Interplanetary Dust Particles Research Articles

Investigation of lunar ejecta dynamics: Particles reaching the near-Earth space and their effect on Earth-based observation

Particles ejected from the lunar surface via hypervelocity impacts form a torus between the Earth and the Moon. According to our previous study, about $2.3 kg/s $ particles impact the Earth after long-term orbital evolution. We mainly focus on these Earth impactors, analyze their orbital element distribution, and estimate their influence on Earth-based observations. In previous work we simulated the long-term orbital evolution of particles ejected from the lunar surface, and obtained their steady-state spatial distribution in the Earth--Moon system. For this work we analyzed the simulation results for the Earth impactors, including the fraction of impactors with different initial parameters among all impactors, the orbital element distribution, and the projection of particles onto several Earth-based observatories. Particles ejected from the lunar surface are more likely to impact the Earth within a certain range of initial parameters. Most of these lunar-ejected impactors ($ reach the Earth within one year, while most of the small ones ($87.2<!PCT!>$ of $0.2\ m $ particles and $64.6<!PCT!>$ of $0.5\ m $ particles) reach the Earth within one week. A large proportion of lunar-ejected Earth impactors can be distinguished from interplanetary dust particles according to the differences in their orbital distributions. In addition, lunar-ejected particles may exhibit distinct configurations and orientations from the perspectives of different Earth-based observatories.

Multi-station Meteor Monitoring (M3) System. II. System Upgrade and a Pathfinder Network

Meteors are important phenomena reflecting many properties of interplanetary dust particles. The study of their origin, mass distribution, and orbit evolution requires a large data volume, which can only be obtained using large meteor networks. After meteor networks in Europe and America, we present our designs and upgrades of a proposed network in China. The new designs are mainly aimed at facilitating the data gathering process. Each of the newly designed meteor stations can now support up to four cameras to cover the full sky. A newer version of the meteor station software now works as an integral system, which can streamline the process of detecting, measuring, and uploading meteors. We have built a meteor data platform to store, process, and display the meteor data automatically. The software and data platform are designed to be easy to learn and use, so they can attract more people to join and operate meteor stations. Four stations are installed as the first phase of the network, and during the operation, in 10 months, the network detected 8683 orbits; we find that half of the orbits can be related to established meteoroid streams. The statistical analysis of sporadic meteoroids shows a bimodal distribution of the velocities, which coincides with previous studies. The distribution of Tisserand parameters, T j , shows the two peaks at T j = 0 and 3, indicating the different orbits of parent bodies (isotropic and ecliptic), which are divided by T j = 2. The falling trajectory of a meteorite was also predicted using the observational data of the network. We are currently expanding the network, and in the future, we will carry out a detailed analysis of the key parameters of the distribution of the meteoroids.

Capture and tracing interstellar and interplanetary dust particles through the China Space Station

Capture and tracing interstellar and interplanetary dust particles through the China Space Station

Isotopic fractionation of methane on Mars via diffusive separation in the subsurface

Many processes have been identified in the Martian subsurface which may produce or release methane that eventually can be emitted into the atmosphere. Given the wide range of isotopic values for source carbon reported on Mars and the importance of atmospheric methane isotopologues as a tracer for subsurface processes, it is critical to quantify the level of isotopic fractionation that can occur during subsurface transport. On Earth, isotopic fractionation occurs when methane transport is dominated by Knudsen diffusion through small pores. However, unlike the Earth, on Mars the low atmospheric pressure and commensurate longer mean free path suggest that most subsurface transport of methane occurs in the Knudsen regime, amplifying this effect. Here, we report on simulations of diffusion through the martian subsurface and report on the level of fractionation that would be expected under two end-member scenarios. For Interplanetary Dust Particles (IDPs) incorporated in near-surface sediments in which methane is released quickly upon generation, atmospheric emissions of methane are expected to be representative of the reservoir isotopic ratio. However, for deeper sources in which methane accumulates as trapped gas, subsurface transport will result in depletions of 13CH4 compared to reservoir concentrations by approximately −31‰. Over time, both the reservoir and the emitted gas will evolve to become isotopically enriched in 13CH4 compared to a standard of constant isotopic ratio. This necessitates temporal measurements of emitted methane to understand the δ13C of the reservoir and depth of the release, preferably with hourly or better frequency. Finally, a seasonal cycle in δ13C with an amplitude of 5.3‰ is expected with adsorption acting to create small temporary reservoirs that are filled and emptied over the year by the subsurface thermal wave. This effect may provide a way to probe near-surface thermophysical properties.

Self-Oxidation of the Atmospheres of Rocky Planets with Implications for the Origin of Life.

Rocky planets may acquire a primordial atmosphere by the outgassing of volatiles from their magma ocean. The distribution of O between H2O, CO, and CO2 in chemical equilibrium subsequently changes significantly with decreasing temperature. We consider here two chemical models: one where CH4 and NH3 are assumed to be irrevocably destroyed by photolysis and second where these molecules persist. In the first case, we show that CO cannot coexist with H2O, since CO oxidizes at low temperatures to form CO2 and H2. In both cases, H escapes from the thermosphere within a few 10 million years by absorption of stellar XUV radiation. This escape drives an atmospheric self-oxidation process, whereby rocky planet atmospheres become dominated by CO2 and H2O regardless of their initial oxidation state at outgassing. HCN is considered a potential precursor of prebiotic compounds and RNA. Oxidizing atmospheres are inefficient at producing HCN by lightning. Alternatively, we have demonstrated that lightning-produced NO, which dissolves as nitrate in oceans, and interplanetary dust particles may be the main sources of fixed nitrogen in emerging biospheres. Our results highlight the need for origin-of-life scenarios where the first metabolism fixes its C from CO2, rather than from HCN and CO.

Petrographic and chemical characterization and carbon and nitrogen isotopic compositions of cometary IDPs and their GEMS amorphous silicates

GEMS (glass with embedded metal and sulfides) are the dominant carrier of amorphous silicates in anhydrous interplanetary dust particles (IDPs) and one of the most suitable materials to study early solar system processes. Amorphous silicates in 105 GEMS from eight IDPs were analyzed regarding texture and chemical composition to reassess GEMS formation theories and genetic relationships to amorphous silicate material in meteorites. Petrography of bulk IDPs was investigated to understand GEMS’ relationships to other IDP components. Furthermore, carbon and nitrogen isotopic compositions were measured. Nearly all GEMS are aggregates of several subgrains with variable amount of nanophase inclusions and different Mg- and Si-contents, while single GEMS are rare. The subgrains within aggregates are typically surrounded by one or more carbon rims with high density. The chemical compositions of GEMS amorphous silicates are subsolar for all major element/Si ratios but exhibit wide heterogeneity. This is not influenced by silicon oil from the capturing process of IDPs as assumed before, as a penetration of the silicon oil is excluded by high resolution EELS (electron energy loss spectroscopy) areal density maps of silicon. Furthermore, low Fe-content in GEMS amorphous silicates shows that these are not altered by aqueous activity on the parent body as it is the case for amorphous silicate material in primitive meteorites. The subsolar element/Si ratios and the wide chemical heterogeneity point to a non-equilibrium fractional condensation origin either in the early solar nebula or in a circumstellar environment and are not in agreement with homogenization via sputtering in the ISM. The close association with carbon around GEMS subgrains and as double-rims around GEMS aggregates argue for a multi-step aggregation after formation of the smallest GEMS subgrains in the ISM or the early solar nebula. Carbon acting as matrix material connecting GEMS and other IDP components has lower areal density as seen from carbon EELS areal density maps and isotopic anomalies varying at the nanometer scale, pointing to different origins and processing of materials to varying extent or at changing temperatures.To balance GEMS’ subsolar element/Si ratios, a supersolar component in IDPs was assumed to account for the overall chondritic composition of bulk IDPs. Nevertheless, our bulk IDP analyses revealed subsolar, but variable, element/Si ratios for complete particles as well, depending on type and amount of mineral phases in each particle. Pyroxenes in the investigated particles can occur as elongated euhedral crystals, but are overall rare. The dominant crystalline fraction in the investigated IDP samples are equilibrated aggregates (EAs) that show the same chemical compositions as GEMS, indicating that the EAs are recrystallized GEMS grains and formed after GEMS formation as secondary phases.

Are Clay Minerals Systematically the Products of Aqueous Alteration in Cosmic Bodies?

The formation of chondrite materials represents one of the earliest mineralogical processes in the solar system. Phyllosilicates are encountered at various stages of the chondrule formation, from the initial stages (IDP agglomerates) to the final steps (chondrule internal alteration). While typically linked to aqueous alteration, recent studies reveal that phyllosilicates could precipitate directly from residual fluids in post-magmatic or deuteric conditions and under a wide range of temperatures, pressures, water/rock ratios, and H2/H2O ratio conditions. This study re-examined the formation of hydrated phyllosilicates in chondrules and associated fine-grained rims (FGRs) using published petrographical, mineralogical, and chemical data on carbonaceous chondrites. Given that chondrules originate from the melting of interplanetary dust particles, the water liberated by the devolatilization of primary phyllosilicates, including clay minerals or ice melting, reduces the melting temperature and leads to water dissolution into the silicate melt. Anhydrous minerals (e.g., olivine and diopside) form first, while volatile and incompatible components are concentrated in the residual liquid, diffusing into the matrix and forming less porous FGRs. Serpentine and cronstedtite are the products of thermal metamorphic-like mineral reactions. The mesostasis in some lobated chondrules is composed of anhydrous and hydrous minerals, i.e., diopside and serpentine. The latter is probably not the alteration product of a glassy precursor but rather a symplectite component (concomitant crystallization of diopside and serpentine). If so, the symplectite has been formed at the end of the cooling process (eutectic-like petrographical features). Water trapped inside chondrule porosity can lead to the local replacement of olivine by serpentine without external water input (auto-alteration). In the absence of water, hydrated phyllosilicates do not crystallize, forming a different mineral assemblage.

Exogenous Carbon is Unlikely to be the Source of Methane Microseepage Emissions on Mars

A complete understanding of methane in the atmosphere of Mars requires information on putative sources. Organic carbon derived from meteoritic sources, such as interplanetary dust particles (IDPs), over geologic time is the best-defined source of organic carbon on the surface of Mars. Here we examine two different mechanisms for degrading this material to produce methane (1) Ultraviolet photolysis and (2) thermal decomposition. Neither of these mechanisms can produce sufficient methane under realistic assumptions to explain observed methane at Gale Crater, suggesting that IDPs are not the primary source material producing methane on Mars.

YOLO-ET: A Machine Learning model for detecting, localising and classifying anthropogenic contaminants and extraterrestrial microparticles optimised for mobile processing systems

Imminent robotic and human activities on the Moon and other planetary bodies would benefit from advanced in situ Computer Vision and Machine Learning capabilities to identify and quantify microparticle terrestrial contaminants, lunar regolith disturbances, the flux of interplanetary dust particles, possible interstellar dust, β-meteoroids, and secondary impact ejecta. The YOLO-ET (ExtraTerrestrial) algorithm, an innovation in this field, fine-tunes Tiny-YOLO to specifically address these challenges. Designed for coreML model transference to mobile devices, the algorithm facilitates edge computing in space environment conditions. YOLO-ET is deployable as an app on an iPhone with LabCam® optical enhancement, ready for space application ruggedisation. Training on images from the Tanpopo aerogel panels returned from Japan’s Kibo module of the International Space Station, YOLO-ET demonstrates a 90% detection rate for surface contaminant microparticles on the aerogels, and shows promising early results for detection of both microparticle contaminants on the Moon and for evaluating asteroid return samples. YOLO-ET’s application to identifying spacecraft-derived microparticles in lunar regolith simulant samples and SEM images of asteroid Ryugu samples returned by Hayabusa2 and curated by JAXA’s Institute of Space and Astronautical Sciences indicate strong model performance and transfer learning capabilities for future extraterrestrial applications.

The lunar dust environment: concerns for Moon-based astronomy.

The Moon has no atmosphere, hence, it offers a unique opportunity to place telescopes on its surface for astronomical observations. It is phase-locked with Earth, and its far side remains free from ground-based interference, enabling the optimal use of radio telescopes. However, the surface of the Moon, as any other airless planetary object in the solar system, is continually bombarded by interplanetary dust particles that cause impact damage and generate secondary ejecta particles that continually overturn the top layer of the lunar regolith. In addition, there is evidence, that small particles comprising the lunar regolith can be electrically charged, mobilized and transported, also representing a hazard for covering sensitive surfaces and interfering with exposed mechanical structures. In addition to the naturally occurring dust transport, rocket firings during landings and take-offs, pedestrian and motorized vehicle traffic will also liberate copious amounts of dust, representing a potential hazard for the safe and optimal use of optical platforms. This article is part of a discussion meeting issue 'Astronomy from the Moon: the next decades (part 2)'.

Measurement of the zodiacal light absolute intensity through Fraunhofer line spectroscopy of the night sky with the Hale telescope

Abstract Measuring the absolute brightness of the zodiacal light (ZL), which is the sunlight scattered by interplanetary dust particles, is important not only for understanding the physical properties of the dust but also for constraining the extragalactic background light (EBL) by subtracting the ZL foreground. We describe the results of high-resolution spectroscopic observations of the night sky in the wavelength range of 300–900 nm with the double spectrograph on the Hale telescope to determine the absolute brightness of the ZL continuum spectra from the Fraunhofer absorption line intensities. The observed fields are part of the fields observed by the Spitzer Space Telescope for the EBL study. Assuming that the spectral shape of the zodiacal light is identical to the solar spectrum in a narrow region around the Fraunhofer lines, we decomposed the observed sky brightness into multiple emission components by amplitude parameter fitting with spectral templates of the airglow, ZL, diffuse Galactic light, integrated starlight, and other isotropic components including EBL. As a result, the ZL component with the Ca ii λλ 393.3, 396.8 nm Fraunhofer lines around 400 nm is clearly separated from the others in all fields with uncertainties around 20%, mainly due to the template errors and the time variability of the airglow. The observed ZL brightness in most of the observed fields is consistent with the modeled ZL brightness calculated by combining the most conventional ZL model at 1250 nm based on the Diffuse Infrared Background Experiment and the observational ZL template spectrum based on the Hubble Space Telescope. However, the ecliptic plane observation is considerably fainter than the ZL model, and this discrepancy is discussed in terms of the optical properties of the interplanetary dust accreted in the ecliptic plane.

Correlated IR-SEM-TEM studies of three different grains from Ryugu: From the initial material to post-accretional processes

In order to better constrain the alteration history of the Ryugu parent body, we performed a multi-analytical study combining scanning electron microscopy, transmission electron microscopy and infrared spectroscopy on sections extracted from the three fragments A0064-FO019, A0064-FO021 and C0002-FO019 returned from Ryugu by the Hayabusa2 space mission. The three sections show large differences in terms of structure, mineralogy and infrared signature. Section A0064-FO019 resembles the major Ryugu lithology with the presence of both fine-grained phyllosilicates (fg-phyllos) with embedded nanosulfides and coarse-grained phyllosilicates (cg-phyllos), whereas section C0002-FO019 belongs to the group of the less altered lithologies with the presence of anhydrous minerals embedded in a partially amorphous matrix. Section A0064-FO021 also belongs to this group but shows two different lithologies, a compact amorphous one and a more porous and very fractured one showing the presence of Na-rich phosphate, calcite and olivine. The two less altered lithologies (sections A0064-FO021 and C0002-FO019) show the presence of numerous mineralogical features similar to those observed in cometary interplanetary dust particles, ultra-carbonaceous Antarctic micrometeorites or in the CM Paris meteorite, i.e. amorphous and partially crystallized matrix with GEMS-like ghosts objects, whisker olivine, phosphide, or FeNi metal. This supports an outer solar system origin common with that of cometary material for the Ryugu parent body. Combined with the results of Nakamura et al. (2022b) reporting the presence of a lithology showing the presence of GEMS-like objects, we propose that section C0002-FO019 represents the onset of aqueous alteration of such primitive materials. The cg-phyllos and fg-phyllos of section A0064-FO019, i.e. of the major Ryugu lithology, representing the advanced stage of alteration, exhibit distinctive IR signatures with a higher abundance of oxygen-rich functional groups in the organic matter (OM) from the cg-phyllos. We thus suggest the following chronology of formation and evolution for Ryugu: (1) accretion of highly porous aggregate of GEMS-like units with fine-grained high-temperature anhydrous silicates, (2) onset of alteration with the dissolution of primary nanosulfides and development of amorphous/partially crystallized material in the pores, (3) crystallization of fg-phyllos with a second generation of sulfides, (4) later formation of cg-phyllos devoid of nanosulfides and their associated oxygen-rich OM in a more water-rich environment.

Iron depletion in mineral dust grains from Saturn’s main rings

ABSTRACT During the Grand Finale orbits, Cassini’s Cosmic Dust Analyzer (CDA) recorded in situ mass spectra of ice and mineral nanodust grains ejected from Saturn’s main rings falling into the planet’s atmosphere. We present a compositional analysis of the mineral dust fraction employing a spectral deconvolution method to determine the elemental composition of these grains. The results indicate a relatively homogenous composition of exclusively Mg-rich silicates, with Mg, Si, and Ca close to CI chondritic abundances but a significant depletion in Fe and only traces of organic material at best. The Fe depletion becomes even more pronounced when compared to Fe-rich interplanetary dust particles encountered by CDA in the Saturnian system, which are assumed to contaminate and darken the main rings over time. We discuss potential explanations for the depletion, from which we favour compositional alteration of the infalling dust grains by impact-triggered chemistry in combination with dynamical selection effects and instrumental bias as the most plausible ones. This might cause an accumulation of Fe in the main rings over time, most likely in the form of oxides.

Delivery of Organic Matter to the Early Earth

The inner Solar System—including the planet Earth—was heavily bombarded by comets, asteroids, and their fragments (i.e., meteorites, micrometeorites, and interplanetary dust particles) from 4.56 to about 3.5 billion years ago. This bombardment resulted in a rich assortment of organics delivered to the Earth, as comets and many asteroids contain carbonaceous material. These organic compounds were likely further processed on the early Earth (e.g., by impact-shock reactions), providing a feedstock of prebiotic molecules to the crust and oceans. In this chapter, we review the mechanisms of organic matter delivery to the primitive Earth, further reactions and processing, and the importance of exogenous material in the evolution of our planet and life.

New Horizons Venetia Burney Student Dust Counter Observes Higher than Expected Fluxes Approaching 60 au

The NASA New Horizons Venetia Burney Student Dust Counter (SDC) measures dust particle impacts along the spacecraft’s flight path for grains with mass ≥10−12 g, mapping out their spatial density distribution. We present the latest SDC dust density, size distribution, and flux measurements through 55 au and compare them to numerical model predictions. Kuiper Belt objects (KBOs) are thought to be the dominant source of interplanetary dust particles in the outer solar system due to both collisions between KBOs and their continual bombardment by interstellar dust particles. Continued measurements through 55 au show higher than model-predicted dust fluxes as New Horizons approaches the putative outer edge of the Kuiper Belt (KB). We discuss potential explanations for the growing deviation: radiation pressure stretches the dust distribution to further heliocentric distances than its parent body distribution; icy dust grains undergo photosputtering that rapidly increases their response to radiation pressure forces and pushes them further away from the Sun; and the distribution of KBOs may extend much further than existing observations suggest. Ongoing SDC measurements at even larger heliocentric distances will continue to constrain the contributions of dust production in the KB. Continued SDC measurements remain crucial for understanding the Kuiper Belt and the interpretation of dust disks around other stars.

Microstructural and chemical features of impact melts on Ryugu particle surfaces: Records of interplanetary dust hit on asteroid Ryugu.

The Hayabusa2 spacecraft delivered samples of the carbonaceous asteroid Ryugu to Earth. Some of the sample particles show evidence of micrometeoroid impacts, which occurred on the asteroid surface. Among those, particles A0067 and A0094 have flat surfaces on which a large number of microcraters and impact melt splashes are observed. Two impact melt splashes and one microcrater were analyzed to unveil the nature of the objects that impacted the asteroid surface. The melt splashes consist mainly of Mg-Fe-rich glassy silicates and Fe-Ni sulfides. The microcrater trapped an impact melt consisting mainly of Mg-Fe-rich glassy silicate, Fe-Ni sulfides, and minor silica-rich glass. These impact melts show a single compositional trend indicating mixing of Ryugu surface materials and impactors having chondritic chemical compositions. The relict impactor in one of the melt splashes shows mineralogical similarity with anhydrous chondritic interplanetary dust particles having a probable cometary origin. The chondritic micrometeoroids probably impacted the Ryugu surface during its residence in a near-Earth orbit.

Using Zodiacal Light For Spaceborne Calibration Of Polarimetric Imagers.

We propose that spaceborne polarimetric imagers can be calibrated, or self-calibrated using zodiacal light (ZL). ZL is created by a cloud of interplanetary dust particles. It has a significant degree of polarization in a wide field of view. From space, ZL is unaffected by terrestrial disturbances. ZL is insensitive to the camera location, so it is suited for simultaneous cross-calibration of satellite constellations. ZL changes on a scale of months, thus being a quasi-constant target in realistic calibration sessions. We derive a forward model for polarimetric image formation. Based on it, we formulate an inverse problem for polarimetric calibration and self-calibration, as well as an algorithm for the solution. The methods here are demonstrated in simulations. Towards these simulations, we render polarized images of the sky, including ZL from space, polarimetric disturbances, and imaging noise.

Role of Low-Energy (

We demonstrate for the first time that Galactic cosmic rays with energies as high as ∼1010 eV can trigger a cascade of low-energy (<20 eV) secondary electrons that could be a significant contributor to the interstellar synthesis of prebiotic molecules whose delivery by comets, meteorites, and interplanetary dust particles may have kick-started life on Earth. For the energetic processing of interstellar ice mantles inside dark, dense molecular clouds, we explore the relative importance of low-energy (<20 eV) secondary electrons-agents of radiation chemistry-and low-energy (<10 eV), nonionizing photons-instigators of photochemistry. Our calculations indicate fluxes of ∼102 electrons cm-2 s-1 for low-energy secondary electrons produced within interstellar ices due to attenuated Galactic cosmic-ray protons. Consequently, in certain star-forming regions where internal high-energy radiation sources produce ionization rates that are observed to be a thousand times greater than the typical interstellar Galactic ionization rate, the flux of low-energy secondary electrons should far exceed that of nonionizing photons. Because reaction cross sections can be several orders of magnitude larger for electrons than for photons, even in the absence of such enhancement, our calculations indicate that secondary low-energy (<20 eV) electrons are at least as significant as low-energy (<10 eV) nonionizing photons in the interstellar synthesis of prebiotic molecules. Most importantly, our results demonstrate the pressing need for explicitly incorporating low-energy electrons in current and future astrochemical simulations of cosmic ices. Such models are critically important for interpreting James Webb Space Telescope infrared measurements, which are currently being used to probe the origins of life by studying complex organic molecules found in ices near star-forming regions.

The polarisation properties of the HD 18327 debris ring. Evidence for sub-micron particles from scattered light observations

Polarisation is a powerful remote-sensing tool to study the nature of particles scattering the starlight. It is widely used to characterise interplanetary dust particles in the Solar System and increasingly employed to investigate extrasolar dust in debris discs' systems. We aim to measure the scattering properties of the dust from the debris ring around at near-infrared wavelengths. We obtained high-contrast polarimetric images of in the H band with the SPHERE / IRDIS instrument on the Very Large Telescope (ESO). We complemented them with archival data from HST / NICMOS in the F110W filter reprocessed in the context of the Archival Legacy Investigations of Circumstellar Environments (ALICE) project. We developed a combined forward-modelling framework to simultaneously retrieve the scattering phase function in polarisation and intensity. We detected the debris disc around in polarised light and total intensity. We measured the scattering phase function and the degree of linear polarisation of the dust at 1.6 in the birth ring. The maximum polarisation is $23.6&lt;!PCT!&gt; 2.6&lt;!PCT!&gt;$ and occurs between a scattering angle of $70^ and $82^ We show that compact spherical particles made of a highly refractive and relatively absorbing material in a differential power-law size distribution of exponent $-3.5$ can simultaneously reproduce the polarimetric and total intensity scattering properties of the dust. This type of material cannot be obtained with a mixture of silicates, amorphous carbon, water ice, and porosity, and requires a more refracting component such as iron-bearing minerals. We reveal a striking analogy between the near-infrared polarisation of comets and that of The methodology developed here combining VLT/SPHERE and HST/NICMOS may be applicable in the future to combine the polarimetric capabilities of SPHERE with the sensitivity of JWST.

Oxygen-bearing organic molecules in comet 67P’s dusty coma: First evidence for abundant heterocycles

The puzzling complexity of terrestrial biomolecules is driving the search for complex organic molecules in the interstellar medium (ISM) and serves as a motivation for many in situ studies of reservoirs of extraterrestrial organics, from meteorites and interplanetary dust particles to comets and asteroids. Comet 67P/Churyumov-Gerasimenko (67P), the best-studied comet to date, has been visited and accompanied for 2 yr by the European Space Agency’s Rosetta spacecraft. Around 67P’s perihelion and under dusty conditions, the high-resolution mass spectrometer on board Rosetta has provided a spectacular glimpse into this comet’s chemical complexity. For this work, we analyzed the O-bearing organic volatiles in unprecedented detail. Through a comparison of 67P’s inventory with molecules detected in the ISM, in other comets, and in soluble organic matter extracted from the Murchison meteorite, we also highlight the (pre)biotic relevance of different chemical groups of species. We report first evidence for abundant extraterrestrial O-bearing heterocycles (with abundances relative to methanol often on the order of 10% and a relative error margin of 30–50%) and various representatives of other molecule classes, such as carboxylic acids and esters, aldehydes, ketones, and alcohols. As with the pure hydrocarbons, some hydrogenated forms seem to be dominant over their dehydrogenated counterparts. An interesting example is tetrahydrofuran, as it might be a more promising candidate for searches in the ISM than the long-sought furan. Our findings not only support and guide future efforts to investigate the origins of chemical complexity in space, but they also strongly encourage the study, in the laboratory as well as by modeling, of such topics as the ratios of unbranched versus branched species and hydrogenated versus dehydrogenated species in astrophysical ice analogs.