocity gradient from large to small scales, indicative of gravitational collapse, something also revealed by the correlation between velocity dispersion and column density of gas structures. Gas structures at different scales in the galaxy may be organized into hierarchical systems through gravitational coupling. All the features of gas kinematics on galaxy-cloud scale are very similar to that on cloud-clump and clump-core scales studied in previous works. Thus, the interstellar medium from galaxy to dense core scales presents multi-scale/hierarchical hub-filament structures. Like dense core as the hub in clump, clump as the hub in molecular cloud, now we verify that cloud or cloud complex can be the hub in spiral galaxies. Although the scaling relations and the measured velocity gradients support the gravitational collapse of gas structures on galaxy-cloud scales, the collapse is much slower than a pure free-fall gravitational collapse.

Observation of HI around three satellite galaxies of the M31 with the FAST: Andromeda II, NGC 205, and NGC 185

Abstract With the exceptional sensitivity of the Five-hundred-meter Aperture Spherical radio Telescope (FAST), we conducted observations of the neutral hydrogen (HI) in the Circular Galactical Medium (CGM) of Andromeda's (M31) satellite galaxies, specifically Andromeda II, NGC 205, and NGC 185. Initially, three drift scans were executed for these satellites, with a detection limit of 4×10^18 cm/s ( approximately 1.88×10^3 M_sun of HI mass), followed by a more in-depth scan of a specific region. We discovered a C-shaped HI arc structure sharing a position and line-of-sight velocity similar to a stellar ring structure around Andromeda II, hinting at a potential connection with Andromeda II. In the context of NGC 205, we identified two mass concentrations in the northeast direction, which could be indicative of tidal streams resulting from the interaction between this galaxy and M31. These new lumps discovered could be very helpful in solving the missing interstellar medium (ISM) problem for NGC 205. Observations regarding NGC 185 are consistent with previous studies, and we did not detect any additional HI material around this galaxy. These observational results enhance our understanding of the evolution of these satellite galaxies and provide insight into their historical interactions with the M31 galaxy.

Revisiting the abundance pattern and charge-exchange emission in the centre of M 82

Context. The interstellar medium (ISM) in starburst galaxies contains many chemical elements that are synthesised by core-collapse supernova explosions. By measuring the abundances of these metals, we can study the chemical enrichment within the galaxies and the transportation of metals into the circumgalactic environment through powerful outflows. Aims. We performed a spectral analysis of the X-ray emissions from the core of M 82 using the Reflection Grating Spectrometer (RGS) on board XMM-Newton to accurately estimate the metal abundances in the ISM. Methods. We analysed over 300 ks of RGS data observed with 14 position angles, covering a cross-dispersion width of 80 arcsec. We employed multi-temperature thermal plasma components in collisional ionisation equilibrium (CIE) to reproduce the observed spectra, each of which exhibited a different spatial broadening. Results. The O VII band CCD image shows a broader distribution that those for the O VIII and Fe-L bands. The O VIII line profiles have a prominent double-peaked structure that corresponds to the north- and southward outflows. The O VII triplet feature exhibits marginal peaks. A single CIE component that is convolved with the O VII band image approximately reproduces the spectral shape. A CIE model combined with a charge-exchange emission model also successfully reproduces the O VII line profiles. However, the ratio of these two components varies significantly with the observed position angles, which is physically implausible. Spectral fitting of the broadband spectra suggests a multi-temperature phase in the ISM that is approximated by three components at 0.1, 0.4, and 0.7 keV. Notably, the 0.1 keV component exhibits a broader distribution than the 0.4 and 0.7 keV plasmas. The derived abundance pattern shows super-solar N/O, solar Ne/O and Mg/O, and half-solar Fe/O ratios. These results indicate the chemical enrichment by core-collapse supernovae in starburst galaxies.

PHANGS-ML: Dissecting Multiphase Gas and Dust in Nearby Galaxies Using Machine Learning

The PHANGS survey uses Atacama Large Millimeter/submillimeter Array, Hubble Space Telescope, Very Large Telescope, and JWST to obtain an unprecedented high-resolution view of nearby galaxies, covering millions of spatially independent regions. The high dimensionality of such a diverse multiwavelength data set makes it challenging to identify new trends, particularly when they connect observables from different wavelengths. Here, we use unsupervised machine-learning algorithms to mine this information-rich data set to identify novel patterns. We focus on three of the PHANGS-JWST galaxies, for which we extract properties pertaining to their stellar populations; warm ionized and cold molecular gas; and polycyclic aromatic hydrocarbons (PAHs), as measured over 150 pc scale regions. We show that we can divide the regions into groups with distinct multiphase gas and PAH properties. In the process, we identify previously unknown galaxy-wide correlations between PAH band and optical line ratios and use our identified groups to interpret them. The correlations we measure can be naturally explained in a scenario where the PAHs and the ionized gas are exposed to different parts of the same radiation field that varies spatially across the galaxies. This scenario has several implications for nearby galaxies: (i) The uniform PAH ionized fraction on 150 pc scales suggests significant self-regulation in the interstellar medium, (ii) the PAH 11.3/7.7 μm band ratio may be used to constrain the shape of the non-ionizing far-ultraviolet to optical part of the radiation field, and (iii) the varying radiation field affects line ratios that are commonly used as PAH size diagnostics. Neglecting this effect leads to incorrect or biased PAH sizes.

Interstellar meteors from the tidal disruption of rocky planets on eccentric orbits around M dwarfs

Context. Low-mass stars appear to frequently host planetary systems. When these rocky planets develop high eccentricities as a result of secular torques or dynamical scatterings, they occasionally pass close to the host star. In these close passages, the planets can be tidally disrupted, and sheared into bound and unbound debris tails. To suffer such a disruption, the stellar density must be higher than the planetary density. Aims. This condition is met for the most common star and planet systems, M dwarf stars hosting rocky planets. We describe the dynamics of a tidal disruption, and estimate the typical velocities of unbound ejecta. Methods. We simulate the gas dynamics of a planetary tidal disruption, and show that disruptions preserve the layered structure of a rocky body, with the outermost layers flung into interstellar space with the highest velocities. Results. We compare these properties to those of the candidate interstellar meteoroid CNEOS-2014-01-08 (IM1). IM1's approximately 60 km s−1 excess speed relative to the local standard of rest is naturally reproduced by the unbound debris of the disruption of an Earth-like planet around an M dwarf star. We suggest that such an encounter might explain the interstellar kinematics of IM1, and its unusual composition, especially if it originated in the fastest-expelled crust of a differentiated rocky planet. Finally, we estimate that the disruption of ~10 M⊕ reservoirs of rocky planets per M dwarf are needed to reproduce the inferred rate of IM1-like objects.

Multiwavelength study of the HII region LHA 120-N11 in the Large Magellanic Cloud with eROSITA

Aims. We studied the diffuse X-ray emission around the HII region LHA 120-N11, which is one of the most active star-forming regions in the Large Magellanic Cloud. We want to determine the nature of the diffuse X-ray emission and improve our understanding of its origin including related interactions with the cold interstellar medium. Methods. We analyzed the diffuse X-ray emission observed with the extended Roentgen Survey with an Imaging Telescope Array (eROSITA) on the Spectrum-Roentgen-Gamma mission to determine the physical properties of the hot diffuse X-ray emission. Four spectral extraction regions were defined based on the morphology of the X-ray emission. We also studied HI and CO data, as well as Hα line emission in the optical, and compared them with the properties of the diffuse X-ray emission. Results. The X-ray emission in the four regions is well fitted with an absorbed model consisting of thermal plasma models (vapec) yielding temperatures of kT = ~0.2 keV and kT = 0.8–1.0 keV. The comparison of the X-ray absorption column density and the hydrogen column density shows that the X-ray dark lane located north of N11 is apparently caused by the absorption by HI and CO clouds. By estimating the energy budget of the thermal plasma, we also investigated the heating mechanism of the X-ray emitting plasma. The energy of the diffuse X-ray emission in the superbubble which is a star-forming bubble with a radius of ~120 pc including OB associations LH9, LH10, LH11, and LH13 can be explained by heating from high-mass stars. In the surrounding regions we find that the energy implied by the X-ray emission suggests that additional heating might have been caused by shocks generated by cloud–cloud collisions.

Mass and wind luminosity of young Galactic open clusters in Gaia DR2

Context. Star clusters constitute a significant part of the stellar population in our Galaxy. The feedback processes they exert on the interstellar medium impact multiple physical processes from the chemical to the dynamical evolution of the Galaxy. In addition, young and massive stellar clusters might act as efficient particle accelerators and contribute to the production of cosmic rays. Aims. We aim at evaluating the wind luminosity driven by the young (< 30 Myr) Galactic open stellar clusters observed by the Gaia space mission. This is crucial for determining the energy channeled into accelerated particles. Methods. To do this, we developed a method relying on the number, magnitude, and line-of-sight extinction of the stars observed per cluster. Assuming that the stellar mass function follows a Kroupa mass distribution and accounting for the maximum stellar mass allowed by the age and mass of the parent cluster, we conservatively estimated the mass and wind luminosity of 387 local clusters within the second data release of Gaia. Results. We compared the results of our computation with recent estimates of young cluster masses. With respect to these, our sample is three times more abundant, particularly above a few thousand solar masses. This is of the utmost relevance for predicting the gamma-ray emission resulting from the interaction of accelerated particles. The cluster wind luminosity distribution we obtained extends up to 3 × 1038 erg s−1. This is a promising feature in terms of potential particle acceleration scenarios.

Extended measurements and calculations of CH3C14N-N2 rotational lineshape parameters

Spectroscopic parameters of methyl cyanide are of interest for astrophysical applications because of presence of this molecule in planetary atmospheres, comets, and interstellar medium. For radiative-transfer modeling a key role is played by the pressure-induced linewidths which are strongly influenced by the collision partner and the temperature. To complete the extremely scarce experimental data available, rotational lines of room-temperature CH3C14N in collision with molecular nitrogen have been recorded in a very large (180–1400 GHz) frequency range for J = 9 → 10, 12 → 13, 15 → 16, 21 → 22, 27 → 28, 33 → 34, 42 → 43, 48 → 49, 63 → 64, 69 → 70, 75 → 76 and K = 0–15. The high sensitivity of the frequency-modulated spectrometer has enabled observation of clear deviations of the recorded lineshapes from the usual Voigt profile. Their additional analyses performed with advanced non-Voigt models have demonstrated that the observed lineshapes are mainly governed by the speed dependence of relaxation rates and that the optical diffusion related to velocity changing collisions (Dicke effect) has a nearly negligible role. Compared to infrared-region results available in the literature, our Voigt-profile values lie systematically lower by about 0.5 MHz/Torr, which argues in favor of observable vibrational dependence for the CH3CN-N2 system. Line-broadening parameters have been also evaluated by a semi-empirical method based on the Anderson-Tsao-Curnutte theory. The model parameters determined from fits on some selected experimental values confirm the tendences previously stated for the case of vibrotational transitions and allow better theoretical predictions for extended ranges of rotational quantum numbers. Being temperature-independent, these parameters can be directly used in calculations for other temperatures concerned by radiative transfer models.

The High-Redshift Gas-Phase Mass–Metallicity Relation in FIRE-2

The unprecedented infrared spectroscopic capabilities of JWST have provided high-quality interstellar medium metallicity measurements and enabled characterization of the gas-phase mass–metallicity relation (MZR) for galaxies at z ≳ 5 for the first time. We analyze the gas-phase MZR and its evolution in a high-redshift suite of FIRE-2 cosmological zoom-in simulations at z = 5–12 and for stellar masses M * ∼ 106–1010 M ⊙. These simulations implement a multichannel stellar feedback model and produce broadly realistic galaxy properties, including when evolved to z = 0. The simulations predict very weak redshift evolution of the MZR over the redshift range studied, with the normalization of the MZR increasing by less than 0.01 dex as redshift decreases from z = 12 to z = 5. The median MZR in the simulations is well approximated as a constant power-law relation across this redshift range given by log(Z/Z⊙)=0.37log(M*/M⊙)−4.3 . We find good agreement between our best-fit model and recent observations made by JWST at high redshift. The weak evolution of the MZR at z > 5 contrasts with the evolution at z ≲ 3, where increasing normalization of the MZR with decreasing redshift is observed and predicted by most models. The FIRE-2 simulations predict increasing scatter in the gas-phase MZR with decreasing stellar mass, in qualitative agreement with some observations.

The hot circumgalactic media of massive cluster satellites in the TNG-Cluster simulation: Existence and detectability

The most massive galaxy clusters in the Universe host tens to hundreds of massive satellite galaxies M⋆ ∼ 1010 − 12.5 M⊙, but it is unclear if these satellites are able to retain their own gaseous atmospheres. We analyze the evolution of ≈90 000 satellites of stellar mass ∼109 − 12.5 M⊙ around 352 galaxy clusters of mass M200c ∼ 1014.3 − 15.4 M⊙ at z = 0 from the new TNG-Cluster suite of cosmological magneto-hydrodynamical galaxy cluster simulations. The number of massive satellites per host increases with host mass, and the mass–richness relation broadly agrees with observations. A halo of mass M200chost ∼ 1014.5(1015) M⊙ hosts ∼100 (300) satellites today. Only a minority of satellites retain some gas, hot or cold, and this fraction increases with stellar mass. lower-mass satellites ∼109 − 10 M⊙ are more likely to retain part of their cold interstellar medium, consistent with ram pressure preferentially removing hot extended gas first. At higher stellar masses ∼1010.5 − 12.5 M⊙, the fraction of gas-rich satellites increases to unity, and nearly all satellites retain a sizeable portion of their hot, spatially extended circumgalactic medium (CGM), despite the ejective activity of their supermassive black holes. According to TNG-Cluster, the CGM of these gaseous satellites can be seen in soft X-ray emission (0.5−2.0 keV) that is, ≳10 times brighter than the local background. This X-ray surface brightness excess around satellites extends to ≈30 − 100 kpc, and is strongest for galaxies with higher stellar masses and larger host-centric distances. Approximately 10% of the soft X-ray emission in cluster outskirts ≈0.75 − 1.5 R200c originates from satellites. The CGM of member galaxies reflects the dynamics of cluster-satellite interactions and contributes to the observationally inferred properties of the intracluster medium.

Turbulent circumnuclear disc and cold gas outflow in the newborn radio source 4C 31.04

We present deep kiloparsec- and parsec-scale neutral atomic hydrogen ( absorption observations of a very young radio source ($ 5000$ years) using the Westerbork Synthesis Radio Telescope (WSRT) and the Global Very Long Baseline Interferometry (VLBI) array. Using $z=0.0598$, derived from molecular gas observations, we detect, at both kpc and pc scales, a broad absorption feature (FWZI $= 360$ centred at the systemic velocity, and narrow absorption (FWZI $= 6.6$ redshifted by 220 both previously observed. Additionally, we detect a new blueshifted, broad, shallow absorption wing. At pc scales, the broad absorption at the systemic velocity is detected across the entire radio source while the shallow wing is only seen against part of the eastern lobe. The gas has higher column density along the eastern lobe than along the western one. The velocity dispersion of the gas is high ($ along the entire radio continuum, and is highest ($ in the region including the outflow and the radio hot spot. While we detect a velocity gradient along the western lobe and parts of the eastern lobe at PA most of the gas along the rest of the eastern lobe exhibits no signs of rotation. Earlier optical spectroscopy suggests that the optical AGN is very weak. We therefore conclude that the radio lobes of are expanding into a circumnuclear disc, partially disrupting it and making the gas highly turbulent. The distribution of gas is predominantly smooth at the spatial resolution of 4 pc studied here. However, clumps of gas are also present, particularly along the eastern lobe. This lobe appears to be strongly interacting with the clouds and driving an outflow 35 pc from the radio core, with a mass-outflow rate of $0.3 M year . It is likely that this interaction has caused the eastern lobe to be rebrightened, giving the source an asymmetric morphology. We compare our observations with the predictions of a recent analytical model regarding the survival of atomic gas clouds in radio-jet-driven outflows and find that the existence of a subkpc-scale outflow in this case could imply inefficient mixing of the cold gas with the hot medium and high gas density, leading to very short cooling times. Overall, our study provides further evidence of the strong impact of radio jets on the cold interstellar medium (ISM) in the early stages of their evolution and supports the predictions of numerical simulations regarding jet--ISM interactions and the nature of the circumnuclear gas into which the jets expand.

Radiative and mechanical energies in galaxies. I. Contributions of molecular shocks and PDRs in 3C 326 N

Atomic and molecular lines emitted from galaxies are fundamental tracers of the medium responsible for the emission and contain valuable information regarding the energy budget and the strength of the different feedback mechanisms. The goal of this work is to provide a new framework for the interpretation of atomic and molecular lines originating from extragalactic sources and a robust method to deduce the mechanical and radiative energy budget from a set of observations. Atomic and molecular lines detected in a given object are assumed to result from the combination of distributions of shocks and photo-dissociation regions (PDRs) within the observational beam. The emission of individual structures is computed using the Paris-Durham shock code and the Meudon PDR code over a wide range of parameters. The total emission is then calculated assuming probability distribution functions for shocks and PDRs. A distance between the observational dataset and the model is finally defined based on the ratios of the observed to the predicted intensities. As a test case scenario, we consider the radio galaxy 3C 326 N. The dataset is composed of 12 rotational and ro-vibrational lines of and the fine structure lines of C$^+$ and O. Our interpretative framework shows that both shocks and PDRs are required to explain the line fluxes. Surprisingly, viable solutions are obtained at low density only ($ n_H < 100 $), indicating that most of the emission originates from diffuse interstellar matter. The optimal solution, obtained for $ n_H = 10 $, corresponds to a distribution of low-velocity shocks (between $5$ and $20$ km s$^ $) propagating in PDR environments illuminated by a UV radiation field ten times larger than that in the solar neighborhood. This solution implies that at least 4<!PCT!> of the total mass carried by the PDRs is shocked. The 0-0 S(0) $28 CII and OI lines originate from the PDR components, while all the other lines are mostly emitted by shocks. The total solid angles sustained by PDRs and shocks imply that the radiative and mechanical energies reprocessed by these structures are $ L UV L_ odot $ and $ L K L_ odot $, respectively, in remarkable agreement with the values of the IR luminosity deduced from the fit of the spectral energy distribution (SED) of 3C 326 N, and consistent with a small fraction of the active galactic nuclei (AGN) jet kinetic power dissipated in the interstellar medium ($ 1$<!PCT!>). This work shows that the radiative and mechanical energy budget of galaxies can be derived from the sole observations of atomic and molecular lines. It reveals the unexpected importance of the diffuse medium for 3C 326 N, in contrast to previous studies. A last-minute comparison of the model to new JWST data obtained in 3C 326 N shows a striking agreement and demonstrates the ability of the model to make accurate predictions. This framework opens new prospects for the prediction and interpretation of extragalactic observations, in particular in the context of JWST observations.

Molecular isotopologue measurements toward super star clusters and the relation to their ages in NGC 253 with ALCHEMI

Context. Determining the evolution of the CNO isotopes in the interstellar medium (ISM) of starburst galaxies can yield important constraints on the ages of super star clusters (SSCs), or on other aspects and factors contributing to their evolution, such as the initial mass function (IMF). Due to the time-dependent nature of the abundances of isotopes within the ISM – as they are supplied from processes such as nucleosynthesis or chemical fractionation –, this provides the opportunity to test whether or not isotope ratios trace the ages of highly star-forming regions, such as SSCs. Aims. The goal of this study is to investigate whether the isotopic variations in SSC regions within NGC 253 are correlated with their different ages as derived from stellar population modelling. Methods. We measured abundance ratios of CO, HCN, and HCO+ isotopologues in six regions containing SSCs within NGC 253 using high-spatial-resolution (1.6″, ∼28 pc) data from the ALCHEMI (ALma Comprehensive High-resolution Extragalactic Molecular Inventory) ALMA Large program. We then analysed these ratios using RADEX radiative transfer modelling, with the parameter space sampled using the nested sampling Monte Carlo algorithm MLFriends. These abundance ratios were then compared to ages predicted in each region via the fitting of observed star-formation tracers (such as Brγ) to Starburst99 starburst stellar population evolution models. Results. We determined the isotopic column density ratios across multiple regions of SSC activity in NGC 253 using non-LTE radiative transfer modelling. We do not find any significant trend with age for the CO and HCN isotopologue ratios on timescales of the ages of the SSC* regions observed. However, HCO+ may show a correlation with age over these timescales in 12C/13C. Conclusions. The driving factors of these ratios within SSCs could be the IMF or fractionation effects. To further probe these effects in SSCs over time, a larger sample of SSCs must be observed spanning a larger age range.

Detection and quantification of organosulfur species in the Tagish Lake Meteorite by highly sensitive LC‐MS

AbstractWe analyzed the methanol extracts of six pristine specimens of the Tagish Lake meteorite (TL1, TL4, TL5A, TL6, TL7, and TL10a) and heated and unheated samples of Allende using high‐performance liquid chromatography coupled with high‐resolution, accurate mass–mass spectrometry (HPLC‐HRAM‐MS). All samples contained ppm levels of sulfate and methyl sulfate. The most abundant organosulfur compound in the methanol extracts of the Tagish Lake and Allende samples was methyl sulfate, which was likely formed primarily via an esterification reaction between intrinsic sources of methanol and sulfate. A homologous series of polythionic acids was also observed in the extracts of the Tagish Lake specimens and Allende. The polythionic acids were the most abundant soluble inorganic sulfur species found in the meteorites. Our results were confirmed using retention time, accurate mass, isotope matching, and tandem mass spectrometry (MS/MS). Hydroxymethanesulfonic acid, previously reported in Tagish Lake, was found only in an unheated Allende sample and in low abundance. Here, we propose possible sulfate formation pathways that begin with interstellar dimethyl sulfide, dimethyl disulfide, methyl sulfide, or methanethiol via cold, nebular processes within the interstellar medium and continue via MSA as an intermediary compound ending within planetary bodies with sulfate and methyl sulfate as the final products.

A new analytical model of the cosmic-ray energy flux for Galactic diffuse radio emission

Low-frequency radio observations of diffuse synchrotron radiation offer a unique vantage point from which to investigate the intricate relationship between gas and magnetic fields in the formation of structures within the Galaxy, spanning from the diffuse interstellar medium (ISM) to star-forming regions. Achieving this pivotal objective hinges on a comprehensive understanding of cosmic-ray properties; these dictate the effective energy distribution of relativistic electrons, which are primarily responsible for the observable synchrotron radiation. Notably, cosmic-ray electrons (CRe) with energies of between 100 MeV and 10 GeV play a crucial role in determining the majority of the sky brightness below the GHz range. However, their energy flux (je) remains elusive because of solar modulation. We propose a way to derive observational constraints on this energy gap of interstellar CRe through the brightness temperature spectral index of low-frequency radio emission, here denoted βobs. We introduce a new parametric analytical model that fits available data for je in accordance with the βobs values measured in the literature between 50 MHz and 1 GHz for diffuse emission in the Milky Way. Our model accounts for multiple observations considering magnetic-field strengths consistent with existing measurements below 10 μG. We present a first all-sky map of the average component of the magnetic field perpendicular to the line of sight and validate our methodology against state-of-the art numerical simulations of the diffuse ISM. This research makes headway in modeling Galactic diffuse emission with a practical, parametric form. It provides essential insights that will help preparations for the imminent arrival of the Square Kilometre Array.