Internal Conversion Efficiency Research Articles

Tracing the electron transport behavior in quantum-dot light-emitting diodes via single photon counting technique

The electron injection and transport behavior are of vital importance to the performance of quantum-dot light-emitting diodes. By simultaneously measuring the electroluminescence-photoluminescence of the quantum-dot light-emitting diodes, we identify the presence of leakage electrons which leads to the discrepancy of the electroluminescence and the photoluminescence roll-off. To trace the transport paths of the leakage electrons, a single photon counting technique is developed. This technique enables us to detect the weak photon signals and thus provides a means to visualize the electron transport paths at different voltages. The results show that, the electrons, except those recombining within the quantum-dots, leak to the hole transport layer or recombine at the hole transport layer/quantum-dot interface, thus leading to the reduction of efficiency. By reducing the amount of leakage electrons, quantum-dot light-emitting diode with an internal power conversion efficiency of over 98% can be achieved.

Integrated frequency-modulated optical parametric oscillator.

Optical frequency combs have revolutionized precision measurement, time-keeping and molecular spectroscopy1-7. A substantial effort has developed around 'microcombs': integrating comb-generating technologies into compact photonic platforms5,7-9. Current approaches for generating these microcombs involve either the electro-optic10 or Kerr mechanisms11. Despite rapid progress, maintaining high efficiency and wide bandwidth remains challenging. Here we introduce a previously unknown class of microcomb-an integrated device that combines electro-optics and parametric amplification to yield a frequency-modulated optical parametric oscillator (FM-OPO). In contrast to the other solutions, it does not form pulses but maintains operational simplicity and highly efficient pump power use with an output resembling a frequency-modulated laser12. We outline the working principles of our device and demonstrate it by fabricating the complete optical system in thin-film lithium niobate. We measure pump-to-comb internal conversion efficiency exceeding 93% (34% out-coupled) over a nearly flat-top spectral distribution spanning about 200 modes (over 1 THz). Compared with an electro-optic comb, the cavity dispersion rather than loss determines the FM-OPO bandwidth, enabling broadband combs with a smaller radio-frequency modulation power. The FM-OPO microcomb offers robust operational dynamics, high efficiency and broad bandwidth, promising compact precision tools for metrology, spectroscopy, telecommunications, sensing and computing.

Optomechanical ring resonator for efficient microwave-optical frequency conversion

Phonons traveling in solid-state devices are emerging as a universal excitation for coupling different physical systems. Phonons at microwave frequencies have a similar wavelength to optical photons in solids, enabling optomechanical microwave-optical transduction of classical and quantum signals. It becomes conceivable to build optomechanical integrated circuits (OMIC) that guide both photons and phonons and interconnect photonic and phononic devices. Here, we demonstrate an OMIC including an optomechanical ring resonator (OMR), where co-resonant infrared photons and GHz phonons induce significantly enhanced interconversion. The platform is hybrid, using wide bandgap semiconductor gallium phosphide (GaP) for waveguiding and piezoelectric zinc oxide (ZnO) for phonon generation. The OMR features photonic and phononic quality factors of >1 × 105 and 3.2 × 103, respectively. The optomechanical interconversion between photonic modes achieved an internal conversion efficiency {eta }_{i}=(2.1pm 0.1)% and a total device efficiency {eta }_{{tot}}=0.57{times 10}^{-6} at a low acoustic pump power of 1.6 mW. The efficient conversion in OMICs enables microwave-optical transduction for quantum information and microwave photonics applications.

Highly efficient on-chip erbium–ytterbium co-doped lithium niobate waveguide amplifiers

The ability to amplify optical signals is of paramount importance in photonic integrated circuits (PICs). Recently, lithium niobate on insulator (LNOI) has attracted increasing interest as an emerging PIC platform. However, the shortage of efficient active devices on the LNOI platform limits the development of optical amplification. Here, we report an efficient waveguide amplifier based on erbium and ytterbium co-doped LNOI by using electron beam lithography and an inductively coupled plasma reactive ion etching process. We have demonstrated that signal amplification emerges at a low pump power of 0.1 mW, and the net internal gain in the communication band is 16.52 dB/cm under pumping of a 974 nm continuous laser. Benefiting from the efficient pumping facilitated by energy transfer between ytterbium and erbium ions, an internal conversion efficiency of 10% has been achieved, which is currently the most efficient waveguide amplifier under unidirectional pumping reported on the LNOI platform, to our knowledge. This work proposes an efficient active device for LNOI integrated optical systems that may become an important fundamental component of future lithium niobate photonic integration platforms.

Quantum frequency conversion and single-photon detection with lithium niobate nanophotonic chips

The lithium niobate on insulator (LNOI) platform has revolutionized lithium niobate materials, and a series of quantum photonic chips have exhibited unprecedented performances. Quantum frequency conversion (QFC) that enables quantum state preservation during frequency conversion is crucial in quantum technology. This work demonstrates a low-noise QFC process on the LNOI nanophotonic platform, connecting telecom and near-visible bands. An internal conversion efficiency of 73% and an on-chip noise count of 900 counts per second (cps) are achieved. Furthermore, the preservation of quantum statistical properties is verified, indicating the QFC chip’s promise for extensive applications of LNOI integrated circuits in quantum information. Based on this chip, we constructed an upconversion single-photon detector with a detection efficiency of 8.7% and a noise of 300 cps, paving the way to integrated on-chip single-photon detection. The realization of a low-noise QFC device also provide a pathway for practical chip-scale QFC-based quantum systems in heterogeneous configurations.

Quantum-enabled millimetre wave to optical transduction using neutral atoms.

Early experiments with transiting circular Rydberg atoms in a superconducting resonator laid the foundations of modern cavity and circuit quantum electrodynamics1, and helped explore the defining features of quantum mechanics such as entanglement. Whereas ultracold atoms and superconducting circuits have since taken rather independent paths in the exploration of new physics, taking advantage of their complementary strengths in an integrated system enables access to fundamentally new parameter regimes and device capabilities2,3. Here we report on such a system, coupling an ensemble of cold 85Rb atoms simultaneously to an, as far as we are aware, first-of-its-kind optically accessible, three-dimensional superconducting resonator4 and a vibration-suppressed optical cavity in a cryogenic (5 K) environment. To demonstrate the capabilities of this platform, and with an eye towards quantum networking5, we leverage the strong coupling between Rydberg atoms and the superconducting resonator to implement a quantum-enabled millimetre wave (mmwave) photon to optical photon transducer6. We measured an internal conversion efficiency of 58(11)%, a conversion bandwidth of 360(20) kHz and added thermal noise of 0.6 photons, in agreement with a parameter-free theory. Extensions of this technique will allow near-unity efficiency transduction in both the mmwave and microwave regimes. More broadly, our results open a new field of hybrid mmwave/optical quantum science, with prospects for operation deep in the strong coupling regime for efficient generation of metrologically or computationally useful entangled states7 and quantum simulation/computation with strong non-local interactions8.

Optical mode conversion via spatiotemporally modulated atomic susceptibility.

Light is an excellent medium for both classical and quantum information transmission due to its speed, manipulability, and abundant degrees of freedom into which to encode information. Recently, space-division multiplexing has gained attention as a means to substantially increase the rate of information transfer by utilizing sets of infinite-dimensional propagation eigenmodes such as the Laguerre-Gaussian "donut" modes. Encoding in these high-dimensional spaces necessitates devices capable of manipulating photonic degrees of freedom with high efficiency. In this work, we demonstrate controlling the optical susceptibility of an atomic sample can be used as powerful tool for manipulating the degrees of freedom of light that pass through the sample. Utilizing this tool, we demonstrate photonic mode conversion between two Laguerre-Gaussian modes of a twisted optical cavity with high efficiency. We spatiotemporally modulate the optical susceptibility of an atomic sample that sits at the cavity waist using an auxiliary Stark-shifting beam, in effect creating a mode-coupling optic that converts modes of orbital angular momentum l = 3 → l = 0. The internal conversion efficiency saturates near unity as a function of the atom number and modulation beam intensity, finding application in topological few-body state preparation, quantum communication, and potential development as a flexible tabletop device.

Off-Angle Amplified Spontaneous Emission of Upconversion Nanoparticles by Propagating Lattice Plasmons.

Lanthanide-doped upconversion nanoparticles (UCNPs) are appealing for light emitting applications because their high internal conversion efficiency facilitates the amplified spontaneous emission (ASE) under low pumping. In addition, the integration of photonic crystals and microcavities with optical quantum emitters provides a unique opportunity to manipulate their light emissions and generate coherent light sources for quantum photonics. Here, this work describes a two-dimensional (2D) plasmonic lattice of Al nanocone array (Al NCA), which can confine the light at the tip. Light confinement by the enhancement effect supports narrow linewidth resonances as optical feedback for the ASE of UCNPs doped with sensitizer Yb3+ ions/emitter Ho3+ ions/relaxator Ce3+ ions. An off-angle ASE with an enhancement of 19-fold from UCNPs is achieved by propagating lattice plasmons from the Al NCA. Moreover, this upconverting ASE can be switched on or off by adjusting the polarization state of the incident pump light, and photonic band engineering can be used to manipulate it intentionally. This composite plasmonic system opens prospective applications for the ASE as directional emission, real-time tunable wavelengths, controlled multimode lasing, and optical switches.

Highly-doped lanthanide nanomaterials for efficient photothermal conversion – selection of the most promising ions and matrices

Materials doped with rare earth ions are widely used in luminescence applications. However, alternative uses of these materials, such as photothermal conversion, have not yet been systematically investigated. In this work, we systematically and quantitatively compare internal and external photothermal conversion efficiency of materials doped with neodymium, thulium and ytterbium ions, and co-doped with samarium and dysprosium ions. Furthermore, we investigate influence of various matrix materials on photothermal conversion efficiency. These include fluoride, oxide, vanadate and perovskite materials. This was done to determine if photothermal conversion efficiency is dependent on dopant and matrix selection. Our research indicates that the highest internal and external photothermal conversion efficiency is achieved with neodymium ions. Moreover, NdVO4 was found to be the most promising host for future applications. Although the internal photothermal conversion efficiency was relatively low (19%), NdVO4 exhibited significant external photothermal conversion efficiency of 0.08 L/g·cm at 806 nm, which is ca. 14 times higher than that of NaNdF4 at the same wavelength.

Influence of Permeability Dispersion on Radiation of BAW Antenna: Modeling of Multiphysics Dynamic Coupling

Coupling of multiphysics including electrodynamics, elastodynamics, magnetodynamics, and electromagnetic (EM) radiation is involved in the operating process of bulk acoustic wave (BAW) antenna. There is still no good way to design the structure and evaluate the performance of the antenna in theory. Therefore, the multiphysics dynamic coupling model of the antenna is constructed by uniting Newton’s equation for acoustic wave, Maxwell’s equation for EM wave, and Landau–Lifshitz–Gilbert (LLG) equation for spin wave with constitutive relations of multiferroic materials to discuss the dispersion law of permeability and magnetomechanical coupling factor for the magnetostrictive layer. The importance of consistency between ferromagnetic resonance (FMR) frequency and BAW resonant frequency is demonstrated. The analysis shows that both increasing the anisotropic field or the saturation magnetization and decreasing the FMR linewidth are beneficial to improving the internal energy conversion efficiency and the average radiated power for BAW antenna. In addition, a micromagnetic module is introduced into finite element analysis (FEA) software to simulate the precession of unit magnetic moment at different frequencies. Thus, the analytical model is verified from the perspective of power absorption.

High-efficiency near-infrared optical parametric amplifier for intense, narrowband THz pulses tunable in the 4 to 19 THz region

Dynamic control of material properties using strong-field, narrowband THz sources has drawn attention because it allows selective manipulation of quantum states on demand by coherent excitation of specific low-energy modes in solids. Yet, the lack of powerful narrowband lasers with frequencies in the range of a few to a few tens of THz has restricted the exploration of hidden states in condensed matter. Here, we report the optimization of an optical parametric amplifier (OPA) and the efficient generation of a strong, narrowband THz field. The OPA has a total conversion efficiency of > 55%, which is the highest value reported to date, with an excellent energy-stability of 0.7% RMS over 3 h. We found that the injection of a high-energy signal beam to a power amplification stage in an OPA leads to high-efficiency and a super-Gaussian profile. By difference-frequency generation of two chirped OPA signal pulses in an organic nonlinear crystal, we obtained a THz pulse with an energy of 3.2 μJ, a bandwidth of 0.5 THz, and a pulse duration of 860 fs tunable between the 4 and 19 THz regions. This corresponds to an internal THz conversion efficiency of 0.4% and a THz field strength of 6.7 MV/cm. This approach demonstrates an effective way to generate narrow-bandwidth, intense THz fields.

Composite Indium Tin Oxide Nanofibers with Embedded Hematite Nanoparticles for Photoelectrochemical Water Splitting.

Hematite is a classical photoanode material for photoelectrochemical water splitting due to its stability, performance, and low cost. However, the effect of particle size is still a question due to the charge transfer to the electrodes. In this work, we addressed this subject by the fabrication of a photoelectrode with hematite nanoparticles embedded in close contact with the electrode substrate. The nanoparticles were synthesized by a solvothermal method and colloidal stabilization with charged hydroxide molecules, and we were able to further use them to prepare electrodes for water photo-oxidation. Hematite nanoparticles were embedded within electrospun tin-doped indium oxide nanofibers. The fibrous layer acted as a current collector scaffold for the nanoparticles, supporting the effective transport of charge carriers. This method allows better contact of the nanoparticles with the substrate, and also, the fibrous scaffold increases the optical density of the photoelectrode. Electrodes based on nanofibers with embedded nanoparticles display significantly enhanced photoelectrochemical performance compared to their flat nanoparticle-based layer counterparts. This nanofiber architecture increases the photocurrent density and photon-to-current internal conversion efficiency by factors of 2 and 10, respectively.

Second‐Harmonic Generation in Heteroepitaxially Grown, Orientation‐Patterned, Ternary GaAsP Periodic Structures

Orientation‐patterned GaAs0.85P0.15 is grown by hydride vapor phase heteroepitaxy on an orientation‐patterned GaAs template and second‐harmonic generation is demonstrated for this ternary periodic structure using ultrashort pulses with an internal conversion efficiency exceeding 19%.

Efficient Low Threshold Frequency Conversion in AlGaAs-On-Insulator Waveguides

A design study is presented for an efficient, compact and robust device to convert the frequency of single-photons from the near-infrared to the telecom C-band. The material platform aluminum gallium arsenide (AlGaAs)-on-insulator, with its relatively large second-order nonlinearity, is used to create highly confined optical modes. This platform can feasibly incorporate single-photon emitters such as indium arsenide (InAs) on gallium arsenide (GaAs), paving the way towards direct integration of single-photon sources and nonlinear waveguides on the same chip. In this design study, single-pass difference-frequency generation (DFG) producing C-band single-photons is enabled via form birefringent phase-matching between a 930 nm single-photon pump and continuous wave (CW) idler at 2,325 nm. In particular the idler and single-photons are combined with an on-chip directional coupler, and then tapered to a single waveguide where the three modes are phase-matched. The design is studied at a special case, showing high fabrication tolerances, and an internal conversion efficiency up to 41%.

Quantum-enabled operation of a microwave-optical interface

Solid-state microwave systems offer strong interactions for fast quantum logic and sensing but photons at telecom wavelength are the ideal choice for high-density low-loss quantum interconnects. A general-purpose interface that can make use of single photon effects requires < 1 input noise quanta, which has remained elusive due to either low efficiency or pump induced heating. Here we demonstrate coherent electro-optic modulation on nanosecond-timescales with only 0.1{6}_{-0.01}^{+0.02} microwave input noise photons with a total bidirectional transduction efficiency of 8.7% (or up to 15% with 0.4{1}_{-0.02}^{+0.02}), as required for near-term heralded quantum network protocols. The use of short and high-power optical pump pulses also enables near-unity cooperativity of the electro-optic interaction leading to an internal pure conversion efficiency of up to 99.5%. Together with the low mode occupancy this provides evidence for electro-optic laser cooling and vacuum amplification as predicted a decade ago.

Generation of multiple triplet states in an orthogonal bodipy dimer: a breakthrough spectroscopic and theoretical approach.

Generation of triplet states in assemblies of organic chromophores is extremely appealing for their potential use in optoelectronic applications. In this work, we investigate the intricacies of triplet state generation in an orthogonal BODIPY dimer by combining delayed photoemission techniques with electronic structure calculations. Our analysis provides a deep understanding of the electronic states involved, and describes different competing deactivation channels beyond prompt radiative decay. In particular, we identify charge-transfer (CT) mediated intersystem crossing (ISC) as the most likely mechanism for the triplet state generation in this system. The different emission bands at long times can be associated with delayed fluorescence, CT emission and phosphorescence from multiple low-energy triplets. Interestingly, the dependence of the yield of triplet state population and emission profiles with the solvent polarity evidences the decisive role of the CT configuration in the fate of the photoactivated dimer, controlling the relative ISC, reverse ISC, and internal conversion efficiencies. Overall, the present results provide a rather complete description of the delayed photophysics in the BODIPY dimer, but are not able to fully rationalize the unexpected photoluminescence recorded at long wavelengths (≥ 900 nm). We hypothesize that the origin of this emission, not present in BODIPY monomers, emerges from intermonomer interactions triggered by intramolecular distortions opening up a new vision in the controverted mechanism driving the photophysical behavior from orthogonally linked organic monomers.

Continuous-Wave Frequency Upconversion with a Molecular Optomechanical Nanocavity

Frequency upconversion is a cornerstone of electromagnetic signal processing, analysis and detection. It is used to transfer energy and information from one frequency domain to another where transmission, modulation or detection is technically easier or more efficient. Optomechanical transduction is emerging as a flexible approach to coherent frequency upconversion; it has been successfully demonstrated for conversion from radio- and microwaves (kHz to GHz) to optical fields. Nevertheless, optomechanical transduction of multi-THz and mid-infrared signals remains an open challenge. Here, we utilize molecular cavity optomechanics to demonstrate upconversion of sub-microwatt continuous-wave signals at $\sim$32~THz into the visible domain at ambient conditions. The device consists in a plasmonic nanocavity hosting a small number of molecules. The incoming field resonantly drives a collective molecular vibration, which imprints an optomechanical modulation on a visible pump laser and results in Stokes and anti-Stokes upconverted Raman sidebands with sub-natural linewidth, indicating a coherent process. The nanocavity offers 13 orders of magnitude enhancement of upconversion efficiency per molecule compared to free space, with a measured phonon-to-photon internal conversion efficiency larger than $10^{-4}$ per milliwatt of pump power. Our results establish a flexible paradigm for optomechanical frequency conversion using molecular oscillators coupled to plasmonic nanocavities, whose vibrational and electromagnetic properties can be tailored at will using chemical engineering and nanofabrication.

Application of Triplet-Triplet Annihilation Upconversion in Organic Optoelectronic Devices: Advances and Perspectives.

Organic semiconductor materials have been widely used in various optoelectronic devices due to their rich optical and/or electrical properties, which are highly related to their excited states. Therefore, how to manage and utilize the excited states in organic semiconductors is essential for the realization of high-performance optoelectronic devices. Triplet-triplet annihilation (TTA) upconversion is a unique process of converting two non-emissive triplet excitons to one singlet exciton with higher energy. Efficient optical-to-electrical devices can be realized by harvesting sub-bandgap photons through TTA-based upconversion. In electrical-to-optical devices, triplets generated after the combination of electrons and holes also can be efficiently utilized via TTA, which resulted in a high internal conversion efficiency of 62.5%. Currently, many interesting explorations and significant advances have been demonstrated in these fields. In this review, a comprehensive summary of these intriguing advances on developing efficient TTA upconversion materials and their application in optoelectronic devices is systematically given along with some discussions. Finally, the key challenges and perspectives of TTA upconversion systems for further improvement for optoelectronic devices and other related research directions are provided. This review hopes to provide valuable guidelines for future related research and advancement in organic optoelectronics.

Laser to laser power conversion with remote signaling.

We demonstrate laser power conversion using an edge-coupled waveguide configuration. A laser with an emission energy of 0.87 eV (1427 nm) optically pumps a second with an emission energy of 0.80 eV (1540 nm), achieving the maximum possible open circuit voltage of 0.83 V due to optically pumped lasing. A fiber to device power conversion efficiency of 33% is achieved with internal power conversion efficiency ranging from 57% to 51%. The voltage at maximum power is 0.6 V, which is a record for the wavelength range. The same optically pumped device is used for effectively power-free 500 Mbps upstream data transmission, enabling compact powering and signaling for emerging applications in minimally invasive medical interventions and remote photonics.

Efficient Brillouin Optomechanical Interaction Assisted by Piezomechanics on the SOI Platform

A hybrid silicon/aluminum nitride waveguide on the silicon-on-insulator platform is proposed to achieve an efficient Brillouin optomechanical interaction. Both intra-optical-mode and inter-optical-mode Brillouin scattering can be achieved. The novel arrangement of symmetric electrodes provides out-of-plane electric fields for piezoelectric materials and the possibility of suspended waveguides and cavities. The piezomechanical interaction coupling strength and the Brillouin optomechanical interaction coupling strength are numerically calculated. The simulation results show that near-unity internal conversion efficiency from the microwave domain to the optical domain can be achieved. Relatively low microwave power can be used to produced up to 5 order sidebands acousto-optical modulation. The proposed scheme paves the way for efficient classical and quantum application in integrated silicon photonics.